Lithium hydroxide monohydrate supplier

Name
Lithium hydroxide monohydrate
EINECS 215-183-4
CAS No. 1310-66-3
Article Data25
CAS DataBase
Density 1.51 g/cm³
Solubility 109 g/L (20 °C) in water
Melting Point 462 °C
Formula LiOH^.H₂O
Boiling Point 100 °C at 760 mmHg
Molecular Weight 41.9636
Flash Point
Transport Information UN 2680 8/PG 2
Appearance colourless, hygroscopic crystals
Safety 26-36/37/39-45-22
Risk Codes 20/22-35
Molecular Structure
Hazard Symbols C
Synonyms Lithium hydroxide, monohydrate or lithium hydroxide, solid;Lithium Hydroxide ];Lithium hydroxide, solution;
PSA 32.29000
LogP -0.24110

Synthetic route

: 7732-18-5
water

: 1310-65-2
lithium hydroxide

: 1310-66-3
lithium hydroxide monohydrate

Conditions

Conditions	Yield
In ethanol; water boiling soln. of LiOH in 62.8 vol.-% alcohol, pptn. of hydrate on vaporization or cooling ;;
With sulfuric acid In water vaporization of cold. concd. LiOH soln. over H2SO4;;
In water aq. LiOH soln.; various conditions;;

: 7732-18-5
water

: 554-13-2
lithium carbonate

: 1310-66-3
lithium hydroxide monohydrate

Conditions

Conditions	Yield
With sulfuric acid In sulfuric acid Electrolysis; electrochemical conversion of LiCO3 into LiOH in aq. H2SO4 at temp. 30-40°C in membrane electrolyzer is suggested; soln. of LiOH cooled, evapd. and LiOH*H2O crystd.; product washed with LiOH soln. and dried; elem. anal.;

: lithium chloride

: 1310-66-3
lithium hydroxide monohydrate

Conditions

Conditions	Yield
In water Electrolysis; formation by electrolysis of aq. LiCl with a Hg-circulation cathode;; the formed LiOH*H2O is free of Cl(1-), SO4(2-), PO4(3-) and Fe(3+);;
In water

: 1310-65-2
lithium hydroxide

: 1310-66-3
lithium hydroxide monohydrate

Conditions

Conditions	Yield
In water formation as precipitate on evaporation a aq. soln. of LiOH;;
In water formation as precipitate on evaporation a aq. soln. of LiOH;;

: 554-13-2
lithium carbonate

: 1310-66-3
lithium hydroxide monohydrate

Conditions

Conditions	Yield
With caustic lime In water reaction of Li2CO3 with caustic lime in aq. soln.;;
With caustic lime In water

: 109-72-8, 29786-93-4
n-butyllithium

potassium based lithium manganese oxyiodide: potassium based lithium manganese oxyiodide

A: 1310-66-3
lithium hydroxide monohydrate

: Li(x)Mn(x)O(x), cubic

C: potassium based lithium manganese oxyiodide

Conditions

Conditions	Yield
In hexane 1.6 M n-BuLi in hexane, 48 h; ppt. was washed thoroughly with hexane and EtOH, dried in vac., elem. anal., detected by X-ray powder diffractometry;	A n/a B 0% C n/a

...Expand

: 109-72-8, 29786-93-4
n-butyllithium

sodium-based lithium manganese oxyiodide: sodium-based lithium manganese oxyiodide

A: 1310-66-3
lithium hydroxide monohydrate

: Li(x)Mn(x)O(x), cubic

C: sodium-based lithium manganese oxyiodide

Conditions

Conditions	Yield
In hexane 1.6 M n-BuLi in hexane, 48 h; ppt. was washed thoroughly with hexane and EtOH, dried in vac., elem. anal., detected by powder X-ray diffractometry;	A n/a B 0% C n/a

...Expand

: Li7.9MnN3.2O1.6

A: lithium manganese oxide

B: 1310-66-3
lithium hydroxide monohydrate

C: manganese(II) oxide

D: 554-13-2
lithium carbonate

Conditions

Conditions	Yield
In neat (no solvent) stored in open air for 8 wk; detd. by X-ray diffraction;

...Expand

: Li11.9MnN3.7O3

A: 1310-66-3
lithium hydroxide monohydrate

B: manganese(II) oxide

Conditions

Conditions	Yield
In neat (no solvent) stored in open air for 8 wk; detd. by X-ray diffraction;

: Li34.2MnN3.9O13.7

A: 1310-66-3
lithium hydroxide monohydrate

B: manganese(II) oxide

C: 554-13-2
lithium carbonate

Conditions

Conditions	Yield
In neat (no solvent) stored in open air for 8 wk; detd. by X-ray diffraction;

...Expand

: Li34.2MnN3.9O13.7

: 1310-66-3
lithium hydroxide monohydrate

Conditions

Conditions	Yield
In neat (no solvent) stored in open air for 1 wk; detd. by X-ray diffraction;

: pentalithium ferrite

: 7732-18-5
water

: 1310-66-3
lithium hydroxide monohydrate

Conditions

Conditions	Yield
With air for 1h;

: Li1.97Co1.04Se1.05O0.93

: 7732-18-5
water

A: cobalt (II) selenide

B: 1310-66-3
lithium hydroxide monohydrate

C: cobalt diselenide

Conditions

Conditions	Yield
With air at 20℃; for 0.5h;

...Expand

: Li1.97Mn1008S0.98O1.043

: 7732-18-5
water

A: manganese(II) sulfide

B: manganese(II) hydroxide

C: 1310-66-3
lithium hydroxide monohydrate

Conditions

Conditions	Yield
With air at 20℃; for 0.5h;

...Expand

: Iron(III) nitrate nonahydrate

: 1310-66-3
lithium hydroxide monohydrate

: 86119-84-8, 7664-38-2
phosphoric acid

: lithium nitrate

: lithium iron(II) phosphate

Conditions

Conditions	Yield
In water evpn. of stoich. soln. of Fe(NO3)3*9H2O and LiH2PO4 at 20°C; two-steps termal treatment at 350 and 700°C under N2/H2 during 10 h; WO 2002/099913 A1; sintered for 12 h at 800°C (under Ar) for electrical measurements; detd. by XRD;	100%

...Expand

: manganese (II) nitrate tetrahydrate

: 1310-66-3
lithium hydroxide monohydrate

: 86119-84-8, 7664-38-2
phosphoric acid

: lithium nitrate

: lithium manganese(II) phosphate

Conditions

Conditions	Yield
In water pptd. in soln. of Mn(NO3)24H2O (0.1M), H3PO4 (0.1M), LiNO3 (1M) and LiOHH2O (0.3M) after 5 d under refluxing and stirring (pH=10); Chem. Mater., 16, 93 (2004); sintered for 12 h at 900°C (under air) for electrical conductivity measurements; detd. by XRD;	100%

...Expand

: Iron(III) nitrate nonahydrate

: 1310-66-3
lithium hydroxide monohydrate

: 94794-28-2, 16434-32-5
5-bromosalicylaldehyde thiosemicarbazone

: 7732-18-5
water

: Li[Fe(III)(5-bromosalicylaldehyde thiosemicarbazone)2]*H2O

Conditions

Conditions	Yield
In water LiOH and ligand were mixed at 100°C, soln. of Fe salt was added to refluxing mixt., stirring for 30 min; soln. was cooled to room temp. overnight, ppt. was filtered off, washed with water, dried in vac. first at room temp., then at 50°C overnight; elem. anal.;	100%

...Expand

: 1310-66-3
lithium hydroxide monohydrate

: tricarbonyl[tris(2-isocyanosuccinate methyl ester)]Mo(0)

: tricarbonyl[tris(lithium 2-isocyanosuccinate)]Mo(0)

Conditions

Conditions	Yield
In tetrahydrofuran at 0 - 20℃;	100%

: 1310-66-3
lithium hydroxide monohydrate

: potassium benzophenone-2-yltrifluoroborate

: benzophenon-2-ylboronic acid

Conditions

Conditions	Yield
In water; acetonitrile at 22℃; for 24h; Inert atmosphere;	100%

: 1271-42-7
ferrocenecarboxylic acid

: 1310-66-3
lithium hydroxide monohydrate

: lithium ferrocenoate

Conditions

Conditions	Yield
In water all manipulations under inert atm.; excess of complex suspended in waterand treated with hydroxide, stirred for 15 min; filtered, washed with water, filtrate evapd. to dryness;	99%

: 1310-66-3
lithium hydroxide monohydrate

: Et3NH[Ni4(diacetylmonoxime(1-))4(ethanolamine)2(ethanolamine(1-))2](ClO4)3

: 1246204-92-1
[Ni(2-(2-hydroxymethyl)amino-3-oximobutane(1-))3(μ3-O)]ClO4

Conditions

Conditions	Yield
In methanol (under aerobic conditions); Ni-complex refluxed with LiOH*H2O in MeOH;	99%

: 1310-66-3
lithium hydroxide monohydrate

: 1321624-12-7
benzo[ghi]perylene 1,2,4,5,10,11-hexacarboxylic trianhydride

: benzoperylrene-1,2,4,5,10,11-hexacarboxylic acid hexa-lithium salt

Conditions

Conditions	Yield
In methanol at 80℃; for 24h;	99%

: 1310-66-3
lithium hydroxide monohydrate

: 11113-50-1
boric acid

: 6153-56-6
oxalic acid dihydrate

: lithium bis(oxalato)borate

Conditions

Conditions	Yield
In neat (no solvent) mixed in stoich. ratio, heated at 60 °C for 2 h, pressed; dried at 120 °C for 7 h, at 150 °C for 16 h;	97%

...Expand

: 1310-66-3
lithium hydroxide monohydrate

: copper(II) nitrate dihydrate

: 64-17-5
ethanol

: 7732-18-5
water

: 1‐ethyl‐4‐hydroxy‐3‐(nitroacetyl)quinolin‐2‐(1H)‐one

: C15H22CuN2O9*0.5H2O

Conditions

Conditions	Yield
for 15h; Heating;	96%

...Expand

: 1313-13-9
manganese(IV) oxide

: 1310-66-3
lithium hydroxide monohydrate

: lithium nitrate

: lithium manganate

Conditions

Conditions	Yield
In melt mixing of LiOH*H2O, LiNO3 and MnO2 by grinding in a mortar, heating at 280°C for 12 h in air, cooling to room temp.; washing with distd. water, centrifuging, drying at 80°C under vac.;	95%

...Expand

: 1310-66-3
lithium hydroxide monohydrate

: 114601-77-3
bis(fluorosulfonyl)imide ammonium salt

: bis(fluorosulfonyl)imide lithium salt

Conditions

Conditions	Yield
at -5℃; for 0.5h; Temperature;	95%
In isopropyl alcohol at 20℃; for 7h; Solvent;	91%
In water at 20℃; for 1.5h; Inert atmosphere;	89%
In Isopropyl acetate at 31 - 35℃; under 65.0315 Torr; for 4h; Temperature; Solvent; Pressure; Reflux;	114.8 g

: 1310-66-3
lithium hydroxide monohydrate

: 1414813-93-6
ethyl 2,2-bis(3,5-bis(2-methoxyphenyl)-1H-pyrazol-1-yl)acetate

: 2,2-bis(3,5-bis(2-methoxyphenyl)-1H-pyrazol-1-yl)acetic acid

Conditions

Conditions	Yield
In tetrahydrofuran; water at 20℃;	94%

: 1310-66-3
lithium hydroxide monohydrate

: methyl 4-(3-methylbutan-2-yl)benzoate

: 4-(3-methylbutan-2-yl)benzoic acid

Conditions

Conditions	Yield
In tetrahydrofuran; methanol; water at 20℃; for 3h;	94%

: gallium(III) oxide

: 1310-66-3
lithium hydroxide monohydrate

: hydrated silica

: 15652-24-1
δ-eucryptite

Conditions

Conditions	Yield
In water lithium hydroxide slurried in a small amt. of water, gallia added; mixt. stirred at ca. 40°C (40 min); addn. of silica; boiling, evapn. to dryness; residue dried at 120°C (2 h); addn. of water, heating at 180°C (4-5 d); filtration, washing, drying; elem. anal.;	92%

...Expand

: gallium(III) oxide

: 1310-66-3
lithium hydroxide monohydrate

: hydrated silica

: 57565-11-4
LiGaSiO4*H2O

Conditions

Conditions	Yield
In water lithium hydroxide slurried in a small amt. of water, gallia added; mixt. stirred at ca. 40°C (40 min); addn. of silica; boiling, evapn. to dryness; residue dried at 120°C (2 h); addn. of water, heating at 180°C (6 d); filtration, washing, drying; elem. anal.;	92%

...Expand

: 1310-66-3
lithium hydroxide monohydrate

: [7,8,12,13-tetraethyl-2,18-bis(methoxycarbonylethyl)-3,17dimethylcorrolato]manganese(III) semihydrate

: [7,8,12,13-tetraethyl-2,18-dipropionyl-3,17dimethylcorrolato]manganese(III)

Conditions

Conditions	Yield
With CH3COOH In tetrahydrofuran; water under N2; soln. of Mn compd. in THF treated with aq. soln. of LiOH (1:10molar ratio), mixt. stirred for 25 h, Et2O and water added, phases sepd ., glacial acetic acid added dropwise to aq. soln.; ppt. sepd., washed with water; elem. anal.;	92%

: lead(II) nitrate

: 1310-66-3
lithium hydroxide monohydrate

: 16Pb(2+)*16NO3(1-)*16HO(1-)

Conditions

Conditions	Yield
In water at 200℃; for 72h;	92%

: 1310-66-3
lithium hydroxide monohydrate

: 7646-78-8
tin(IV) chloride

: lithium hexahydroxostannate(IV) dihydrat

Conditions

Conditions	Yield
In water heating (80°C), pptn.; filtn., washing (H2O, EtOH), drying (air atm.);	91.2%

: cobalt(II) nitrate hexahydrate

: 1310-66-3
lithium hydroxide monohydrate

: 64-17-5
ethanol

: 2161-85-5
1-(5-acetyl-2,4-dihydroxyphenyl)-1-ethanone

: 7732-18-5
water

: 123-54-6
acetylacetone

: [(HL)2Co2(acetylacetone)2]*1.5H2O

Conditions

Conditions	Yield
for 7h; Reflux;	90%

...Expand

: borax

: 1310-66-3
lithium hydroxide monohydrate

: Li2Na[B5O8(OH)2]

Conditions

Conditions	Yield
With strontium(II) hydroxide octahydrate; potassium hydroxide In water at 180℃; for 24h; High pressure; Autoclave;	90%

: 1310-66-3
lithium hydroxide monohydrate

: 64-17-5
ethanol

: 2161-85-5
1-(5-acetyl-2,4-dihydroxyphenyl)-1-ethanone

: 7732-18-5
water

: 7758-99-8
copper(II) sulfate

: [(H2L)Cu2(SO4)2(H2O)6]*4H2O

Conditions

Conditions	Yield
for 7h; Reflux;	89%

...Expand

: 1310-66-3
lithium hydroxide monohydrate

: 87-69-4
L-Tartaric acid

: bis{tris(1,2-ethanediamine)iridium(III) chloride} lithium chloride, hexahydrate

: Li(1+)*{Ir(NH2(CH2)2NH2)3}(3+)*2((COOCHOH)2)(2-)*3H2O=Li{Ir(NH2(CH2)2NH2)3}((COOCHOH)2)2*3H2O

: {Ir(NH2(CH2)2NH2)3}(3+)*3Cl(1-)={Ir(NH2(CH2)2NH2)3}Cl3

Conditions

Conditions	Yield
In ethanol; water the components were dissolved in boiling water, after cooling EtOH was added and the solution was reheated to boiling, allowed to stand for one day at room temp. with occasional shaking; filtrated, washed with 96% EtOH, dried in air, recrystd. from H2O/ethanol; elem. anal., crude (+)-Ir(en)3Cl3 was sepd. by evapn., dissoln. in 12 M HCl, pptn. by ethanol, 1 h, heating at 160°C;	A 87% B n/a

...Expand

: bis(acetylacetonate)nickel(II)

: 1310-66-3
lithium hydroxide monohydrate

: meso-tris(3,5-di-tert-butylphenyl)-mono-ortho-carbomethoxyphenylporphyrin

: 437653-43-5
(((CH3)3C)2C6H3)3C27H11N4ONi

Conditions

Conditions	Yield
With (COCl)2; SnCl4 In benzene Ni compd. added to toluene soln. of porphyrin; 24 h at 100°C; evapd.; chromd. (slica gel, CH2Cl2); LiOH*H2O and water added to dioxane soln.; refluxed (24 h); evapd.; toluene added; evapd.; chromd. (silica gel, CH2Cl2-hexane, CH2Cl2-AcOH); evapd.; benzene and (COCl)2 added; stirred (room temp., 2 h); solvent distd.; SnCl4 added; 1 h at room temp.; CH2Cl2 added; aq. NaOH added; org. phase washed (water); dried (Na2SO4); evapd.; chromd.(silica gel, hexane-CH2Cl2); crystd. (CH2Cl2-MeOH); elem. anal.;	87%

Yield

With (COCl)2; SnCl4 In benzene Ni compd. added to toluene soln. of porphyrin; 24 h at 100°C; evapd.; chromd. (slica gel, CH2Cl2); LiOH*H2O and water added to dioxane soln.; refluxed (24 h); evapd.; toluene added; evapd.; chromd. (silica gel, CH2Cl2-hexane, CH2Cl2-AcOH); evapd.; benzene and (COCl)2 added; stirred (room temp., 2 h); solvent distd.; SnCl4 added; 1 h at room temp.; CH2Cl2 added; aq. NaOH added; org. phase washed (water); dried (Na2SO4); evapd.; chromd.(silica gel, hexane-CH2Cl2); crystd. (CH2Cl2-MeOH); elem. anal.;

87%

...Expand

: 1310-66-3
lithium hydroxide monohydrate

: europium(III) chloride hexahydrate

: 185514-39-0
N,N'-ethylenebis(L-aspartic acid) tetramethyl ester

: Li(Eu(N,N'-ethylenebis(L-aspartate)))*5H2O

Conditions

Conditions	Yield
In water aq. LiOH added to a soln. of the ligand in MeOH; stirred overnight untilcomplete hydrolysis (checked by TLC) and evapd.; residue dissolved in a small amt. of water, and aq. soln. of Eu salt added; left to stand for 8 h; ppt. removed by filtration; filtrate evapd.; residue purified by repptn.in H2O-EtOH and gel filtration; elem. anal.;	87%

...Expand

: molybdic acid

: 1310-66-3
lithium hydroxide monohydrate

: 13568-40-6
lithium molybdate

Conditions

Conditions	Yield
In water H2MoO4H2O (1 mmol) added to aq. soln. of LiOHH2O (2 mmol), stirred for20 min; filtered, allowed to stant (air) at room temp. for 1 week;	87%

: 1310-66-3
lithium hydroxide monohydrate

: 64-17-5
ethanol

: 2161-85-5
1-(5-acetyl-2,4-dihydroxyphenyl)-1-ethanone

: 7732-18-5
water

: 142-71-2
copper diacetate

: 123-54-6
acetylacetone

: [(HL)2Cu2(acetylacetone)2]*2.5H2O

Conditions

Conditions	Yield
for 7h; Reflux;	87%

...Expand

Lithium hydroxide monohydrate Specification

The Lithium hydroxide monohydrate, with the CAS registry number 1310-66-3,is also known as Lithium hydroxide. It belongs to the product categories of Chemical Synthesis;metal hydroxide. This chemical's molecular formula is LiOH^.H₂O and molecular weight is 41.96.Its EINECS number is 206-114-9. What's more,Its systematic name is Lithium hydroxide monohydrate. It is a white crystals or pellets which is stable,incompatible with moisture,strong acids,carbon dioxide. And it absorbs carbon dioxide from the air.It is used as analytical reagent, photographic developer, Besides it is also used in the manufacture of lithium .

Physical properties about Lithium hydroxide monohydrate are:
(1)ACD/LogP: -1.38; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -1.38; (4)ACD/LogD (pH 7.4): -1.38; (5)ACD/BCF (pH 5.5): 1.00; (6)ACD/BCF (pH 7.4): 1.00; (7)#H bond acceptors: 1; (8)#H bond donors: 2; (9)#Freely Rotating Bonds: 0; (10)Enthalpy of Vaporization: 40.65 kJ/mol; (11)Boiling Point: 100 °C at 760 mmHg; (12)Vapour Pressure: 24.5 mmHg at 25°C.

You can still convert the following datas into molecular structure:
(1)SMILES:[Li+].[OH-].O;
(2)Std. InChI:InChI=1S/Li.2H2O/h;2*1H2/q+1;;/p-1;
(3)Std. InChIKey:GLXDVVHUTZTUQK-UHFFFAOYSA-M.

Safety Information of Lithium hydroxide monohydrate:
The Lithium hydroxide monohydrate is harmful by inhalation and if swallowed. In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) .It can causes severe burns. When you use it ,you should wear suitable protective clothing, gloves and eye/face protection and do not breathe dust.. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Take off immediately all contaminated clothing.

Product Name

Lithium hydroxide monohydrate

Synthetic route

Lithium hydroxide monohydrate Specification

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