Methoxymethyldiphenylamine supplier

Name
Methoxymethyldiphenylamine
EINECS 255-310-0
CAS No. 41317-15-1
Article Data20
CAS DataBase
Density 1.089 g/cm³
Solubility 16.79mg/L at 25℃
Melting Point 80-83 °C
Formula C₁₄H₁₅NO
Boiling Point 344.6 °C at 760 mmHg
Molecular Weight 213.279
Flash Point 140.1 °C
Transport Information
Appearance
Safety 26
Risk Codes 22-36
Molecular Structure
Hazard Symbols Xn
Synonyms p-Anisidine,2-methyl-N-phenyl- (6CI);2-Methyl-4-methoxydiphenylamine;3-Methoxy-6-anilinotoluene;4-Methoxy-2-methyl-N-phenylaniline;4-Methoxy-2-methyldiphenylamine;6-Anilino-3-methoxytoluene;N-(2-Methyl-4-methoxyphenyl)aniline;
PSA 21.26000
LogP 3.82020

Synthetic route

: 13334-71-9
1-chloro-4-methoxy-2-methylbenzene

: 62-53-3
aniline

: 41317-15-1
4-phenylamino-3-methyl-1-methoxybenzene

Conditions

Conditions	Yield
With potassium phosphate; aniline; triphenylphosphine; tris(dibenzylideneacetone)dipalladium (0) at 184℃; for 8h; Buchwald-Hartwig amination;	96%
With potassium phosphate; DavePhos; tris-(dibenzylideneacetone)dipalladium(0) at 184℃;	96%

: 67-56-1
methanol

: 88-72-2
1-methyl-2-nitrobenzene

: 108-95-2
phenol

: 41317-15-1
4-phenylamino-3-methyl-1-methoxybenzene

Conditions

Conditions	Yield
Stage #1: methanol; 1-methyl-2-nitrobenzene With 3 % platinum on carbon; hydrogen In water at 50℃; under 750.075 Torr; for 8h; Autoclave; Inert atmosphere; Stage #2: phenol With 3 % platinum on carbon In cyclohexanone at 250℃; under 7500.75 Torr; for 2h; Autoclave; Inert atmosphere;	95.4%

...Expand

: 27060-75-9
4-bromo-3-methylanisole

: 103-84-4
Acetanilid

: 41317-15-1
4-phenylamino-3-methyl-1-methoxybenzene

Conditions

Conditions	Yield
Stage #1: Acetanilid With sodium methylate In 1-methyl-pyrrolidin-2-one at 100℃; Stage #2: 4-bromo-3-methylanisole In 1-methyl-pyrrolidin-2-one at 20 - 40℃; for 1.25h; Stage #3: In 1-methyl-pyrrolidin-2-one; methanol at 100℃; for 1h; Reagent/catalyst; Temperature; Solvent;	95.3%

: 27060-75-9
4-bromo-3-methylanisole

: 62-53-3
aniline

: 41317-15-1
4-phenylamino-3-methyl-1-methoxybenzene

Conditions

Conditions	Yield
With potassium hydroxide; bis(tri-t-butylphosphine)palladium(0); cetyltrimethylammonim bromide In water; toluene at 90℃; for 0.25h;	95%
With caesium carbonate; aniline; DavePhos; tris(dibenzylideneacetone)dipalladium (0) at 184℃; for 8h; Buchwald-Hartwig amination;	93%
With caesium carbonate; triphenylphosphine; tris-(dibenzylideneacetone)dipalladium(0) at 184℃;	93%

: 108-90-7
chlorobenzene

: 102-50-1
2-methyl-4-methoxyaniline

: 41317-15-1
4-phenylamino-3-methyl-1-methoxybenzene

Conditions

Conditions	Yield
With potassium phosphate; DavePhos; tris(dibenzylideneacetone)dipalladium (0) In toluene at 110℃; for 8h; Buchwald-Hartwig amination;	95%
With potassium phosphate; DavePhos; tris-(dibenzylideneacetone)dipalladium(0) In toluene Heating;	95%

: 108-86-1
bromobenzene

: 102-50-1
2-methyl-4-methoxyaniline

: 41317-15-1
4-phenylamino-3-methyl-1-methoxybenzene

Conditions

Conditions	Yield
With caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; tris(dibenzylideneacetone)dipalladium (0) In toluene at 110℃; Buchwald-Hartwig amination;	95%
With 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; tris-(dibenzylideneacetone)dipalladium(0) In toluene Heating;	95%
With potassium phosphate; copper(l) iodide; C18H15N3O2 at 25℃; for 24h; Reagent/catalyst; Temperature; Sealed tube;	93%
With potassium phosphate; copper(l) iodide In diethylene glycol at 70℃; for 14h; Sealed tube;	93%

: 102-50-1
2-methyl-4-methoxyaniline

A: 41317-15-1
4-phenylamino-3-methyl-1-methoxybenzene

B: 108-95-2
phenol

Conditions

Conditions	Yield
	A n/a B 94%

: 2-(4-methoxy-2-methylphenylamino)benzoic acid

: 41317-15-1
4-phenylamino-3-methyl-1-methoxybenzene

Conditions

Conditions	Yield
With methanol Reagent/catalyst;	90.99%
In methanol at 60 - 180℃; for 20h; Sealed tube; Large scale;	85.6%

: 108-86-1
bromobenzene

: 31601-41-9
N-(4-methoxy-2-methylphenyl)acetamide

: 12775-96-1, 15158-11-9, 15721-63-8, 16941-75-6, 17493-86-6, 19498-52-3, 20499-83-6, 20499-84-7, 20499-85-8, 20499-86-9, 20573-10-8, 20573-11-9, 21595-51-7, 21595-52-8, 22206-52-6, 26445-28-3, 28959-95-7, 37362-93-9, 39417-05-5, 54603-16-6, 54603-23-5, 54603-32-6, 54603-40-6, 54603-48-4, 54603-81-5, 54603-89-3, 56316-56-4, 95985-91-4, 122297-32-9, 7440-50-8
copper

A: 41317-15-1
4-phenylamino-3-methyl-1-methoxybenzene

B: 41317-14-0
3-methoxy-6-(N-acetylanilino) toluene

Conditions

Conditions	Yield
With iodine; potassium carbonate	A n/a B 90.5%

...Expand

: 100-63-0
phenylhydrazine

: 102-50-1
2-methyl-4-methoxyaniline

: 41317-15-1
4-phenylamino-3-methyl-1-methoxybenzene

Conditions

Conditions	Yield
With cobalt(II) phthalocyanine; copper(l) chloride In dichloromethane at 10℃;	86%

: 108-86-1
bromobenzene

: 31601-41-9
N-(4-methoxy-2-methylphenyl)acetamide

: 41317-15-1
4-phenylamino-3-methyl-1-methoxybenzene

: 27060-75-9
4-bromo-3-methylanisole

: 12775-96-1, 15158-11-9, 15721-63-8, 16941-75-6, 17493-86-6, 19498-52-3, 20499-83-6, 20499-84-7, 20499-85-8, 20499-86-9, 20573-10-8, 20573-11-9, 21595-51-7, 21595-52-8, 22206-52-6, 26445-28-3, 28959-95-7, 37362-93-9, 39417-05-5, 54603-16-6, 54603-23-5, 54603-32-6, 54603-40-6, 54603-48-4, 54603-81-5, 54603-89-3, 56316-56-4, 95985-91-4, 122297-32-9, 7440-50-8
copper

: 103-70-8
Formanilid

: 41317-15-1
4-phenylamino-3-methyl-1-methoxybenzene

Conditions

Conditions	Yield
With potassium hydroxide; iodine; potassium carbonate In toluene

...Expand

: 102-50-1
2-methyl-4-methoxyaniline

: 88-65-3
2-bromobenzoic-acid

: 41317-15-1
4-phenylamino-3-methyl-1-methoxybenzene

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: sodium hydroxide / toluene / 6 h / 100 - 110 °C 2: methanol / 20 h / 60 - 180 °C / Sealed tube; Large scale View Scheme

: 41317-15-1
4-phenylamino-3-methyl-1-methoxybenzene

: C14H15NO4S

Conditions

Conditions	Yield
With sulfuric acid at 50℃; for 0.5h;	98.47%

: 41317-15-1
4-phenylamino-3-methyl-1-methoxybenzene

: 54574-82-2
2-(4'-di-n-butylamino-2'-hydroxybenzoyl)benzoic acid

: 89331-94-2
2'-anilino-3'-methyl-6'-(dibutylamino)spiro[isobenzofuran-1(3H),9'-(9H)xanthen]-3-one

Conditions

Conditions	Yield
With sulfuric acid In dichloromethane; water at 35 - 40℃; for 4.5h; Temperature; Solvent;	94.6%
Stage #1: 4-phenylamino-3-methyl-1-methoxybenzene; 2-(4'-di-n-butylamino-2'-hydroxybenzoyl)benzoic acid With sulfuric acid at 15 - 25℃; for 24h; Condensation; Stage #2: With sodium hydroxide In toluene for 1h; Cyclization; Heating;	93%
With sulfuric acid	58%
With sulfuric acid	58 %Spectr.
With sulfuric acid

: 41317-15-1
4-phenylamino-3-methyl-1-methoxybenzene

: 42529-89-5
2-carboxy-4'-(N-ethyl-N-phenyl)amino-2'-hydroxybenzophenone

: 3-(N-ethyl-N-phenyl)amino-6-methyl-7-phenylaminofluoran

Conditions

Conditions	Yield
With sulfuric acid In dichloromethane; water at 35 - 40℃; for 4.5h; Temperature; Solvent;	94%

: 91458-42-3
2-carboxy-4'-(N-ethyl-N-isopentyl)amino-2'-hydroxybenzophenone

: 41317-15-1
4-phenylamino-3-methyl-1-methoxybenzene

: 70516-41-5
2'-anilino-6'-(N-ethyl-N-isopentylamino)-3'-methylspiro[isobenzofuran-1-(3H),9'-(9H)xanthen]-3-one

Conditions

Conditions	Yield
With sulfuric acid In dichloromethane; water at 35 - 40℃; for 4.5h; Temperature; Solvent;	93.8%

: 41317-15-1
4-phenylamino-3-methyl-1-methoxybenzene

: 5809-23-4
2'-Carboxy-4-diethylamino-2-hydroxybenzophenon

: 3-(Diethylamino)-6-(methyl)-7-(aminophenyl)xanthen>-3-one

Conditions

Conditions	Yield
With sulfuric acid In dichloromethane; water at 35 - 40℃; for 4.5h; Temperature; Solvent;	93.8%

: 41317-15-1
4-phenylamino-3-methyl-1-methoxybenzene

: 4891-38-7
phenylpropynoic acid methyl ester

: 1-(4-methoxy-2-methyl-phenyl)-2-phenylquinolin-4(1H)-one

Conditions

Conditions	Yield
With trifluorormethanesulfonic acid; copper(II) bis(trifluoromethanesulfonate) In 1,2-dichloro-ethane at 120℃; for 12h;	90%

: 41317-15-1
4-phenylamino-3-methyl-1-methoxybenzene

: 54574-82-2
2-(4'-di-n-butylamino-2'-hydroxybenzoyl)benzoic acid

: 197163-54-5
3-(dibutylamino)-6-methyl-7-anilinofluoran

Conditions

Conditions	Yield
Stage #1: 2-(4'-di-n-butylamino-2'-hydroxybenzoyl)benzoic acid With sulfuric acid; sulfur trioxide at 15 - 20℃; for 6.75h; Stage #2: 4-phenylamino-3-methyl-1-methoxybenzene In water; toluene at 20 - 70℃; for 11.25h;	89.6%

: 92-86-4
4-(4-bromophenyl)bromobenzene

: 41317-15-1
4-phenylamino-3-methyl-1-methoxybenzene

: 169685-34-1
N,N'-bis(2'-methyl-4'-methoxyphenyl)-N,N'-diphenylbenzidine

Conditions

Conditions	Yield
With sodium t-butanolate; palladium diacetate; 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride In toluene at 20 - 130℃; Inert atmosphere;	88%

: 19053-14-6
4,4''-diiodo-1,1':4',1''-terphenyl

: 41317-15-1
4-phenylamino-3-methyl-1-methoxybenzene

: N,N'-di(4-methoxy-2-methylphenyl)-N,N'-diphenyl-4,4"-diamino-p-terphenyl

Conditions

Conditions	Yield
With potassium carbonate; copper In dodecane at 200 - 210℃; for 30h;	80%

: 884866-01-7
1-(4-methylbenzensulfonyl)-4-phenyl-1H-1,2,3-triazole

: 41317-15-1
4-phenylamino-3-methyl-1-methoxybenzene

: (Z)-N-(2-((4-methoxy-2-methylphenyl)(phenyl)amino)-2-phenylvinyl)-4-methylbenzenesulfonamide

Conditions

Conditions	Yield
With dirhodium tetraacetate In 1,2-dichloro-ethane at 90℃; for 2h; regioselective reaction;	80%

: 41317-15-1
4-phenylamino-3-methyl-1-methoxybenzene

: 1257334-76-1
3-methyl-4-(phenylimino)cyclohexa-2,5-dienone

Conditions

Conditions	Yield
With sodium cyanide; nitromethane; bis-[(trifluoroacetoxy)iodo]benzene In water at 20℃; for 0.05h;	78%
With 1,1,1-triacetoxy-1,1-dihydro-1,2-benziodoxol-3(1H)-one; water In dichloromethane at 15 - 25℃; chemoselective reaction;	54%

: 41317-15-1
4-phenylamino-3-methyl-1-methoxybenzene

: 150-76-5
4-methoxy-phenol

: C21H21NO3

Conditions

Conditions	Yield
With ammonium peroxydisulfate; 2,4,6-triphenylpyrylium tetrafluoroborate In dichloromethane at 20℃; Irradiation;	72%

: 1293-79-4
ferrocenoyl chloride

: 41317-15-1
4-phenylamino-3-methyl-1-methoxybenzene

: N-phenyl-N-(2-Methyl-4-Methoxyphenyl)ferrocenecarboxamide

Conditions

Conditions	Yield
With triethylamine In dichloromethane at 20℃; for 10h; Inert atmosphere;	70%

: 622-62-8
4-Ethoxyphenol

: 41317-15-1
4-phenylamino-3-methyl-1-methoxybenzene

: C22H23NO3

Conditions

Conditions	Yield
With ammonium peroxydisulfate; 2,4,6-triphenylpyrylium tetrafluoroborate In dichloromethane at 20℃; Irradiation;	70%

: 41317-15-1
4-phenylamino-3-methyl-1-methoxybenzene

: 6411-34-3
4-allyloxyphenol

: C23H23NO3

Conditions

Conditions	Yield
With ammonium peroxydisulfate; 2,4,6-triphenylpyrylium tetrafluoroborate In dichloromethane at 20℃; Irradiation;	68%

: 103-16-2
4-Benzyloxyphenol

: 41317-15-1
4-phenylamino-3-methyl-1-methoxybenzene

: C27H25NO3

Conditions

Conditions	Yield
With ammonium peroxydisulfate; 2,4,6-triphenylpyrylium tetrafluoroborate In dichloromethane at 20℃; Irradiation;	65%

: 41317-15-1
4-phenylamino-3-methyl-1-methoxybenzene

: C13H11FO2

: C27H24FNO3

Conditions

Conditions	Yield
With ammonium peroxydisulfate; 2,4,6-triphenylpyrylium tetrafluoroborate In dichloromethane at 20℃; Irradiation;	61%

: 17332-11-5
2-bromo-4-methoxyphenol

: 41317-15-1
4-phenylamino-3-methyl-1-methoxybenzene

: C21H20BrNO3

Conditions

Conditions	Yield
With ammonium peroxydisulfate; 2,4,6-triphenylpyrylium tetrafluoroborate In dichloromethane at 20℃; Irradiation;	54%

: 41317-15-1
4-phenylamino-3-methyl-1-methoxybenzene

: 68065-11-2
4-(3-bromopropyl)-1,4-hydroquinone

: C23H24BrNO3

Conditions

Conditions	Yield
With ammonium peroxydisulfate; 2,4,6-triphenylpyrylium tetrafluoroborate In dichloromethane at 20℃; Irradiation;	52%

Methoxymethyldiphenylamine Chemical Properties

Molecular Formula:C₁₄H₁₅NO
Molecular Weight:213.28
EINECS:255-310-0
Density:1.089g/cm³
Melting Point:80-83 °C
Boiling Point:171 °C / 4mmHg
Flash Point:140.1°C
4-Methoxy-2-Methyldiphenylamine's Synonyms: ACME;4-METHOXY-2-METHYLDIPHENYLAMINE;2-METHYL-4-METHOXYDIPHENYLAMINE;methoxymethyldiphenylamine;ANMT/DPA;MMD;4-methoxy-N-phenyl-o-toluidine;2-methyl-4-methoxy diphenylamine C₁₄H₁₅NO

Methoxymethyldiphenylamine Uses

4-Methoxy-2-methyldiphenylamine is a synthetic organic chemical used in the production of black color formers

Methoxymethyldiphenylamine Safety Profile

These products are toxic carbon oxides (CO, CO 2), nitrogen oxides (NO, NO2).
Fire Fighting Mediaand Instructions:Small fire: Use dry chemical powder.
Large fire: Use water spray, fog or foam. do not use water jet.

Methoxymethyldiphenylamine Specification

4-Methoxy-2-Methyldiphenylamine's handling and storage
Keep away from HEAT. Mechanical exhaust required. When not in use, tightly seal the container and store in a dry, cool
place. Avoid excessive HEAT and light. Do not breathe dust.
Always store away from incompatible compounds such as oxidizing agents.
4-Methoxy-2-Methyldiphenylamine's Hazards Identification
Acute Health Effects:No specific information is available in our data base regarding the toxic effects of this material for humans. However,exposure to any chemical should be kept to a minimum. Skin and eye contact may result in irritation. May be harmful if inhaled or ingested. Always follow safe industrial hygiene practices and wear proper protective equipment when handling
this compound.Follow safe industrial hygiene practices and always wear proper protective equipment when handling this compound.

Product Name

Methoxymethyldiphenylamine

Synthetic route

Methoxymethyldiphenylamine Chemical Properties

Methoxymethyldiphenylamine Uses

Methoxymethyldiphenylamine Safety Profile

Methoxymethyldiphenylamine Specification

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