Furfuryl alcohol supplier

Name
Furfuryl alcohol
EINECS 202-626-1
CAS No. 98-00-0
Article Data451
CAS DataBase
Density 1.14 g/cm³
Solubility miscible with water
Melting Point -29 °C
Formula C₅H₆O₂
Boiling Point 169.999 °C at 760 mmHg
Molecular Weight 98.1014
Flash Point 65 °C
Transport Information UN 2874 6.1/PG 3
Appearance clear yellow liquid
Safety 23-36/37/39
Risk Codes 20/21/22
Molecular Structure
Hazard Symbols Xn
Synonyms 2-Furylcarbinol;alpha-Furylcarbinol;2-(Hydroxymethyl)furan;Furylcarbinol (VAN);Furfurylcarb;1/C5H6O2/c6-4-5-2-1-3-7-5/h1-3,6H,4H;Methanol, (2-furyl)-;2-Furfurylalkohol;5-17-03-00338 (Beilstein Handbook Reference);Furfuryl alcohol [UN2874] [Poison];.alpha.-Furylcarbinol;.alpha.-Furfuryl alcohol;2-Furanylmethanol;2-Furylmethanol;2-Furanmethanol;2-Furfuryl alcohol;Furfuralcohol;Furfurylalkohol;Furan-2-methanol;Furfurol (2-Furfuryl alcohol);Furylcarbinol;NCI-C56224;Furfuranol;2-Furfurylalkohol [Czech];FEMA No. 2491;
PSA 33.37000
LogP 0.77190

Synthetic route

: 98-01-1
furfural

: 98-00-0
(2-furyl)methyl alcohol

Conditions

Conditions	Yield
With Pt(3)Co(3)/C; hydrogen In water at 35℃; under 750.075 Torr; for 10h; Reagent/catalyst; Pressure; Temperature; Solvent; Concentration;	100%
With HRO/TiO2; hydrogen In water at 150℃; under 15001.5 Torr; for 3h;	100%
With hydrogen In isopropyl alcohol at 179.84℃; under 22502.3 Torr; for 1.25h; Reagent/catalyst;	100%

: C20H20BO8(1-)*Na(1+)

: 98-00-0
(2-furyl)methyl alcohol

Conditions

Conditions	Yield
With water	100%

: 98-01-1
furfural

A: 98-00-0
(2-furyl)methyl alcohol

B: 88-14-2
2-furanoic acid

Conditions

Conditions	Yield
Stage #1: furfural With potassium hydroxide for 0.0833333h; Cannizzaro Reaction; Milling; Inert atmosphere; Sealed tube; Green chemistry; Stage #2: With hydrogenchloride In water for 0.0833333h; Green chemistry;	A 99% B 99%
With TEA; magnesium bromide In dichloromethane at 20℃; for 48h; Cannizzaro reaction;	A 90% B n/a
With sodium hydroxide In water at 0 - 20℃; for 12h; Reagent/catalyst; Cannizzaro Reaction;	A 88% B 83%

: 611-13-2
2-furoic acid methyl ester

: 98-00-0
(2-furyl)methyl alcohol

Conditions

Conditions	Yield
With ethanol; [bis({2‐[bis(propan‐2‐yl)phosphanyl]ethyl})amine](borohydride)(carbonyl)(hydride)iron(II) at 100℃; for 24h; Inert atmosphere; Sealed tube; Darkness;	99%
With C13H34BFeNOP2; hydrogen In tetrahydrofuran at 100℃; under 22502.3 Torr; for 18h; Autoclave; Inert atmosphere;	95%
With [Ru(2-(methylthio)-N-[(pyridin-2-yl)methyl]ethan-1-amine)(triphenylphosphine)Cl2]; potassium tert-butylate; hydrogen In toluene at 80℃; under 37503.8 Torr; for 10h;	80%

: 67-47-0
5-hydroxymethyl-2-furfuraldehyde

: 14694-95-2
Wilkinson's catalyst

A: 98-00-0
(2-furyl)methyl alcohol

B: 15318-33-9, 16353-77-8, 13938-94-8
chlorocarbonylbis(triphenylphosphine)rhodium(I)

Conditions

Conditions	Yield
In further solvent(s) argon-filled glovebox, durene, bibenzyl, heating 24h at 70°C; detn. of products by GC;	A 99% B n/a
In further solvent(s) argon-filled glovebox, durene, bibenzyl, heating 2h at 70°C; detn. of products by GC;	A 48% B n/a

...Expand

: 65148-89-2
2-(furan-2-ylmethoxy)tetrahydro-2H-pyran

: 98-00-0
(2-furyl)methyl alcohol

Conditions

Conditions	Yield
With chloral hydrate In hexane at 0 - 5℃; for 0.5h; Inert atmosphere;	98%
With methanol; Montmorillonite K-10 clay at 20℃; Methanolytic deprotection;	95%
With zinc tetrafluoroborate In methanol; dichloromethane; water at 20℃; for 0.75h;	92%

: 614-99-3
Ethyl 2-furoate

: 98-00-0
(2-furyl)methyl alcohol

Conditions

Conditions	Yield
With C30H34Cl2N2P2Ru; potassium methanolate; hydrogen In tetrahydrofuran at 100℃; under 38002.6 - 76005.1 Torr; for 5h; Glovebox; Autoclave;	97%
With ethanol; ruthenium(bis[2‐(ethylsulfanyl)ethyl]amine)(dichloro)(triphenylphosphine); potassium tert-butylate In toluene at 80℃; for 16h;	95%
With ethylmagnesium bromide; poly(methylhydrosiloxane); bis(cyclopentadienyl)titanium dichloride In tetrahydrofuran; diethyl ether for 17.5h; Ambient temperature;	89%

: 98-01-1
furfural

: 62-53-3
aniline

A: 98-00-0
(2-furyl)methyl alcohol

B: 4439-56-9
N-(furan-2-ylmethyl)aniline

Conditions

Conditions	Yield
Stage #1: furfural; aniline at 25℃; for 0.166667h; Stage #2: With sodium tetrahydroborate; toluene-4-sulfonic acid at 25℃; for 0.166667h;	A n/a B 97%
With hydrogen; edetate disodium; iron(II) sulfate In water at 150℃; under 20686.5 Torr; for 12h; Title compound not separated from byproducts.;	A 7 % Chromat. B 72 % Chromat.
Stage #1: furfural at 40℃; for 0.166667h; Stage #2: aniline With sodium tetrahydroborate at 40℃; for 3h; Stage #3: With methanol at 0℃; for 0.5h; chemoselective reaction;

...Expand

: 121389-55-7
tert-butyl(furan-2-ylmethoxy)dimethylsilane

: 98-00-0
(2-furyl)methyl alcohol

Conditions

Conditions	Yield
With Decaborane In methanol at 20℃; for 0.5h;	96%
With sodium hydride In N,N,N,N,N,N-hexamethylphosphoric triamide at 25℃; for 8h;	93%
With acetyl chloride In methanol at 20℃; for 0.583333h;	85%
With tin(ll) chloride In water for 5h; Heating;	85%
With acetonyltriphenylphosphonium bromide In methanol; dichloromethane at 20℃; for 0.166667h;	83%

: 67-47-0
5-hydroxymethyl-2-furfuraldehyde

: 98-00-0
(2-furyl)methyl alcohol

Conditions

Conditions	Yield
With palladium nanoparticles deposited on porous SBA-15 In cyclohexane at 130℃; for 12h; Reagent/catalyst; Temperature; Solvent; Time; Molecular sieve;	96%
With palladium/alumina In hexane at 145℃; under 45004.5 Torr; for 4h; Catalytic behavior; Reagent/catalyst; Green chemistry;	95.6%
With zirconium hydroxide; ethanol at 150℃; Flow reactor;	84%

: C13H21BO2

: 98-00-0
(2-furyl)methyl alcohol

Conditions

Conditions	Yield
With sodium hydroxide In water Inert atmosphere;	95%

: 98-01-1
furfural

A: 98-00-0
(2-furyl)methyl alcohol

B: 4464-77-1, 69314-24-5, 69314-25-6, 116204-42-3
1,2-di-furan-2-yl-ethane-1,2-diol

Conditions

Conditions	Yield
With potassium hydroxide at 20℃; under 760.051 Torr; Reagent/catalyst; Electrochemical reaction; Green chemistry;	A n/a B 94%
With sodium hydroxide; aluminium In methanol; water for 0.166667h; pinacol coupling; microwave irradiation;	A 10% B 70%
With acetic acid; zinc In water at 20℃; for 0.333333h; Green chemistry;	A 39% B 51%
With naphthalene; lithium; manganese(ll) chloride In tetrahydrofuran at 50 - 54℃; for 1h; sonication;	A 12% B 37%
With manganese; 2,4,6-collidine hydrochloride In tetrahydrofuran; water at 27℃; for 24h; Inert atmosphere; Schlenk technique; Overall yield = 95 %; Overall yield = 92 mg; chemoselective reaction;

: 14694-95-2
Wilkinson's catalyst

: 57-48-7, 87-79-6, 87-81-0, 551-68-8, 3615-39-2, 3615-56-3, 6035-50-3, 7776-48-9, 16354-64-6, 17598-81-1, 17598-82-2, 23140-52-5, 30237-26-4, 65732-90-3, 73952-10-0, 73952-11-1, 139686-85-4
sorbose

A: 98-00-0
(2-furyl)methyl alcohol

B: 15318-33-9, 16353-77-8, 13938-94-8
chlorocarbonylbis(triphenylphosphine)rhodium(I)

C: 87-99-0
XYLITOL

: 4144-94-9, 4435-50-1, 33818-52-9, 41167-49-1, 61913-75-5, 61913-76-6, 122920-28-9, 138257-33-7
DL-1-deoxy-threitol

Conditions

Conditions	Yield
In further solvent(s) argon-filled glovebox, durene, bibenzyl, heating 6h;	A 59% B 94% C 1% D 5%

...Expand

: 2-(furan-2-ylmethoxy)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

: 98-00-0
(2-furyl)methyl alcohol

Conditions

Conditions	Yield
With silica gel In ethyl acetate; Petroleum ether	94%
With water; silica gel In methanol at 60℃; Inert atmosphere;	88%
In methanol at 20℃; for 6h; Inert atmosphere; Glovebox;	74%

: 67-47-0
5-hydroxymethyl-2-furfuraldehyde

A: 534-22-5
2-methylfuran

B: 98-00-0
(2-furyl)methyl alcohol

C: 625-86-5
2,5-dimethylfuran

Conditions

Conditions	Yield
With hydrogen In 1,4-dioxane at 180℃; under 11251.1 Torr; for 2h; Catalytic behavior;	A n/a B n/a C 93.4%

...Expand

: 2846-62-0
(furan-2-ylmethoxy)trimethylsilane

: 98-00-0
(2-furyl)methyl alcohol

Conditions

Conditions	Yield
With 1,4-diazabicyclo[2.2.2]octane tribromide supported on magnetic Fe3O4 nanoparticles In methanol at 20℃; for 0.0833333h;	93%
With water; boric acid at 20℃; for 1h;	87%
With aminosulfonic acid; water at 20℃; for 2h;	85%

: 98-01-1
furfural

: 108-91-8
cyclohexylamine

A: 98-00-0
(2-furyl)methyl alcohol

B: 4439-54-7
N-cyclohexan-1-(furan-2-yl)methanamine

C: 69819-61-0
N-(furan-2-ylmethylene)cyclohexanamine

D: N-((tetrahydrofuran-2-yl)methyl)cyclohexanamine

Conditions

Conditions	Yield
With hydrogen; Pd on polytris(hydroxymethyl)melamine In ethanol at 45℃; under 757.6 Torr; for 1h; Rate constant; Kinetics; activation energy, other catalysts: Pd/C, palladium on aminated and chloromethylated styrene-divinylbenzene copolymer anion exchange resin AV-17-8 matrix, other solvents: 1-propanol, 2-propanol, 1-butanol, 2-methyl-2-propanol, toluene, hexane;	A n/a B n/a C n/a D 92%

...Expand

: 1899-24-7
5-bromo-2-furancarboxaldehyde

A: 98-00-0
(2-furyl)methyl alcohol

B: 27230-58-6
(5-bromo-2-furan-2-yl)methanol

Conditions

Conditions	Yield
With lithium aluminium tetrahydride In diethyl ether at 0℃; for 2h;	A 9% B 91%

: 67-47-0
5-hydroxymethyl-2-furfuraldehyde

A: 98-00-0
(2-furyl)methyl alcohol

B: 823-82-5
2,5-diformylfurane

Conditions

Conditions	Yield
With carbon dioxide; palladium/alumina In tetrahydrofuran at 145℃; under 45004.5 Torr; for 4h; Catalytic behavior; Reagent/catalyst; Green chemistry;	A 90.9% B 5.5%
With Pd/γ-Al2O3 In 1,4-dioxane at 160℃; for 16h; Inert atmosphere; Autoclave;

: 98-01-1
furfural

A: 97-99-4
Tetrahydrofurfuryl alcohol

B: 98-00-0
(2-furyl)methyl alcohol

Conditions

Conditions	Yield
With hydrogen at 90℃; under 15001.5 Torr; Reagent/catalyst;	A 90.5% B 8.4%
With hydrogen In butan-1-ol at 40℃; under 30003 Torr; for 7h; Catalytic behavior; Reagent/catalyst;	A 12% B 85%
With hydrogen In tetrahydrofuran at 175℃; under 7500.75 Torr; for 8h; Catalytic behavior; Pressure; Temperature; Time; chemoselective reaction;	A 10% B 79.5%

: 58-86-6
D-xylose

: 98-00-0
(2-furyl)methyl alcohol

Conditions

Conditions	Yield
With dodecatungstosilic acid; formic acid In tert-butyl alcohol for 3h; Kinetics; Activation energy; Reagent/catalyst; chemoselective reaction;	90.1%
Multi-step reaction with 2 steps 1.1: formic acid / tetrahydrofuran; dimethyl sulfoxide / 150 °C 2.1: Cp*Ir(TsDPEN); triethylamine / tetrahydrofuran; dimethyl sulfoxide / 0.08 h / 40 °C 2.2: 40 °C View Scheme
Multi-step reaction with 2 steps 1: sodium chloride; aluminum (III) chloride / iso-butanol / 140 °C / Autoclave 2: isopropyl alcohol; iron oxide / 5 h / 160 °C / Autoclave View Scheme

: 98-01-1
furfural

: 67-63-0
isopropyl alcohol

A: 98-00-0
(2-furyl)methyl alcohol

B: 623-15-4
4-(furan-2-yl)but-3-en-2-one

C: 113984-01-3
isopropopyl (2-methylfuran) ether

Conditions

Conditions	Yield
With iron oxide at 160℃; for 5h; Reagent/catalyst; Temperature; Autoclave;	A 90.1% B n/a C n/a
at 219.84℃; under 760.051 Torr; Temperature; Flow reactor; Inert atmosphere;
With 2 wt% MgO loaded on amorphous silica at 159.84℃; under 3750.38 Torr; for 12h; Reagent/catalyst; Inert atmosphere;	A 9.2 %Chromat. B 9.2 %Chromat. C 14.2 %Chromat.

...Expand

: 88-14-2
2-furanoic acid

: 98-00-0
(2-furyl)methyl alcohol

Conditions

Conditions	Yield
With strain of the zygomycete fungus S. racemosum MUT 770 In dimethyl sulfoxide for 72h; Enzymatic reaction;	90%
Stage #1: 2-furanoic acid With trimethylphenylsilane; C69H55ClP3Ru In tetrahydrofuran at 60℃; for 16h; Glovebox; Stage #2: With hydrogenchloride In tetrahydrofuran; water at 20℃; for 1h; Glovebox; chemoselective reaction;	65%
With sodium tetrahydroborate; N,N-dimethylchloromethyleniminium chloride 1.) acetonitrile, THF, 0 deg C, 1 h; 2.) acetonitrile, THF, N,N-dimethylformamide, -78 deg C to -20 deg C, 2 h; Yield given. Multistep reaction;

: 623-17-6
furfurylacetate

: 98-00-0
(2-furyl)methyl alcohol

Conditions

Conditions	Yield
With lipase B from Candida antarctica immobilized on Immobead 150 In aq. phosphate buffer at 40℃; for 0.333333h; pH=7.4;	89%
With methanol; potassium permanganate; trimethylsulphonium iodide at 25℃; under 760.051 Torr; chemoselective reaction;	80%
With methanol; potassium permanganate at 25℃; chemoselective reaction;	78%
With [t-Bu2SnOH(Cl)]2 In methanol at 30℃; for 24h; Deacetylation;	82 % Chromat.
[t-Bu2SnOH(Cl)]2 In methanol at 30℃; for 24h;	82 % Chromat.

: 613-75-2
(furan-2-yl)methylene diacetate

: 98-00-0
(2-furyl)methyl alcohol

Conditions

Conditions	Yield
With sodium tetrahydroborate; nickel(II) chloride hexahydrate In methanol at 20℃; for 4h; chemoselective reaction;	86%

: 498-60-2
furan-3-carboxaldehyde

: 98-00-0
(2-furyl)methyl alcohol

Conditions

Conditions	Yield
With C22H21ClN3RuS2(1+)*F6P(1-); isopropyl alcohol; potassium hydroxide In acetonitrile at 80℃; for 3h; Catalytic behavior; Concentration; Reagent/catalyst;	85%

: C11H12O2Si

: 98-00-0
(2-furyl)methyl alcohol

Conditions

Conditions	Yield
With sodium hydroxide In water Schlenk technique; Inert atmosphere;	85%
With sodium hydroxide In water

: 98-01-1
furfural

A: 534-22-5
2-methylfuran

B: 98-00-0
(2-furyl)methyl alcohol

Conditions

Conditions	Yield
With hydrogen at 160℃; under 760.051 Torr; for 24h; Reagent/catalyst; Temperature;	A n/a B 84.7%
With hydrogen; CuO on Al2O3 at 250℃; Product distribution; gas phase, flow reactor, oth. temperature, var. ratio of reactants;	A 69.7% B 4.2%
With hydrogen In isopropyl alcohol at 200℃; under 22502.3 Torr; Autoclave;	A 66% B 6%

: 17357-38-9
S-phenyl furan-2-carbothioate

: 98-00-0
(2-furyl)methyl alcohol

Conditions

Conditions	Yield
With zinc(II) tetrahydroborate In tetrahydrofuran; diethyl ether for 96h; Ambient temperature;	84%

: 98-00-0
(2-furyl)methyl alcohol

: 97-99-4
Tetrahydrofurfuryl alcohol

Conditions

Conditions	Yield
With 3% Pd/C; hydrogen In isopropyl alcohol at 219.84℃; under 25858.1 Torr; for 5h; Inert atmosphere;	100%
With hydrogen In isopropyl alcohol at 25℃; under 7500.75 Torr; for 3h; Green chemistry;	100%
With palladium on activated charcoal; ammonia; hydrogen In tetrahydrofuran at 160℃; for 4h; Reagent/catalyst; Autoclave;	100%

: 98-00-0
(2-furyl)methyl alcohol

: 18162-48-6
tert-butyldimethylsilyl chloride

: 121389-55-7
tert-butyl(furan-2-ylmethoxy)dimethylsilane

Conditions

Conditions	Yield
With dmap; triethylamine In dichloromethane at -78 - 20℃;	100%
With 1H-imidazole In N,N-dimethyl-formamide	99%
With 1H-imidazole In N,N-dimethyl-formamide at 23℃; for 0.5h;	97%

: 98-00-0
(2-furyl)methyl alcohol

: 106-96-7
propargyl bromide

: 32904-79-3
2-((prop-2-yn-1-yloxy)methyl)furan

Conditions

Conditions	Yield
Stage #1: (2-furyl)methyl alcohol With sodium hydride In N,N-dimethyl-formamide at 0℃; for 1.5h; Stage #2: propargyl bromide In N,N-dimethyl-formamide at 20℃; Reagent/catalyst;	100%
With para-chlorotoluene; lithium In tetrahydrofuran at -35 - 20℃; for 10h; Heating / reflux;	93%
Stage #1: (2-furyl)methyl alcohol With sodium hydride In N,N-dimethyl-formamide at 0℃; for 0.166667h; Stage #2: propargyl bromide In N,N-dimethyl-formamide; toluene at 23℃; for 4h;	86%

: 98-00-0
(2-furyl)methyl alcohol

: 98-01-1
furfural

Conditions

Conditions	Yield
With bis(2,2'-bipyridyl) copper(II) permanganate In acetone for 0.1h; Ambient temperature;	100%
With 4 A molecular sieve; tetrabutylammonium perchlorate; Ru-Cu-Al-hydrotalcite In toluene at 60℃; for 3h;	100%
With potassium carbonate In toluene at 70℃; for 2.5h; Reagent/catalyst;	100%

: 98-00-0
(2-furyl)methyl alcohol

: 22536-63-6
2-chloro-4-methoxypyrimidine

: 2-(Furan-2-ylmethoxy)-4-methoxy-pyrimidine

Conditions

Conditions	Yield
With sodium alkoxide	100%

: 98-00-0
(2-furyl)methyl alcohol

: potassium 4-(methoxy)phenyltrifluoroborate

: 2-(4-methoxyphenoxymethyl) furan

Conditions

Conditions	Yield
Stage #1: potassium 4-(methoxy)phenyltrifluoroborate With dmap; copper diacetate; 4 A molecular sieve In dichloromethane at 20℃; for 0.0833333h; Stage #2: (2-furyl)methyl alcohol With oxygen In dichloromethane at 20℃; for 24h;	100%

: 98-00-0
(2-furyl)methyl alcohol

: 819813-95-1
2-nitro-N-[2-(tetrahydropyran-2-yloxy)ethyl]benzenesulfonamide

: 819813-96-2
N-furfuryl-2-nitro-N-[2-(tetrahydropyran-2-yloxy)ethyl]benzenesulfonamide

Conditions

Conditions	Yield
With triphenylphosphine; diethylazodicarboxylate In toluene at 20℃; for 1h;	100%

: 504-29-0
2-aminopyridine

: 98-00-0
(2-furyl)methyl alcohol

: 46230-01-7
furan-2-ylmethyl-pyridin-2-yl-amine

Conditions

Conditions	Yield
With dichloro-[1,3-bis(4-tert-butylbenzyl)perhydrobenzimidazol-2-ylidene](p-cymene)ruthenium(II); potassium tert-butylate at 120℃; for 24h; Reagent/catalyst; Inert atmosphere; Schlenk technique; Sealed tube;	100%
With [RuCl(N,N-dimethyl-1-[6-(4'-methylphenyl)pyridin-2-yl]methaneamine(-H))(dppb)]; potassium tert-butylate In tetrahydrofuran; toluene at 110℃; for 24h; Inert atmosphere; Molecular sieve;	81%
With C46H45ClN4PRu(1+)*F6P(1-); potassium 2-methylbutan-2-olate In toluene at 150℃; for 18h;	77%

: 98-00-0
(2-furyl)methyl alcohol

: 62-53-3
aniline

: 4439-56-9
N-(furan-2-ylmethyl)aniline

Conditions

Conditions	Yield
With dichloro-[1,3-bis(4-methylbenzyl)perhydrobenzimidazol-2-ylidene](p-cymene)ruthenium(II); potassium tert-butylate at 120℃; for 24h; Reagent/catalyst; Inert atmosphere; Schlenk technique; Sealed tube;	100%
With titanium triflimide complex; pyridine ligand In toluene at 100℃; for 2h; Microwave irradiation;	98%
With C36H35IrN2P(1+)*C32H12BF24(1-); potassium tert-butylate In diethylene glycol dimethyl ether at 50℃; for 24h; Inert atmosphere;	94%

: 98-00-0
(2-furyl)methyl alcohol

: 546-68-9
titanium(IV) isopropylate

: 1346523-07-6
C16H24O6Ti

Conditions

Conditions	Yield
In cyclohexane Inert atmosphere; Reflux;	100%
In cyclohexane for 0.5h; Schlenk technique; Inert atmosphere; Reflux;	100%

: 98-00-0
(2-furyl)methyl alcohol

: 79-04-9
chloroacetyl chloride

: 51618-39-4
(furan-2-yl)methyl 2-chloroacetate

Conditions

Conditions	Yield
With pyridine In diethyl ether at 0℃;	100%

: 98-00-0
(2-furyl)methyl alcohol

: 95-68-1
2,4-Xylidine

: C13H15NO

Conditions

Conditions	Yield
With dichloro-[1,3-bis(4-isopropylbenzyl)perhydrobenzimidazol-2-ylidene](p-cymene)ruthenium(II); potassium tert-butylate at 120℃; for 24h; Reagent/catalyst; Inert atmosphere; Schlenk technique; Sealed tube;	100%
With dichloro(1‐(2‐vinyloxyethyl)benzimidazole)‐(p‐cymene)ruthenium(II); potassium tert-butylate at 120℃; for 24h; Reagent/catalyst; Schlenk technique; Inert atmosphere;
With [dichloro‑[1,3‑bis(4‑phenylbenzyl)perhydrobenzimidazol‑2‑ylidene](η6-p‑cymene)ruthenium(II)]; potassium tert-butylate In neat (no solvent) at 120℃; for 24h; Reagent/catalyst; Inert atmosphere; Schlenk technique; Sealed tube;	100 %Chromat.
With potassium tert-butylate; C46H56Cl2N2Ru In neat (no solvent) at 120℃; for 24h; Reagent/catalyst; Inert atmosphere; Schlenk technique; Sealed tube;	76 %Chromat.

: 98-00-0
(2-furyl)methyl alcohol

: 4-methyl-2-oxo-2H-chromen-7-yl carbonochloridate

: furan-2-ylmethyl (4-methyl-2-oxo-2H-chromen-7-yl) carbonate

Conditions

Conditions	Yield
With pyridine In dichloromethane at 0 - 20℃; Inert atmosphere;	100%

: 98-00-0
(2-furyl)methyl alcohol

: 123-76-2
levulinic acid

: furfuryl levulinate

Conditions

Conditions	Yield
With dmap; dicyclohexyl-carbodiimide In tetrahydrofuran at 20℃; for 3h;	100%

: 98-00-0
(2-furyl)methyl alcohol

: 67-56-1
methanol

Nafion-H: Nafion-H

: 624-45-3
levulinic acid methyl ester

Conditions

Conditions	Yield
at 20 - 80℃; for 6h; Temperature; Reagent/catalyst;	99.32%

...Expand

: 98-00-0
(2-furyl)methyl alcohol

: 71-36-3
butan-1-ol

: 2052-15-5
butyl levulinate

Conditions

Conditions	Yield
With 5-sulfosalicylic Acid at 118℃; under 760.051 Torr; for 10h; Catalytic behavior; Temperature;	99.3%
With toluene-4-sulfonic acid at 80℃; for 4h; Reagent/catalyst; Temperature; Inert atmosphere;	94.2%
With [BmimSO3H]3PW12O40; water at 110℃; for 12h;	93%

: 98-00-0
(2-furyl)methyl alcohol

: 109-87-5
Dimethoxymethane

: 126825-52-3
2-((methoxymethoxy)methyl)furan

Conditions

Conditions	Yield
With Mo(VI)/ZrO2 at 40℃; for 0.333333h; Reagent/catalyst; Reflux; Inert atmosphere; Green chemistry;	99.2%

: 98-00-0
(2-furyl)methyl alcohol

: 75-15-0
carbon disulfide

: 89712-86-7
potassium O-furfuryl dithiocarbonate

Conditions

Conditions	Yield
With potassium hydroxide In diethyl ether at 20℃; for 12h;	99%
With potassium hydroxide In acetone	67%
With potassium hydroxide
With potassium hydroxide In tetrahydrofuran at 20℃; under 760.051 Torr;
With potassium hydroxide

: 98-00-0
(2-furyl)methyl alcohol

: 108-24-7
acetic anhydride

: 623-17-6
furfurylacetate

Conditions

Conditions	Yield
With tin(IV) tetraphenylporphyrin perchlorate at 20℃; for 0.0833333h;	99%
tetradecafluorohexane at 20℃; for 6h;	99%
With [{CpHf(OH2)3}2(μ2-OH)2][OSO2C8F17]44H202THF at 20℃; for 0.0833333h; chemoselective reaction;	98%

: 98-00-0
(2-furyl)methyl alcohol

: 88-14-2
2-furanoic acid

Conditions

Conditions	Yield
With manganese(IV) oxide; oxygen; sodium hydrogencarbonate In water at 100℃; under 7500.75 Torr; for 24h;	99%
With oxygen; 1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazolium chloride; sodium t-butanolate In dichloromethane at 20℃; for 30h; Reagent/catalyst; Molecular sieve;	95%
With sodium carbonate In water at 30℃; for 40h; Wavelength; Irradiation;	93%

: 98-00-0
(2-furyl)methyl alcohol

: 922-67-8
propynoic acid methyl ester

: methyl (E)-3-(furan-2-ylmethoxy)acrylate

Conditions

Conditions	Yield
With 1,4-diaza-bicyclo[2.2.2]octane In dichloromethane	99%
With tributylphosphine In dichloromethane for 0.0833333h; Ambient temperature;	98%

: 98-00-0
(2-furyl)methyl alcohol

: 59995-47-0, 59995-49-2, 61305-27-9, 61740-29-2
4-Hydroxycyclopent-2-enone

Conditions

Conditions	Yield
With sodium hydroxide In water at 240℃; Temperature; Reagent/catalyst; Solvent; Autoclave;	99%
With sodium hydroxide In water at 240℃; for 0.02h; Catalytic behavior; Reagent/catalyst; Solvent; Temperature; Autoclave;	99%
With sodium hydroxide In water at 240℃; for 0.02h; Reagent/catalyst; Temperature; Solvent; Concentration;	99%

: 98-00-0
(2-furyl)methyl alcohol

: 999-97-3
1,1,1,3,3,3-hexamethyl-disilazane

: 2846-62-0
(furan-2-ylmethoxy)trimethylsilane

Conditions

Conditions	Yield
With phenyltrimethylammonium tribromide In dichloromethane at 20℃; for 0.166667h; chemoselective reaction;	99%
With lithium perchlorate; silica gel In dichloromethane at 20℃; for 0.0833333h;	96%
With Nafion SAC-13 at 20℃; for 0.0833333h;	96%

: 98-00-0
(2-furyl)methyl alcohol

: 2325-27-1
N-phenyltriphenyliminophosphorane

: 4439-56-9
N-(furan-2-ylmethyl)aniline

Conditions

Conditions	Yield
With cesium hydroxide; palladium diacetate In toluene at 150℃; for 48h; Aza-Wittig reaction;	99%
With 1,1'-bis-(diphenylphosphino)ferrocene; potassium carbonate; bis(1,5-cyclooctadiene)diiridium(I) dichloride In toluene at 110℃; for 24h; indirect aza-Wittig reaction;	71%

: 98-00-0
(2-furyl)methyl alcohol

: 60750-38-1
1,2,3,4-tetrahydro-1,6-dimethyl-2-oxo-4-phenylpyrimidine-5-carboxylic acid

: 95928-47-5
Furfuryl Ester of 1,6-Dimethyl-4-phenyl-2-oxo-1,2,3,4-tetrahydropyrimidine-5-carboxylic Acid

Conditions

Conditions	Yield
With di-isopropyl azodicarboxylate; triphenylphosphine In tetrahydrofuran at 20℃; for 0.00833333h; Mitsunobu esterification;	99%

Furfuryl alcohol Chemical Properties

The Molecular Structure of Furfuryl alcohol (CAS NO.98-00-0):

Empirical Formula: C₅H₆O₂
Molecular Weight: 98.0999
IUPAC Name: furan-2-ylmethanol
Product Categories: Furans;alcohol Flavor
Appearance: clear yellow liquid
Nominal Mass: 98 Da
Average Mass: 98.0999 Da
Monoisotopic Mass: 98.036779 Da
Index of Refraction: 1.492
Molar Refractivity: 25 cm³
Molar Volume: 86 cm³
Surface Tension: 38.8 dyne/cm
Density: 1.14 g/cm³
Flash Point: 65 °C
Enthalpy of Vaporization: 42.98 kJ/mol
Boiling Point: 170 °C at 760 mmHg
Vapour Pressure: 1.01 mmHg at 25°C
Melting point: -29 ºC
Refractive index: 1.485-1.487
Water solubility: MISCIBLE
InChI
InChI=1/C5H6O2/c6-4-5-2-1-3-7-5/h1-3,6H,4H2
Smiles
Synonyms: c1(ccco1)CO ; AI3-01171 ; BRN 0106291 ; CCRIS 2922 ; NCI-C56224 ; NSC 8843 ; UNII-D582054MUH ; EINECS 202-626-1 ; FEMA No. 2491 ; UN2874 ; HSDB 711

Furfuryl alcohol Uses

Furfuryl alcohol (CAS NO.98-00-0) has been used in rocketry as a fuel which ignites hypergolically (immediately and energetically in contact) with white fuming nitric acid or red fuming nitric acid oxidizer.The use of hypergolics avoids the need for an igniter. Furfuryl alcohol (CAS NO.98-00-0) is probably a BK channel agonist.and may be used as a food additive.

Furfuryl alcohol Production

Furfuryl alcohol (CAS NO.98-00-0) is manufactured industrially by the catalytic reduction of FURFURAL which is obtained from corncobs and sugar cane bagasse. It finds use as a solvent, but is primarily used as an ingredient in the manufacture of various chemical products such as foundry resins, adhesives, and wetting agents.

Furfuryl alcohol Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
mammal (species unspecified)	LD50	oral	360mg/kg (360mg/kg)		Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 39(4), Pg. 86, 1974.
mouse	LCLo	inhalation	597ppm/6H (597ppm)		"Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969Vol. -, Pg. 280, 1969.
mouse	LD50	oral	160mg/kg (160mg/kg)		Biochemical Journal. Vol. 34, Pg. 1196, 1940.
mouse	LD50	unreported	338mg/kg (338mg/kg)		Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 55(6), Pg. 73, 1990.
rabbit	LD50	intravenous	650mg/kg (650mg/kg)		Federation Proceedings, Federation of American Societies for Experimental Biology. Vol. 8, Pg. 294, 1949.
rabbit	LD50	skin	400mg/kg (400mg/kg)	BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD	"Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969Vol. -, Pg. 280, 1969.
rabbit	LD50	unreported	632mg/kg (632mg/kg)		Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 55(6), Pg. 73, 1990.
rat	LC50	inhalation	233ppm/4H (233ppm)		American Industrial Hygiene Association Journal. Vol. 19, Pg. 91, 1958.
rat	LD50	intraperitoneal	650mg/kg (650mg/kg)		Raw Material Data Handbook, Vol.1: Organic Solvents, 1974. Vol. 1, Pg. 64, 1974.
rat	LD50	oral	177mg/kg (177mg/kg)	BEHAVIORAL: EXCITEMENT BEHAVIORAL: ATAXIA LUNGS, THORAX, OR RESPIRATION: CYANOSIS	Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 25(9), Pg. 52, 1981.
rat	LD50	skin	3825mg/kg (3825mg/kg)		Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 25(9), Pg. 52, 1981.
rat	LD50	subcutaneous	85mg/kg (85mg/kg)	BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD	"Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969Vol. -, Pg. 280, 1969.
rat	LD50	unreported	460mg/kg (460mg/kg)		Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 55(6), Pg. 73, 1990.

Furfuryl alcohol Safety Profile

Hazard Codes: Harmful Xn
Risk Statements: 20/21/22
R20/21/22: Harmful by inhalation, in contact with skin and if swallowed
Safety Statements: 23-36/37/39
S23: Do not breathe vapour
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection
RIDADR: UN 2874 6.1/PG 3
WGK Germany: 1
RTECS: LU9100000
F 8: Photosensitive
HazardClass: 6.1
PackingGroup: III

Furfuryl alcohol Specification

Furfuryl alcohol (CAS NO.98-00-0) is also called as 2-Furancarbinol ; 2-Furanmethanol ; 2-Furfuryl alcohol ; 2-Furfurylalkohol [Czech] ; 2-Furylcarbinol ; 5-Hydroxymethylfuran ; 2-Hydroxymethylfuran ; Furfuranol ; Furfurylcarb ; Furylcarbinol (VAN) ; Methanol, (2-furyl)- ; alpha-Furylcarbinol . Furfuryl alcohol is an organic compound containing a furan substitited with a hydroxymethyl group. It is a clear amber liquid with a faint burning odor and a bitter taste. It is soluble in common organic solvents. Upon treatment with acids, heat and/or catalysts, furfuryl alcohol can be made to polymerize into a resin, poly .

Product Name

Furfuryl alcohol

Synthetic route

Furfuryl alcohol Chemical Properties

Furfuryl alcohol Uses

Furfuryl alcohol Production

Furfuryl alcohol Toxicity Data With Reference

Furfuryl alcohol Safety Profile

Furfuryl alcohol Specification

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