Product Name

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  • Name

    Phosphorus

  • EINECS 231-768-7
  • CAS No. 7723-14-0
  • Density 2.34 g/mL at 25 °C
  • Solubility insoluble in water
  • Melting Point 590 °C
  • Formula P
  • Boiling Point 280 °C
  • Molecular Weight 36.0135
  • Flash Point 30 °C
  • Transport Information UN 1381/1338/2447
  • Appearance reddish-brown powder
  • Safety 7-43-61-43C-45-38-26-5-27-6
  • Risk Codes 11-16-52/53-50-35-26/28-17
  • Molecular Structure Molecular Structure of 7723-14-0 (Phosphorus)
  • Hazard Symbols FlammableF,CorrosiveC,DangerousN,VeryT+
  • Synonyms Black phosphorus;Exolit 385;Exolit 405;Exolit LPKN 275;Exolit PR 602;Exolit RP 605;Exolit RP 607;Exolit RP 650;ExolitRP 6500;Exolit RP 652;Exolit RP 654;Exolit RP 683;Exolit RP 689;Exolit RP694;Exolit RP 695;Exolit VPK-n 361;FR 120UFA;FR-P;FR-T 2;FR-T 2(element);FRW 30;Hishigado;Hishigado AP;Hishigado CP;Hishigado EL-Z;Hishigado LP-E;Hishigado LP-F;Hishigado NP 10;Hishigado PL;Hishigado TP-A10;Hishigado White LP;Hostaflam RP 602;Hostaflam RP 614;Hostaflam RP 622;Hostaflam RP 654;Masteret 70450;NVE 140;Nova Quell;Nova Sol R 20;Novaexcel140;Novaexcel 140F;Novaexcel 150;Novaexcel F 5;Novaexcel ST 100;NovaexcelST 140;Novaexcel ST 300;Novared 1200;Novared 120F;Novared 120UF;Novared120UFA;Novared 120VFA;Novared 140;Novared 280;Novared C 120;Novared F 5;PX 140;Phosphorus-31;RP 614;RP 654;RPM 540B;RPM 650;Safest A;120UFA;31P;Amgard CPC;Amgard CPC 405;
  • PSA 13.59000
  • LogP 0.05810

Synthetic route

lithium aluminium tetrahydride
16853-85-3

lithium aluminium tetrahydride

phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

A

phosphorane
7723-14-0

phosphorane

B

phosphan
7803-51-2

phosphan

Conditions
ConditionsYield
In not given byproducts: H2; reduction of PCl5 with LiAlH4; formation of decompn. products of PH5;;A 0%
B n/a
In not given byproducts: H2; reduction of PCl5 with LiAlH4; formation of decompn. products of PH5;;A 0%
B n/a
hydrogen

hydrogen

phosphan
7803-51-2

phosphan

phosphorane
7723-14-0

phosphorane

Conditions
ConditionsYield
In not given byproducts: H2; react. of H with PH3 at ambient temp. or at the temp. of liquid air;;0%
In not given reaction H with PH3;;
In not given reaction of H with PH3;;0%
In not given reaction H with PH3;;
In not given reaction of H with PH3;;0%
lithium borohydride

lithium borohydride

phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

A

phosphorane
7723-14-0

phosphorane

B

phosphan
7803-51-2

phosphan

Conditions
ConditionsYield
In not given byproducts: H2; reduction of PCl5 with LiBH4; formation of decompn. products of PH5;;A 0%
B n/a
In not given byproducts: H2; reduction of PCl5 with LiBH4; formation of decompn. products of PH5;;A 0%
B n/a
phosphorane
7723-14-0

phosphorane

2-(2-Thienyl)-4-benzyloxycarbonyl-2-butenoic acid

2-(2-Thienyl)-4-benzyloxycarbonyl-2-butenoic acid

2-fluoroethyl tosylate
383-50-6

2-fluoroethyl tosylate

7beta-Amino-3-(2-fluoroethylthio)-3-cephem-4-carboxylic acid p-nitrobenzyl ester

7beta-Amino-3-(2-fluoroethylthio)-3-cephem-4-carboxylic acid p-nitrobenzyl ester

Conditions
ConditionsYield
With sodium iodide In N,N,N,N,N,N-hexamethylphosphoric triamide; dichloromethane87.8%
phosphorane
7723-14-0

phosphorane

3-oxo-4,4-dimethyl-5α-chola-8,14-dien-24-aldehyde

3-oxo-4,4-dimethyl-5α-chola-8,14-dien-24-aldehyde

isopropyltriphenylphosphonium bromide
1530-33-2

isopropyltriphenylphosphonium bromide

Ph3PCH(CH3)2

Ph3PCH(CH3)2

Conditions
ConditionsYield
With n-butyllithium; ammonium chloride In tetrahydrofuran; diethyl ether50%
With n-butyllithium; ammonium chloride In tetrahydrofuran; diethyl ether50%
phosphorane
7723-14-0

phosphorane

1-{8-[2-(4-Cyclobutyl-1,3-thiazol-2-yl)ethyl]-3-formyl-4-oxo-4H-pyrido[1,2-a]-pyrimidin-2-yl}-3-piperidyl formate
475057-74-0

1-{8-[2-(4-Cyclobutyl-1,3-thiazol-2-yl)ethyl]-3-formyl-4-oxo-4H-pyrido[1,2-a]-pyrimidin-2-yl}-3-piperidyl formate

(tert-Butoxycarbonylmethylene)triphenylphosphorane
86302-43-4

(tert-Butoxycarbonylmethylene)triphenylphosphorane

tert-Butyl (E)-3-[8-[2-(4-cyclobutyl-1,3-thiazol-2-yl)ethyl]-2-(3-formyloxy-piperidino)-4-oxo-4H-pyrido[1,2-a]pyrimidin-3-yl]-2-propenoate
475057-75-1

tert-Butyl (E)-3-[8-[2-(4-cyclobutyl-1,3-thiazol-2-yl)ethyl]-2-(3-formyloxy-piperidino)-4-oxo-4H-pyrido[1,2-a]pyrimidin-3-yl]-2-propenoate

Conditions
ConditionsYield
In tetrahydrofuran
phosphorane
7723-14-0

phosphorane

acetaldehyde
75-07-0

acetaldehyde

2-benzyl-but-2-enoic acid tert-butyl ester

2-benzyl-but-2-enoic acid tert-butyl ester

phosphorane
7723-14-0

phosphorane

diethyl ether
60-29-7

diethyl ether

(carbethoxyethylidene)triphenylphosphorane
21382-82-1

(carbethoxyethylidene)triphenylphosphorane

ethyl 5-<3,4-dihydro-6-<(2-methoxyethoxy)methoxy>-2,5,7,8-tetramethyl-2H-1-benzopyran-2-yl>-2-methyl-2(E)-pentanoate
135897-86-8

ethyl 5-<3,4-dihydro-6-<(2-methoxyethoxy)methoxy>-2,5,7,8-tetramethyl-2H-1-benzopyran-2-yl>-2-methyl-2(E)-pentanoate

Conditions
ConditionsYield
In benzene
phosphorane
7723-14-0

phosphorane

tetrabutyl ammonium fluoride
429-41-4

tetrabutyl ammonium fluoride

(4-chlorobenzyl)triphenylphosphonium chloride
1530-39-8

(4-chlorobenzyl)triphenylphosphonium chloride

6-(1-p-chlorophenylbuten-4-yl)-5-hydroxy-3-methyl-2-p-methoxybenzyl-2,3-dihydrobenzofuran

6-(1-p-chlorophenylbuten-4-yl)-5-hydroxy-3-methyl-2-p-methoxybenzyl-2,3-dihydrobenzofuran

Conditions
ConditionsYield
In ethanol; hexane; ethyl acetate
phosphorane
7723-14-0

phosphorane

methyl (triphenylphosphoranylidene)acetate
21204-67-1

methyl (triphenylphosphoranylidene)acetate

A

phthalide ester

phthalide ester

B

phthalidyl 6-(3-methoxycarbonylprop-2-ene-1-yl)-7-oxo-1-azabicyclo[3.2.0]hept-2-ene-2-carboxylate

phthalidyl 6-(3-methoxycarbonylprop-2-ene-1-yl)-7-oxo-1-azabicyclo[3.2.0]hept-2-ene-2-carboxylate

Conditions
ConditionsYield
With sodium bicarbonate In ethyl acetate; trifluoroacetic acid
With sodium bicarbonate In ethyl acetate; trifluoroacetic acid
phosphorane
7723-14-0

phosphorane

methyl (triphenylphosphoranylidene)acetate
21204-67-1

methyl (triphenylphosphoranylidene)acetate

Phthalimidomethyl 6-(3-methoxycarbonyl-2-propen-1-yl)-7-oxo-1-azabicyclo[3,2,0]hept-2-ene-2-carboxylate

Phthalimidomethyl 6-(3-methoxycarbonyl-2-propen-1-yl)-7-oxo-1-azabicyclo[3,2,0]hept-2-ene-2-carboxylate

Conditions
ConditionsYield
With sodium bicarbonate; trifluoroacetic acid In ethyl acetate
phosphorane
7723-14-0

phosphorane

methyl (triphenylphosphoranylidene)acetate
21204-67-1

methyl (triphenylphosphoranylidene)acetate

Pivaloyloxymethyl 6-(3-methoxycarbonyl-2-propen-1-yl)-7-oxo-1-azabicyclo[3,2,0]hept-2-ene-2-carboxylate
68485-77-8, 104974-74-5

Pivaloyloxymethyl 6-(3-methoxycarbonyl-2-propen-1-yl)-7-oxo-1-azabicyclo[3,2,0]hept-2-ene-2-carboxylate

Conditions
ConditionsYield
With ozone; sodium bicarbonate; trifluoroacetic acid In dichloromethane; ethyl acetate
With ozone; sodium bicarbonate; trifluoroacetic acid In dichloromethane; ethyl acetate
2,6-dimethylpyridine
108-48-5

2,6-dimethylpyridine

p-nitrobenzyl ester

p-nitrobenzyl ester

chloro-azetidinone
153357-31-4

chloro-azetidinone

palladium on Celite

palladium on Celite

phosphorane
7723-14-0

phosphorane

water
7732-18-5

water

triphenylphosphine
603-35-0

triphenylphosphine

2-ethylpenem-3-carboxylic acid

2-ethylpenem-3-carboxylic acid

Conditions
ConditionsYield
With hydrogenchloride; sodium hydrogencarbonate In tetrahydrofuran; toluene; benzene
2,6-dimethylpyridine
108-48-5

2,6-dimethylpyridine

phosphorane
7723-14-0

phosphorane

4-thiobenzoyloxy 2-azetidinone

4-thiobenzoyloxy 2-azetidinone

p-nitrobenzyl glyoxylate monohydrate

p-nitrobenzyl glyoxylate monohydrate

sodium-1-carba-2-phenyl-2-penem-3-carboxylate

sodium-1-carba-2-phenyl-2-penem-3-carboxylate

Conditions
ConditionsYield
With thionyl chloride; triphenylphosphine In dichloromethane; toluene; benzene
phosphorane
7723-14-0

phosphorane

(1S,5R,6R,7R)-6-formyl-7-benzoyloxy-2-oxabicyclo[3.3.0]octan-3-one
39746-01-5

(1S,5R,6R,7R)-6-formyl-7-benzoyloxy-2-oxabicyclo[3.3.0]octan-3-one

(1S,5R,6R,7R)-7-benzoyloxy-6-[(E)-7-methyl-3-oxo-1,6-octadienyl]-2-oxabicyclo[3.3.0]-octan-3-one

(1S,5R,6R,7R)-7-benzoyloxy-6-[(E)-7-methyl-3-oxo-1,6-octadienyl]-2-oxabicyclo[3.3.0]-octan-3-one

Conditions
ConditionsYield
In hexane; ethyl acetate; benzene
phosphorane
7723-14-0

phosphorane

2-(triphenylphosphoranylidene)propionaldehyde
24720-64-7

2-(triphenylphosphoranylidene)propionaldehyde

ethyl iodide
75-03-6

ethyl iodide

triphenylphosphine
603-35-0

triphenylphosphine

ethyltriphenylphosphonium iodide
4736-60-1

ethyltriphenylphosphonium iodide

Conditions
ConditionsYield
In pentane; benzene
ethyl 2-methyl-3-(2-methyl-5-isopropyl-cyclopent-1-en-1-yl)-prop-2-enoate

ethyl 2-methyl-3-(2-methyl-5-isopropyl-cyclopent-1-en-1-yl)-prop-2-enoate

phosphorane
7723-14-0

phosphorane

triphenylphosphine
603-35-0

triphenylphosphine

Ethyl 2-bromopropionate
535-11-5, 41978-69-2

Ethyl 2-bromopropionate

2-methyl-3-(2-methyl-5-isopropyl-cyclopent-1-en-1-yl)-prop-2-enol

2-methyl-3-(2-methyl-5-isopropyl-cyclopent-1-en-1-yl)-prop-2-enol

Conditions
ConditionsYield
In benzene
phosphorane
7723-14-0

phosphorane

methyl (triphenylphosphoranylidene)acetate
21204-67-1

methyl (triphenylphosphoranylidene)acetate

benzyl 6-(3-methoxycarbonylprop-2-ene-1-yl)-7-oxo-1-azabicyclo[3.2.0]hept-2-ene-2-carboxylate
68485-41-6, 71559-75-6, 72746-90-8

benzyl 6-(3-methoxycarbonylprop-2-ene-1-yl)-7-oxo-1-azabicyclo[3.2.0]hept-2-ene-2-carboxylate

Conditions
ConditionsYield
With trifluoroacetic acid In chloroform; ethyl acetate
phosphorane
7723-14-0

phosphorane

methyl (triphenylphosphoranylidene)acetate
21204-67-1

methyl (triphenylphosphoranylidene)acetate

2,2,2-Trichloroethyl 6-(3-methoxycarbonylprop-2-ene-1-yl)-7-oxo-1-azabicyclo[3.2.0]hept-2-ene-2-carboxylate
68485-44-9, 72746-80-6

2,2,2-Trichloroethyl 6-(3-methoxycarbonylprop-2-ene-1-yl)-7-oxo-1-azabicyclo[3.2.0]hept-2-ene-2-carboxylate

Conditions
ConditionsYield
With trifluoroacetic acid In EtAc; chloroform

Phosphorus Consensus Reports

EPA Extremely Hazardous Substances List. Reported in EPA TSCA Inventory.

Phosphorus Standards and Recommendations

OSHA PEL: TWA 0.1 mg/m3
ACGIH TLV: TWA 0.1 mg/m3
DOT Classification:  4.2; Label: Spontaneously Combustible, Poison

Phosphorus Analytical Methods

For occupational chemical analysis use NIOSH: Elements (ICP) 7300; Phosphorus 7905.

Phosphorus Specification

The IUPAC name of Phosphorus is phosphane. With the CAS registry number 7723-14-0, it is also named as Red phosphorus. The product's categories are Inorganic Chemicals; Inorganics; Elemental PhosphorusMicro / Nanoelectronics; Catalysis and Inorganic Chemistry; Electronic Chemicals; Phosphorus Compounds; Pure Elements; Elemental Phosphorus; AA Standard Solutions Spectroscopy; AAS; Matrix Selection; OtherAlphabetic; P; PER - POLASpectroscopy; Reference / Calibration Standards; Single Solution; Standard Solutions, and the other registry number is 29879-37-6. Besides, it is reddish-brown powder, which is insoluble in water and denser than water. It should be kept in the water and immersed in water, with isolation from the air. In addition, it is incompatible with strong oxidizing agents, strong bases which is light and heat sensitive.

The other characteristics of this product can be summarized as: (1)H bond acceptors: 0; (2)H bond donors: 0; (3)Freely Rotating Bonds: 0; (4)Density: 2.34 g/mL at 25 °C; (5)Flash Point: 30 °C; (6)Enthalpy of Vaporization: 16.96 kJ/mol; (7)Boiling Point: 280 °C; (8)Melting point: 590 °C; (9)Vapour Pressure: 27300 mmHg at 25 °C; (10)Vapor Density: 0.02 (vs air); (11)EINECS: 231-768-7.

Preparation of Phosphorus: Please put Yellow Phosphorus in the sealed cast iron pot. And you should heat Yellow Phosphorus for several hours slight below 420 °C with isolation from the air. It would be converted to red Phosphorus.

Uses of Phosphorus: this chemical is used for the preparation of semiconductor compound and doping agent of semiconductor material. Furthermore, this chemical is used for producing matches, fireworks, and Aluminum phosphide, Phosphorus pentoxide, Phosphorus trichloride, etc. And it is the raw material of producing organic phosphorus pesticide. Additionally, it is used for the production of phosphor bronze in metallurgical industry. It is also used for deacidification of light metal and pharmaceutical.

When you are using this chemical, please be cautious about it as the following: it is highly flammable and spontaneously flammable in air. It also may explosive when mixed with oxidizing substances and cause severe burns. Moreover, it is very toxic by inhalation and if swallowed and very toxic to aquatic organisms. It is harmful to aquatic organisms, which may cause long-term adverse effects in the aquatic environment. Please keep contents under ... (there follows the name of a liquid). and under ... (there follows the name of an inert gas). And you should keep container tightly closed. In case of contact with eyes, please rinse immediately with plenty of water and seek medical advice. Aditionally, you should take off immediately all contaminated clothing. And in case of insufficient ventilation, please wear suitable respiratory equipment. Besides, in case of fire use ... (there follows the type of fire-fighting equipment to be used.). In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.). And you should avoid release to the environment and please refer to special instructions / safety data sheets.

People can use the following data to convert to the molecule structure.
(1)SMILES:P
(2)InChI:InChI=1/P
(3)InChIKey:OAICVXFJPJFONN-UHFFFAOYAC
(4)Std. InChI:InChI=1S/P
(5)Std. InChIKey:OAICVXFJPJFONN-UHFFFAOYSA-N

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
cat LDLo oral 4mg/kg (4mg/kg)   Yakkyoku. Pharmacy. Vol. 28, Pg. 329, 1977.
dog LDLo oral 10mg/kg (10mg/kg)   Yakkyoku. Pharmacy. Vol. 28, Pg. 329, 1977.
dog LDLo subcutaneous 2mg/kg (2mg/kg) BEHAVIORAL: FOOD INTAKE (ANIMAL)

LIVER: FATTY LIVER DEGERATION

CARDIAC: OTHER CHANGES
Archiv fuer Experimentelle Pathologie und Pharmakologie. Vol. 52, Pg. 173, 1905.
duck LDLo oral 3mg/kg (3mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: MUSCLE WEAKNESS

BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD
Journal of the American Pharmaceutical Association, Scientific Edition. Vol. 39, Pg. 151, 1950.
human LDLo oral 1400ug/kg (1.4mg/kg)   Pesticide Chemicals Official Compendium, Association of the American Pesticide Control Officials, Inc., 1966. Vol. -, Pg. 901, 1966.
mammal (species unspecified) LDLo oral 200mg/kg (200mg/kg)   "Pesticide Index," Frear, E.H., ed., State College, PA, College Science Pub., 1969Vol. 4, Pg. 321, 1969.
man LDLo unreported 4412ug/kg (4.412mg/kg)   "Poisoning; Toxicology, Symptoms, Treatments," 2nd ed., Arena, J.M., Springfield, IL, C.C. Thomas, 1970Vol. 2, Pg. 73, 1970.
mouse LD50 oral 4820ug/kg (4.82mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES

BEHAVIORAL: FOOD INTAKE (ANIMAL)
National Technical Information Service. Vol. AD-B011-150,
pig LDLo oral 160mg/kg (160mg/kg)   "Pesticide Index," Frear, E.H., ed., State College, PA, College Science Pub., 1969Vol. 4, Pg. 321, 1969.
rabbit LDLo subcutaneous 10mg/kg (10mg/kg) BEHAVIORAL: MUSCLE WEAKNESS

ENDOCRINE: HYPOGLYCEMIA
Archiv fuer Experimentelle Pathologie und Pharmakologie. Vol. 64, Pg. 274, 1911.
rat LD50 oral 3030ug/kg (3.03mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: FOOD INTAKE (ANIMAL)

LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
National Technical Information Service. Vol. AD-B011-150,
women LDLo oral 4600ug/kg (4.6mg/kg) LUNGS, THORAX, OR RESPIRATION: CYANOSIS

SKIN AND APPENDAGES (SKIN): SWEATING: OTHER

GASTROINTESTINAL: NAUSEA OR VOMITING
Archives of Internal Medicine. Vol. 83, Pg. 164, 1949.
women LDLo oral 22mg/kg (22mg/kg) CARDIAC: CARDIOMYOPATHY INCLUDING INFARCTION American Heart Journal. Vol. 84, Pg. 139, 1972.
women TDLo oral 2600ug/kg (2.6mg/kg) BEHAVIORAL: FLUID INTAKE

GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA"

GASTROINTESTINAL: NAUSEA OR VOMITING
New England Journal of Medicine. Vol. 232, Pg. 247, 1945.
women TDLo oral 11mg/kg (11mg/kg) GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA"

GASTROINTESTINAL: NAUSEA OR VOMITING
American Journal of the Medical Sciences. Vol. 209, Pg. 223, 1944.

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