Conditions | Yield |
---|---|
In n-heptane reaction of excess (C6H5)3SnH on refluxing for 3 h;; | 85% |
In not given reaction at 70°C for 0.5 h;; | 17% |
Conditions | Yield |
---|---|
In not given byproducts: (C2H5)3PbH; |
triphenyl(4-t-butylphenoxo)tin(IV)
triphenyltin acetate
Conditions | Yield |
---|---|
With acetic acid In benzene mixt. refluxed, resulting solid washed with petroleum ether; resulting solid washed with petroleum ether, dried under reduced pressure, elem. anal.; |
(CO)3CrC6H5Sn(C6H5)3
triphenyltin acetate
Conditions | Yield |
---|---|
With acetic acid | |
With CH3COOH |
acetic acid
(Z)-1-ethoxy-2-triphenylstannylethene
A
triphenyltin acetate
B
ethyl vinyl ether
Conditions | Yield |
---|---|
In chloroform-d1 Kinetics; (Ar); addn. of a soln. of acetic acid in CDCl3 to a soln. of tin compd. in CDCl3 at room temp.; detected by NMR; |
acetic acid
(E)-1-ethoxy-2-triphenylstannylethene
A
triphenyltin acetate
B
ethyl vinyl ether
Conditions | Yield |
---|---|
In chloroform-d1 Kinetics; (Ar); addn. of a soln. of acetic acid in CDCl3 to a soln. of tin compd. in CDCl3 at room temp.; detected by NMR; |
acetic acid-(2-triphenylstannyl-ethyl ester)
triphenyltin acetate
Conditions | Yield |
---|---|
In neat (no solvent) byproducts: CH2CH2; decomposition above 180 °C;; | |
In neat (no solvent) byproducts: CH2CH2; decomposition above 180 °C;; | |
Multi-step reaction with 2 steps 1: water 2: CH3COOH / neat (no solvent) View Scheme |
(C6H5)3SnCH(CH3)CH(CH3)OH
triphenyltin acetate
Conditions | Yield |
---|---|
With acetic acid In methanol Kinetics; byproducts: CH3CHCHCH3; | |
With acetic acid In methanol Kinetics; byproducts: CH3CHCHCH3; |
(C6H5)3SnCH2C(CH3)2OH
triphenyltin acetate
Conditions | Yield |
---|---|
With acetic acid In methanol Kinetics; byproducts: CH2C(CH3)2; | |
With acetic acid In methanol Kinetics; byproducts: CH2C(CH3)2; |
2-triphenylstannyl-ethanol
triphenyltin acetate
Conditions | Yield |
---|---|
With acetic acid In neat (no solvent) Kinetics; byproducts: CH2CH2, H2O; reaction with CH3COOH in presence of HClO4;; | |
With CH3COOH In neat (no solvent) Kinetics; byproducts: CH2CH2, H2O; reaction with CH3COOH in presence of HClO4;; |
Conditions | Yield |
---|---|
With oxygen | |
With O2 |
(C6H5)3SnCH2CH(OH)CH3
triphenyltin acetate
Conditions | Yield |
---|---|
With acetic acid In methanol Kinetics; byproducts: CH2CHCH3, H2O; | |
With acetic acid In methanol Kinetics; byproducts: CH2CHCH3, H2O; |
acetic acid
(Z)-1-ethylthio-2-triphenylstannylethene
A
triphenyltin acetate
B
vinyl ethylsulfide
Conditions | Yield |
---|---|
In chloroform-d1 Kinetics; (Ar); addn. of a soln. of acetic acid in CDCl3 to a soln. of tin compd. in CDCl3 at room temp.; detected by NMR; |
acetic acid
(E)-1-ethylthio-2-triphenylstannylethene
A
triphenyltin acetate
B
vinyl ethylsulfide
Conditions | Yield |
---|---|
In chloroform-d1 Kinetics; (Ar); addn. of a soln. of acetic acid in CDCl3 to a soln. of tin compd. in CDCl3 at room temp.; detected by NMR; |
acetic acid
A
(E)-N,N-dimethyl-2-phenylethen-1-amine
B
triphenyltin acetate
Conditions | Yield |
---|---|
In chloroform-d1 Kinetics; (Ar); addn. of a soln. of acetic acid in CDCl3 to a soln. of tin compd. in CDCl3 at room temp.; detected by NMR; |
acetic acid
(Z)-1-ethoxy-2-triphenylstannylhex-1-ene
A
1-ethoxy-hex-1-ene
B
triphenyltin acetate
Conditions | Yield |
---|---|
In chloroform-d1 Kinetics; (Ar); addn. of a soln. of acetic acid in CDCl3 to a soln. of tin compd. in CDCl3 at room temp.; detected by NMR; |
acetic acid
(E)-1-ethoxy-2-triphenylstannylhex-1-ene
A
1-ethoxy-hex-1-ene
B
triphenyltin acetate
Conditions | Yield |
---|---|
In chloroform-d1 Kinetics; (Ar); addn. of a soln. of acetic acid in CDCl3 to a soln. of tin compd. in CDCl3 at room temp.; detected by NMR; |
β-methoxycarbonyl ethyl triphenyltin(IV)
triphenyltin acetate
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: KOH / ethanol 2: CH3COOH / neat (no solvent) View Scheme |
2-(2-triphenylstannylethyl)-4,4,6-trimethyl-1,3,2-dioxaborinan
triphenyltin acetate
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: H2O2 / ethanol; sodium hydroxide 2: CH3COOH / neat (no solvent) View Scheme |
bis(triphenylstannyl)magnesium
triphenyltin acetate
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: CH3COCl 2: O2 View Scheme |
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 2: H2O2 / ethanol; sodium hydroxide 3: CH3COOH / neat (no solvent) View Scheme | |
Multi-step reaction with 2 steps 2: CH3COOH / neat (no solvent) View Scheme | |
Multi-step reaction with 2 steps 2: neat (no solvent) View Scheme | |
Multi-step reaction with 3 steps 2: water 3: CH3COOH / neat (no solvent) View Scheme | |
Multi-step reaction with 3 steps 2: KOH / ethanol 3: CH3COOH / neat (no solvent) View Scheme |
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 1,2-dimethoxyethane 2: CH3COOH / neat (no solvent) View Scheme | |
Multi-step reaction with 2 steps 1: CH3COCl / tetrahydrofuran 2: O2 View Scheme |
triphenyltin acetate
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: diethyl ether 2: CH3COOH / neat (no solvent) View Scheme | |
Multi-step reaction with 2 steps 1: 1,2-dimethoxyethane 2: acetic acid / methanol View Scheme | |
Multi-step reaction with 2 steps 1: 1,2-dimethoxyethane 2: acetic acid / methanol View Scheme | |
Multi-step reaction with 2 steps 1: 1,2-dimethoxyethane 2: acetic acid / methanol View Scheme |
Conditions | Yield |
---|---|
In 5,5-dimethyl-1,3-cyclohexadiene for 6h; Reflux; | 98% |
In toluene exclusion of moisture, heated, isopropylacetate fractionated out continuously from 80°C to the boiling point of toluene; excess of toluene distd. off under reduced pressure; elem. anal.; | 95% |
Conditions | Yield |
---|---|
In toluene The suspn. of InX and Ph3SnX in toluene was cooled to -20°C, diamine was added stirring was continued for about 1 h; allowed to warm to room temp. for 1-2 h (N2 atm.);; filtered, solid was washed with toluene and dried in vac. at room temp.; elem. anal.;; | 98% |
triphenyltin acetate
Conditions | Yield |
---|---|
In benzene equimolar amt. of educts refluxed in benzene for about 8 h; hot mixt. was filtered, filtrate concd. under vac. at 50°C, recrystd. from either benzene or chloroform, dried in vac., elem. anal.; | 95% |
Conditions | Yield |
---|---|
In toluene The suspn. of InX and Ph3SnX in toluene was cooled to -20°C, diamine was added stirring was continued for about 1 h; allowed to warm to room temp. for 1-2 h (N2 atm.);; filtered, solid was washed with toluene and dried in vac. at room temp.; elem. anal.;; | 94% |
Conditions | Yield |
---|---|
In toluene The suspn. of InX and Ph3SnX in toluene was cooled to -20°C, diamine was added stirring was continued for about 1 h; allowed to warm to room temp. for 1-2 h (N2 atm.);; filtered, solid was washed with toluene and dried in vac. at room temp. recrysd. from THF-MeOH; elem. anal.;; | 92% |
Conditions | Yield |
---|---|
In N,N-dimethyl acetamide Electrolysis; supporting electrolite LiClO4; filtration, washing with methanol then ether; | 91% |
C5H5FeC5H4CHNNHC(O)C6H4NO2
triphenyltin acetate
Conditions | Yield |
---|---|
In benzene equimolar amt. of educts refluxed in benzene for about 8 h; hot mixt. was filtered, filtrate concd. under vac. at 50°C, recrystd. from either benzene or chloroform, dried in vac., elem. anal.; | 90% |
triphenyltin acetate
(C6H5)3Sn(C5H5FeC5H4CHNNCO(C6H4Cl))
Conditions | Yield |
---|---|
In benzene equimolar amt. of educts refluxed in benzene for about 8 h; hot mixt. was filtered, filtrate concd. under vac. at 50°C, recrystd. from either benzene or chloroform, dried in vac., elem. anal.; | 85% |
triphenyltin acetate
Conditions | Yield |
---|---|
In benzene equimolar amt. of educts refluxed in benzene for about 8 h; hot mixt. was filtered, filtrate concd. under vac. at 50°C, recrystd. from either benzene or chloroform, dried in vac., elem. anal.; | 80% |
Conditions | Yield |
---|---|
In benzene equimolar amt. of educts refluxed in benzene for about 8 h; hot mixt. was filtered, filtrate concd. under vac. at 50°C, recrystd. from either benzene or chloroform, dried in vac., elem. anal.; | 78% |
sodium piperazine-N,N'-bisdithiocarboxylate
triphenyltin acetate
[(triphenyltin(IV))2 piperazine bis(dithiocarbamate)]
Conditions | Yield |
---|---|
In ethanol byproducts: NaCH3COO; in a dry box flushed with N2; mixing an alc. soln. of dithiocarbamate with an alc. soln. of Sn-compd.; filtering off the ppt., washing with alc. and drying in vac.; elem. anal.; | 70% |
Conditions | Yield |
---|---|
In tetrahydrofuran Sonication; sonicating (room temp., 30 min); filtering, crystn. on concg. and n-hexane addn. (-20°C, overnight); elem. anal.; | 70% |
sodium N,N-diethyldithiocarbamate
triphenyltin acetate
(C6H5)3Sn(S2CN(C2H5)2)
Conditions | Yield |
---|---|
In ethanol; chloroform byproducts: NaCH3COO; in a dry box flushed with N2; mixing an alc./CHCl3 soln. of dithiocarbamate with Sn-compd. in alc., stirring for ca 2 h; elem. anal.; | 60% |
borane
triphenyltin acetate
ethanolamine
A
phenylboronic acid
B
2-aminoethoxydiphenyl borate
Conditions | Yield |
---|---|
With water In tetrahydrofuran; diethyl ether; ethanol to THF soln. of Sn compd. added BH3 (N2, room temp.),refluxed (1 h), added H2O,stirred (30 min),extd. (Et2O), dried (MgSO4),evapd. in vac.,heated with pentane,filtered PhB(OH)2,filtrate evapd.,added Et2O,EtOH soln. of HOCH2CH2NH2 added,refluxed (30 min); filtered hot, complex pptd. by cooling, filtered; PhB(OH)2 recrystd. from H2O; compds. identified by m. p., IR, NMR; |
EPA Extremely Hazardous Substances List. Reported in EPA TSCA Inventory.
OSHA PEL: TWA 0.1 mg(Sn)/m3 (skin)
ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL 0.2 mg(Sn)/m3 (skin).
NIOSH REL: (Organotin Compounds) TWA 0.1 mg(Sn)/m3
For occupational chemical analysis use NIOSH: organotin compounds 5504.
The Fentin acetate, with the CAS registry number 900-95-8, is also known as Triphenylaceto stannane. It belongs to the product categories of Herbicide; Organotin Compound. Its EINECS number is 212-984-0. This chemical is an organotin compound with the formula C20H18O2Sn and its molecular weight is 409.05. What's more, its systematic name is Triphenylstannanylium acetate. This chemical is stable at common pressure and temperature, and it should be sealed and stored in a cool, ventilated and dry place. Moreover, it should be protected from oxides. Its classification codes are: (1)Agricultural Chemical; (2)Fungicide, bactericide, wood preservative; (3)Fungicides, industrial; (4)Herbicide; (5)Insect attractant, repellent and chemosterilant; (6)Molluscicide; (7)Mutation data; (8)Noxae; (9)Organometallic; (10)Pesticides; (11)Reproductive Effect; (12)Teratogens; (13)Tumor data. It is a colourless solid that is used as a fungicide.
When you are using this chemical, please be cautious about it as the following:
This chemical is toxic in contact with skin and if swallowed and is very toxic by inhalation. It is irritating to respiratory system and skin. It has a limited evidence of a carcinogenic effect and a risk of serious damage to eyes. This substance is toxic as it has a danger of serious damage to health by prolonged exposure through inhalation. It is very toxic to aquatic organisms as it may cause long-term adverse effects in the aquatic environment. It has a possible risk of harm to the unborn child. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. When using it, you need wear suitable protective gloves and eye/face protection. In case of accident or if you feel unwell, you must seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. You should avoid releasing it to the environment, and you need refer to special instructions/safety data sheet.
You can still convert the following datas into molecular structure:
(1)SMILES: [O-]C(=O)C.c3c([Sn+](c1ccccc1)c2ccccc2)cccc3
(2)Std. InChI: InChI=1S/3C6H5.C2H4O2.Sn/c3*1-2-4-6-5-3-1;1-2(3)4;/h3*1-5H;1H3,(H,3,4);/q;;;;+1/p-1
(3)Std. InChIKey: WDQNIWFZKXZFAY-UHFFFAOYSA-M
The toxicity data is as follows:
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
bird - wild | LD50 | oral | 100mg/kg (100mg/kg) | Archives of Environmental Contamination and Toxicology. Vol. 12, Pg. 355, 1983. | |
chicken | LD | oral | > 300mg/kg (300mg/kg) | British Journal of Industrial Medicine. Vol. 23, Pg. 222, 1966. | |
chicken | LDLo | intraperitoneal | 40mg/kg (40mg/kg) | BEHAVIORAL: MUSCLE WEAKNESS BEHAVIORAL: ALTERED SLEEP TIME (INCLUDING CHANGE IN RIGHTING REFLEX) | British Journal of Industrial Medicine. Vol. 23, Pg. 222, 1966. |
guinea pig | LD50 | intraperitoneal | 3740ug/kg (3.74mg/kg) | BEHAVIORAL: MUSCLE WEAKNESS PERIPHERAL NERVE AND SENSATION: FLACCID PARALYSIS WITHOUT ANESTHESIA (USUALLY NEUROMUSCULAR BLOCKAGE) | British Journal of Industrial Medicine. Vol. 23, Pg. 222, 1966. |
guinea pig | LD50 | oral | 21mg/kg (21mg/kg) | "Pflanzenschutz-und Schaedlingsbekaempfungsmittel: Abriss einer Toxikologie und Therapie von Vergiftungen," 2nd ed., Klimmer, O.R., Hattingen, Fed. Rep. Ger., Hundt-Verlag, 1971Vol. -, Pg. 127, 1971. | |
guinea pig | LDLo | skin | 180mg/kg (180mg/kg) | British Journal of Industrial Medicine. Vol. 23, Pg. 222, 1966. | |
guinea pig | LDLo | skin | 180mg/kg (180mg/kg) | BEHAVIORAL: MUSCLE WEAKNESS PERIPHERAL NERVE AND SENSATION: FLACCID PARALYSIS WITHOUT ANESTHESIA (USUALLY NEUROMUSCULAR BLOCKAGE) | British Journal of Industrial Medicine. Vol. 23, Pg. 222, 1966. |
mouse | LD50 | intraperitoneal | 7900ug/kg (7.9mg/kg) | BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) | British Journal of Industrial Medicine. Vol. 23, Pg. 222, 1966. |
mouse | LD50 | intravenous | 18mg/kg (18mg/kg) | U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#00648, | |
mouse | LD50 | oral | 81mg/kg (81mg/kg) | BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) | British Journal of Industrial Medicine. Vol. 23, Pg. 222, 1966. |
mouse | LD50 | subcutaneous | 44mg/kg (44mg/kg) | Guide to the Chemicals Used in Crop Protection. Vol. 6, Pg. 281, 1973. | |
quail | LD50 | oral | 100mg/kg (100mg/kg) | Journal of Reproduction and Fertility. Vol. 48, Pg. 371, 1976. | |
rabbit | LD50 | intraperitoneal | 10mg/kg (10mg/kg) | LUNGS, THORAX, OR RESPIRATION: DYSPNEA | Arzneimittel-Forschung. Drug Research. Vol. 13, Pg. 432, 1963. |
rabbit | LD50 | oral | 30mg/kg (30mg/kg) | "Wirksubstanzen der Pflanzenschutz und Schadlingsbekampfungsmittel," Perkow, W., Berlin, Verlag Paul Parey, 1971-1976Vol. -, Pg. -, 1971/1976. | |
rat | LD50 | intraperitoneal | 8500ug/kg (8.5mg/kg) | BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) | British Journal of Industrial Medicine. Vol. 23, Pg. 222, 1966. |
rat | LD50 | intravenous | 18mg/kg (18mg/kg) | Guide to the Chemicals Used in Crop Protection. Vol. 6, Pg. 281, 1973. | |
rat | LD50 | oral | 125mg/kg (125mg/kg) | Tin and Its Uses. Vol. 43, Pg. 9, 1958. | |
rat | LD50 | skin | 450mg/kg (450mg/kg) | Arzneimittel-Forschung. Drug Research. Vol. 19, Pg. 934, 1969. |
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