Product Name

  • Name

    ISOPROPYLMAGNESIUM CHLORIDE

  • EINECS 213-947-1
  • CAS No. 1068-55-9
  • Article Data19
  • CAS DataBase
  • Density 0.98 g/mL at 20 °C
  • Solubility It reacts violently with water.
  • Melting Point 155-157 °C
  • Formula C3H7ClMg
  • Boiling Point 256 °C
  • Molecular Weight 102.847
  • Flash Point 72 °F
  • Transport Information UN 3399 4.3/PG 2
  • Appearance powder
  • Safety 26-36/37/39-43-45
  • Risk Codes 10-11-12-14/15-19-22-34-66-67
  • Molecular Structure Molecular Structure of 1068-55-9 (ISOPROPYLMAGNESIUM CHLORIDE)
  • Hazard Symbols CorrosiveC, HighlyF+, FlammableF
  • Synonyms Isopropylmagnesiumchloride (6CI);Magnesium, chloroisopropyl- (7CI,8CI);2-Propylmagnesiumchloride;Chloroisopropylmagnesium;
  • PSA 0.00000
  • LogP 2.05350

Synthetic route

isopropyl chloride
75-29-6

isopropyl chloride

isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

Conditions
ConditionsYield
With magnesium In tetrahydrofuran-d8 at 80℃; under 5171.62 Torr; Temperature; Concentration; Inert atmosphere; Flow reactor;95%
With magnesium In tetrahydrofuran at 21 - 29℃; for 0.5h; Inert atmosphere; Flow reactor;94.5%
With magnesium In tetrahydrofuran
isopropyl chloride
75-29-6

isopropyl chloride

A

isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

B

diisopropylmagnesium
3536-97-8

diisopropylmagnesium

Conditions
ConditionsYield
With diethyl ether; magnesium In toluene Ambient temperature; solvatation of Grignard reagent by diethyl ether;
isopropyl chloride
75-29-6

isopropyl chloride

magnesium
7439-95-4

magnesium

isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

Conditions
ConditionsYield
In tetrahydrofuran at 40℃;
C11H19NO4
1194059-56-7

C11H19NO4

C17H33NO4Si
1194059-55-6

C17H33NO4Si

dimethyl 1-(1-diazo-2-oxopropyl)phosphonate
90965-06-3

dimethyl 1-(1-diazo-2-oxopropyl)phosphonate

A

C18H33NO3Si
1194059-57-8

C18H33NO3Si

B

isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

Conditions
ConditionsYield
Stage #1: dimethyl 1-(1-diazo-2-oxopropyl)phosphonate With 4-toluenesulfonyl azide; potassium carbonate In acetonitrile at 0 - 20℃; for 2h; Bestmann alkynylation; Inert atmosphere; Cooling with ice bath;
Stage #2: C11H19NO4; C17H33NO4Si In methanol; acetonitrile at 20℃; Inert atmosphere;
...Expand
isopropyl chloride
75-29-6

isopropyl chloride

magnesium

magnesium

isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

Conditions
ConditionsYield
With diethyl ether
cyclohexenone
930-68-7

cyclohexenone

isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

3-isopropylcyclohexanone
23396-36-3

3-isopropylcyclohexanone

Conditions
ConditionsYield
Stage #1: isopropylmagnesium chloride With copper(l) chloride In tetrahydrofuran at -78℃; for 1.5h; Inert atmosphere;
Stage #2: cyclohexenone With chloro-trimethyl-silane In tetrahydrofuran at -78℃; for 20h; Inert atmosphere;		100%
With zinc(II) chloride; (2S,2'S)-2-hydroxymethyl-1-<(1-methylpyrrolidine-2-yl)methyl>pyrrolidine In tetrahydrofuran at -90℃; for 0.25h;97%
Grignard Reaction;78%
isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

2,2-dimethylpropylidynephosphine
78129-68-7

2,2-dimethylpropylidynephosphine

(Z)-1-tert-butyl-2-isopropyl-2-phosphavinylmagnesium chloride

(Z)-1-tert-butyl-2-isopropyl-2-phosphavinylmagnesium chloride

Conditions
ConditionsYield
In diethyl ether at -78 - 20℃; for 14.5h;100%
isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

7-methoxy-10-(4-methoxyphenyl)-5-methylphenanthren-2-carbonitrile
452307-58-3

7-methoxy-10-(4-methoxyphenyl)-5-methylphenanthren-2-carbonitrile

1-[7-methoxy-10-(4-methoxyphenyl)-5-methylphenanthren-2-yl]-2-methylpropan-1-one
452307-59-4

1-[7-methoxy-10-(4-methoxyphenyl)-5-methylphenanthren-2-yl]-2-methylpropan-1-one

Conditions
ConditionsYield
Stage #1: isopropylmagnesium chloride; 7-methoxy-10-(4-methoxyphenyl)-5-methylphenanthren-2-carbonitrile With copper(I) bromide In tetrahydrofuran
Stage #2: With sulfuric acid In tetrahydrofuran		100%
(E)-1-chloro-2-nonene
67242-74-4

(E)-1-chloro-2-nonene

isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

3-isopropyl-non-1-ene

3-isopropyl-non-1-ene

Conditions
ConditionsYield
CUCl-N-heterocyclic carbene In diethyl ether at 0℃;100%
isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

[(Z)-4-[(tert-butyldimethylsilyl)oxy]-2-buten-1-yl] ethyl carbonate
163976-62-3

[(Z)-4-[(tert-butyldimethylsilyl)oxy]-2-buten-1-yl] ethyl carbonate

tert-butyl-(2-isopropyl-but-3-enyloxy)-dimethyl-silane

tert-butyl-(2-isopropyl-but-3-enyloxy)-dimethyl-silane

Conditions
ConditionsYield
CuCl - N-heterocyclic carbene In diethyl ether at 0℃;100%
isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

Carbonic acid (Z)-4-benzyloxy-but-2-enyl ester ethyl ester
158478-10-5

Carbonic acid (Z)-4-benzyloxy-but-2-enyl ester ethyl ester

(2-isopropyl-but-3-enyloxymethyl)-benzene

(2-isopropyl-but-3-enyloxymethyl)-benzene

Conditions
ConditionsYield
CuCl - N-heterocyclic carbene In diethyl ether at 0℃;100%
isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

diethyl (E)-2-nonen-1-yl phosphate
463933-91-7

diethyl (E)-2-nonen-1-yl phosphate

3-isopropyl-non-1-ene

3-isopropyl-non-1-ene

Conditions
ConditionsYield
CUCl-N-heterocyclic carbene In diethyl ether at 0℃;100%
isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

Carbonic acid ethyl ester (E)-non-2-enyl ester

Carbonic acid ethyl ester (E)-non-2-enyl ester

3-isopropyl-non-1-ene

3-isopropyl-non-1-ene

Conditions
ConditionsYield
CUCl-N-heterocyclic carbene In diethyl ether at 0℃; for 0.5h;100%
ethyl (E)-3-phenyl-2-propenyl carbonate
106625-69-8

ethyl (E)-3-phenyl-2-propenyl carbonate

isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

3-phenyl-4-methylpent-1-ene
103979-23-3

3-phenyl-4-methylpent-1-ene

Conditions
ConditionsYield
[Cl(IMesH2)Cu] In diethyl ether at 0℃; for 0.5h;100%
4'-benzyloxy-3-fluoro-3',5'-dimethylbiphenyl-4-carboxylic acid
915307-30-1

4'-benzyloxy-3-fluoro-3',5'-dimethylbiphenyl-4-carboxylic acid

isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

4'-benzyloxy-3-isopropyl-3',5'-dimethylbiphenyl-4-carboxylic acid

4'-benzyloxy-3-isopropyl-3',5'-dimethylbiphenyl-4-carboxylic acid

Conditions
ConditionsYield
Stage #1: 4'-benzyloxy-3-fluoro-3',5'-dimethylbiphenyl-4-carboxylic acid; isopropylmagnesium chloride In tetrahydrofuran at 0 - 40℃; for 2h;
Stage #2: With hydrogenchloride; water In tetrahydrofuran at 0℃;		100%
bis(tetramethylcyclopentadienyl)dichlorotitan
115857-31-3

bis(tetramethylcyclopentadienyl)dichlorotitan

isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

{(C5H(CH3)4)2TiH2Mg(O(C2H5)2)Cl}2

{(C5H(CH3)4)2TiH2Mg(O(C2H5)2)Cl}2

Conditions
ConditionsYield
In diethyl ether byproducts: MgCl2; addn. of a soln. of i-PrMgCl in ether to the evacuated titanocene dihalide under argon, cooling in liquid nitrogen, evacuation, sealing off, warming to room temp., shaking, standing for 3 days; washing out MgCl2 using a silica wool plug;100%
1,3-dibromo-5-fluorobenzene
1435-51-4

1,3-dibromo-5-fluorobenzene

isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

3-bromo-5-fluorobenzaldehyde
188813-02-7

3-bromo-5-fluorobenzaldehyde

Conditions
ConditionsYield
Stage #1: 1,3-dibromo-5-fluorobenzene; isopropylmagnesium chloride In tetrahydrofuran at 0 - 20℃; for 2.5h;
Stage #2: N,N-dimethyl-formamide In tetrahydrofuran at 0 - 20℃;		100%
...Expand
2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
61676-62-8

2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

1,1-dimethylethyl (5-bromo-6-chloro-3-{[(2S)-2-({[(1,1-dimethylethyl)oxy]carbonyl}amino)-3-(1H-indol-3-yl)propyl]oxy}-2-pyridinyl)carbamate
1131041-74-1

1,1-dimethylethyl (5-bromo-6-chloro-3-{[(2S)-2-({[(1,1-dimethylethyl)oxy]carbonyl}amino)-3-(1H-indol-3-yl)propyl]oxy}-2-pyridinyl)carbamate

isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

A

C26H34BClN4O7

C26H34BClN4O7

B

1,1-dimethylethyl [6-chloro-3-{[(2S)-2-({[(1,1-dimethylethyl)oxy]carbonyl}amino)-3-(1H-indol-3-yl)propyl]oxy}-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2-pyridinyl]carbamate
1131042-33-5

1,1-dimethylethyl [6-chloro-3-{[(2S)-2-({[(1,1-dimethylethyl)oxy]carbonyl}amino)-3-(1H-indol-3-yl)propyl]oxy}-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2-pyridinyl]carbamate

Conditions
ConditionsYield
With lithium chloride In tetrahydrofuran at -78 - 20℃;A n/a
B 100%
...Expand
isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

(-)-(2S)-trifluoromethanesulfonyloxy-propionic acid tert-butyl ester
111757-80-3

(-)-(2S)-trifluoromethanesulfonyloxy-propionic acid tert-butyl ester

(+)-(2S,3)-dimethyl-butyric acid tert-butyl ester
1059043-99-0

(+)-(2S,3)-dimethyl-butyric acid tert-butyl ester

Conditions
ConditionsYield
With zinc(II) chloride In tetrahydrofuran at 0℃; for 3h; Product distribution / selectivity; Inert atmosphere;100%
(+)-(R)-1-(benzyloxy)-7-[3-methoxy-4-methyl-2-(triisopropylsilyloxy)phenyl]hept-4-yn-3-yl diethylphosphate

(+)-(R)-1-(benzyloxy)-7-[3-methoxy-4-methyl-2-(triisopropylsilyloxy)phenyl]hept-4-yn-3-yl diethylphosphate

isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

(-)-(S)-1-[7-(benzyloxy)-3-isopropylhepta-3,4-dienyl]-3-methoxy-4-methyl-2-(triisopropylsilyloxy)benzene

(-)-(S)-1-[7-(benzyloxy)-3-isopropylhepta-3,4-dienyl]-3-methoxy-4-methyl-2-(triisopropylsilyloxy)benzene

Conditions
ConditionsYield
Stage #1: isopropylmagnesium chloride With copper(l) cyanide; lithium chloride In tetrahydrofuran; diethyl ether at -40℃; Inert atmosphere;
Stage #2: (+)-(R)-1-(benzyloxy)-7-[3-methoxy-4-methyl-2-(triisopropylsilyloxy)phenyl]hept-4-yn-3-yl diethylphosphate In tetrahydrofuran; diethyl ether at -78℃; for 0.166667h; Inert atmosphere;		100%
isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

acetylacetone
123-54-6

acetylacetone

spiro[adamantane-2,3'-diazirine]
41736-95-2

spiro[adamantane-2,3'-diazirine]

A

2-Adamantanone
700-58-3

2-Adamantanone

B

1-isopropyl-3,5-dimethylpyrazole hydrochloride
1526941-44-5

1-isopropyl-3,5-dimethylpyrazole hydrochloride

Conditions
ConditionsYield
Stage #1: isopropylmagnesium chloride; spiro[adamantane-2,3'-diazirine] In diethyl ether at 0℃; for 2h; Inert atmosphere;
Stage #2: acetylacetone With toluene-4-sulfonic acid In ethanol at 80℃; for 24h; Inert atmosphere;
Stage #3: With hydrogenchloride In diethyl ether Inert atmosphere;		A 100%
B 70%
...Expand
tert-butyl 3-{[methoxy(methyl)amino]carbonyl}azetidine-1-carboxylate
820971-67-3

tert-butyl 3-{[methoxy(methyl)amino]carbonyl}azetidine-1-carboxylate

isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

C12H21NO3

C12H21NO3

Conditions
ConditionsYield
In tetrahydrofuran at 5 - 40℃; for 6.5h; Inert atmosphere;100%
isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

tert-butyl (4S)-4-[(3E)-3-tert-butylsulfinyliminopropyl]-2,2-dimethylpyrrolidine-1-carboxylate

tert-butyl (4S)-4-[(3E)-3-tert-butylsulfinyliminopropyl]-2,2-dimethylpyrrolidine-1-carboxylate

tert-butyl (4S)-4-[3-(tert-butylsulfinylamino)-4-methylpentyl]-2,2-dimethylpyrrolidine-1-carboxylate

tert-butyl (4S)-4-[3-(tert-butylsulfinylamino)-4-methylpentyl]-2,2-dimethylpyrrolidine-1-carboxylate

Conditions
ConditionsYield
In tetrahydrofuran at -78 - -35℃; for 1h; Inert atmosphere;100%
4-chloro-1-{[(4-chloro-2-fluorophenyl)methyl]oxy}-2-iodobenzene
892664-11-8

4-chloro-1-{[(4-chloro-2-fluorophenyl)methyl]oxy}-2-iodobenzene

2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
61676-62-8

2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

A

2-(5-chloro-2-{[4-chloro-2-fluorophenylmethyl]oxy}phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
892664-20-9

2-(5-chloro-2-{[4-chloro-2-fluorophenylmethyl]oxy}phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

B

C26H17BCl4F2O3

C26H17BCl4F2O3

Conditions
ConditionsYield
Stage #1: 4-chloro-1-{[(4-chloro-2-fluorophenyl)methyl]oxy}-2-iodobenzene; isopropylmagnesium chloride In toluene at -10 - -3℃;
Stage #2: 2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane In toluene at 0 - 20℃;		A n/a
B 99.1%
...Expand
isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

acetophenone
98-86-2

acetophenone

1,2-dimethyl-1-phenyl-1-propanol
62837-59-6, 62837-77-8, 139561-50-5, 4383-11-3

1,2-dimethyl-1-phenyl-1-propanol

Conditions
ConditionsYield
Stage #1: isopropylmagnesium chloride With (trimethylsilyl)methylmagnesium chloride; lithium chloride; zinc(II) chloride In tetrahydrofuran; diethyl ether at 20℃; Grignard addition;
Stage #2: acetophenone In tetrahydrofuran; diethyl ether at 0℃; for 3h; Grignard addition;		99%
Stage #1: isopropylmagnesium chloride With (trimethylsilyl)methylmagnesium chloride; lithium chloride; zinc(II) chloride In tetrahydrofuran; diethyl ether at 20℃; for 0.75h; Inert atmosphere;
Stage #2: acetophenone In tetrahydrofuran; diethyl ether at 0℃; for 3h; Inert atmosphere;		99%
Stage #1: isopropylmagnesium chloride With diethylene glycol dimethyl ether; tetrabutyl-ammonium chloride In tetrahydrofuran at 0℃; for 0.5h; Inert atmosphere;
Stage #2: acetophenone In tetrahydrofuran at 0℃; for 2.5h; Inert atmosphere;		74%
In diethyl ether 1) r.t., 2) reflux;63%
isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

Acetic acid (Z)-1-(2-benzyloxy-ethyl)-4,4,4-trifluoro-but-2-enyl ester

Acetic acid (Z)-1-(2-benzyloxy-ethyl)-4,4,4-trifluoro-but-2-enyl ester

(E)-1-benzyloxy-5-(trifluoromethyl)-6-methylhept-3-ene

(E)-1-benzyloxy-5-(trifluoromethyl)-6-methylhept-3-ene

Conditions
ConditionsYield
With chloro-trimethyl-silane In diethyl ether at 0℃;99%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

4-(6-chlorohexyl)cyclopent-2-en-1-one
249747-49-7

4-(6-chlorohexyl)cyclopent-2-en-1-one

[4-(6-chloro-hexyl)-3-isopropyl-cyclopent-1-enyloxy]-trimethyl-silane

[4-(6-chloro-hexyl)-3-isopropyl-cyclopent-1-enyloxy]-trimethyl-silane

Conditions
ConditionsYield
With copper(l) iodide; lithium chloride In tetrahydrofuran Addition;99%
...Expand
isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

(2R,3S)-3-Isopropyl-N-(2,4,6-trimethylphenylsulfonyl)-2-vinylaziridine
187532-11-2

(2R,3S)-3-Isopropyl-N-(2,4,6-trimethylphenylsulfonyl)-2-vinylaziridine

(E,3S)-2,7-dimethyl-3-[N-(2,4,6-trimethylbenzene)sulfonyl]amino-4-octene

(E,3S)-2,7-dimethyl-3-[N-(2,4,6-trimethylbenzene)sulfonyl]amino-4-octene

Conditions
ConditionsYield
Stage #1: isopropylmagnesium chloride With CuCN In tetrahydrofuran; diethyl ether at -78 - 0℃; for 0.25h; transmetallation;
Stage #2: (2R,3S)-3-Isopropyl-N-(2,4,6-trimethylphenylsulfonyl)-2-vinylaziridine In tetrahydrofuran; diethyl ether at -78℃; for 0.5h; Ring cleavage;		99%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

6-(tert-butyl-dimethyl-silanyloxy)-cyclohex-1-enecarboxylic acid ethyl ester
221124-23-8

6-(tert-butyl-dimethyl-silanyloxy)-cyclohex-1-enecarboxylic acid ethyl ester

(Z) (anti) 1-isopropyl-3-(tert-butyl-dimethyl-silanyloxy)-2-[ethoxy-(trimethyl-silanyloxy)-methylene]-cyclohexane

(Z) (anti) 1-isopropyl-3-(tert-butyl-dimethyl-silanyloxy)-2-[ethoxy-(trimethyl-silanyloxy)-methylene]-cyclohexane

Conditions
ConditionsYield
Stage #1: chloro-trimethyl-silane; isopropylmagnesium chloride; 6-(tert-butyl-dimethyl-silanyloxy)-cyclohex-1-enecarboxylic acid ethyl ester With Br2Cu(1-)*Li(1+) In tetrahydrofuran at -10℃;
Stage #2: With ammonium chloride In tetrahydrofuran; water		99%
...Expand
isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

4-methoxy-N-[(E)-phenylmethylidene]aniline
1613-90-7

4-methoxy-N-[(E)-phenylmethylidene]aniline

N-(4-methoxyphenyl)-N-(2-methyl-1-phenylpropyl)amine
412271-30-8

N-(4-methoxyphenyl)-N-(2-methyl-1-phenylpropyl)amine

Conditions
ConditionsYield
With scandium tris(trifluoromethanesulfonate) In diethyl ether; toluene at 0℃; for 5h;99%
With lanthanum(III) chloride; lithium chloride In tetrahydrofuran at 20℃; for 12h;84%
isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

13α-t-butyldimethylsilyloxy-podocarpan-14-one
843664-11-9

13α-t-butyldimethylsilyloxy-podocarpan-14-one

13α-t-butyldimethylsilyloxy-totaran-14α-ol
843664-12-0

13α-t-butyldimethylsilyloxy-totaran-14α-ol

Conditions
ConditionsYield
In tetrahydrofuran; diethyl ether at 20℃; for 1.5h;99%
N-(5-methyl-2-phenyl[1,3]dioxan-5-yl)phenylnitrone
135950-88-8

N-(5-methyl-2-phenyl[1,3]dioxan-5-yl)phenylnitrone

isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

N-(5-methyl-2-phenyl-[1,3]dioxan-5-yl)-N-(2-methyl-1-phenyl-propyl)-hydroxylamine

N-(5-methyl-2-phenyl-[1,3]dioxan-5-yl)-N-(2-methyl-1-phenyl-propyl)-hydroxylamine

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 16h; Grignard addition;99%
1-Fluoro-2-iodobenzene
348-52-7

1-Fluoro-2-iodobenzene

isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

(Z)-5<(tert-butyldimethylsilyl)oxy>3,4-epoxy-3-methyl-1-pentyne

(Z)-5<(tert-butyldimethylsilyl)oxy>3,4-epoxy-3-methyl-1-pentyne

C18H27FO2Si

C18H27FO2Si

Conditions
ConditionsYield
Stage #1: 1-Fluoro-2-iodobenzene; isopropylmagnesium chloride In tetrahydrofuran; diethyl ether at -40℃;
Stage #2: With tributylphosphine; copper(l) cyanide In tetrahydrofuran; diethyl ether at -30℃;
Stage #3: (Z)-5<(tert-butyldimethylsilyl)oxy>3,4-epoxy-3-methyl-1-pentyne In tetrahydrofuran; diethyl ether at -30 - 20℃; Further stages.;		99%
...Expand
1,2,3,4-tetrahydroisoquinoline
91-21-4

1,2,3,4-tetrahydroisoquinoline

3,3,3-Trifluoropropyl(1,2,3,4-tetrahydroisoquinolinyl)dimethoxysilane - A

3,3,3-Trifluoropropyl(1,2,3,4-tetrahydroisoquinolinyl)dimethoxysilane - A

3,3,3-trifluoropropyltrimethoxysilane
429-60-7

3,3,3-trifluoropropyltrimethoxysilane

isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

3,3,3-trifluoropropyl(1,2,3,4-tetrahydroisoquinolinyl)dimethoxysilane

3,3,3-trifluoropropyl(1,2,3,4-tetrahydroisoquinolinyl)dimethoxysilane

Conditions
ConditionsYield
In tetrahydrofuran99%
...Expand
1,2,3,4-tetrahydroisoquinoline
635-46-1

1,2,3,4-tetrahydroisoquinoline

3,3,3-Trifluoropropyl(1,2,3,4-tetrahydroquinolinyl)dimethoxysilane - A

3,3,3-Trifluoropropyl(1,2,3,4-tetrahydroquinolinyl)dimethoxysilane - A

3,3,3-trifluoropropyltrimethoxysilane
429-60-7

3,3,3-trifluoropropyltrimethoxysilane

isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

3,3,3-trifluoropropyl(1,2,3,4-tetrahydroquinolinyl)dimethoxysilane

3,3,3-trifluoropropyl(1,2,3,4-tetrahydroquinolinyl)dimethoxysilane

Conditions
ConditionsYield
In tetrahydrofuran99%
...Expand

Isopropylmagnesium chloride Specification

The Magnesium,chloro(1-methylethyl)-, with the CAS registry number 1068-55-9, has the IUPAC name of magnesium propane chloride. Its product categories are including Classes of Metal Compounds; Grignard Reagents; Grignard Reagents & Alkyl Metals; Mg (Magnesium) Compounds; Synthetic Organic Chemistry; Typical Metal Compounds; AlkylChemical Synthesis; Grignard Reagents; Organic Bases; Organometallic Reagents; Synthetic Reagents.

The physical properties of this chemical are as follows: (1)#H bond acceptors: 0; (2)#H bond donors: 0; (3)#Freely Rotating Bonds: 1; (4)Polar Surface Area: 0; (5)Exact Mass: 102.00867; (6)MonoIsotopic Mass: 102.00867; (7)Heavy Atom Count: 5; (8)Complexity: 6.9; (9)Covalently-Bonded Unit Count: 3.

Use of this chemical: Magnesium,chloro(1-methylethyl)- could react with isobutyryl chloride to produce 2,4-dimethyl-pentan-3-one. This reaction could happen in the presence of the reagent of diethyl ether.

When you are dealing with this chemical, you should be very cautious. For one thing, it is extremely flammable which may have an extremely low flash point and boiling point, and gases that catch fire in contact with air. For another thing, it is corrosive which may destroy living tissue on contact. Besides, it could react violently with water, liberating extremely flammable gases and then may form explosive peroxides. In addition, the repeated exposure may cause skin dryness or cracking and then the vapours may cause drowsiness and dizziness.

Therefore, you should take the following instructions to deal with different cases. The first important thing is to wear suitable protective clothing, gloves and eye/face protection. And if in case of contact with eyes, rinse immediately with plenty of water and seek medical advice; In case of fire use ... (there follows the type of fire-fighting equipment to be used.); In case of accident or if you feel unwell, seek medical advice immediately (show the

In addition, you could convert the following datas into the molecular structure:
(1)Canonical SMILES: C[CH-]C.[Mg+2].[Cl-]
(2)InChI: InChI=1S/C3H7.ClH.Mg/c1-3-2;;/h3H,1-2H3;1H;/q-1;;+2/p-1
(3)InChIKey: IUYHWZFSGMZEOG-UHFFFAOYSA-M 

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