Phenyltrimethylammonium bromide supplier

Name
Phenyltrimethylammonium bromide
EINECS 240-202-8
CAS No. 16056-11-4
Density 1.2
Solubility almost transparency in Water
Melting Point 215 °C (dec.)(lit.)
Formula C₉H₁₄BrN
Boiling Point
Molecular Weight 216.121
Flash Point
Transport Information UN 2811
Appearance white to blue crystalline powder or chunks
Safety 26-37/39
Risk Codes 36/37/38
Molecular Structure
Hazard Symbols Xi
Synonyms Ammonium,trimethylphenyl-, bromide (8CI);Benzenaminium, N,N,N-trimethyl-, bromide(9CI);Trimethylphenylammonium bromide (6CI,7CI);N,N,N-Trimethylaniliniumbromide;
PSA 0.00000
LogP -1.11270

Synthetic route

: 67-56-1
methanol

: 121-69-7
N,N-dimethyl-aniline

: 16056-11-4
N,N,N-trimethylanilinium bromide

Conditions

Conditions	Yield
at 120 - 130℃; beim Erhitzen von feuchtem bromwasserstoffsauren Dimethylanilin im Druckrohr;

: 74-83-9
methyl bromide

: 121-69-7
N,N-dimethyl-aniline

: 16056-11-4
N,N,N-trimethylanilinium bromide

: 506-68-3
bromocyane

: 121-69-7
N,N-dimethyl-aniline

A: 18773-77-8
methyl(phenyl)cyanamide

B: 16056-11-4
N,N,N-trimethylanilinium bromide

...Expand

: 506-96-7
Acetyl bromide

: 121-69-7
N,N-dimethyl-aniline

A: 579-10-2
N-acetyl-N-methylaniline

B: 16056-11-4
N,N,N-trimethylanilinium bromide

...Expand

: 121-69-7
N,N-dimethyl-aniline

: 70-11-1
α-bromoacetophenone

A: 32119-53-2
N-methyl-N-phenacylaniline

B: 16056-11-4
N,N,N-trimethylanilinium bromide

...Expand

: 121-69-7
N,N-dimethyl-aniline

: 107-82-4
i-pentyl bromide

A: 91935-09-0
N-isopentyl-N-methylaniline

B: 16056-11-4
N,N,N-trimethylanilinium bromide

Conditions

Conditions	Yield
at 150 - 160℃;

...Expand

: 121-69-7
N,N-dimethyl-aniline

: 535-11-5, 41978-69-2
Ethyl 2-bromopropionate

A: 214709-69-0
2-(methyl-phenyl-amino)-propionic acid ethyl ester

B: 16056-11-4
N,N,N-trimethylanilinium bromide

Conditions

Conditions	Yield
at 125 - 130℃;

...Expand

: 121-69-7
N,N-dimethyl-aniline

: 590-17-0
cyanomethyl bromide

: 16056-11-4
N,N,N-trimethylanilinium bromide

: 67-56-1
methanol

: 62-53-3
aniline

A: 16056-11-4
N,N,N-trimethylanilinium bromide

B: 121-69-7
N,N-dimethyl-aniline

Conditions

Conditions	Yield
at 120 - 130℃; beim Erhitzen von bromwasserstoffsaurem Anilin;

...Expand

: 4207-56-1
phenyltrimethylammonium tribromide

: 67-64-1
acetone

: 16056-11-4
N,N,N-trimethylanilinium bromide

Conditions

Conditions	Yield
beim gelinden Erwaermen;

: 52045-06-4
tri-N-methyl-anilinium; dibromo iodate(I)

: 67-64-1
acetone

: 16056-11-4
N,N,N-trimethylanilinium bromide

: tri-N-methyl-anilinium; bromochloro iodate(I)

: 67-64-1
acetone

: 16056-11-4
N,N,N-trimethylanilinium bromide

: 121-69-7
N,N-dimethyl-aniline

: 572-09-8
2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide

: 16056-11-4
N,N,N-trimethylanilinium bromide

Conditions

Conditions	Yield
at 25℃;

: 32119-53-2
N-methyl-N-phenacylaniline

: 121-69-7
N,N-dimethyl-aniline

: 70-11-1
α-bromoacetophenone

A: 16056-11-4
N,N,N-trimethylanilinium bromide

B diphenylacyl-aniline: diphenylacyl-aniline

...Expand

: 121-69-7
N,N-dimethyl-aniline

A: 16056-11-4
N,N,N-trimethylanilinium bromide

B hydrobromide of monomethylaniline: hydrobromide of monomethylaniline

Conditions

Conditions	Yield
at 150℃; beim Erhitzen von bromwasserstoffsaurem Dimethylanilin;

: 121-69-7
N,N-dimethyl-aniline

: 70-11-1
α-bromoacetophenone

A: 16056-11-4
N,N,N-trimethylanilinium bromide

B N-methyl-N-phenacyl-aniline: N-methyl-N-phenacyl-aniline

...Expand

: 121-69-7
N,N-dimethyl-aniline

: 70-11-1
α-bromoacetophenone

A: 41120-12-1
N,N-diphenacylaniline

B: 16056-11-4
N,N,N-trimethylanilinium bromide

C N-methyl-N-phenacyl-aniline: N-methyl-N-phenacyl-aniline

...Expand

: 7732-18-5
water

: 4207-56-1
phenyltrimethylammonium tribromide

: 16056-11-4
N,N,N-trimethylanilinium bromide

Conditions

Conditions	Yield
beim Kochen;

: 67-56-1
methanol

hydrobromide of dimethylaniline: hydrobromide of dimethylaniline

: 16056-11-4
N,N,N-trimethylanilinium bromide

: 121-69-7
N,N-dimethyl-aniline

: 70-11-1
α-bromoacetophenone

A: 16056-11-4
N,N,N-trimethylanilinium bromide

B methyl-phenacyl-aniline; diphenacyl-aniline: methyl-phenacyl-aniline; diphenacyl-aniline

...Expand

: 16056-11-4
N,N,N-trimethylanilinium bromide

: 93296-10-7
(4-(dimethylamino)phenyl)zinc(II) chloride

: 1137-79-7
N,N-dimethyl-4-biphenylamine

Conditions

Conditions	Yield
With C27H22Cl2N3NiP In tetrahydrofuran; 1-methyl-pyrrolidin-2-one for 12h; Inert atmosphere; Schlenk technique; Heating;	98%
With bis(tricyclohexylphosphine)nickel(II) dichloride In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 90℃; for 8h; Negishi coupling reaction; Inert atmosphere;	84%

: 16056-11-4
N,N,N-trimethylanilinium bromide

: 93296-09-4
4-methoxyphenylzinc chloride

: 613-37-6
4-methoxylbiphenyl

Conditions

Conditions	Yield
With C27H22Cl2N3NiP In tetrahydrofuran; 1-methyl-pyrrolidin-2-one for 12h; Solvent; Inert atmosphere; Schlenk technique; Heating;	98%
With C38H34Br2N4Ni2P2 In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 65℃; for 12h; Inert atmosphere; Schlenk technique;	94%
With C32H26ClN2NiP In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 85℃; for 12h; Inert atmosphere;	74%

: 16056-11-4
N,N,N-trimethylanilinium bromide

: 90252-89-4
p-tolylzinc(II) chloride

: 644-08-6
4-Methylbiphenyl

Conditions

Conditions	Yield
With C27H22Cl2N3NiP In tetrahydrofuran; 1-methyl-pyrrolidin-2-one for 12h; Inert atmosphere; Heating; Schlenk technique;	90%

: 1182669-71-1
N-(2-methylbenzoyl)-8-aminoquinoline

: 16056-11-4
N,N,N-trimethylanilinium bromide

: 1609401-42-4
2,6-dimethyl-N-(quinolin-8-yl)benzamide

Conditions

Conditions	Yield
With nickel(II) triflate; sodium carbonate; triphenylphosphine In toluene at 160℃; for 14h;	90%

: 16056-11-4
N,N,N-trimethylanilinium bromide

: 2C9H14N(1+)*Br6Te2(2-)

Conditions

Conditions	Yield
With tellurium; bromine In acetonitrile for 24h; Heating;	88%

: 16056-11-4
N,N,N-trimethylanilinium bromide

: phenyltrimethylammonium hexabromoselenate

Conditions

Conditions	Yield
With selenium; bromine In acetonitrile Heating;	87%

: 16056-11-4
N,N,N-trimethylanilinium bromide

: phenyltrimetylammonium selenocyanate

: phenyltrimethylammonium hexabromoselenate

Conditions

Conditions	Yield
With bromine In acetonitrile Ambient temperature;	86%

: 16056-11-4
N,N,N-trimethylanilinium bromide

: 73183-34-3
bis(pinacol)diborane

: 13327-62-3
2-mercaptopyridine sodium salt

A: 18438-38-5
2-methylsulfanyl-pyridine

B: 24388-23-6
2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

C: 121-69-7
N,N-dimethyl-aniline

D: 108-95-2
phenol

Conditions

Conditions	Yield
In acetonitrile at 30 - 35℃; for 24h; Irradiation; Inert atmosphere;	A 64% B 22% C 81% D 6%

...Expand

: 16056-11-4
N,N,N-trimethylanilinium bromide

: 73183-34-3
bis(pinacol)diborane

: 24388-23-6
2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

Conditions

Conditions	Yield
With 10H-phenothiazine; caesium carbonate In acetonitrile for 18h; Irradiation; Sealed tube; Inert atmosphere;	76%

: 16056-11-4
N,N,N-trimethylanilinium bromide

: 766-97-2
4-n-methylphenylacetylene

: 3287-02-3
4-(phenylethynyl)toluene

Conditions

Conditions	Yield
With SIPr-PdCl2-Py; sodium t-butanolate In tetrahydrofuran at 45℃; for 4h; Sonogashira Cross-Coupling; Inert atmosphere;	60%

: disodium closo-dodecaborate

: 1643-19-2
tetrabutylammomium bromide

: 16056-11-4
N,N,N-trimethylanilinium bromide

: 122-04-3
4-nitro-benzoyl chloride

A: [N(C4H9)4]2 (hydroxo)undecahydro-closo-dodecaborane

B: 2(CH3)3(C6H5)N(1+)*B12H11COC6H4NO2(2-) = [(CH3)3(C6H5)N]2(B12H11COC6H4NO2)

Conditions

Conditions	Yield
In acetone byproducts: NaCl; stirring (-20°C, 30 min and 20°C, 20 h); pptn., drying; elem. anal.;	A 1% B 58%

...Expand

: 16056-11-4
N,N,N-trimethylanilinium bromide

: 13327-62-3
2-mercaptopyridine sodium salt

A: 18438-38-5
2-methylsulfanyl-pyridine

B: 3111-54-4
2-phenylsulfanylpyridine

C: 121-69-7
N,N-dimethyl-aniline

D: 108-95-2
phenol

Conditions

Conditions	Yield
In acetonitrile at 30 - 35℃; for 24h; Irradiation; Inert atmosphere;	A 49% B 22% C 37% D 15%

...Expand

: 16056-11-4
N,N,N-trimethylanilinium bromide

: 84109-17-1
2-methylphenylzinc chloride

: 643-58-3
2-methylbiphenyl

Conditions

Conditions	Yield
With C27H22Cl2N3NiP In tetrahydrofuran; 1-methyl-pyrrolidin-2-one for 12h; Inert atmosphere; Heating; Schlenk technique;	46%

: 439145-80-9
5-Acetyl-2-benzyloxy-N-[3,5-bis(trifluoromethyl)phenyl]benzamide

: 16056-11-4
N,N,N-trimethylanilinium bromide

: 439145-82-1
2-Benzyloxy-5-(2-bromoacetyl)-N-[3,5-bis(trifluoromethyl)phenyl]benzamide

Conditions

Conditions	Yield
In tetrahydrofuran	42.7%

: 16056-11-4
N,N,N-trimethylanilinium bromide

: 6427-70-9
benzyltrimethylammonium hexafluorophosphate

Conditions

Conditions	Yield
With ammonium hexafluorophosphate In water; acetone for 4h; Inert atmosphere; Schlenk technique;	40%

: 16056-11-4
N,N,N-trimethylanilinium bromide

: 13139-86-1
4-methoxyphenyl magnesium bromide

: 613-37-6
4-methoxylbiphenyl

Conditions

Conditions	Yield
With 1,3-bis[(diphenylphosphino)propane]dichloronickel(II) In tetrahydrofuran at 20℃; for 48h; Inert atmosphere;	12%

: 16056-11-4
N,N,N-trimethylanilinium bromide

: 3,4-dibromo-tri-N-methyl-anilinium; bromide

Conditions

Conditions	Yield
With bromine; iron at 100 - 120℃;

: 16056-11-4
N,N,N-trimethylanilinium bromide

: tri-N-methyl-anilinium; bromide, compound with bromine

Conditions

Conditions	Yield
With bromine; acetic acid

: 16056-11-4
N,N,N-trimethylanilinium bromide

: 3-bromo-tri-N-methyl-anilinium; bromide

Conditions

Conditions	Yield
With bromine; iron at 70℃;

: 16056-11-4
N,N,N-trimethylanilinium bromide

: 4207-56-1
phenyltrimethylammonium tribromide

Conditions

Conditions	Yield
With bromine

: 16056-11-4
N,N,N-trimethylanilinium bromide

: 52045-06-4
tri-N-methyl-anilinium; dibromo iodate(I)

Conditions

Conditions	Yield
With iodine(I) bromide; acetic acid

: 16056-11-4
N,N,N-trimethylanilinium bromide

: phenyltrimethylammonium dichloroiodate

Conditions

Conditions	Yield
With Iodine monochloride; acetic acid
With iodine trichloride; acetic acid

: 16056-11-4
N,N,N-trimethylanilinium bromide

: tri-N-methyl-anilinium; bromochloro iodate(I)

Conditions

Conditions	Yield
With Iodine monochloride; acetic acid

: 16056-11-4
N,N,N-trimethylanilinium bromide

: 16091-28-4
tri-N-methyl-anilinium; dichloro bromate(I)

Conditions

Conditions	Yield
With chlorine; acetic acid at 60℃;

: 16056-11-4
N,N,N-trimethylanilinium bromide

: tri-N-methyl-anilinium; bromide, compound with iodine

Conditions

Conditions	Yield
With iodine; acetic acid at 100℃;

: 16056-11-4
N,N,N-trimethylanilinium bromide

A: 74-83-9
methyl bromide

B: 121-69-7
N,N-dimethyl-aniline

Conditions

Conditions	Yield
at 240℃;
In dimethylsulfoxide-d6 at 120℃; for 0.333333h;

Phenyltrimethylammonium bromide Chemical Properties

IUPAC Name: Benzenaminium, N,N,N-trimethyl-, bromide (1:1)
The MF of Benzenaminium, N,N,N-trimethyl-, bromide (1:1) (16056-11-4) is C₉H₁₄BrN.

The MW of Benzenaminium, N,N,N-trimethyl-, bromide (1:1) (16056-11-4) is 216.12.
Synonyms of Benzenaminium, N,N,N-trimethyl-, bromide (1:1) (16056-11-4): Trimethylphenylammonium bromide ; N,N,N-Trimethylanilinium bromide ; Phenyltrimethylammonium bromide ; N,N-Trimethyl-benzenaminiumbromide ; Phenyltrimethyl-ammoniubromide ; N-Phenyl-N,N,N-Trimethylammonium bromide
Product Categories: Ammonium Bromides (Quaternary);Quaternary Ammonium Compounds
Form: white to blue crystalline powder or chunks
Melting Point: 215 °C (dec.)(lit.)
Storage temp: Refrigerator
Density: 1.2 g/ml
EINECS: 240-202-8

Phenyltrimethylammonium bromide Uses

Benzenaminium, N,N,N-trimethyl-, bromide (1:1) (16056-11-4) is used as transfer catalyst and surface active agent.

Phenyltrimethylammonium bromide Toxicity Data With Reference

ivn-mus LD50:4 mg/kg

JPETAB Journal of Pharmacology and Experimental Therapeutics. 99 (1950),16.

Phenyltrimethylammonium bromide Consensus Reports

Reported in EPA TSCA Inventory.

Phenyltrimethylammonium bromide Safety Profile

Poison by intravenous route. When heated to decomposition it emits very toxic fumes of NO_x, NH₃, and Br⁻. See also BROMIDES.
Safety information of Benzenaminium, N,N,N-trimethyl-, bromide (1:1) (16056-11-4):
Hazard Codes Xi
Risk Statements
36/37/38 Irritating to eyes, respiratory system and skin
Safety Statements
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
37/39 Wear suitable gloves and eye/face protection
RIDADR 2811
WGK Germany 3
RTECS BT2100000
HazardClass 6.1(b)
PackingGroup III

Product Name

Phenyltrimethylammonium bromide

Synthetic route

Phenyltrimethylammonium bromide Chemical Properties

Phenyltrimethylammonium bromide Uses

Phenyltrimethylammonium bromide Toxicity Data With Reference

Phenyltrimethylammonium bromide Consensus Reports

Phenyltrimethylammonium bromide Safety Profile

Related Products

Hot Products