• Name

  MANGANESE PHTHALOCYANINE

• EINECS
• CAS No. 14325-24-7
• Article Data19
• CAS DataBase
• Density
• Solubility Soluble in pyridine, chloronaphthalene, and conc. sulfuric acid. Insoluble in water.
• Melting Point >300 °C
• Formula C₃₂H₁₆MnN₈
• Boiling Point
• Molecular Weight 567.471
• Flash Point
• Transport Information
• Appearance
• Safety 22-24/25
• Risk Codes
• Molecular Structure
• Hazard Symbols
• Synonyms Manganese,[29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]-, (SP-4-1)-;Manganese, [phthalocyaninato(2-)]-(6CI,7CI,8CI);29H,31H-Phthalocyanine, manganese complex;(Phthalocyaninato)manganese;KJB 006;Manganese phthalocyanine;Manganese(II)phthalocyanine;[Phthalocyaninato(2-)]manganese;
• PSA 84.02000
• LogP 1.46440

Synthetic route

6156-78-1

manganese (II) acetate tetrahydrate

91-15-6

phthalonitrile

14325-24-7

manganese(II) phthalocyanin

Conditions

Conditions	Yield
In ethanol at 190℃; for 3h; Autoclave; High pressure; Green chemistry;	45%
In ethanol at 190℃; for 1h; Temperature; Solvent; Autoclave;	40%

85-44-9

phthalic anhydride

manganese(II)

57-13-6

urea

14325-24-7

manganese(II) phthalocyanin

Conditions

Conditions	Yield
With (NH4)2Mo2O7 In neat (no solvent) other Radiation; mixt. of O-phthalic anhydride, urea, metal salt and (NH4)2Mo2O7 irradiated in microwave oven at 460W for 8 min. the at 800W for 8 min, cooling to room temp.; washed (H2O, acetone, MeOH, 6M HCl), reflux with acetone, MeOH and CHCl3resp. about 12 h; elem. anal.;	31%

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7439-96-5

manganese

hexaammonium heptamolybdate tetrahydrate

91-15-6

phthalonitrile

14325-24-7

manganese(II) phthalocyanin

Conditions

Conditions	Yield
With I2 In neat (no solvent) tube was loaded with ligand, Mn, I2 and (NH4)6Mo7O24*4H2O under N2, tube was immersed in a 300°C salt bath, after a few min mixt. was solidified, mixt. was left at 300°C for 6 h, cooled; powder was sublimed in a tube furnace in vac. over 2 d at 480°C, crude ppt. was resublimed in vac. at <=460°C (caution: unsublimed material is pyrophoric); elem. anal.;	21%

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68027-09-8

oxovanadium phthalocyanine

14325-24-7

manganese(II) phthalocyanin

Conditions

Conditions	Yield
With imidazole In N,N-dimethyl acetamide soln. of complex in DMA was degassed, imidazole was added, 10 min; product was not isolated; analyzed by ESR or UV;

manganese(II)

91-15-6

phthalonitrile

14325-24-7

manganese(II) phthalocyanin

Conditions

Conditions	Yield
In not given react. of phthalonitrile with Mn(2+); washing, sublimation;

manganese(II) sulfate

91-15-6

phthalonitrile

14325-24-7

manganese(II) phthalocyanin

Conditions

Conditions	Yield
In methanol React. at 65-100°C, 9-11.5 kbar for 1.75-18 h in presence of hydroquinone.; Extg. with MeOH and acetone, sublimed in vac.;	2-50

63105-50-0

Mn(OH)-phthalocyanine

14325-24-7

manganese(II) phthalocyanin

Conditions

Conditions	Yield
In not given Irradiation (UV/VIS);

77648-32-9

(phthalocyaninato)bis(pyridine)manganese(II)

14325-24-7

manganese(II) phthalocyanin

Conditions

Conditions	Yield
In neat (no solvent) above 180°C;

manganese phthalocyanine (1-)

14325-24-7

manganese(II) phthalocyanin

Conditions

Conditions	Yield
In tetrahydrofuran; N,N-dimethyl-formamide Irradiation (UV/VIS);

manganese(II) sulfate

85-44-9

phthalic anhydride

14325-24-7

manganese(II) phthalocyanin

Conditions

Conditions	Yield
With ammonium heptamolybdate; urea Microwave irradiation;

manganese(II) chloride dihydrate

91-15-6

phthalonitrile

14325-24-7

manganese(II) phthalocyanin

Conditions

Conditions	Yield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In pentan-1-ol at 140℃; for 2h; Inert atmosphere;	162 mg

1835-65-0

Tetrafluorophthalonitrile

6156-78-1

manganese (II) acetate tetrahydrate

14325-24-7

manganese(II) phthalocyanin

Conditions

Conditions	Yield
at 250℃; for 3h; Inert atmosphere;	613 mg

6156-78-1

manganese (II) acetate tetrahydrate

574-93-6

29H,31H-Phthalocyanine

14325-24-7

manganese(II) phthalocyanin

Conditions

Conditions	Yield
With tributyl-amine In pentan-1-ol at 160℃; for 2h; Inert atmosphere;	12 mg

14325-24-7

manganese(II) phthalocyanin

65758-30-7

[2-(dimethylamino)ethyl]trimethylazanium iodide

99685-96-8, 161105-99-3, 161106-00-9, 111138-12-6, 133318-63-5, 134053-11-5, 134931-35-4, 134931-36-5, 139703-76-7, 145633-27-8, 175414-73-0, 175414-74-1, 175414-75-2, 175519-12-7, 175519-13-8, 175519-14-9, 175519-15-0, 136376-46-0, 144906-37-6, 144906-38-7, 151767-00-9, 152882-97-8, 152882-98-9, 152882-99-0, 153062-34-1, 154171-74-1, 154171-75-2, 154333-99-0, 154334-00-6, 154397-63-4, 154460-59-0, 199456-56-9, 108739-25-9, 120329-57-9, 120329-58-0

fullerene-C60

95-50-1

1,2-dichloro-benzene

811-51-8

sodium thioethylate

manganese(II)phthalocyanine(ethanethiolate)0.87(iodide)0.13(C60)(N,N,N',N',N'-pentamethyldiaminoethane)2*o-dichlorobenzene

Conditions

Conditions	Yield
In benzonitrile (under inert atm.); C60, Na-salt, ligand, Mn-complex stirred in C6H4Cl2-C6H5CN 6:1 mixt. for 4 h at 60°C, cooled to 20°C; filtered, hexane layered, diffused for 1 month, solvent poured down, collected, washed with hexane; elem. anal.;	50%

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7226-23-5

1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone

14325-24-7

manganese(II) phthalocyanin

29261-33-4

2,3,5,6-tetrafluoro-7,7',8,8'-tetracyanoquinodimethane

7732-18-5

water

[(manganese phthalocyanine)(H2O)2(1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidin-7-one)4]·[2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethanate]

Conditions

Conditions	Yield
In N,N-dimethyl acetamide at 20℃; for 336h;	49.1%

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553-26-4

4,4'-bipyridine

14325-24-7

manganese(II) phthalocyanin

95-50-1

1,2-dichloro-benzene

Mn(2+)*C32H16N8(2-)*C10H8N2*4C6H4Cl2

Conditions

Conditions	Yield
Stage #1: manganese(II) phthalocyanin; 1,2-dichloro-benzene at 100℃; for 6h; Glovebox; Stage #2: 4,4'-bipyridine In hexane Glovebox;	48%

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Manganese(II) phthalocyanine Specification