DL-phenylalanine methyl ester
1-O-(glycylglycylglycyl)-β-D-glucopyranose
A
glycine-glycine-glycine
B
glycylglycylglycyl-D,L-phenylalanine methyl ester
Conditions | Yield |
---|---|
With 4-methyl-morpholine In N,N-dimethyl-formamide at 38℃; for 72h; | A 67% B 92% |
With 4-methyl-morpholine In N,N-dimethyl-formamide at 38℃; for 72h; | A 67% B 28% |
[2-(2-Benzyloxycarbonylamino-acetylamino)-acetylamino]-acetic acid
glycine-glycine-glycine
Conditions | Yield |
---|---|
With acetic acid In methanol Ambient temperature; electrolysis: palladium/graphite cathode, -0.6 V to -1.0 V SCE, current density = 15 mA/cm2, catholyte: NaClO4; | 90% |
With cell extract of Sphingomonas paucimobilis SC 16113 In water at 42℃; for 20h; Enzymatic reaction; | 23 % Chromat. |
Conditions | Yield |
---|---|
Stage #1: tetrabutylphosphonium glycinate for 3h; Inert atmosphere; Stage #2: glycine ethyl ester hydrochloride In chloroform at 60℃; for 24h; Stage #3: With acetic acid In chloroform at 20℃; for 10h; | 66% |
glycine
A
glycine-glycine-glycine
B
N-carbamoylmethyl-glycine
C
H-Gly-NH2
Conditions | Yield |
---|---|
With 1,2,4-Triazole; Sodium trimetaphosphate; magnesium chloride In water for 20h; Ambient temperature; var.reag.: pyrrole, pyrrolidine, pyrrazole, imidazole, tetrazole, adenine,quanine, thyamine, uracile, adenosine, quanosine,thymidine, uridine and add of MgCl2: var. pH, time and temp.; | A 5.5% B 23.6% C 3.2% |
Conditions | Yield |
---|---|
With ammonia; water at 25℃; |
N-carboxy-glycyl=>glycyl=>glycine
glycine-glycine-glycine
Conditions | Yield |
---|---|
With borax; sodium dihydrogenphosphate at 26℃; Equilibrium constant; |
1-O-(glycylglycylglycyl)-β-D-glucopyranose mono-oxalate
A
β-D-glucose
B
glycine-glycine-glycine
Conditions | Yield |
---|---|
With β-D-glucosidase; nitrate buffer In water at 37℃; for 6h; |
1-O-(glycylglycylglycyl)-β-D-glucopyranose
A
β-D-glucose
B
glycine-glycine-glycine
Conditions | Yield |
---|---|
In water for 96h; decompn. with/without 0.1M HCl; |
glycine
A
glycine-glycine-glycine
B
tetraglycine
C
pentaglycine
D
glycylglycine
Conditions | Yield |
---|---|
titanium(IV) oxide In water for 24h; Product distribution; Irradiation; reactions between var. conditions and with var. semiconductor photocatalysts with and without platinization; | A 0.00021 mmol B 0.00018 mmol C 0.00010 mmol D 0.01026 mmol |
Conditions | Yield |
---|---|
With copper dichloride In water at 80 - 90℃; Mechanism; Product distribution; Rate constant; other alkali and alkaline-earth-metal cations; | |
Cu(2+)-doted montmorillonite In water at 80℃; Product distribution; evaporation during 24 h, 4-5 cycles; also by constant volume; natural montmorillonite as catalyst, diglycine as substrate, other products; |
glycine
A
glycine-glycine-glycine
B
glycylglycine
D
N-(carboxymethyl)phophoroamidate
Conditions | Yield |
---|---|
With sodium hydroxide; Sodium trimetaphosphate In water for 96h; Product distribution; Ambient temperature; variation of mixing ratio of the starting materials, pH, reaction time; | A n/a B n/a C 25.3 % Chromat. D 22.7 % Chromat. |
With sodium hydroxide; Sodium trimetaphosphate In water for 96h; Ambient temperature; pH=12; | A n/a B n/a C 25.3 % Chromat. D 22.7 % Chromat. |
Conditions | Yield |
---|---|
at 100℃; |
glycine-glycine-glycine
Conditions | Yield |
---|---|
mit Hefe-Polypeptidase bei pH 7.0; |
glycine-glycine-glycine
Conditions | Yield |
---|---|
With palladium; acetic acid at 80℃; Hydrogenation; |
glycine-glycine-glycine
Conditions | Yield |
---|---|
With ethanol; hydrazine hydrate |
glycine-glycine-glycine
Conditions | Yield |
---|---|
With sodium hydrogencarbonate; platinum Hydrogenation.Erhitzen des Reaktionsprodukts mit H2O; |
glycine-glycine-glycine
Conditions | Yield |
---|---|
With hydrogen bromide; acetic acid |
glycine-glycine-glycine
Conditions | Yield |
---|---|
With hydrogen bromide; acetic acid |
glycine-glycine-glycine
Conditions | Yield |
---|---|
With lithium hydroxide; water; 1,2-diamino-benzene |
glycine-glycine-glycine
Conditions | Yield |
---|---|
With barium dihydroxide |
Conditions | Yield |
---|---|
dl-leucyl-diglycyl-glycine; |
N-benzyloxycarbonylglycylglycylglycylglycine
A
glycine-glycine-glycine
B
N-(Benzyloxycarbonyl)glycine
Conditions | Yield |
---|---|
Hydrolysis; |
glycine
A
Glycine anhydride
B
glycine-glycine-glycine
C
tetraglycine
D
glycylglycine
Conditions | Yield |
---|---|
With hydrogen In water at 200℃; under 187515 Torr; for 0.0333333h; Product distribution; Further Variations:; Temperatures; Reagents; |
Conditions | Yield |
---|---|
With deuteriated sodium hydroxide; dihydrogen peroxide; water-d2 at 37℃; Kinetics; |
Glycine anhydride
glycine
A
glycine-glycine-glycine
B
glycylglycine
Conditions | Yield |
---|---|
With water at 200℃; under 187515 Torr; pH=5.9; Kinetics; |
glycylglycine
glycine
A
Glycine anhydride
B
glycine-glycine-glycine
Conditions | Yield |
---|---|
In water at 200℃; under 187515 Torr; pH=5.7; Kinetics; |
((N-(tert-butoxycarbonyl)glycyl)glycyl)glycine
glycine-glycine-glycine
Conditions | Yield |
---|---|
With trifluoroacetic acid at 20℃; for 2h; |
N-(fluoren-9-ylmethoxycarbonyl)glycine
glycine-glycine-glycine
Conditions | Yield |
---|---|
Multistep reaction.; |
Conditions | Yield |
---|---|
With recombinant Pseudomonas nitroreducens IFO12694 γ-glutamyltranspeptidase at 30℃; for 0.0333333h; pH=10.5; aq. buffer; Enzymatic reaction; |
glycine-glycine-glycine
(fluorenylmethoxy)carbonyl chloride
Conditions | Yield |
---|---|
With sodium carbonate In tetrahydrofuran at 0 - 20℃; for 4h; | 100% |
Conditions | Yield |
---|---|
In toluene for 3h; Heating; | 99% |
glycine-glycine-glycine
di-tert-butyl dicarbonate
((N-(tert-butoxycarbonyl)glycyl)glycyl)glycine
Conditions | Yield |
---|---|
With sodium hydrogencarbonate In N,N-dimethyl-formamide at 0 - 20℃; for 30h; | 98% |
With sodium hydrogencarbonate In water; N,N-dimethyl-formamide at 20℃; for 1h; | 96% |
With guanidine hydrochloride In ethanol at 35 - 40℃; for 10h; | 91% |
Conditions | Yield |
---|---|
With palladium 10% on activated carbon; hydrogen In water under 3000.3 Torr; for 4h; | 98% |
Conditions | Yield |
---|---|
With sodium hydroxide at -13℃; for 5h; α-chymotrypsin; in ice; | 91.2% |
glycine-glycine-glycine
N-[(diethylamino)carbonothioyl]benzenecarboximidoyl chloride
Conditions | Yield |
---|---|
With potassium hydroxide In ethanol at 20℃; for 8h; | 90% |
Conditions | Yield |
---|---|
In toluene Heating; | 89% |
In toluene Reflux; Dean-Stark; | 89% |
Conditions | Yield |
---|---|
With sodium hydrogencarbonate In 1,4-dioxane; water for 24h; Ambient temperature; | 85% |
Conditions | Yield |
---|---|
Stage #1: glycine-glycine-glycine With magnesium oxide In water at 25℃; for 4h; Stage #2: N-phthaloylglycine chloride In 1,4-dioxane; water at 25℃; for 2h; | 85% |
N-benzyloxycarbonyl-S-benzyl-L-cysteine succinimido-ester
glycine-glycine-glycine
Z-Cys(Bzl)-Gly3-OH
Conditions | Yield |
---|---|
With sodium hydrogencarbonate In 1,4-dioxane for 24h; Ambient temperature; | 84% |
glycine-glycine-glycine
ethanol
glycyl-glycyl-glycine ethyl ester hydrochloride
Conditions | Yield |
---|---|
With thionyl chloride for 4h; Heating; | 83% |
With hydrogenchloride for 72h; | 52.9% |
Conditions | Yield |
---|---|
In toluene for 96h; Heating; | 83% |
for 4h; Heating; | 72.2% |
glycine-glycine-glycine
succinimidyl-S-benzoylthioglycolate
benzoylmercaptoacetylglycylglycylglycine
Conditions | Yield |
---|---|
With sodium hydroxide In acetonitrile at 20 - 60℃; for 6h; | 82% |
With sodium hydroxide In water for 2.5h; Heating; |
glycine-glycine-glycine
(9H-fluoren-9-yl)methyl 1,2-dimethyl-2-((1-(3-oxo-3-(perfluorophenoxy)propyl)-1H-indol-2-yl)methyl)hydrazine-1-carboxylate
Conditions | Yield |
---|---|
With sodium hydrogencarbonate In N,N-dimethyl acetamide; water; acetonitrile at 20℃; for 22h; | 82% |
glycine-glycine-glycine
[(morpholinyl)(thiocarbonyl)]benzimidoyl chloride
Conditions | Yield |
---|---|
With potassium hydroxide In ethanol at 20℃; for 8h; | 82% |
Conditions | Yield |
---|---|
With sodium; methanol In methanol byproducts: NaCl; N2; dissolving sodium in dry methanol, addn. of this soln. to methanolicsoln. of triglycine, refluxing with stirring for 3-4 h, addn. of methan olic soln. of triphenyltin(IV) chloride, refluxing with stirring for 6-7h; filtration of the centrifuged mixt., solvent removal under reduced pressure, trituration with hexane or petroleum ether, recrystn. from methanol-hexane or methanol-petroleum ether; elem. anal.; | 80% |
tetrahydrofuran
glycine-glycine-glycine
[MoCl(η3-methylallyl)(CO)2(κ2(N,O)-pyridine-2-carboxaldehyde)]
[MoCl(η3-methallyl)(CO)2(NC5H4-2-C(H)=NCH2CONHCH2CONHCH2COOH)]*THF
Conditions | Yield |
---|---|
In tetrahydrofuran; methanol (N2); Schlenk technique; mixt. of Mo complex and peptide in THF/MeOH wasrefluxed for 7 h; evapd. (vac.); washed (CH2Cl2); extd. (THF); filtered through kieselguhr; hexane slowly diffused into concd. THF soln. at -20°C; elem. anal.; | 78% |
Conditions | Yield |
---|---|
With sodium hydroxide In acetone for 0.5h; | 77% |
Conditions | Yield |
---|---|
In toluene Heating; | 77% |
In toluene for 8h; Heating; | 77% |
potassium tetrachloroplatinate(II)
glycine-glycine-glycine
cis-dichloro-bis(glycylglycylclycine)platinum(II)
Conditions | Yield |
---|---|
In potassium hydroxide Gly-Gly-Gly and K2PtCl4 stirred in aq. KOH for 3 d at room temp.; evapd.in vac.; dissolved in aq. HCl; evapd.; dissolved in DMF and filtered; a dded dropwise to acetone/Et2O; repeated pptn. from DMF/acetone with Et2O; centrifuged; washed with Et2O; dried over P2O5 in vac.; elem. anal.; | 77% |
methanol
glycine-glycine-glycine
methyl 2-(2-(2-aminoacetamido)acetamido)acetate hydrochloride
Conditions | Yield |
---|---|
With hydrogenchloride for 3h; Heating; | 76% |
With hydrogenchloride |
dichloro(benzene)ruthenium(II) dimer
glycine-glycine-glycine
{(η6-C6H6)Ru(NH2CH2CONCH2CONHCH2CO2H)Cl}
Conditions | Yield |
---|---|
In water dissolving Ru-compd. in water by heating, filtration, addn of triglycine; redn. of vol. to 1 ml, crystn. by addn. of methanol and cooling to o°C; elem. anal.; | 76% |
glycine-glycine-glycine
Conditions | Yield |
---|---|
With sodium hydrogencarbonate In water; acetonitrile | 75.4% |
glycine-glycine-glycine
4-uulfamoyl-benzoic acid 2,5-dioxo-pyrrolidin-1-yl ester
1-<((glycylglycyl)glycyl)carbonyl>-4-sulfamoylbenzene
Conditions | Yield |
---|---|
With potassium dihydrogenphosphate In acetone for 2h; Ambient temperature; | 75% |
In acetone at 20℃; for 2h; pH=7.0 - 7.5; |
Conditions | Yield |
---|---|
In methanol N2; dropwise addn. of a dry hot methanolic soln. of tin compd. to hot methanolic soln. of triglycine (1:1 mol. ratio), refluxing with stirring for 14-16 h with azeotropic removal of water; filtration, solvent removal under reduced pressure, crystn. by trituration with hexane, recrystn. from methanol-hexane; elem. anal.; | 75% |
Conditions | Yield |
---|---|
In ethanol (N2); Schlenk technique; mixt. of Re complex and peptide in EtOH was refluxed for 2 h; evapd. (vac.); washed (hexane, CH2Cl2/hexane, 1/1); dissolved in THF; filtered through kieselguhr; hexane added; evapd. (vac.); elem. anal.; | 75% |
Conditions | Yield |
---|---|
In ethanol (N2); Schlenk technique; mixt. of Mn complex and peptide in EtOH was refluxed for 9 h; evapd. (vac.); washed (hexane, CH2Cl2/hexane, 1/1); dissolved in THF/MeOH; filtered through kieselguhr; hexane added; evapd. (vac.); elem. anal.; | 73% |
glycine-glycine-glycine
Methacryloyl chloride
N-Methacryloyldiglycylglycin
Conditions | Yield |
---|---|
Stage #1: glycine-glycine-glycine With sodium hydroxide In water at 0 - 5℃; pH=9 - 10.5; ice salt bath; Stage #2: Methacryloyl chloride In water at 0 - 20℃; pH=9 - 10.5; Stage #3: With nitric acid In water | 73% |
The Glycine, glycylglycyl-, with CAS registry number 556-33-2, belongs to the following product categories: (1)Biochemistry; (2)Oligopeptides; (3)Peptide Synthesis. It has the systematic name of glycylglycylglycine. This chemical is a kind of white crystalline powder. And it should be stored at the temperature of 2-8°C. What's more, its EINECS is 209-122-0.
Physical properties of Glycine, glycylglycyl-: (1)ACD/LogP: -2.04; (2)# of Rule of 5 Violations: 1; (3)ACD/LogD (pH 5.5): -4.53; (4)ACD/LogD (pH 7.4): -5.02; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 1; (8)ACD/KOC (pH 7.4): 1; (9)#H bond acceptors: 7; (10)#H bond donors: 5; (11)#Freely Rotating Bonds: 6; (12)Polar Surface Area: 70.16 Å2; (13)Index of Refraction: 1.524; (14)Molar Refractivity: 42.19 cm3; (15)Molar Volume: 137.7 cm3; (16)Polarizability: 16.72×10-24cm3; (17)Surface Tension: 62.7 dyne/cm; (18)Density: 1.373 g/cm3; (19)Flash Point: 340.1 °C; (20)Enthalpy of Vaporization: 102.93 kJ/mol; (21)Boiling Point: 638.8 °C at 760 mmHg; (22)Vapour Pressure: 5.82E-18 mmHg at 25°C.
You can still convert the following datas into molecular structure:
(1)SMILES: O=C(NCC(=O)O)CNC(=O)CN
(2)InChI: InChI=1/C6H11N3O4/c7-1-4(10)8-2-5(11)9-3-6(12)13/h1-3,7H2,(H,8,10)(H,9,11)(H,12,13)
(3)InChIKey: XKUKSGPZAADMRA-UHFFFAOYAU
(4)Std. InChI: InChI=1S/C6H11N3O4/c7-1-4(10)8-2-5(11)9-3-6(12)13/h1-3,7H2,(H,8,10)(H,9,11)(H,12,13)
(5)Std. InChIKey: XKUKSGPZAADMRA-UHFFFAOYSA-N
About|Contact|Cas|Product Name|Molecular|Country|Encyclopedia
Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog
©2008 LookChem.com,License: ICP
NO.:Zhejiang16009103
complaints:service@lookchem.com Desktop View