Lithium molybdate(VI) supplier

Name
Lithium molybdate(VI)
EINECS 236-977-7
CAS No. 13568-40-6
Article Data64
CAS DataBase
Density 2.66 g/mL at 25 °C(lit.)
Solubility soluble in water
Melting Point 705 °C
Formula Li₂MoO₄
Boiling Point
Molecular Weight 173.82
Flash Point
Transport Information
Appearance white to almost white crystalline powder
Safety 26-37/39
Risk Codes 36/37/38
Molecular Structure
Hazard Symbols Xi
Synonyms Lithiummolybdate(VI) (Li2MoO4) (6CI,7CI);Molybdate (MoO42-), dilithium, (T-4)- (9CI);Molybdic acid (H2MoO4), dilithium salt (8CI);Dilithium molybdate (Li2MoO4);Dilithium molybdenum tetraoxide;Dilithium tetraoxomolybdate(2-);Lithiummolybdate;Lithium molybdate (Li2MoO4);Lithium molybdenum oxide (Li2MoO4);
PSA 80.26000
LogP -0.47520

Synthetic route

: molybdenum(VI) oxide

: 1310-65-2
lithium hydroxide

: 13568-40-6
lithium molybdate

Conditions

Conditions	Yield
In water pH 7-7.5; 2 h boiling on water bath; filtering, drying;	94%
In water pH 7-7.5; 2 h boiling on water bath; filtering, drying;	94%
In neat (no solvent, solid phase) for 5 mo; not isolated, detected by XRD;
Heating;

: molybdic acid

: 1310-66-3
lithium hydroxide monohydrate

: 13568-40-6
lithium molybdate

Conditions

Conditions	Yield
In water H2MoO4H2O (1 mmol) added to aq. soln. of LiOHH2O (2 mmol), stirred for20 min; filtered, allowed to stant (air) at room temp. for 1 week;	87%

: 554-13-2
lithium carbonate

: molybdenum(VI) oxide

: 13568-40-6
lithium molybdate

Conditions

Conditions	Yield
MoO3:Li2CO3 (1:1); reaction begins at 300°C;
heating (823 K);

: lithium oxide

: 7439-98-7
molybdenum

: 13568-40-6
lithium molybdate

Conditions

Conditions	Yield
byproducts: Li; above 1150 °C, Li2O a Mo crucible;
at 1320°C, in Mo vessel;
at 1320°C, in Mo vessel;

: molybdenum(VI) oxide

: lithium oxide

: 13568-40-6
lithium molybdate

Conditions

Conditions	Yield
In neat (no solvent) mixing, firing in air (740K) in a silica crucible fo 48 h with one intermediate grinding;
In neat (no solvent) mixing of powdered and dried stoichiometric amounts of starting materials, firing in air at around 740 K for 48 h;

: molybdenum(VI) oxide

: lithium oxide

A: 13568-40-6
lithium molybdate

B: Li4MoO5

Conditions

Conditions	Yield
at 350°C, Li2O:MoO3 mol ratio beetween 1:1 and 2:1;
at 350°C, Li2O:MoO3 mol ratio beetween 1:1 and 2:1;

...Expand

: 1310-66-3
lithium hydroxide monohydrate

: molybdenum(VI) oxide

: 13568-40-6
lithium molybdate

Conditions

Conditions	Yield
In water standing (some d); recrystn. (H2O);
In neat (no solvent) byproducts: H2O; ground under ambient conditions in air for 1 min, allowed to dry at roomtemp. for ca 1 h;

: ammonium molybdate

: 1310-65-2
lithium hydroxide

: 13568-40-6
lithium molybdate

Conditions

Conditions	Yield
With ammonium molybdate In water
With ammonium molybdate In water

: lithium oxide

: 7439-98-7
molybdenum

A: 13568-40-6
lithium molybdate

B: 7439-93-2
lithium

Conditions

Conditions	Yield
above 1150°C;
above 1150°C;

...Expand

: lithium sulfate

: calcium molybdate

: 13568-40-6
lithium molybdate

Conditions

Conditions	Yield
In not given byproducts: CaSO4; equilibrium react. at 25°C;;
In not given byproducts: CaSO4; equilibrium react. at 25°C;;

: zinc molybdate

: lithium orthoferrite

A: 13568-40-6
lithium molybdate

B: zinc ferrite

Conditions

Conditions	Yield
In neat (no solvent) reaction at 705°C;;
In neat (no solvent) reaction at 705°C;;

...Expand

: magnesium molybdate

: lithium orthoferrite

A: 13568-40-6
lithium molybdate

B: magnesium ferrite

Conditions

Conditions	Yield
In neat (no solvent) accelerated reaction above 705°C;;

...Expand

: lithium sodium molybdate tetrahydrate

A: 13568-40-6
lithium molybdate

B: Li(1+)*3Na(1+)*2MoO4(2-)=LiNa3(MoO4)2

Conditions

Conditions	Yield
In neat (no solvent) byproducts: H2O; 149°C; no isolation, monitoring by DTA;

: 7Li(1+)*3Y(3+)*8MoO4(2-)=Li7Y3(MoO4)8

A: 13568-40-6
lithium molybdate

B: lithium yttrium molybdate

Conditions

Conditions	Yield
In neat (no solvent) decomposition at 735°C;;

: 1304-76-3
bismuth(III) oxide

: 554-13-2
lithium carbonate

: molybdenum(VI) oxide

A: 13568-40-6
lithium molybdate

B: bismuth molybdate

Conditions

Conditions	Yield
In neat (no solvent, solid phase) MoO3, Bi2O3 and Li2CO3, milled for 4.5 h, dried, calcined at 500-550°C for 4 h, remilled for 5 h with H2O, pressed into pellets at 200 MPa with polyvinyl alcohol, sintered at 660°C for 2 h in ambient atm.; monitored by XRD;

...Expand

: lithium nitrate

: molybdenum(VI) oxide

: 13568-40-6
lithium molybdate

Conditions

Conditions	Yield
In neat (no solvent, solid phase) stoich. mixt. was initially calcined at 350°C, then annealed for 80-100 h; XRD;

: magnesium oxide

: 554-13-2
lithium carbonate

: molybdenum(VI) oxide

A: 13568-40-6
lithium molybdate

: (2-2x)Li(1+)*3MoO4(2-)*(2+x)Mg(2+)

Conditions

Conditions	Yield
In melt

...Expand

: ammonium molybdate

: 1310-65-2
lithium hydroxide

: 13568-40-6
lithium molybdate

Conditions

Conditions	Yield
In ethanol at 20℃;

: molybdenum(IV) oxide

: 554-13-2
lithium carbonate

: 13568-40-6
lithium molybdate

Conditions

Conditions	Yield
at 500℃; for 5h;

: molybdenum (IV) sulfide

: lithium fluoride

air: air

: 13568-40-6
lithium molybdate

Conditions

Conditions	Yield
at 400℃; for 4h; Temperature;

...Expand

: molybdenum(IV) oxide

: 13568-40-6
lithium molybdate

: zinc(II) oxide

: 7439-98-7
molybdenum

: 78402-82-1
LiZn2Mo3O8

Conditions

Conditions	Yield
In neat (no solvent, solid phase) Li2MoO4, ZnO, MoO2 and Mo powder in stoich. ratio were sealed in an evacuated tube and held at 1100°C for 5 days; ppt. was washed with HCl and deionized water, solid was then dried under vac. at 110°C; elem.anal.;	90%

...Expand

: 13568-40-6
lithium molybdate

: 142-73-4
iminodiacetic acid

: 2Li(1+)*MoO3*NH(CH2COO)2(2-)*2H2O=Li2MoO3(NH(CH2COO)2)(H2O)2

Conditions

Conditions	Yield
In water aq. soln. of Li2MoO4 (1 mmol) added to aq. soln. of iminodiacetic acid (1 mmol), refluxed for 6 h; filtered, allowed to stand (air) at room temp. for 4 weeks; elem. anal.;	82%

: 13568-40-6
lithium molybdate

: 1984-15-2
Methylenediphosphonic acid

: 7732-18-5
water

: 1310-65-2
lithium hydroxide

: Li8[(Mo2O4)3(methylenediphosphonato)3(MoO4)]*19H2O

Conditions

Conditions	Yield
With N2H4H2O In water Mo compd. dissolved in HCl soln., N2H4H2O added, stirred at 60°C, allowed to cool to room temp., Mo compd. and CH2(PO3H2)2 added, LiOH soln. added dropwise until pH 6.0; crystd. at room temp. for 5 d; elem. anal.;	53%

...Expand

: 13568-40-6
lithium molybdate

: 1984-15-2
Methylenediphosphonic acid

: 7732-18-5
water

: 1310-65-2
lithium hydroxide

: Li14[(Mo2O4)4(methylenediphosphonato(4-))4(methylenediphosphonato(3-))2]*34H2O

Conditions

Conditions	Yield
With N2H4H2O In water Mo compd. dissolved in HCl soln., N2H4H2O added, stirred at 60°C, allowed to cool to room temp., LiOH soln. added dropwise until pH 1.5,CH2(PO3H2)2 added, LiOH soln. added dropwise until pH 3.5; crystd. for 5 d; elem. anal.;	50%

...Expand

: 13568-40-6
lithium molybdate

: [(MoO3)176(H2O)80H32]*400H2O*20LiCl

Conditions

Conditions	Yield
With SnCl22H2O In hydrogenchloride addn. of aq. HCl to Li2MoO4 in H2O, addn. of SnCl22H2O; storage (20°C, 6 weeks), mechanical sepn. of crystals, washing (filtrated mother-liquor), drying in air on filter paper;	4%

: sodium molybdate

: 13568-40-6
lithium molybdate

: molybdenum(VI) oxide

: molybdenum(IV) oxide

Conditions

Conditions	Yield
In neat (no solvent) Electrolysis; in MoO3 melt contg. 7.5-20 mol % Na2MoO4 + 15.5-3 mol % Li2MoO4, Pt-electrodes, 0.02 to < 1 A cm**-2, 30-100°C over m. p. of electrolyte,6-8 h; washing of product deposited on cathode (hot water);

...Expand

: sodium molybdate

: 13568-40-6
lithium molybdate

: molybdenum(VI) oxide

A: molybdenum(IV) oxide

B: Na0.24Li0.72Mo6O17

Conditions

Conditions	Yield
In neat (no solvent) Electrolysis; in MoO3 melt contg. 3 mol % Na2MoO4 + 20 mol % Li2MoO4, Pt-electrodes, 1A cm**-2, 10-15°C over m. p. of electrolyte, 6-8 h; washing of product mixt. deposited on cathode (hot water); powder X-ray diffraction;

...Expand

: sodium molybdate

: 13568-40-6
lithium molybdate

: molybdenum(VI) oxide

A: molybdenum(IV) oxide

B: Na0.78Li0.06Mo6O17

Conditions

Conditions	Yield
In neat (no solvent) Electrolysis; in MoO3 melt contg. 15.5 mol % Na2MoO4 + 7.5 mol % Li2MoO4, Pt-electrodes, 1 A cm**-2, 10-15°C over m. p. of electrolyte, 6-8 h; washing of product mixt. deposited on cathode (hot water); powder X-ray diffraction;

...Expand

: sodium molybdate

: 13568-40-6
lithium molybdate

: molybdenum(VI) oxide

A: molybdenum(IV) oxide

B: sodium molybdenum purple bronze

Conditions

Conditions	Yield
In neat (no solvent) Electrolysis; in MoO3 melt contg. 13 mol % Na2MoO4 + 10 mol % Li2MoO4, Pt-electrodes, 1 A cm**-2, 10-15°C over m. p. of electrolyte, 6-8 h; washing of product mixt. deposited on cathode (hot water); powder X-ray diffraction;

...Expand

: sodium molybdate

: 13568-40-6
lithium molybdate

: molybdenum(VI) oxide

: Na0.24Li0.72Mo6O17

Conditions

Conditions	Yield
In neat (no solvent) Electrolysis; in MoO3 melt contg. 3 mol % Na2MoO4 + 20 mol % Li2MoO4, Pt-electrodes, 0.02 to < 1 A cm**-2, 10-15°C over m. p. of electrolyte, 6-8 h; washing of product deposited on cathode (hot water);

...Expand

: sodium molybdate

: 13568-40-6
lithium molybdate

: molybdenum(VI) oxide

: Na0.78Li0.06Mo6O17

Conditions

Conditions	Yield
In neat (no solvent) Electrolysis; in MoO3 melt contg. 15.5 mol % Na2MoO4 + 7.5 mol % Li2MoO4, Pt-electrodes, 0.02 to < 1 A cm**-2, 10-15°C over m. p. of electrolyte, 6-8 h; washing of product deposited on cathode (hot water);

...Expand

: sodium molybdate

: 13568-40-6
lithium molybdate

: molybdenum(VI) oxide

: sodium molybdenum purple bronze

Conditions

Conditions	Yield
In neat (no solvent) Electrolysis; in MoO3 melt contg. 13 mol % Na2MoO4 + 10 mol % Li2MoO4, Pt-electrodes,0.02 to < 1 A cm**-2, 10-15°C over m. p. of electrolyte, 6-8 h; washing of product deposited on cathode (hot water);

...Expand

: 13568-40-6
lithium molybdate

: molybdenum(VI) oxide

A: Li2O*2MoO3

B: lithium molybdate

...Expand

: 13568-40-6
lithium molybdate

: molybdenum(VI) oxide

: molybdenum(IV) oxide

Conditions

Conditions	Yield
In melt Electrolysis; outgassed sample electrolysis (molar ratio MoO3:Li2MoO4=50.5:49.5, crucible, nitrogen flow, 560°C, 6.8 mA, start voltage 1.7 V, 6 d, end voltage 0.6 V); crystals sepn. (crucible soaking into hot dilute HCl); single crystal and powder X-ray diffraction, atomic absorption spectroscopy;
In neat (no solvent) Electrolysis; in MoO3 melt contg. 23 mol % Li2MoO4, Pt-electrodes, 0.02 to < 1 A cm**-2, 30-100°C over m. p. of electrolyte, 6-8 h; washing of product deposited on cathode (hot water);

: 13568-40-6
lithium molybdate

: molybdenum(VI) oxide

A: molybdenum(IV) oxide

B: lithium molybdenum bronze

Conditions

Conditions	Yield
In neat (no solvent) Electrolysis; in MoO3 melt contg. 23 mol % Li2MoO4, Pt-electrodes, 1 A cm**-2, 10-15°C over m. p. of electrolyte, 6-8 h; washing of product mixt. deposited on cathode (hot water); powder X-ray diffraction;

...Expand

: 13568-40-6
lithium molybdate

: molybdenum(VI) oxide

: lithium molybdenum bronze

Conditions

Conditions	Yield
In melt Electrochem. Process; electrolytic redn. of a melt of Li2MoO4;
Electrolysis; electrolysis (0.03 A/cm**2, 4-5 h, 20-25 mol% Li2MoO4); detd. by gravimetry, X-ray photoelectron spectroscopy, laser emission spectroscopy, flame photometry, potentiometric titration; elem. anal.;
In neat (no solvent) Electrolysis; in MoO3 melt contg. 23 mol % Li2MoO4, Pt-electrodes, 0.02 to < 1 A cm**-2, 10-15°C over m. p. of electrolyte, 6-8 h; washing of product deposited on cathode (hot water);

: potassium molybdate(VI)

: 13568-40-6
lithium molybdate

: molybdenum(VI) oxide

: molybdenum(IV) oxide

Conditions

Conditions	Yield
In neat (no solvent) Electrolysis; in MoO3 melt contg. 18-13 mol % K2MoO4 + 5-10 mol % Li2MoO4, Pt-electrodes, 0.02 to < 1 A cm**-2, 30-100°C over m. p. of electrolyte, 6-8h; washing of product deposited on cathode (hot water);

...Expand

: potassium molybdate(VI)

: 13568-40-6
lithium molybdate

: molybdenum(VI) oxide

A: molybdenum(IV) oxide

B: K0.28Li0.02MoO3

Conditions

Conditions	Yield
In neat (no solvent) Electrolysis; in MoO3 melt contg. 18 mol % K2MoO4 + 5 mol % Li2MoO4, Pt-electrodes, 1 A cm**-2, 10-15°C over m. p. of electrolyte, 6-8 h; washing of product mixt. deposited on cathode (hot water); powder X-ray diffraction;

...Expand

: potassium molybdate(VI)

: 13568-40-6
lithium molybdate

: molybdenum(VI) oxide

A: molybdenum(IV) oxide

B: K0.26Li0.03MoO3

Conditions

Conditions	Yield
In neat (no solvent) Electrolysis; in MoO3 melt contg. 13 mol % K2MoO4 + 10 mol % Li2MoO4, Pt-electrodes, 1A cm**-2, 10-15°C over m. p. of electrolyte, 6-8 h; washing of product mixt. deposited on cathode (hot water); powder X-ray diffraction;

...Expand

: potassium molybdate(VI)

: 13568-40-6
lithium molybdate

: molybdenum(VI) oxide

: K0.28Li0.02MoO3

Conditions

Conditions	Yield
In neat (no solvent) Electrolysis; in MoO3 melt contg. 18 mol % K2MoO4 + 5 mol % Li2MoO4, Pt-electrodes, 0.02 to < 1 A cm**-2, 10-15°C over m. p. of electrolyte, 6-8 h; washing of product deposited on cathode (hot water);

...Expand

: potassium molybdate(VI)

: 13568-40-6
lithium molybdate

: molybdenum(VI) oxide

: K0.26Li0.03MoO3

Conditions

Conditions	Yield
In neat (no solvent) Electrolysis; in MoO3 melt contg. 13 mol % K2MoO4 + 10 mol % Li2MoO4, Pt-electrodes, 0.02 to < 1 A cm**-2, 10-15°C over m. p. of electrolyte, 6-8 h; washing of product deposited on cathode (hot water);

...Expand

: 13568-40-6
lithium molybdate

: 7439-98-7
molybdenum

Conditions

Conditions	Yield
In melt Electrolysis; electrolysis of 77.5mol%KF-7.5mol%Li2B4O7-15.0%Li2MoO4 bath, anode: Mo or graphite, cathode: Ni, Cu, Mo, steel or graphite, varying bath temp. and current density; detn. by X-ray;

: 13568-40-6
lithium molybdate

: ammonium chloride

: hexaammonium heptamolybdate tetrahydrate

Conditions

Conditions	Yield
In water aq. soln. of 1 mol Li2MoO4 and 5 mol NH4Cl;; crystn.;;

: 13568-40-6
lithium molybdate

: 1304-76-3
bismuth(III) oxide

: molybdenum(VI) oxide

: lithium bismuth molybdate

Conditions

Conditions	Yield
In neat (no solvent) melting;

...Expand

: lanthanum(III) oxide

: 13568-40-6
lithium molybdate

: molybdenum(VI) oxide

: lithium lanthanum molybdate

Conditions

Conditions	Yield
In melt crystallization from melt;; separation from excess Li2MoO4 with boiling H2O;;

...Expand

: 13568-40-6
lithium molybdate

: 2Am(3+)*3MoO4(2-)=Am2(MoO4)3

: Li(1+)*Am(3+)*2MoO4(2-)=LiAm(MoO4)2

Conditions

Conditions	Yield
at 550°C;
at 550°C;

Lithium molybdate(VI) Specification

The CAS register number of Lithium molybdate(VI) is 13568-40-6. It also can be called as Dilithium molybdate and the IUPAC name about this chemical is dilithium dioxido(dioxo)molybdenum. The molecular formula about this chemical is Li₂MoO₄and the molecular weight is 173.82. It belongs to the following product categories, such as Alternative Energy; Catalysis and Inorganic Chemistry; Electrode MaterialsChemical Synthesis; Materials Science; Molybdenum and so on.

Physical properties about Lithium molybdate(VI) are: (1)#H bond acceptors: 4; (2)#H bond donors: 2; (3)Polar Surface Area: 74.6Å²; (4)H-Bond Acceptor: 4; (5)Exact Mass: 175.917074; (6)MonoIsotopic Mass: 175.917074; (7)Topological Polar Surface Area: 80.3; (8)Heavy Atom Count: 7; (9)Complexit: 62.2; (10)Covalently-Bonded Unit Count: 3.

When you are using this chemical, please be cautious about it as the following:
This chemical is irritating to eyes, respiratory system and skin. When you are using it, wear suitable protective clothing, gloves and eye/face protection. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1)SMILES: [Li+].[Li+].[O-][Mo]([O-])(=O)=O
(2)InChI: InChI=1/2Li.Mo.4O/q2*+1;;;;2*-1/r2Li.MoO4/c;;2-1(3,4)5/q2*+1;-2
(3)InChIKey: NMHMDUCCVHOJQI-FFXFYZCHAF
(4)Std. InChI: InChI=1S/2Li.Mo.4O/q2*+1;;;;2*-1
(5)Std. InChIKey: NMHMDUCCVHOJQI-UHFFFAOYSA-N

Product Name

Lithium molybdate(VI)

Synthetic route

Lithium molybdate(VI) Specification

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