Ethyl hydroperoxide supplier

Name
ethyl hydroperoxide
EINECS
CAS No. 3031-74-1
Article Data45
CAS DataBase
Density 0.948g/cm³
Solubility
Melting Point -100°C
Formula C2H6 O2
Boiling Point 95°Cat760mmHg
Molecular Weight 62.0684
Flash Point 11.3°C
Transport Information
Appearance
Safety Explodes violently when superheated. The barium salt is heat- and impact-sensitive. Explosive reaction with hydroiodic acid or finely divided silver. When heated to decomposition it emits acrid smoke and irritating fumes. See also PEROXIDES, INORGANIC; PEROXIDES, ORGANIC.
Risk Codes
Molecular Structure
Hazard Symbols
Synonyms Ethylhydroperoxide (6CI,7CI,8CI); Ethyl hydrogen peroxide
PSA 29.46000
LogP 0.49590

Synthetic route

: 74-84-0
ethane

A: 79-21-0
peracetic acid

B: 3031-73-0
methyl hydroperoxide

C: 3031-74-1
ethyl hydroperoxide

D: 15932-89-5
hydroxymethylhydroperoxide

Conditions

Conditions	Yield
With nitrogen; oxygen; chlorine at 24.85℃; under 760 Torr; for 0.5h; Kinetics; Oxidation; Photolysis;	A 2% B 6.2% C 10.2% D 0.4%

...Expand

: 74-98-6
propane

A: 79-21-0
peracetic acid

B: 3031-73-0
methyl hydroperoxide

C: 3031-74-1
ethyl hydroperoxide

D: 15932-89-5
hydroxymethylhydroperoxide

Conditions

Conditions	Yield
With nitrogen; oxygen; chlorine at 24.85℃; under 760 Torr; for 0.333333h; Kinetics; Oxidation; Photolysis;	A 0.1% B 3.39% C 0.61% D 0.14%

...Expand

: 64-67-5
diethyl sulfate

: 3031-74-1
ethyl hydroperoxide

Conditions

Conditions	Yield
With dihydrogen peroxide
With dihydrogen peroxide
With potassium hydroxide; dihydrogen peroxide man saeuert 10-stdg. Schuetteln mit Schwefelsaeure an und destilliert das zwischen 90grad und 100grad uebergegangene Destillat wird mit Kalilauge versetzt und im Vakuum konzentriert darauf saeuert man abermals an und destilliert ueber;
With potassium hydroxide; dihydrogen peroxide In water Heating;

: 64-67-5
diethyl sulfate

A: 3031-74-1
ethyl hydroperoxide

B: 628-37-5
diethyl peroxide

Conditions

Conditions	Yield
With dihydrogen peroxide

: 74-84-0
ethane

: 3031-74-1
ethyl hydroperoxide

Conditions

Conditions	Yield
With oxygen at 25℃; Irradiation.mit UV-Licht <253.7 nm; Quecksilber-Sensibilisierung>;
With AuPd; dihydrogen peroxide In water at 21℃; under 750.075 Torr; for 1h;

: 2386-64-3
ethylmagnesium chloride

: 3031-74-1
ethyl hydroperoxide

Conditions

Conditions	Yield
With diethyl ether; oxygen at -75℃;

: 74-84-0
ethane

A: 3031-74-1
ethyl hydroperoxide

B: 3170-61-4
ethylperoxy radical

Conditions

Conditions	Yield
With hydrogen; fluorine at -63.1 - 89.9℃; Rate constant; Irradiation; investigated by flash photolysis-time-resolved UV spectroscopy;

: 74-84-0
ethane

A: 67-56-1
methanol

B: 50-00-0
formaldehyd

C: 64-18-6
formic acid

D: 74-85-1
ethene

E: 3031-74-1
ethyl hydroperoxide

F: 75-07-0
acetaldehyde

Conditions

Conditions	Yield
With nitrogen; oxygen; chlorine at 298℃; under 700 Torr; for 4h; Product distribution; Irradiation;

...Expand

: 821-14-7
azoethane

A: 64-17-5
ethanol

B: 3031-74-1
ethyl hydroperoxide

C: 628-37-5
diethyl peroxide

D: 124-38-9
carbon dioxide

E: 201230-82-2
carbon monoxide

F: 75-07-0
acetaldehyde

Conditions

Conditions	Yield
With nitrogen; oxygen at 298℃; under 700 Torr; for 0.416667h; Product distribution; Irradiation;

...Expand

: 70-29-1
diethyl sulphide

: 3031-74-1
ethyl hydroperoxide

Conditions

Conditions	Yield
With dihydrogen peroxide

: 3170-61-4
ethylperoxy radical

: 3031-74-1
ethyl hydroperoxide

Conditions

Conditions	Yield
With hydroperoxyl at -63.1 - 89.9℃; Rate constant; Mechanism; Irradiation; investigated by flash photolysis-time-resolved UV spectroscopy;
With HO2 at 24.84℃; under 75 Torr; Kinetics; Further Variations:; Pressures; Temperatures;

: 3170-61-4
ethylperoxy radical

A: 64-17-5
ethanol

B: 3031-74-1
ethyl hydroperoxide

C: 75-07-0
acetaldehyde

Conditions

Conditions	Yield
With oxygen In gaseous matrix Kinetics; Mechanism; Irradiation; in nitrogen-atmosphere; variation of oxygen pressure;

...Expand

: 15463-99-7
E-azoethane

A: 64-17-5
ethanol

B: 3031-74-1
ethyl hydroperoxide

C: 75-07-0
acetaldehyde

Conditions

Conditions	Yield
With oxygen In gaseous matrix Product distribution; Mechanism; Kinetics; Irradiation; in nitrogen-atmosphere; variation of oxygen pressure;

...Expand

: 74-84-0
ethane

A: 64-17-5
ethanol

B: 74-85-1
ethene

C: 3031-74-1
ethyl hydroperoxide

D: 75-07-0
acetaldehyde

Conditions

Conditions	Yield
With oxygen; chlorine at 255.9℃; under 1000 Torr; Product distribution; Kinetics; Mechanism; Irradiation; ΔH(excit.), variation of pressure;

...Expand

: 2025-56-1
ethyl radical

A: 64-17-5
ethanol

B: 74-85-1
ethene

C: 3031-74-1
ethyl hydroperoxide

D: 75-07-0
acetaldehyde

Conditions

Conditions	Yield
With oxygen at 255.9℃; under 1000 Torr; Product distribution; Kinetics; Mechanism; ΔH(excit.), variation of pressure;

...Expand

: 74-84-0
ethane

A: 64-17-5
ethanol

B: 3031-74-1
ethyl hydroperoxide

C: 75-07-0
acetaldehyde

D: 64-19-7
acetic acid

Conditions

Conditions	Yield
With 2-pyrazylcarboxylic acid; air; dihydrogen peroxide; [n-Bu4N]VO3 In acetonitrile at 40 - 75℃; Product distribution; Mechanism;
With dihydrogen peroxide; chromic acid In acetonitrile at 60℃; under 22501.8 Torr; for 1h; Product distribution;
With 2-pyrazylcarboxylic acid; C30H34N4O10V2; dihydrogen peroxide In water; acetonitrile at 50℃; under 7600.51 Torr; for 6h; Catalytic behavior; Kinetics; Time; Autoclave; Overall yield = 10 %;

...Expand

: 74-84-0
ethane

A: 64-17-5
ethanol

B: 3031-74-1
ethyl hydroperoxide

C: 75-07-0
acetaldehyde

Conditions

Conditions	Yield
With air; tris(μ-oxo)di[(1,4,7-trimethyl-1,4,7-triazanonane)manganese(IV)] hexafluorophosphate; dihydrogen peroxide; acetic acid In acetonitrile at 0℃; under 750.06 Torr; for 21h; Product distribution; Mechanism;
With dihydrogen peroxide; iron(III) perchlorate In acetonitrile at 25℃; under 20252 Torr; for 3h; Product distribution; Further Variations:; Catalysts;

...Expand

: 64-67-5
diethyl sulfate

alkali: alkali

hydroperoxide: hydroperoxide

A: 3031-74-1
ethyl hydroperoxide

B: 628-37-5
diethyl peroxide

...Expand

: 74-84-0
ethane

oxygen: oxygen

3P1-mercury: 3P1-mercury

: 3031-74-1
ethyl hydroperoxide

Conditions

Conditions	Yield
at 40 - 200℃; Kinetics;

...Expand

: 28567-28-4
1-(ethylperoxy)ethanol

: 7732-18-5
water

A: 3031-74-1
ethyl hydroperoxide

B: 75-07-0
acetaldehyde

...Expand

: 1-ethylperoxy-propan-1-ol

: 7732-18-5
water

A: 3031-74-1
ethyl hydroperoxide

B: 123-38-6
propionaldehyde

...Expand

: 3170-61-4
ethylperoxy radical

A: 3031-74-1
ethyl hydroperoxide

B O2: O2

Conditions

Conditions	Yield
With HO2 In gas at -25.1℃; under 760 Torr; Kinetics; up to 480 K;

: 108991-57-7
diperoxyterephthalic acid diethyl ester

: 7732-18-5
water

A: 3031-74-1
ethyl hydroperoxide

B: 100-21-0
terephthalic acid

...Expand

: 108991-57-7
diperoxyterephthalic acid diethyl ester

aqueous alkali: aqueous alkali

A: 3031-74-1
ethyl hydroperoxide

B: 100-21-0
terephthalic acid

...Expand

: 121519-87-7
Ethyl peroxybenzoate

: 3031-74-1
ethyl hydroperoxide

Conditions

Conditions	Yield
With bis(tri-n-butyltin)oxide In diethyl ether at -10℃; for 12h;

: 74-84-0
ethane

A: 3031-74-1
ethyl hydroperoxide

B: 75-07-0
acetaldehyde

C: 64-19-7
acetic acid

Conditions

Conditions	Yield
With 2-pyrazylcarboxylic acid; dihydrogen peroxide; [Fe2(HPTB)(μ-OH)(NO3)2](NO3)2CH3OH2H2O In acetonitrile at 25℃; under 22501.8 Torr; for 6h; Product distribution;
With AuPd; dihydrogen peroxide In water at 21℃; under 750.075 Torr; for 1h; Time;
With oxygen at 35℃; for 2h; Temperature; Irradiation; Autoclave;

...Expand

: 74-84-0
ethane

A: 3031-74-1
ethyl hydroperoxide

B: 75-07-0
acetaldehyde

Conditions

Conditions	Yield
With oxygen; chlorine In methanol Product distribution; Further Variations:; Solvents;

: 126327-28-4
(tetraphenylporphyrin)(germanium(IV))(ethylhydroperoxide)2

A: 41150-80-5
dihydroxo(meso-tetraphenylporphyrinato)germanium(IV)

B: 3031-74-1
ethyl hydroperoxide

Conditions

Conditions	Yield
With water In benzene water is added to benzene soln. of TPPGe(OOCH2CH3)2; detected by NMR spectroscopy;

: 74344-36-8
(tetraphenylporphyrin)(germanium(IV))(OOCH2CH3)(CH2CH3)

A: 126294-64-2
(tetraphenylporphyrin)(germanium(IV))(Cl)(CH2CH3)

B: 3031-74-1
ethyl hydroperoxide

Conditions

Conditions	Yield
With hydrogen chloride treatment of TPPGe(OOCH2CH3)(CH2CH3) with hydrogen chloride; (1)H-NMR;

: 41150-80-5
dihydroxo(meso-tetraphenylporphyrinato)germanium(IV)

: 3031-74-1
ethyl hydroperoxide

: 126327-28-4
(tetraphenylporphyrin)(germanium(IV))(ethylhydroperoxide)2

Conditions

Conditions	Yield
In diethyl ether; dichloromethane soln. of ethyl hydroperoxide in ether is added to TPPGe(OH)2 dissolved in dichloromethane in a darkened room, stirring for 5 min; solvent is removed (vac.); (1)H-NMR;	92%

: 186581-53-3, 908094-01-9
diazomethane

: 3031-74-1
ethyl hydroperoxide

: 70299-48-8
methoxyethylether

Conditions

Conditions	Yield
With Petroleum ether

: 50-00-0
formaldehyd

: 60-29-7
diethyl ether

: 3031-74-1
ethyl hydroperoxide

: 856340-88-0
ethylperoxy-methanol

Conditions

Conditions	Yield
reagiert analog mit Acetaldehyd und Propionaldehyd;

...Expand

: 50-00-0
formaldehyd

: 3031-74-1
ethyl hydroperoxide

: 856340-88-0
ethylperoxy-methanol

Conditions

Conditions	Yield
With diethyl ether

: 109-95-5
ethyl nitrite

: 3031-74-1
ethyl hydroperoxide

: 625-58-1
ethyl nitrate

: 3031-74-1
ethyl hydroperoxide

: 625-58-1
ethyl nitrate

Conditions

Conditions	Yield
With cis-nitrous acid

: 3031-74-1
ethyl hydroperoxide

A: 50-00-0
formaldehyd

B: 64-17-5
ethanol

C: 75-07-0
acetaldehyde

Conditions

Conditions	Yield
at 170 - 200℃; bei langsamer Zersetztung;

...Expand

: 3031-74-1
ethyl hydroperoxide

: 894-61-1
2-ethoxy-1-methyl-6,8-dinitro-1,2-dihydro-quinoline

: 100115-45-5
ethyl-(1-methyl-6,8-dinitro-1,2-dihydro-[2]quinolyl)-peroxide

Conditions

Conditions	Yield
With acetic acid; benzene

: 3031-74-1
ethyl hydroperoxide

: 140-29-4
phenylacetonitrile

: 2-phenyl-peroxyacetimidic acid ethyl ester

Conditions

Conditions	Yield
With sodium hydroxide at 50 - 60℃;

: 3031-74-1
ethyl hydroperoxide

: 75-07-0
acetaldehyde

: 28567-28-4
1-(ethylperoxy)ethanol

Conditions

Conditions	Yield
With diethyl ether

: 3031-74-1
ethyl hydroperoxide

: 123-38-6
propionaldehyde

: 1-ethylperoxy-propan-1-ol

Conditions

Conditions	Yield
With diethyl ether

: 3031-74-1
ethyl hydroperoxide

: 123-72-8
butyraldehyde

: ethyl-(1-hydroxy-butyl)-peroxide

Conditions

Conditions	Yield
With diethyl ether

: 3031-74-1
ethyl hydroperoxide

: 802294-64-0
propionic acid

: 15719-64-9, 15719-76-3, 97762-63-5
methylammonium carbonate

Conditions

Conditions	Yield
in Gegenwart von Mohrschem Salz;

: 50-00-0
formaldehyd

: 3031-74-1
ethyl hydroperoxide

: 124-40-3
dimethyl amine

: 98138-18-2
ethylperoxymethyl-dimethyl-amine

Conditions

Conditions	Yield
With water

...Expand

: 3031-74-1
ethyl hydroperoxide

: 77-78-1
dimethyl sulfate

: 70299-48-8
methoxyethylether

Conditions

Conditions	Yield
With potassium hydroxide anfangs unter Kuehlung, dann bei 70grad;
With potassium hydroxide

: 3031-74-1
ethyl hydroperoxide

: 590-86-3
isovaleraldehyde

: ethyl-(1-hydroxy-3-methyl-butyl)-peroxide

Conditions

Conditions	Yield
With diethyl ether

: 3031-74-1
ethyl hydroperoxide

: 110-46-3
isopentyl nitrite

A: 625-58-1
ethyl nitrate

B: 123-51-3
i-Amyl alcohol

...Expand

: 3031-74-1
ethyl hydroperoxide

: 110-46-3
isopentyl nitrite

A: 625-58-1
ethyl nitrate

B: 71-41-0
pentan-1-ol

...Expand

: 3031-74-1
ethyl hydroperoxide

: 75-07-0
acetaldehyde

Conditions

Conditions	Yield
With catalase In water at 25℃; Kinetics; Mechanism;

: 3031-74-1
ethyl hydroperoxide

A: 64-17-5
ethanol

B: 75-07-0
acetaldehyde

Conditions

Conditions	Yield
(TMP)Fe(III)OH In (2)H8-toluene for 12h; Mechanism;	A 11 % Spectr. B 72 % Spectr.

Ethyl hydroperoxide Chemical Properties

Molecular Structure of Ethyl hydroperoxide (CAS NO.3031-74-1):

IUPAC: Hydroperoxyethane
Molecular Formula:C₂H₆O₂
Molecular Weight:62.0678
Density:0.948 g/cm³
Flash Point:11.3^oC
Boiling Point:95^oC at 760 mmHg
SMILES:O(O)CC
InChI:InChI=1/C2H6O2/c1-2-4-3/h3H,2H2,1H3
InChIKey:ILHIHKRJJMKBEE-UHFFFAOYAS
Index of Refraction:1.364
Molar Volume:65.4 cm³
Surface Tension:26.2 dyne/cm
Molar Refractivity:14.59 cm³
Enthalpy of Vaporization:39.01 kJ/mol
Vapour Pressure:27.4 mmHg at 25^oC

Ethyl hydroperoxide Safety Profile

Explodes violently when superheated. The barium salt is heat- and impact-sensitive. Explosive reaction with hydroiodic acid or finely divided silver. When heated to decomposition it emits acrid smoke and irritating fumes. See also PEROXIDES, INORGANIC; PEROXIDES, ORGANIC.

Ethyl hydroperoxide Standards and Recommendations

DOT Classification: Forbidden

Ethyl hydroperoxide Specification

Ethyl hydroperoxide with cas registry number of 3031-74-1 is also known as Hydroperoxide, ethyl ; Ethyl hydrogen peroxide . It is stable under normal temperatures and pressures but it also should be stored in a tightly closed container when not in use and stored in a cool, dry place. Ethyl hydroperoxide with cas registry number of 3031-74-1 is used as a pharmaceutical intermediate. It can be used to produce singlet molecular oxygen by decomposition.

Product Name

ethyl hydroperoxide

Synthetic route

Ethyl hydroperoxide Chemical Properties

Ethyl hydroperoxide Safety Profile

Ethyl hydroperoxide Standards and Recommendations

Ethyl hydroperoxide Specification

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