lithium aluminium tetrahydride
phosphorus pentachloride
A
phosphorane
B
phosphan
Conditions | Yield |
---|---|
In not given byproducts: H2; reduction of PCl5 with LiAlH4; formation of decompn. products of PH5;; | A 0% B n/a |
In not given byproducts: H2; reduction of PCl5 with LiAlH4; formation of decompn. products of PH5;; | A 0% B n/a |
Conditions | Yield |
---|---|
In not given byproducts: H2; react. of H with PH3 at ambient temp. or at the temp. of liquid air;; | 0% |
In not given reaction H with PH3;; | |
In not given reaction of H with PH3;; | 0% |
In not given reaction H with PH3;; | |
In not given reaction of H with PH3;; | 0% |
Conditions | Yield |
---|---|
In not given byproducts: H2; reduction of PCl5 with LiBH4; formation of decompn. products of PH5;; | A 0% B n/a |
In not given byproducts: H2; reduction of PCl5 with LiBH4; formation of decompn. products of PH5;; | A 0% B n/a |
Conditions | Yield |
---|---|
With sodium iodide In N,N,N,N,N,N-hexamethylphosphoric triamide; dichloromethane | 87.8% |
Conditions | Yield |
---|---|
With n-butyllithium; ammonium chloride In tetrahydrofuran; diethyl ether | 50% |
With n-butyllithium; ammonium chloride In tetrahydrofuran; diethyl ether | 50% |
phosphorane
1-{8-[2-(4-Cyclobutyl-1,3-thiazol-2-yl)ethyl]-3-formyl-4-oxo-4H-pyrido[1,2-a]-pyrimidin-2-yl}-3-piperidyl formate
(tert-Butoxycarbonylmethylene)triphenylphosphorane
tert-Butyl (E)-3-[8-[2-(4-cyclobutyl-1,3-thiazol-2-yl)ethyl]-2-(3-formyloxy-piperidino)-4-oxo-4H-pyrido[1,2-a]pyrimidin-3-yl]-2-propenoate
Conditions | Yield |
---|---|
In tetrahydrofuran |
phosphorane
diethyl ether
(carbethoxyethylidene)triphenylphosphorane
ethyl 5-<3,4-dihydro-6-<(2-methoxyethoxy)methoxy>-2,5,7,8-tetramethyl-2H-1-benzopyran-2-yl>-2-methyl-2(E)-pentanoate
Conditions | Yield |
---|---|
In benzene |
phosphorane
tetrabutyl ammonium fluoride
(4-chlorobenzyl)triphenylphosphonium chloride
Conditions | Yield |
---|---|
In ethanol; hexane; ethyl acetate |
phosphorane
methyl (triphenylphosphoranylidene)acetate
Conditions | Yield |
---|---|
With sodium bicarbonate In ethyl acetate; trifluoroacetic acid | |
With sodium bicarbonate In ethyl acetate; trifluoroacetic acid |
phosphorane
methyl (triphenylphosphoranylidene)acetate
Conditions | Yield |
---|---|
With sodium bicarbonate; trifluoroacetic acid In ethyl acetate |
phosphorane
methyl (triphenylphosphoranylidene)acetate
Pivaloyloxymethyl 6-(3-methoxycarbonyl-2-propen-1-yl)-7-oxo-1-azabicyclo[3,2,0]hept-2-ene-2-carboxylate
Conditions | Yield |
---|---|
With ozone; sodium bicarbonate; trifluoroacetic acid In dichloromethane; ethyl acetate | |
With ozone; sodium bicarbonate; trifluoroacetic acid In dichloromethane; ethyl acetate |
2,6-dimethylpyridine
chloro-azetidinone
phosphorane
water
triphenylphosphine
Conditions | Yield |
---|---|
With hydrogenchloride; sodium hydrogencarbonate In tetrahydrofuran; toluene; benzene |
Conditions | Yield |
---|---|
With thionyl chloride; triphenylphosphine In dichloromethane; toluene; benzene |
phosphorane
(1S,5R,6R,7R)-6-formyl-7-benzoyloxy-2-oxabicyclo[3.3.0]octan-3-one
Conditions | Yield |
---|---|
In hexane; ethyl acetate; benzene |
phosphorane
2-(triphenylphosphoranylidene)propionaldehyde
ethyl iodide
triphenylphosphine
ethyltriphenylphosphonium iodide
Conditions | Yield |
---|---|
In pentane; benzene |
Conditions | Yield |
---|---|
In benzene |
phosphorane
methyl (triphenylphosphoranylidene)acetate
benzyl 6-(3-methoxycarbonylprop-2-ene-1-yl)-7-oxo-1-azabicyclo[3.2.0]hept-2-ene-2-carboxylate
Conditions | Yield |
---|---|
With trifluoroacetic acid In chloroform; ethyl acetate |
phosphorane
methyl (triphenylphosphoranylidene)acetate
2,2,2-Trichloroethyl 6-(3-methoxycarbonylprop-2-ene-1-yl)-7-oxo-1-azabicyclo[3.2.0]hept-2-ene-2-carboxylate
Conditions | Yield |
---|---|
With trifluoroacetic acid In EtAc; chloroform |
EPA Extremely Hazardous Substances List. Reported in EPA TSCA Inventory.
OSHA PEL: TWA 0.1 mg/m3
ACGIH TLV: TWA 0.1 mg/m3
DOT Classification: 4.2; Label: Spontaneously Combustible, Poison
For occupational chemical analysis use NIOSH: Elements (ICP) 7300; Phosphorus 7905.
The IUPAC name of Phosphorus is phosphane. With the CAS registry number 7723-14-0, it is also named as Red phosphorus. The product's categories are Inorganic Chemicals; Inorganics; Elemental PhosphorusMicro / Nanoelectronics; Catalysis and Inorganic Chemistry; Electronic Chemicals; Phosphorus Compounds; Pure Elements; Elemental Phosphorus; AA Standard Solutions Spectroscopy; AAS; Matrix Selection; OtherAlphabetic; P; PER - POLASpectroscopy; Reference / Calibration Standards; Single Solution; Standard Solutions, and the other registry number is 29879-37-6. Besides, it is reddish-brown powder, which is insoluble in water and denser than water. It should be kept in the water and immersed in water, with isolation from the air. In addition, it is incompatible with strong oxidizing agents, strong bases which is light and heat sensitive.
The other characteristics of this product can be summarized as: (1)H bond acceptors: 0; (2)H bond donors: 0; (3)Freely Rotating Bonds: 0; (4)Density: 2.34 g/mL at 25 °C; (5)Flash Point: 30 °C; (6)Enthalpy of Vaporization: 16.96 kJ/mol; (7)Boiling Point: 280 °C; (8)Melting point: 590 °C; (9)Vapour Pressure: 27300 mmHg at 25 °C; (10)Vapor Density: 0.02 (vs air); (11)EINECS: 231-768-7.
Preparation of Phosphorus: Please put Yellow Phosphorus in the sealed cast iron pot. And you should heat Yellow Phosphorus for several hours slight below 420 °C with isolation from the air. It would be converted to red Phosphorus.
Uses of Phosphorus: this chemical is used for the preparation of semiconductor compound and doping agent of semiconductor material. Furthermore, this chemical is used for producing matches, fireworks, and Aluminum phosphide, Phosphorus pentoxide, Phosphorus trichloride, etc. And it is the raw material of producing organic phosphorus pesticide. Additionally, it is used for the production of phosphor bronze in metallurgical industry. It is also used for deacidification of light metal and pharmaceutical.
When you are using this chemical, please be cautious about it as the following: it is highly flammable and spontaneously flammable in air. It also may explosive when mixed with oxidizing substances and cause severe burns. Moreover, it is very toxic by inhalation and if swallowed and very toxic to aquatic organisms. It is harmful to aquatic organisms, which may cause long-term adverse effects in the aquatic environment. Please keep contents under ... (there follows the name of a liquid). and under ... (there follows the name of an inert gas). And you should keep container tightly closed. In case of contact with eyes, please rinse immediately with plenty of water and seek medical advice. Aditionally, you should take off immediately all contaminated clothing. And in case of insufficient ventilation, please wear suitable respiratory equipment. Besides, in case of fire use ... (there follows the type of fire-fighting equipment to be used.). In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.). And you should avoid release to the environment and please refer to special instructions / safety data sheets.
People can use the following data to convert to the molecule structure.
(1)SMILES:P
(2)InChI:InChI=1/P
(3)InChIKey:OAICVXFJPJFONN-UHFFFAOYAC
(4)Std. InChI:InChI=1S/P
(5)Std. InChIKey:OAICVXFJPJFONN-UHFFFAOYSA-N
The toxicity data is as follows:
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
cat | LDLo | oral | 4mg/kg (4mg/kg) | Yakkyoku. Pharmacy. Vol. 28, Pg. 329, 1977. | |
dog | LDLo | oral | 10mg/kg (10mg/kg) | Yakkyoku. Pharmacy. Vol. 28, Pg. 329, 1977. | |
dog | LDLo | subcutaneous | 2mg/kg (2mg/kg) | BEHAVIORAL: FOOD INTAKE (ANIMAL) LIVER: FATTY LIVER DEGERATION CARDIAC: OTHER CHANGES | Archiv fuer Experimentelle Pathologie und Pharmakologie. Vol. 52, Pg. 173, 1905. |
duck | LDLo | oral | 3mg/kg (3mg/kg) | BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) BEHAVIORAL: MUSCLE WEAKNESS BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD | Journal of the American Pharmaceutical Association, Scientific Edition. Vol. 39, Pg. 151, 1950. |
human | LDLo | oral | 1400ug/kg (1.4mg/kg) | Pesticide Chemicals Official Compendium, Association of the American Pesticide Control Officials, Inc., 1966. Vol. -, Pg. 901, 1966. | |
mammal (species unspecified) | LDLo | oral | 200mg/kg (200mg/kg) | "Pesticide Index," Frear, E.H., ed., State College, PA, College Science Pub., 1969Vol. 4, Pg. 321, 1969. | |
man | LDLo | unreported | 4412ug/kg (4.412mg/kg) | "Poisoning; Toxicology, Symptoms, Treatments," 2nd ed., Arena, J.M., Springfield, IL, C.C. Thomas, 1970Vol. 2, Pg. 73, 1970. | |
mouse | LD50 | oral | 4820ug/kg (4.82mg/kg) | BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES BEHAVIORAL: FOOD INTAKE (ANIMAL) | National Technical Information Service. Vol. AD-B011-150, |
pig | LDLo | oral | 160mg/kg (160mg/kg) | "Pesticide Index," Frear, E.H., ed., State College, PA, College Science Pub., 1969Vol. 4, Pg. 321, 1969. | |
rabbit | LDLo | subcutaneous | 10mg/kg (10mg/kg) | BEHAVIORAL: MUSCLE WEAKNESS ENDOCRINE: HYPOGLYCEMIA | Archiv fuer Experimentelle Pathologie und Pharmakologie. Vol. 64, Pg. 274, 1911. |
rat | LD50 | oral | 3030ug/kg (3.03mg/kg) | BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) BEHAVIORAL: FOOD INTAKE (ANIMAL) LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES | National Technical Information Service. Vol. AD-B011-150, |
women | LDLo | oral | 4600ug/kg (4.6mg/kg) | LUNGS, THORAX, OR RESPIRATION: CYANOSIS SKIN AND APPENDAGES (SKIN): SWEATING: OTHER GASTROINTESTINAL: NAUSEA OR VOMITING | Archives of Internal Medicine. Vol. 83, Pg. 164, 1949. |
women | LDLo | oral | 22mg/kg (22mg/kg) | CARDIAC: CARDIOMYOPATHY INCLUDING INFARCTION | American Heart Journal. Vol. 84, Pg. 139, 1972. |
women | TDLo | oral | 2600ug/kg (2.6mg/kg) | BEHAVIORAL: FLUID INTAKE GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA" GASTROINTESTINAL: NAUSEA OR VOMITING | New England Journal of Medicine. Vol. 232, Pg. 247, 1945. |
women | TDLo | oral | 11mg/kg (11mg/kg) | GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA" GASTROINTESTINAL: NAUSEA OR VOMITING | American Journal of the Medical Sciences. Vol. 209, Pg. 223, 1944. |
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