Product Name

  • Name

    MANGANESE(II) ACETATE TETRAHYDRATE

  • EINECS 211-334-3
  • CAS No. 6156-78-1
  • Density 1.589 g/mL at 25 °C(lit.)
  • Solubility Soluble in water, methanol, ethanol, and acetic acid.
  • Melting Point >300 °C(lit.)
  • Formula C4H6MnO4.4(H2O)
  • Boiling Point 117.1 °C at 760 mmHg
  • Molecular Weight 245.088
  • Flash Point 40 °C
  • Transport Information
  • Appearance pale pink crystal
  • Safety 26-36
  • Risk Codes 36/37/38
  • Molecular Structure Molecular Structure of 6156-78-1 (MANGANESE(II) ACETATE TETRAHYDRATE)
  • Hazard Symbols IrritantXi
  • Synonyms Manganeseacetate tetrahydrate;Manganese diacetate tetrahydrate;Manganese(2+) acetatetetrahydrate;Manganous acetatetetrahydrate;Manganese(II) acetate tetrahydrate;
  • PSA 89.52000
  • LogP -0.22960

Synthetic route

acetaldehyde
75-07-0

acetaldehyde

acetic acid
64-19-7

acetic acid

manganese (II) acetate tetrahydrate
6156-78-1

manganese (II) acetate tetrahydrate

Conditions
ConditionsYield
With manganese(IV) oxide; alkali cetate at 80℃;
With manganese(IV) oxide; alkaline earth acetate at 80℃;
C6H10(NCHC6H2C(CH3)3OHC15H10O(C(CH3)3)2)2(C6H4COOH)2

C6H10(NCHC6H2C(CH3)3OHC15H10O(C(CH3)3)2)2(C6H4COOH)2

manganese (II) acetate tetrahydrate
6156-78-1

manganese (II) acetate tetrahydrate

sodium chloride
7647-14-5

sodium chloride

MnCl(C6H10(NCHC6H2C(CH3)3OC15H10O(C(CH3)3)2)2(C6H4COOH)2)

MnCl(C6H10(NCHC6H2C(CH3)3OC15H10O(C(CH3)3)2)2(C6H4COOH)2)

Conditions
ConditionsYield
In ethanol xanthene-compound was added to Mn(CH3CO2)2*4H2O in abs. ethanol, the soln. was refluxed in air for 2 h, cooled, aq. satd. NaCl was added, the mixt. was stirred for 10 min; extd. with CH2Cl2, the organic layer was washed with water, dried over MgSO4, the solid was rotary evapd.; elem. anal.;100%
...Expand
5-[2-chloro-6-[(18-crown-6)methyloxy]phenyl]-10,15,20-tri-(2,6-dichlorophenyl) porphyrin

5-[2-chloro-6-[(18-crown-6)methyloxy]phenyl]-10,15,20-tri-(2,6-dichlorophenyl) porphyrin

manganese (II) acetate tetrahydrate
6156-78-1

manganese (II) acetate tetrahydrate

Mn[5-[2-chloro-6-[(18-crown-6)methyloxy]phenyl]-10,15,20-tri-(2,6-dichlorophenyl) porphyrin](1+)
184765-61-5

Mn[5-[2-chloro-6-[(18-crown-6)methyloxy]phenyl]-10,15,20-tri-(2,6-dichlorophenyl) porphyrin](1+)

Conditions
ConditionsYield
In N,N-dimethyl-formamide stirring under reflux (4 h); solvent evapn. (vac.), dissolving in CH2Cl2, washing (water), chromy. (silica gel, CHCl3/EtOH), dissolving in CH2Cl2, stirring with NaCl soln., org. phase drying (MgSO4), solvent evapn.;100%
5-[2-chloro-6-[9-(18-crown-6)nonyloxy]phenyl]-10,15,20-tri-(2,6-dichlorophenyl) porphyrin

5-[2-chloro-6-[9-(18-crown-6)nonyloxy]phenyl]-10,15,20-tri-(2,6-dichlorophenyl) porphyrin

manganese (II) acetate tetrahydrate
6156-78-1

manganese (II) acetate tetrahydrate

Mn[5-[2-chloro-6-[9-(18-crown-6)nonyloxy]phenyl]-10,15,20-tri-(2,6-dichlorophenyl) porphyrin](1+)
184765-68-2

Mn[5-[2-chloro-6-[9-(18-crown-6)nonyloxy]phenyl]-10,15,20-tri-(2,6-dichlorophenyl) porphyrin](1+)

Conditions
ConditionsYield
In N,N-dimethyl-formamide stirring under reflux (4 h); solvent evapn. (vac.), dissolving in CH2Cl2, washing (water), chromy. (silica gel, CHCl3/EtOH), dissolving in CH2Cl2, stirring with NaCl soln., org. phase drying (MgSO4), solvent evapn.;100%
5-[2,6-dichloro-3-[9-(18-crown-6)nonyloxy]phenyl]-10,15,20-tri-(2,6-dichlorophenyl) porphyrin

5-[2,6-dichloro-3-[9-(18-crown-6)nonyloxy]phenyl]-10,15,20-tri-(2,6-dichlorophenyl) porphyrin

manganese (II) acetate tetrahydrate
6156-78-1

manganese (II) acetate tetrahydrate

Mn[5-[2,6-dichloro-3-[9-(18-crown-6)nonyloxy]phenyl]-10,15,20-tri-(2,6-dichlorophenyl) porphyrin](1+)
184765-75-1

Mn[5-[2,6-dichloro-3-[9-(18-crown-6)nonyloxy]phenyl]-10,15,20-tri-(2,6-dichlorophenyl) porphyrin](1+)

Conditions
ConditionsYield
In N,N-dimethyl-formamide stirring under reflux (4 h); solvent evapn. (vac.), dissolving in CH2Cl2, washing (water), chromy. (silica gel, CHCl3/EtOH), dissolving in CH2Cl2, stirring with NaCl soln., org. phase drying (MgSO4), solvent evapn.;100%
H2[C75H64Cl8N4O8]

H2[C75H64Cl8N4O8]

manganese (II) acetate tetrahydrate
6156-78-1

manganese (II) acetate tetrahydrate

Mn[C75H64Cl8N4O8](1+)
184765-80-8

Mn[C75H64Cl8N4O8](1+)

Conditions
ConditionsYield
In N,N-dimethyl-formamide stirring under reflux (4 h); solvent evapn. (vac.), dissolving in CH2Cl2, washing (water), chromy. (silica gel, CHCl3/EtOH), dissolving in CH2Cl2, stirring with NaCl soln., org. phase drying (MgSO4), solvent evapn.;100%
K4[Re6Se8(CN)6]·3.5H2O

K4[Re6Se8(CN)6]·3.5H2O

water
7732-18-5

water

manganese (II) acetate tetrahydrate
6156-78-1

manganese (II) acetate tetrahydrate

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

catena-(octakis(μ3-selenido)-hexakis(μ2-cyano)-hexarhenium(III)-aqua-bis(dimethylformamido)manganese(II))bis(dimethylformamide)

catena-(octakis(μ3-selenido)-hexakis(μ2-cyano)-hexarhenium(III)-aqua-bis(dimethylformamido)manganese(II))bis(dimethylformamide)

Conditions
ConditionsYield
In water; N,N-dimethyl-formamide soln. of K4(Re6Se8(CN)6)*3.5H2O (0.08 mmol) in H2O/DMF added to soln. ofMn(CH3COO)2*4H2O (0.18 mmol) in H2O/DMF under stirring, mixt. refluxed for 1 h, cooled; ppt. filtered off, washed twice with H2O/DMF and CH3CN, air-dried; elem.anal.;100%
...Expand
4K(1+)*[Re6S8(CN)6](4-)=K4[Re6S8(CN)6]

4K(1+)*[Re6S8(CN)6](4-)=K4[Re6S8(CN)6]

water
7732-18-5

water

manganese (II) acetate tetrahydrate
6156-78-1

manganese (II) acetate tetrahydrate

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

catena-(octakis(μ3-sulfido)-hexakis(μ2-cyano)-hexarhenium(III)-aqua-bis(dimethylformamido)manganese(II))bis(dimethylformamide)

catena-(octakis(μ3-sulfido)-hexakis(μ2-cyano)-hexarhenium(III)-aqua-bis(dimethylformamido)manganese(II))bis(dimethylformamide)

Conditions
ConditionsYield
In water mixt. of H2O/DMF (75/1) added dropwise to aq. soln. of K4(Re6S8(CN)6) (0.029 mmol) and Mn(CH3COO)2*4H2O (0.068 mmol) under stirring; soln. concd., stored in air for a week, crystals filtered off, washed twice (CH3CN), air-dried; elem. anal.;100%
...Expand
4Cs(1+)*Re6Te8(CN)6(4-) = Cs4[Re6Te8(CN)6]

4Cs(1+)*Re6Te8(CN)6(4-) = Cs4[Re6Te8(CN)6]

water
7732-18-5

water

manganese (II) acetate tetrahydrate
6156-78-1

manganese (II) acetate tetrahydrate

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

catena-(octakis(μ3-tellurido)-hexakis(μ2-cyano)-hexarhenium(III)-aqua-bis(dimethylformamido)manganese(II))bis(dimethylformamide)

catena-(octakis(μ3-tellurido)-hexakis(μ2-cyano)-hexarhenium(III)-aqua-bis(dimethylformamido)manganese(II))bis(dimethylformamide)

Conditions
ConditionsYield
In water; N,N-dimethyl-formamide soln. of Cs4(Re6Te8(CN)6) (0.08 mmol) in H2O/DMF slowly added to soln. of Mn(CH3COO)2*4H2O (0.18 mmol) in H2O/DMF under stirring, mixt. refluxedfor 1 h, cooled; ppt. filtered off, washed with H2O/DMF and CH3CN, air-dried; elem. anal.;100%
...Expand
K4[Re6Se8(CN)6]·3.5H2O

K4[Re6Se8(CN)6]·3.5H2O

manganese (II) acetate tetrahydrate
6156-78-1

manganese (II) acetate tetrahydrate

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

catena-(octakis(μ3-selenido)-hexakis(μ2-cyano)-hexarhenium(III)-tris(dimethylformamido)manganese(II))

catena-(octakis(μ3-selenido)-hexakis(μ2-cyano)-hexarhenium(III)-tris(dimethylformamido)manganese(II))

Conditions
ConditionsYield
In water; N,N-dimethyl-formamide soln. of K4(Re6Se8(CN)6)*3.5H2O in H2O/DMF added to soln. of Mn(CH3COO)2*4H2O in H2O/DMF with vigorous stirring, mixt. stirred for 2 h; ppt. filtered off, washed twice with H2O/DMF (1/1) and CH3CN, air-dried;elem. anal.;100%
...Expand
bis(tetrabutylammonium) {(o-phenylenebis(oxamato))copper(II)}

bis(tetrabutylammonium) {(o-phenylenebis(oxamato))copper(II)}

manganese (II) acetate tetrahydrate
6156-78-1

manganese (II) acetate tetrahydrate

bis(tetrabutylammonium)oxalate
33081-83-3

bis(tetrabutylammonium)oxalate

(tetrabutylammonium)2[Mn2{Cu(1,2-phenylenebis(oxamate))}2(oxalate)]

(tetrabutylammonium)2[Mn2{Cu(1,2-phenylenebis(oxamate))}2(oxalate)]

Conditions
ConditionsYield
In water; dimethyl sulfoxide at 20℃; for 730.5h;100%
...Expand
manganese(II) acetate dihydrate

manganese(II) acetate dihydrate

manganese (II) acetate tetrahydrate
6156-78-1

manganese (II) acetate tetrahydrate

zinc manganite

zinc manganite

Conditions
ConditionsYield
In water at 500℃; Green chemistry;100%
manganese (II) acetate tetrahydrate
6156-78-1

manganese (II) acetate tetrahydrate

1,10-phenanthroline hydrate
5144-89-8

1,10-phenanthroline hydrate

{Mn3(O2CCH3)6(1,10-phenanthroline)2}

{Mn3(O2CCH3)6(1,10-phenanthroline)2}

Conditions
ConditionsYield
In N,N-dimethyl-formamide stirred for 10 min; filtered, washed with DMF, acetone and diethyl ether, dried in vac.; elem. anal.;99%
sodium azide

sodium azide

manganese (II) acetate tetrahydrate
6156-78-1

manganese (II) acetate tetrahydrate

meso-tetrakis(pentafluorophenyl)-β-octachloroporphyrinatomanganese(III) azide
170463-43-1

meso-tetrakis(pentafluorophenyl)-β-octachloroporphyrinatomanganese(III) azide

Conditions
ConditionsYield
In methanol; acetone (N2); soln. stiring (room temp., 12 h); filtration, solvent removal (rotary evapn.), solid redissolving (CH2Cl2), washing (water), org. layer drying (Na2SO4), solvent removal (rotary evapn.), drying (vac., overnight, room temp.);99%
2N((CH2)3CH3)4(1+)*Mo2O5(O2C6H2(NCHC6H3(OC2H5)OH)2)2(2-)=[N((CH2)3CH3)4]2[Mo2O5(O2C6H2(NCHC6H3(OC2H5)OH)2)2]

2N((CH2)3CH3)4(1+)*Mo2O5(O2C6H2(NCHC6H3(OC2H5)OH)2)2(2-)=[N((CH2)3CH3)4]2[Mo2O5(O2C6H2(NCHC6H3(OC2H5)OH)2)2]

manganese (II) acetate tetrahydrate
6156-78-1

manganese (II) acetate tetrahydrate

2N((CH2)3CH3)4(1+)*Mo2O5(O2C6H2(NCHC6H3(OC2H5)O)2Mn)2(2-)=[N((CH2)3CH3)4]2[Mo2O5(O2C6H2(NCHC6H3(OC2H5)O)2Mn)2]

2N((CH2)3CH3)4(1+)*Mo2O5(O2C6H2(NCHC6H3(OC2H5)O)2Mn)2(2-)=[N((CH2)3CH3)4]2[Mo2O5(O2C6H2(NCHC6H3(OC2H5)O)2Mn)2]

Conditions
ConditionsYield
In methanol; acetone byproducts: H2O; inert atmosphere; dropwise addn. of metal acetate (in MeOH) to 0.5 equiv. Mn-complex (in Me2CO), stirring for 1 h; solvent removal (vac.), dissoln. in THF/CH2Cl2=10:1, pptn. on Et2O addn., standing overnight;99%
manganese (II) acetate tetrahydrate
6156-78-1

manganese (II) acetate tetrahydrate

bis(acetato)manganese(II)

bis(acetato)manganese(II)

Conditions
ConditionsYield
In acetonitrile evacuated sealed ampoule (150°C, 6 weeks); elem. anal.;99%
In acetonitrile High Pressure; Mn(CH3COO)2*4H2O dehydrated in acetonitrile at 150°C for 6 weeks;99%
5-(2-chloro-6-{(ethoxycarbonyl)methoxy}phenyl)-10,15,20-tris(2,6-dichlorophenyl)porphyrin

5-(2-chloro-6-{(ethoxycarbonyl)methoxy}phenyl)-10,15,20-tris(2,6-dichlorophenyl)porphyrin

manganese (II) acetate tetrahydrate
6156-78-1

manganese (II) acetate tetrahydrate

5-{2-(OOC-methoxy)-6-chlorophenyl}-10,15,20-tris(2,6-dichlorophenyl)porphyrin Mn(III)
749180-71-0, 151421-96-4

5-{2-(OOC-methoxy)-6-chlorophenyl}-10,15,20-tris(2,6-dichlorophenyl)porphyrin Mn(III)

Conditions
ConditionsYield
In N,N-dimethyl-formamide a soln. of porphyrin-compd. in DMF is stirred at reflux with Mn(OAc)2*4H2O for 6 h; evapn. under reduced pressure, the residue is dissolved in in CH2Cl2 and washed with water, evapn., the residue is dissolved in EtOH and NaOH and refluxed for 2 h, evapn., addn. of H2O and HCl, extn. with CH2Cl2, column chromy., dried over MgSO4;99%
(1S,2S)-N-(5-benzoylthio-3-tert-butylsalicylidene)-N'-(3,5-di-tert-butylsalicylidene)-1,2-diphenylethylenediamine

(1S,2S)-N-(5-benzoylthio-3-tert-butylsalicylidene)-N'-(3,5-di-tert-butylsalicylidene)-1,2-diphenylethylenediamine

manganese (II) acetate tetrahydrate
6156-78-1

manganese (II) acetate tetrahydrate

sodium chloride
7647-14-5

sodium chloride

MnCl(OC6H2(C(CH3)3)(SC(O)C6H5)CHNCH(C6H5)CH(C6H5)NCHC6H2(C(CH3)3)2O)

MnCl(OC6H2(C(CH3)3)(SC(O)C6H5)CHNCH(C6H5)CH(C6H5)NCHC6H2(C(CH3)3)2O)

Conditions
ConditionsYield
With air In methanol Mn compd. added to soln. of ligand (molar ratio 2:1) in MeOH; stirred for 30 min at 50°C; brine added; stirred for 30 min at 50°C; solvent evapd. in vac.; dissolved in CH2Cl2; washed with brine and H2O; org. phase dried over Na2SO4; evapd. in vac.;99%
...Expand
(1S,2S)-N-(5-(2-[4-(acetylthio)phenyl]ethynyl)-3-tert-butylsalicylidene)-N'-(3,5-di-tert-butylsalicylidene)-1,2-diphenylethylenediamine

(1S,2S)-N-(5-(2-[4-(acetylthio)phenyl]ethynyl)-3-tert-butylsalicylidene)-N'-(3,5-di-tert-butylsalicylidene)-1,2-diphenylethylenediamine

manganese (II) acetate tetrahydrate
6156-78-1

manganese (II) acetate tetrahydrate

sodium chloride
7647-14-5

sodium chloride

MnCl(OC6H2(C(CH3)3)(C2C6H4SC(O)CH3)CHNCH(C6H5)CH(C6H5)NCHC6H2(C(CH3)3)2O)

MnCl(OC6H2(C(CH3)3)(C2C6H4SC(O)CH3)CHNCH(C6H5)CH(C6H5)NCHC6H2(C(CH3)3)2O)

Conditions
ConditionsYield
With air In methanol Mn compd. added to soln. of ligand (molar ratio 2:1) in MeOH; stirred for 30 min at 50°C; brine added; stirred for 30 min at 50°C; solvent evapd. in vac.; dissolved in CH2Cl2; washed with brine and H2O; org. phase dried over Na2SO4; evapd. in vac.;99%
...Expand
(1S,2S)-N-(5-[2-(4-(2-[4-(acetylthio)phenyl]ethynyl)phenyl)ethynyl]-3-tert-butylsalicylidene)-N'-(3,5-di-tert-butylsalicylidene)-1,2-diphenylethylenediamine

(1S,2S)-N-(5-[2-(4-(2-[4-(acetylthio)phenyl]ethynyl)phenyl)ethynyl]-3-tert-butylsalicylidene)-N'-(3,5-di-tert-butylsalicylidene)-1,2-diphenylethylenediamine

manganese (II) acetate tetrahydrate
6156-78-1

manganese (II) acetate tetrahydrate

sodium chloride
7647-14-5

sodium chloride

MnCl(OC6H2(C(CH3)3)((C2C6H4)2SC(O)CH3)CHNCH(C6H5)CH(C6H5)NCHC6H2(C(CH3)3)2O)

MnCl(OC6H2(C(CH3)3)((C2C6H4)2SC(O)CH3)CHNCH(C6H5)CH(C6H5)NCHC6H2(C(CH3)3)2O)

Conditions
ConditionsYield
With air In methanol Mn compd. added to soln. of ligand (molar ratio 2:1) in MeOH; stirred for 30 min at 50°C; brine added; stirred for 30 min at 50°C; solvent evapd. in vac.; dissolved in CH2Cl2; washed with brine and H2O; org. phase dried over Na2SO4; evapd. in vac.;99%
...Expand
pyridine
110-86-1

pyridine

manganese (II) acetate tetrahydrate
6156-78-1

manganese (II) acetate tetrahydrate

1,3-bis-(3-oxo-3-phenyl-propionyl)-2-hydroxy-5-methylbenzene
377736-65-7

1,3-bis-(3-oxo-3-phenyl-propionyl)-2-hydroxy-5-methylbenzene

Mn2((C6H5COCHCO)2CH3C6H2OH)2(C5H5N)4

Mn2((C6H5COCHCO)2CH3C6H2OH)2(C5H5N)4

Conditions
ConditionsYield
In pyridine to a stirred soln. of Mn-salt in pyridine was added a soln. of tetraketone in pyridine, stirred for a few min (inert atm.); diethyl ether was added, the flask was stopped and left undisturbed for 2 days, crystals were filtered, dried in vac.; elem. anal.;99%
...Expand
(C8F17)2C6H2(OH)CHNC6H10NCHC6H2(OH)(C8F17)2

(C8F17)2C6H2(OH)CHNC6H10NCHC6H2(OH)(C8F17)2

manganese (II) acetate tetrahydrate
6156-78-1

manganese (II) acetate tetrahydrate

Mn(C8F17)2C6H2(O)CHNC6H10NCHC6H2(O)(C8F17)2

Mn(C8F17)2C6H2(O)CHNC6H10NCHC6H2(O)(C8F17)2

Conditions
ConditionsYield
In ethanol refluxing;99%
(C8F17)2C6H2(OH)CHNCH(C6H5)CH(C6H5)NCHC6H2(OH)(C8F17)2

(C8F17)2C6H2(OH)CHNCH(C6H5)CH(C6H5)NCHC6H2(OH)(C8F17)2

manganese (II) acetate tetrahydrate
6156-78-1

manganese (II) acetate tetrahydrate

Mn(C8F17)2C6H2(O)CHNCH(C6H5)CH(C6H5)NCHC6H2(O)(C8F17)2

Mn(C8F17)2C6H2(O)CHNCH(C6H5)CH(C6H5)NCHC6H2(O)(C8F17)2

Conditions
ConditionsYield
In ethanol refluxing;99%
4Cs(1+)*Re6Te8(CN)6(4-)*3H2O=Cs4Re6Te8(CN)6*3H2O

4Cs(1+)*Re6Te8(CN)6(4-)*3H2O=Cs4Re6Te8(CN)6*3H2O

manganese (II) acetate tetrahydrate
6156-78-1

manganese (II) acetate tetrahydrate

ethylenediamine
107-15-3

ethylenediamine

[Mn(H2O)bis(ethylenediamine)][Mn bis(ethylenediamine)]2 Re6Te8(CN)6 (H2O)3

[Mn(H2O)bis(ethylenediamine)][Mn bis(ethylenediamine)]2 Re6Te8(CN)6 (H2O)3

Conditions
ConditionsYield
In water; glycerol Re complex in H2O layered on top of Mn salt and ethylenediamine in glycerol, crystd. for 2 weeks; filtered, dried, elem. anal.;99%
...Expand
C6H10(NCHC6H2C(CH3)3OHC15H10O(C(CH3)3)2)2(COOH)2

C6H10(NCHC6H2C(CH3)3OHC15H10O(C(CH3)3)2)2(COOH)2

manganese (II) acetate tetrahydrate
6156-78-1

manganese (II) acetate tetrahydrate

sodium chloride
7647-14-5

sodium chloride

MnCl(C6H10(NCHC6H2C(CH3)3OC15H10O(C(CH3)3)2)2(COOH)2)

MnCl(C6H10(NCHC6H2C(CH3)3OC15H10O(C(CH3)3)2)2(COOH)2)

Conditions
ConditionsYield
In ethanol xanthene-compound was added to Mn(CH3CO2)2*4H2O in abs. ethanol, the soln. was refluxed in air for 2 h, cooled, aq. satd. NaCl was added, the mixt. was stirred for 10 min; extd. with CH2Cl2, the organic layer was washed with water, dried over MgSO4, the solid was rotary evapd.; elem. anal.;99%
...Expand
N,N'-ethylenebis(2-hydroxybenzylimine)-5,5'-dicarboxylic acid

N,N'-ethylenebis(2-hydroxybenzylimine)-5,5'-dicarboxylic acid

water
7732-18-5

water

manganese (II) acetate tetrahydrate
6156-78-1

manganese (II) acetate tetrahydrate

diaqua(N,N'-ethylenebis(2-oxybenzylimine)-5,5'-dicarboxylate)manganese(III) pentahydrate

diaqua(N,N'-ethylenebis(2-oxybenzylimine)-5,5'-dicarboxylate)manganese(III) pentahydrate

Conditions
ConditionsYield
In ethanol High Pressure; heated at 80°C for 3 h;99%
...Expand
titanium(IV) isopropylate
546-68-9

titanium(IV) isopropylate

dichloromethane
75-09-2

dichloromethane

C92H72N2O6

C92H72N2O6

manganese (II) acetate tetrahydrate
6156-78-1

manganese (II) acetate tetrahydrate

lithium chloride

lithium chloride

C92H66N2O6(6-)*Ti(4+)*Mn(3+)*Cl(1-)*3CH2Cl2

C92H66N2O6(6-)*Ti(4+)*Mn(3+)*Cl(1-)*3CH2Cl2

Conditions
ConditionsYield
Stage #1: C92H72N2O6; manganese (II) acetate tetrahydrate With air In ethanol for 0.5h; Reflux;
Stage #2: lithium chloride In ethanol for 0.5h; Reflux;
Stage #3: titanium(IV) isopropylate; dichloromethane Further stages;		99%
...Expand
manganese (II) acetate tetrahydrate
6156-78-1

manganese (II) acetate tetrahydrate

(R,R)-N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine
135616-40-9

(R,R)-N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine

sodium chloride
7647-14-5

sodium chloride

(-)-chloro((1R,2R)-4,4',6,6'-tetra-tert-butyl-2,2'-[cyclohexane-1,2-diylbis(nitrilomethylidyne)]diphenolato)manganese(III)
138124-32-0

(-)-chloro((1R,2R)-4,4',6,6'-tetra-tert-butyl-2,2'-[cyclohexane-1,2-diylbis(nitrilomethylidyne)]diphenolato)manganese(III)

Conditions
ConditionsYield
Stage #1: manganese (II) acetate tetrahydrate; (R,R)-N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine In ethanol; toluene for 2.75h; Reflux;
Stage #2: With air In ethanol; toluene for 1h; Reflux;
Stage #3: sodium chloride In ethanol; water; toluene		99%
...Expand
titanium(IV) isopropylate
546-68-9

titanium(IV) isopropylate

C92H74N2O5

C92H74N2O5

manganese (II) acetate tetrahydrate
6156-78-1

manganese (II) acetate tetrahydrate

lithium chloride

lithium chloride

C92H74N2O6*Ti*Mn*Cl

C92H74N2O6*Ti*Mn*Cl

Conditions
ConditionsYield
Stage #1: C92H74N2O5; manganese (II) acetate tetrahydrate In ethanol for 1h; Schlenk technique; Reflux;
Stage #2: lithium chloride In ethanol for 1h; Schlenk technique; Reflux;
Stage #3: titanium(IV) isopropylate In ethanol at 20℃; for 12h; Schlenk technique;		99%
...Expand
5-(2-chloro-6-{7-(ethoxycarbonyl)heptyloxy}phenyl)-10,15,20-tris(2,6-dichlorophenyl)porphyrin

5-(2-chloro-6-{7-(ethoxycarbonyl)heptyloxy}phenyl)-10,15,20-tris(2,6-dichlorophenyl)porphyrin

manganese (II) acetate tetrahydrate
6156-78-1

manganese (II) acetate tetrahydrate

5-{2-(7-OOC-heptyloxy)-6-chlorophenyl}-10,15,20-tris(2,6-dichlorophenyl)porphyrin Mn(III)
151422-07-0

5-{2-(7-OOC-heptyloxy)-6-chlorophenyl}-10,15,20-tris(2,6-dichlorophenyl)porphyrin Mn(III)

Conditions
ConditionsYield
In N,N-dimethyl-formamide a soln. of porphyrin-compd. in DMF is stirred at reflux with Mn(OAc)2*4H2O for 6 h; evapn. under reduced pressure, the residue is dissolved in in CH2Cl2 and washed with water, evapn., the residue is dissolved in EtOH and NaOH and refluxed for 2 h, evapn., addn. of H2O and HCl, extn. with CH2Cl2, column chromy., dried over MgSO4;98%
C6H10(NCHC6H2C(CH3)3OHC15H10O(C(CH3)3)2)2(COOCH3)2

C6H10(NCHC6H2C(CH3)3OHC15H10O(C(CH3)3)2)2(COOCH3)2

manganese (II) acetate tetrahydrate
6156-78-1

manganese (II) acetate tetrahydrate

sodium chloride
7647-14-5

sodium chloride

MnCl(C6H10(NCHC6H2C(CH3)3OC15H10O(C(CH3)3)2)2(COOCH3)2)

MnCl(C6H10(NCHC6H2C(CH3)3OC15H10O(C(CH3)3)2)2(COOCH3)2)

Conditions
ConditionsYield
In ethanol xanthene-compound was added to Mn(CH3CO2)2*4H2O in abs. ethanol, the soln. was refluxed in air for 2 h, cooled, aq. satd. NaCl was added, the mixt. was stirred for 10 min; extd. with CH2Cl2, the organic layer was washed with water, dried over MgSO4, the solid was rotary evapd.; elem. anal.;98%
...Expand

Manganese(II) acetate tetrahydrate Consensus Reports

Manganese and its compounds are on the Community Right-To-Know List.

Manganese(II) acetate tetrahydrate Standards and Recommendations

OSHA PEL: CL 5 mg(Mn)/m3
ACGIH TLV: TWA 5 mg(Mn)/m3

Manganese(II) acetate tetrahydrate Specification

The Manganese(II) acetate tetrahydrate is an organic compound with the formula C4H6MnO4.4(H2O). The IUPAC name of this chemical is manganese(2+) diacetate tetrahydrate. With the CAS registry number 6156-78-1, it is also named as acetic acid, manganese(2+) salt, hydrate (2:1:2). Besides, it is a pale pink crystal, which should be stored in a dark cool and dry place. It is the raw material of polyester resin, xylene oxidation catalyst, which is used as oxidation catalysts and paint driers.

Physical properties about Manganese(II) acetate tetrahydrate are: (1)ACD/LogP: -0.285; (2)ACD/LogD (pH 5.5): -1.07; (3)ACD/LogD (pH 7.4): -2.86; (4)ACD/BCF (pH 5.5): 1.00; (5)ACD/BCF (pH 7.4): 1.00; (6)ACD/KOC (pH 5.5): 2.73; (7)ACD/KOC (pH 7.4): 1.00; (8)#H bond acceptors: 2; (9)#H bond donors: 1; (10)Flash Point: 40 °C; (11)Enthalpy of Vaporization: 23.7 kJ/mol; (12)Boiling Point: 117.1 °C at 760 mmHg; (13)Vapour Pressure: 13.9 mmHg at 25°C

Preparation of Manganese(II) acetate tetrahydrate : this chemical can be prepared by Manganese and Acetic acid.

When you are using this chemical, please be cautious about it as the following:
This chemical is irritating to eyes, respiratory system and skin. When you are using it, wear suitable suitable protective clothing. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1)InChI=1S/2C2H4O2.Mn.4H2O/c2*1-2(3)4;;;;;/h2*1H3,(H,3,4);;4*1H2/q;;+2;;;;/p-2;
(2)InChIKey=CESXSDZNZGSWSP-UHFFFAOYSA-L;
(3)SmilesC(C)(=O)[O-].C(=O)([O-])C.[Mn+2].O.O.O.O

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
rat LD50 oral 3730mg/kg (3730mg/kg)   American Industrial Hygiene Association Journal. Vol. 30, Pg. 470, 1969.

Related Products

Hot Products

Post buying leads

About|Contact|Cas|Product Name|Molecular|Country|Encyclopedia

Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog

©2008 LookChem.com,License: ICP

NO.:Zhejiang16009103

complaints:service@lookchem.com Desktop View