Ethoxymethylenemalononitrile supplier

Name
Ethoxymethylenemalononitrile
EINECS 204-597-0
CAS No. 123-06-8
Article Data46
CAS DataBase
Density 1.07 g/cm³
Solubility insoluble in water
Melting Point 64-66 °C(lit.)
Formula C₆H₆N₂O
Boiling Point 296.1 °C at 760 mmHg
Molecular Weight 122.126
Flash Point 135.1 °C
Transport Information
Appearance off white to pale yellow
Safety 22-36/37-45-36/37/39-26-36-24/25
Risk Codes 22-42/43-23/24/25-43-20/21/22
Molecular Structure
Hazard Symbols Xn,Xi,T
Synonyms Malononitrile,(ethoxymethylene)- (6CI,7CI,8CI);Propanedinitrile, (ethoxymethylene)- (9CI);(Ethoxymethylene)malonodinitrile;(Ethoxymethylidene)malononitrile;(b-Ethoxymethylene)malononitrile;1,1-Dicyano-2-ethoxyethene;1-Ethoxy-2,2-dicyanoethene;1-Ethoxymethylenemalonitrile;2-Cyano-3-ethoxyacrylonitrile;2-Ethoxy-1,1-ethenedicarbonitrile;NSC 27792;a-Cyano-b-ethoxyacrylonitrile;Propanedinitrile,2-(ethoxymethylene)-;
PSA 56.81000
LogP 0.95396

Synthetic route

: 122-51-0
orthoformic acid triethyl ester

: 109-77-3
malononitrile

: 123-06-8
Ethoxymethylenemalononitrile

Conditions

Conditions	Yield
With acetic anhydride at 110 - 140℃; Reflux;	98%
With acetic anhydride at 110 - 140℃;	98%
With acetic anhydride at 110 - 140℃;	98%

: 109-77-3
malononitrile

: 123-06-8
Ethoxymethylenemalononitrile

Conditions

Conditions	Yield
With orthoformic acid triethyl ester at 140℃;
With orthoformic acid triethyl ester at 140℃;

: 79343-66-1, 79343-67-2
spiro<(2,2-dicyano-3-ethoxy)cyclobutan-1,3'-(1'-acetyl)-2'-oxoindoline>, trans

: 109-92-2
ethyl vinyl ether

A: 79343-70-7
2-ethoxy-9-acetyl-2,3-dihydropyran<2,3-b>indole

B: 123-06-8
Ethoxymethylenemalononitrile

Conditions

Conditions	Yield
at 100℃; for 40h; sealed tube;	A 63% B 50%

...Expand

: 14059-86-0
1-(2',3',4',5'-Tetra-O-acetyl-β-D-galactopyranosyl)urea

: 122-51-0
orthoformic acid triethyl ester

: 109-77-3
malononitrile

A: 91303-01-4
1-(2',3',4',5'-Tetra-O-acetyl-β-D-galactopyranosyl)ureidomethylenemalononitrile

B: 123-06-8
Ethoxymethylenemalononitrile

Conditions

Conditions	Yield
at 70℃; for 12h;	A 52% B n/a

...Expand

: 14241-65-7
1-(2',3',4',5'-Tetra-O-acetyl-β-D-mannopyranosyl)urea

: 122-51-0
orthoformic acid triethyl ester

: 109-77-3
malononitrile

A: 91303-00-3
1-(2',3',4',5'-Tetra-O-acetyl-β-D-mannopyranosyl)ureidomethylenemalononitrile

B: 123-06-8
Ethoxymethylenemalononitrile

Conditions

Conditions	Yield
at 60℃; for 2h;	A 28% B n/a

...Expand

: 79343-66-1, 79343-67-2
(1SR,3SR)-spiro<(2,2-dicyano-3-ethoxy)cyclobutan-1,3'-(1'-acetyl)-2'-oxoindoline>

: 109-92-2
ethyl vinyl ether

A: 79343-70-7
2-ethoxy-9-acetyl-2,3-dihydropyran<2,3-b>indole

B: 123-06-8
Ethoxymethylenemalononitrile

Conditions

Conditions	Yield
at 100℃; for 40h; sealed tube;
sealed tube;

...Expand

: 75-03-6
ethyl iodide

silver-compound of hydroxymethylene-malonic acid dinitrile: silver-compound of hydroxymethylene-malonic acid dinitrile

: 123-06-8
Ethoxymethylenemalononitrile

Conditions

Conditions	Yield
With benzene

: 14241-65-7
1-(2',3',4',5'-Tetra-O-acetyl-β-D-mannopyranosyl)urea

: 122-51-0
orthoformic acid triethyl ester

: 109-77-3
malononitrile

A: 2-Oxo-4-imino-5-cyano-1-(2',3',4',5'-tetra-O-acetyl-β-D-mannopyranosyl)-1,2,3,4-tetrahydropyrimidine

B: 123-06-8
Ethoxymethylenemalononitrile

Conditions

Conditions	Yield
With triethylamine 1) 60 deg C, 2 h; 2) ethanol, reflux, 15 min.;; Yield given. Multistep reaction;

...Expand

: 122-51-0
orthoformic acid triethyl ester

: 109-77-3
malononitrile

: 123-06-8
Ethoxymethylenemalononitrile

Conditions

Conditions	Yield
With acetic anhydride at 110 - 140℃; Reflux;	98%
With acetic anhydride at 110 - 140℃;	98%
With acetic anhydride at 110 - 140℃;	98%

: 79343-66-1, 79343-67-2
spiro<(2,2-dicyano-3-ethoxy)cyclobutan-1,3'-(1'-acetyl)-2'-oxoindoline>, trans

: 109-92-2
ethyl vinyl ether

A: 79343-70-7
2-ethoxy-9-acetyl-2,3-dihydropyran<2,3-b>indole

B: 123-06-8
Ethoxymethylenemalononitrile

Conditions

Conditions	Yield
at 100℃; for 40h; sealed tube;	A 63% B 50%

...Expand

: 14059-86-0
1-(2',3',4',5'-Tetra-O-acetyl-β-D-galactopyranosyl)urea

: 122-51-0
orthoformic acid triethyl ester

: 109-77-3
malononitrile

A: 91303-01-4
1-(2',3',4',5'-Tetra-O-acetyl-β-D-galactopyranosyl)ureidomethylenemalononitrile

B: 123-06-8
Ethoxymethylenemalononitrile

Conditions

Conditions	Yield
at 70℃; for 12h;	A 52% B n/a

...Expand

: 14059-86-0, 14086-03-4, 14241-65-7, 94345-94-5, 60081-89-2
1-(2',3',4',5'-Tetra-O-acetyl-β-D-glucopyranosyl)urea

: 122-51-0
orthoformic acid triethyl ester

: 109-77-3
malononitrile

A: 91302-99-7
1-(2',3',4',5'-Tetra-O-acetyl-β-D-glucopyranosyl)ureidomethylenemalononitrile

B: 123-06-8
Ethoxymethylenemalononitrile

Conditions

Conditions	Yield
for 10h;	A 39% B n/a

...Expand

: 14241-65-7
1-(2',3',4',5'-Tetra-O-acetyl-β-D-mannopyranosyl)urea

: 122-51-0
orthoformic acid triethyl ester

: 109-77-3
malononitrile

A: 91303-00-3
1-(2',3',4',5'-Tetra-O-acetyl-β-D-mannopyranosyl)ureidomethylenemalononitrile

B: 123-06-8
Ethoxymethylenemalononitrile

Conditions

Conditions	Yield
at 60℃; for 2h;	A 28% B n/a

...Expand

: 108-24-7
acetic anhydride

: 122-51-0
orthoformic acid triethyl ester

: 109-77-3
malononitrile

: 123-06-8
Ethoxymethylenemalononitrile

...Expand

: 109-77-3
malononitrile

: 123-06-8
Ethoxymethylenemalononitrile

Conditions

Conditions	Yield
With orthoformic acid triethyl ester at 140℃;
With orthoformic acid triethyl ester at 140℃;

: (Diethoxymethyl)triethylammonium-tetrafluoroborat

: 109-77-3
malononitrile

: 123-06-8
Ethoxymethylenemalononitrile

: 79343-59-2
1-acetyl-3-(dicyanomethylene)-1,3-dihydro-2H-indol-2-one

: 109-92-2
ethyl vinyl ether

A: 79343-70-7
2-ethoxy-9-acetyl-2,3-dihydropyran<2,3-b>indole

B: 79343-71-8
2-ethoxy-4,4-dicyano-9-acetyl-2,3-dihydropyran<2,3-b>indole

: 79343-66-1, 79343-67-2
(1SR,3SR)-spiro<(2,2-dicyano-3-ethoxy)cyclobutan-1,3'-(1'-acetyl)-2'-oxoindoline>

: 79343-66-1, 79343-67-2
spiro<(2,2-dicyano-3-ethoxy)cyclobutan-1,3'-(1'-acetyl)-2'-oxoindoline>, trans

E: 123-06-8
Ethoxymethylenemalononitrile

Conditions

Conditions	Yield
In acetonitrile Product distribution; with solvent, room temp., or ethylvinylether as solvent, 100 deg C, Paar bomb;

...Expand

: 79343-66-1, 79343-67-2
(1SR,3SR)-spiro<(2,2-dicyano-3-ethoxy)cyclobutan-1,3'-(1'-acetyl)-2'-oxoindoline>

: 109-92-2
ethyl vinyl ether

A: 79343-70-7
2-ethoxy-9-acetyl-2,3-dihydropyran<2,3-b>indole

B: 123-06-8
Ethoxymethylenemalononitrile

Conditions

Conditions	Yield
at 100℃; for 40h; sealed tube;
sealed tube;

...Expand

: 14241-65-7
1-(2',3',4',5'-Tetra-O-acetyl-β-D-mannopyranosyl)urea

: 122-51-0
orthoformic acid triethyl ester

: 109-77-3
malononitrile

A: 2-Oxo-4-imino-5-cyano-1-(2',3',4',5'-tetra-O-acetyl-β-D-mannopyranosyl)-1,2,3,4-tetrahydropyrimidine

B: 123-06-8
Ethoxymethylenemalononitrile

Conditions

Conditions	Yield
With triethylamine 1) 60 deg C, 2 h; 2) ethanol, reflux, 15 min.;; Yield given. Multistep reaction;

...Expand

: 75-03-6
ethyl iodide

silver-compound of hydroxymethylene-malonic acid dinitrile: silver-compound of hydroxymethylene-malonic acid dinitrile

: 123-06-8
Ethoxymethylenemalononitrile

Conditions

Conditions	Yield
With benzene

: 2924-15-4
(2-fluorophenyl)hydrazine hydrochloride

: 123-06-8
Ethoxymethylenemalononitrile

: 135108-48-4
5-amino-1-(2-fluorophenyl)-1H-pyrazole-4-carbonitrile

Conditions

Conditions	Yield
With triethylamine In ethanol at 20℃; for 1.5h; Reflux; Inert atmosphere;	100%
With triethylamine for 4h;	91%
Stage #1: (2-fluorophenyl)hydrazine hydrochloride; Ethoxymethylenemalononitrile With triethylamine In ethanol for 0.666667h; Stage #2: In diethyl ether; hexane for 16h;	67%
With triethylamine
With sodium acetate In ethanol for 1h; Michael Addition; Reflux;

: 896134-44-4
5-hydrazino-2-chloro-benzamide

: 123-06-8
Ethoxymethylenemalononitrile

: 5-(5-amino-4-cyanopyrazol-1-yl)-2-chlorobenzamide

Conditions

Conditions	Yield
In ethanol for 18h; Heating / reflux;	100%

: 40594-29-4, 51523-79-6
(2,4-difluorophenyl)hydrazinium chloride

: 123-06-8
Ethoxymethylenemalononitrile

: 102996-25-8
5-amino-1-(2,4-difluorophenyl)-1H-pyrazole-4-carbonitrile

Conditions

Conditions	Yield
With triethylamine In ethanol at 20℃; for 1.5h; Reflux; Inert atmosphere;	100%
With sodium acetate; triethylamine In acetic acid at 15 - 60℃; for 3.5h; Large scale reaction;	98%
With triethylamine In ethanol for 1h; Heating / reflux;
With triethylamine In ethanol for 1h; Heating / reflux;

: 41052-75-9
o-chlorophenylhydrazine hydrochloride

: 123-06-8
Ethoxymethylenemalononitrile

: 64096-89-5
5-amino-1-(2-chlorophenyl)-1H-pyrazole-4-carbonitrile

Conditions

Conditions	Yield
With triethylamine In ethanol at 20℃; for 1.5h; Reflux; Inert atmosphere;	100%
With triethylamine
With sodium acetate In ethanol for 1h; Michael Addition; Reflux;

: 635-26-7
o-tolylhydrazine hydrochloride

: 123-06-8
Ethoxymethylenemalononitrile

: 142893-46-7
5-amino-1-o-tolyl-1H-pyrazole-4-carbonitrile

Conditions

Conditions	Yield
With triethylamine In ethanol at 20℃; for 1.5h; Reflux; Inert atmosphere;	100%
With triethylamine In methanol

: 1220512-59-3
C6H6F3N3*ClH

: 123-06-8
Ethoxymethylenemalononitrile

: 1019010-69-5
5-amino-1-(3-(trifluoromethyl)pyridin-2-yl)-1H-pyrazole-4-carbonitrile

Conditions

Conditions	Yield
With triethylamine In ethanol at 20℃; for 1.5h; Reflux; Inert atmosphere;	100%

: 123-06-8
Ethoxymethylenemalononitrile

: (2,5-difluorophenyl)hydrazine hydrochloride

: 1220512-60-6
5-amino-1-(2,5-difluorophenyl)-1H-pyrazole-4-carbonitrile

Conditions

Conditions	Yield
With triethylamine In ethanol at 20℃; for 1.5h; Reflux; Inert atmosphere;	100%

: 107-10-8
propylamine

: 123-06-8
Ethoxymethylenemalononitrile

: 2-((propylamino)methylene)malononitrile

Conditions

Conditions	Yield
In ethanol at 20℃; for 1h;	100%

: 1-(2,6-difluorophenyl)hydrazine hydrochloride

: 123-06-8
Ethoxymethylenemalononitrile

: 1188285-05-3
5-amino-1-(2,6-difluorophenyl)-1H-pyrazole-4-carbonitrile

Conditions

Conditions	Yield
With triethylamine In ethanol at 20 - 75℃; for 1.66667h; Inert atmosphere;	99%
With sodium hydroxide In water; acetic acid at 0 - 60℃; for 4.2h; Large scale reaction;	71%
With triethylamine In ethanol at 20℃; for 1.66667h; Reflux;

: 72745-76-7
5-amino-2-methylbenzoxazole

: 123-06-8
Ethoxymethylenemalononitrile

: 2-[(2-Methyl-benzooxazol-5-ylamino)-methylene]-malononitrile

Conditions

Conditions	Yield
In ethanol Ambient temperature;	98%

: 30216-51-4
2-hydrazino-1,3-thiazole

: 123-06-8
Ethoxymethylenemalononitrile

: 650638-01-0
5-amino-1-(1,3-thiazol-2-yl)-1H-pyrazole-4-carbonitrile

Conditions

Conditions	Yield
With triethylamine In ethanol for 2h; Heating / reflux;	98%
In ethanol for 4h; Heating;

: 123-06-8
Ethoxymethylenemalononitrile

: 18772-77-5
3-(4-methylphenyl)-6-hydrazinopyridazine

: 883565-45-5
5-amino-1-(6-p-tolyl-pyridazin-3-yl)-1H-pyrazole-4-carbonitrile

Conditions

Conditions	Yield
In ethanol for 2h; Heating;	98%

: 461-82-5
4-(trifluoromethoxy)aniline

: 123-06-8
Ethoxymethylenemalononitrile

: 2-[(4-(trifluoromethoxy)phenylamino)methylidene]malononitrile

Conditions

Conditions	Yield
In ethanol at 120℃; for 1h;	98%

: 371-14-2
4-fluorophenylhydrazine

: 123-06-8
Ethoxymethylenemalononitrile

: 51516-70-2
5-amino-1-(4-fluorophenyl)-1H-pyrazole-4-carbonitrile

Conditions

Conditions	Yield
In ethanol Reflux;	97%
In ethanol at 105℃; for 0.333333h; microwave irradiation;	71%
In ethanol for 2h; Reflux;	61%

: 823-85-8
4-fluorophenyhydrazine hydrochloride

: 123-06-8
Ethoxymethylenemalononitrile

: 51516-70-2
5-amino-1-(4-fluorophenyl)-1H-pyrazole-4-carbonitrile

Conditions

Conditions	Yield
	97%
With sodium ethanolate; sodium hydride In ethanol at 20℃; for 2h; Heating / reflux;	86%
With triethylamine In ethanol for 10h; Reflux;	66%

: 123-06-8
Ethoxymethylenemalononitrile

: 18772-76-4
3-hydrazino-6-(p-methoxyphenyl)pyridazine

: 5-amino-1-[6-(4-methoxyphenyl)pyridazin-3-yl]-1H-pyrazole-4-carbonitrile

Conditions

Conditions	Yield
In ethanol for 2h; Reflux;	97%

: 32064-67-8
tert-butylhydrazine

: 123-06-8
Ethoxymethylenemalononitrile

: 158001-28-6
5-amino-1-(tert-butyl)-1H-pyrazole-4-carbonitrile

Conditions

Conditions	Yield
With triethylamine In ethanol at 78℃; for 3h;	96.3%
With triethylamine In ethanol at 100℃; for 0.5h; Microwave irradiation;	83%
In ethanol at 70℃; for 18h;	80%
With sodium methylate In ethanol	46 g (87%)
With triethylamine In ethanol at 90℃; Inert atmosphere;

: 100-63-0
phenylhydrazine

: 123-06-8
Ethoxymethylenemalononitrile

: 5334-43-0
5-Amino-4-cyano-1-phenylpyrazole

Conditions

Conditions	Yield
In ethanol for 1h; Reflux;	96%
In ethanol at 120℃; for 0.75h; Solvent; Temperature; Time; Reagent/catalyst; Sealed tube; Microwave irradiation;	95%
With silica gel In N,N-dimethyl acetamide for 0.15h; microwave irradiation;	92%

: 6302-02-9
2-acetonylpyridine

: 123-06-8
Ethoxymethylenemalononitrile

: 123365-98-0
1-Acetyl-4-imino-4H-quinolizine-3-carbonitrile

Conditions

Conditions	Yield
With potassium carbonate In dimethyl sulfoxide Ambient temperature;	96%

: 109152-07-0
ethyl (1,4-dihydro-5,8-dimethoxy-4-oxoquinolin-2-yl)acetate

: 123-06-8
Ethoxymethylenemalononitrile

: 109152-18-3
1-Amino-2-cyano-7,10-dimethoxy-6-oxo-6H-pyrido[1,2-a]quinoline-4-carboxylic acid ethyl ester

Conditions

Conditions	Yield
at 100℃; for 1h;	96%

: 28734-00-1
2-amino-1-benzylideneamino-4-phenyl-1H-imidazole

: 123-06-8
Ethoxymethylenemalononitrile

: 1-benzylideneamino-6-cyano-5-imino-3-phenyl-1H-imidazo[1,2-a]pyrimidine

Conditions

Conditions	Yield
In acetonitrile for 1h; Heating;	96%

: 7400-27-3
tertbutylhydrazine hydrochloride

: 123-06-8
Ethoxymethylenemalononitrile

: 158001-28-6
5-amino-1-(tert-butyl)-1H-pyrazole-4-carbonitrile

Conditions

Conditions	Yield
With triethylamine In ethanol; water at 78℃; for 3h;	96%
With triethylamine In ethanol at 78℃; for 3h;	96%
With triethylamine In ethanol for 3h; Reflux;	95%

: 944478-21-1
3,7-dimethyl-4-(4-nitrophenyl)-2,4-dihydropyrazolo[4',3':5,6]pyrano[2,3-d]pyrimidin-5-ylhydrazine

: 123-06-8
Ethoxymethylenemalononitrile

: 5-amino-1-[3,7-dimethyl-4-(4-nitrophenyl)-2,4-dihydropyrazolo[4',3':5,6]pyrano[2,3-d]pyrimidin-5-yl]-1H-pyrazole-4-carbonitrile

Conditions

Conditions	Yield
In ethanol for 2h; Heating;	96%

: 836684-56-1
N-cyclopropyl-3-hydrazino-4-methyl-benzamide trifluoroacetic acid salt

: 123-06-8
Ethoxymethylenemalononitrile

: 836684-78-7
3-(5-amino-4-cyano-pyrazol-1-yl)-N-cyclopropyl-4-methylbenzamide

Conditions

Conditions	Yield
With N-ethyl-N,N-diisopropylamine In ethanol at 65℃; for 3h;	96%

: (x)C2HF3O2*C6H12F2N2

: 123-06-8
Ethoxymethylenemalononitrile

: 1082745-53-6
5-amino-1-(4,4-difluorocyclohexyl)-1H-pyrazol-4-carbonitrile

Conditions

Conditions	Yield
With triethylamine In ethanol at 50℃; for 2h;	96%

: 1214910-81-2
C2HF3O2*C6H12F2N2

: 123-06-8
Ethoxymethylenemalononitrile

: 1082745-53-6
5-amino-1-(4,4-difluorocyclohexyl)-1H-pyrazol-4-carbonitrile

Conditions

Conditions	Yield
With triethylamine In ethanol at 50℃; for 2h;	96%
With triethylamine In ethanol at 50℃; for 2h;	96%

: 38956-80-8
3-hydrazino-6-phenylpyridazine

: 123-06-8
Ethoxymethylenemalononitrile

: 1177347-71-5
5-amino-1-(6-phenyl-pyridazin-3-yl)-1H-pyrazole-4-carbonitrile

Conditions

Conditions	Yield
In ethanol for 2h; Reflux;	96%
In ethanol for 2h; Reflux;	84%

: 123-06-8
Ethoxymethylenemalononitrile

: 650628-55-0
(1-p-tolyl-1H-pyrazolo[3,4-d]pyrimidin-4-yl)-hydrazine

: 5-amino-1-(1-p-tolyl-1H-pyrazolo[3,4-d]pyrimidin-4-yl)-1H-pyrazole-4-carbonitrile

Conditions

Conditions	Yield
In ethanol for 2h; Heating;	96%

Ethoxymethylenemalononitrile Chemical Properties

Structure of Ethoxymethylenemalononitrile (CAS NO.123-06-8):

IUPAC Name: 2-(ethoxymethylidene)propanedinitrile
Empirical Formula: C₆H₆N₂O
Molecular Weight: 122.1246
EINECS: 204-597-0
Index of Refraction: 1.461
Molar Refractivity: 31.31 cm³
Molar Volume: 114.1 cm³
Polarizability: 12.41×10^-24cm³
Surface Tension: 41.9 dyne/cm
Density: 1.07 g/cm³
Flash Point: 135.1 °C
Enthalpy of Vaporization: 53.59 kJ/mol
Melting Point: 64-66 °C(lit.)
Boiling Point: 296.1 °C at 760 mmHg
Vapour Pressure: 0.00146 mmHg at 25°C
Water Solubility: insoluble
Physical Appearance: Off White to Pale Yellow
Product Categories: Pharmaceutical Intermediates;Aliphatic Compound;Miscellaneous;API intermediates;Various Intermediates;Intermediates;C6 to C7;Cyanides/Nitriles;Nitrogen Compounds

Ethoxymethylenemalononitrile Toxicity Data With Reference

ipr-mus LD50:50 mg/kg

NTIS** National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) AD277-689 .

Ethoxymethylenemalononitrile Consensus Reports

Reported in EPA TSCA Inventory. Cyanide and its compounds are on the Community Right-To-Know List.

Ethoxymethylenemalononitrile Safety Profile

Poison by intraperitoneal route. When heated to decomposition it emits very toxic fumes of NO_x and CN⁻. See also NITRILES.
Hazard Codes: Harmful Xn, Irritant Xi, Toxic T
Risk Statements: 22-42/43-23/24/25-43-20/21/22
22: Harmful if swallowed
42/43: May cause sensitization by inhalation and skin contact
23/24/25: Toxic by inhalation, in contact with skin and if swallowed
43: May cause sensitization by skin contact
20/21/22: Harmful by inhalation, in contact with skin and if swallowed
Safety Statements: 22-36/37-45-36/37/39-26-36-24/25
22: Do not breathe dust
36/37: Wear suitable protective clothing and gloves
45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
36/37/39: Wear suitable protective clothing, gloves and eye/face protection
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36: Wear suitable protective clothing
24/25: Avoid contact with skin and eyes
RIDADR: 3439
WGK Germany: 3
RTECS: OO3850000
F: 21: Sensitive to humidity.
HazardClass: 6.1
PackingGroup: III

Ethoxymethylenemalononitrile Specification

1. First Aid Measures
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
2. Handling and Storage
Storage:
Store in a tightly closed container. Store in a cool, dry area away from incompatible substances.
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. Use with adequate ventilation. Use only in a chemical fume hood. Wash clothing before reuse. Do not breathe dust.

Product Name

Ethoxymethylenemalononitrile

Synthetic route

Ethoxymethylenemalononitrile Chemical Properties

Ethoxymethylenemalononitrile Toxicity Data With Reference

Ethoxymethylenemalononitrile Consensus Reports

Ethoxymethylenemalononitrile Safety Profile

Ethoxymethylenemalononitrile Specification

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