Propoxybenzene supplier | CasNO.622-85-5

Name
Propoxybenzene
EINECS 210-756-5
CAS No. 622-85-5
Article Data80
CAS DataBase
Density 0.929g/cm³
Solubility
Melting Point -28°C(lit.)
Formula C9H12 O
Boiling Point 189.9°C at 760 mmHg
Molecular Weight 136.194
Flash Point 65°C
Transport Information
Appearance
Safety Moderately toxic by ingestion. When heated to decomposition it emits acrid smoke and irritating fumes. See also ETHERS.
Risk Codes
Molecular Structure
Hazard Symbols
Synonyms Ether, phenylpropyl (6CI,7CI,8CI); 1-Phenoxypropane; Phenyl propyl ether; Propoxybenzene;Propyl phenyl ether; Propyloxybenzene
PSA 9.23000
LogP 2.47540

Synthetic route

: 1746-13-0
allyl phenyl ether

: 622-85-5
propoxybenzene

Conditions

Conditions	Yield
With C7H14N3(1+)*Cl(1-); sodium triethylborohydride; cobalt(II) chloride In tetrahydrofuran at 25℃; under 7500.75 Torr; for 16h;	95%
With sodium tetrahydroborate; ruthenium trichloride In tetrahydrofuran; water at 20℃; for 1h;	90%
With 10% Pd on charcoal; diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate In ethanol for 4h; Reflux;	88%

: 107-08-4
1-iodo-propane

: 108-95-2
phenol

: 622-85-5
propoxybenzene

Conditions

Conditions	Yield
With potassium hydroxide; DCH-18-crown-6 immobilized on 2-vinylpyridine-styrene copolymer In chloroform for 6h; Heating;	90%
With potassium carbonate In N,N-dimethyl-formamide at 70℃; for 5h;	1.29 g

: 71-23-8
propan-1-ol

: 591-50-4
iodobenzene

: 622-85-5
propoxybenzene

Conditions

Conditions	Yield
With caesium carbonate; [Cu8(S2P(OiPr)2)6(μ8-Cl)][PF6] at 110℃; for 11h;	90%

: 143885-02-3
propyloxy(diphenyl)-λ6-sulfanenitrile

: 108-95-2
phenol

A: 622-85-5
propoxybenzene

B: 22731-83-5
S,S-diphenylsulphoximine

Conditions

Conditions	Yield
In chloroform-d1 at 20℃; for 336h;	A 89% B n/a

...Expand

: 588-63-6
3-phenoxypropyl bromide

: 622-85-5
propoxybenzene

Conditions

Conditions	Yield
With [2-(di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]ruthenium(II) chlorocarbonyl hydride; isopropyl alcohol; sodium t-butanolate at 100℃; for 18h; Reagent/catalyst; Inert atmosphere; Sealed tube; Green chemistry;	88%
With cetyltrimethylammonium bromide micelle; zinc In water Heating;	83%
With tris-(trimethylsilyl)silane; oxygen at 60℃; for 6h; in sealed vial;	80 % Chromat.

: 118527-13-2
n-propoxy-tris(dimethylamino)phosphonium hexafluorophosphate

: 108-95-2
phenol

: 622-85-5
propoxybenzene

Conditions

Conditions	Yield
With potassium hydroxide In N,N-dimethyl-formamide for 15h; Heating;	86%

: 588-63-6
3-phenoxypropyl bromide

A: 622-85-5
propoxybenzene

B: 122-97-4
3-Phenyl-1-propanol

Conditions

Conditions	Yield
With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride In benzene for 1h; Mechanism; Heating; other aryl ethers;	A 85% B 2%
With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride In benzene for 1h; Heating;	A 85% B 2%

: 71-23-8
propan-1-ol

: 930-68-7
cyclohexenone

: 622-85-5
propoxybenzene

Conditions

Conditions	Yield
With ammonium cerium(IV) nitrate; iodine for 8h; Heating; other alkanol;	81%
With ammonium cerium(IV) nitrate; iodine for 8h; Heating;	81%

: 71-23-8
propan-1-ol

: potassium phenyltrifluoborate

: 622-85-5
propoxybenzene

Conditions

Conditions	Yield
Stage #1: potassium phenyltrifluoborate With dmap; copper diacetate; 4 A molecular sieve In dichloromethane at 20℃; for 0.0833333h; Stage #2: propan-1-ol With oxygen In dichloromethane at 20℃; for 24h;	78%

: 106-94-5
propyl bromide

: 108-95-2
phenol

: 622-85-5
propoxybenzene

Conditions

Conditions	Yield
With potassium carbonate In N,N-dimethyl-formamide at 70℃; for 5h;	72%
With potassium carbonate In ethanol at 140℃;	62%
With sodium hydroxide; cetyltrimethylammonim bromide 1.) 60 deg C, 0.5 h 2.) 80 deg C, 5 h; Yield given. Multistep reaction;
With sodium hydroxide; ethyltriphenylphosphonium bromide In water at 22℃; for 50h;	7.0 %Chromat.

: 87841-77-8
2-(2-Phenoxy-ethylazo)-prop-2-yl-hydroperoxide

: 109-92-2
ethyl vinyl ether

A: 493-08-3
chromane

B: 122-99-6
2-Phenoxyethanol

C: 622-85-5
propoxybenzene

D: 19790-62-6
4-phenoxybutyraldehyde

E: 87841-94-9
2-phenoxypentanal

F: 103-73-1
Phenetole

G further products: further products

Conditions

Conditions	Yield
at 50℃; Mechanism;	A n/a B 1% C 0.6% D 52% E 0.7% F 7% G n/a

...Expand

: 71-23-8
propan-1-ol

: 71-43-2
benzene

: 622-85-5
propoxybenzene

Conditions

Conditions	Yield
With Co(dmgBF2)2(CH3CN)2; 3-cyano-N-methyl-quinolinium perchlorate In acetonitrile at 20℃; for 5h; Sealed tube; Inert atmosphere; Irradiation; High pressure;	41%

: 71-23-8
propan-1-ol

: 108-86-1
bromobenzene

: 6819-41-6
sodium n-propoxide

: 142-71-2
copper diacetate

: 622-85-5
propoxybenzene

...Expand

: 71-23-8
propan-1-ol

: 2684-02-8
benzenediazonium

: 622-85-5
propoxybenzene

Conditions

Conditions	Yield
beim Behandeln von Benzoldiazoniumchlorid;

: 71-23-8
propan-1-ol

: 139-02-6
sodium phenoxide

: 622-85-5
propoxybenzene

Conditions

Conditions	Yield
With carbon monoxide at 180℃;

: 108-86-1
bromobenzene

: 6819-41-6
sodium n-propoxide

: 622-85-5
propoxybenzene

Conditions

Conditions	Yield
With propan-1-ol; ultra-violet light; copper (I) acetate Irradiation;

: 623-98-3
dipropyl sulfite

: 139-02-6
sodium phenoxide

: 622-85-5
propoxybenzene

Conditions

Conditions	Yield
With toluene

: 598-05-0
di-1-propyl sulfate

: 139-02-6
sodium phenoxide

: 622-85-5
propoxybenzene

Conditions

Conditions	Yield
With ammonia
With water at 80℃;

: 540-54-5
1-Chloropropane

: 139-02-6
sodium phenoxide

: 622-85-5
propoxybenzene

: 1746-13-0
allyl phenyl ether

A: 622-85-5
propoxybenzene

B: 108-95-2
phenol

Conditions

Conditions	Yield
With propan-1-ol; Pd-BaSO4 Hydrogenation;

: 20549-68-2
1-(3-iodopropoxy)benzene

: 622-85-5
propoxybenzene

Conditions

Conditions	Yield
With etheric solution; sodium

: 139-02-6
sodium phenoxide

: 106-94-5
propyl bromide

: 622-85-5
propoxybenzene

Conditions

Conditions	Yield
With ethanol

: 100-67-4
potassium phenolate

: 107-08-4
1-iodo-propane

: 622-85-5
propoxybenzene

Conditions

Conditions	Yield
at 100 - 110℃;

: 139-02-6
sodium phenoxide

: 107-08-4
1-iodo-propane

: 622-85-5
propoxybenzene

Conditions

Conditions	Yield
With ethanol
In tetrahydrofuran

: 599-91-7
propyl tosylate

: 108-95-2
phenol

: 622-85-5
propoxybenzene

Conditions

Conditions	Yield
With sodium hydroxide

: 71-23-8
propan-1-ol

: 108-95-2
phenol

: 622-85-5
propoxybenzene

Conditions

Conditions	Yield
With aluminum oxide at 380 - 400℃; unter Druck;
at 420℃; beim Leiten ueber ThO2;
With aluminum oxide at 450 - 500℃;

: 187737-37-7
propene

: 108-95-2
phenol

A: 622-85-5
propoxybenzene

B: 2741-16-4
isopropoxybenzene

Conditions

Conditions	Yield
With Fuller's Earth under 140 Torr;

...Expand

: 513-08-6
phosphoric acid tripropyl ester

: 108-95-2
phenol

: 622-85-5
propoxybenzene

Conditions

Conditions	Yield
With toluene-4-sulfonic acid at 160℃;

: 6738-15-4
N,N-dicyclohexyl-O-(propyl)isourea

: 108-95-2
phenol

: 622-85-5
propoxybenzene

Conditions

Conditions	Yield
at 100℃; for 24h;

: 71-23-8
propan-1-ol

: 108-95-2
phenol

A: 645-56-7
4-n-Propylphenol

B: 644-35-9
5-propylphenol

C: 622-85-5
propoxybenzene

D: 6626-32-0
2,6-di-n-propylphenol

E: 74663-48-2
2-(1-methylethyl)-6-propylphenol

F: 74663-45-9
n-Propyl 2-n-propylphenyl ether

Conditions

Conditions	Yield
aluminum oxide at 250℃; Product distribution; Mechanism; other temperatures, other catalysts;	A 1.4 % Chromat. B 3.1 % Chromat. C 5.8 % Chromat. D 49.5 % Chromat. E 9.2 % Chromat. F 6.5 % Chromat.

...Expand

: 622-85-5
propoxybenzene

: 33382-58-0
1-chloro-4-propoxybenzene

Conditions

Conditions	Yield
With kaolin; sodium chlorite; manganese(III) acetylacetonate In dichloromethane at 25℃; for 1.33333h;	98%
With aluminum oxide; sodium chlorite; (Salen)Mn(III) catalyst In dimethyl sulfoxide for 0.5h; Ambient temperature;	96%
With aluminum oxide; sodium chlorite; (salen)Mn(III) In dichloromethane at 25℃; for 0.5h;	96%
With aluminum oxide; sodium chlorite; water; manganese(III) acetylacetonate In dichloromethane at 25℃; for 0.75h;	93%
With aluminum oxide; copper dichloride In chlorobenzene at 100℃; for 3h;	95 % Chromat.

: 622-85-5
propoxybenzene

: 39969-56-7
1-bromo-4-propoxybenzene

Conditions

Conditions	Yield
With aluminum oxide; sodium chlorite; water; manganese(III) acetylacetonate; sodium bromide In dichloromethane at 20℃; for 1.33333h;	97%
With kaolin; sodium chlorite; manganese(III) acetylacetonate; sodium bromide In dichloromethane at 25℃; for 2.66667h;	97%
With sodium chlorite; Montmorillonite K10; manganese(III) acetylacetonate; sodium bromide In dichloromethane at 25℃; for 1h;	96%
With sodium chlorite; silica gel; manganese(III) acetylacetonate; sodium bromide In dichloromethane at 25℃; for 2h;	95%
With carbon disulfide; bromine at 0℃;

: 5781-53-3
monomethyl oxalyl chloride

: 622-85-5
propoxybenzene

: C12H14O4

Conditions

Conditions	Yield
Stage #1: monomethyl oxalyl chloride With iron(III) chloride In 1,2-dichloro-ethane at 0 - 5℃; for 0.5h; Friedel-Crafts Acylation; Stage #2: propoxybenzene In dichloromethane; 1,2-dichloro-ethane at 20℃; for 3h; Friedel-Crafts Acylation;	92%

: 622-85-5
propoxybenzene

: 555-68-0
(E)-3-Nitrocinnamic acid

: 1304637-19-1
C18H17NO4

Conditions

Conditions	Yield
With phosphoric acid; trifluoroacetic acid at 20℃; for 0.5h;	88%

: 622-85-5
propoxybenzene

: 872415-81-1
chloro(5,10,15,20-tetratolylporphyrinato)carbonyliridium(III)

: 872415-73-1
(5,10,15,20-tetra-p-tolylporphyrinato)propyliridium(III)

Conditions

Conditions	Yield
With potassium hydroxide at 150℃; for 2h; Inert atmosphere; Darkness;	85%

: 79-36-7
dichloroacethyl chloride

: 622-85-5
propoxybenzene

: 2,2-dichloro-1-(4-propoxyphenyl)ethan-1-one

Conditions

Conditions	Yield
Stage #1: dichloroacethyl chloride With aluminum (III) chloride In dichloromethane at 0℃; for 0.166667h; Friedel-Crafts Acylation; Stage #2: propoxybenzene In dichloromethane Friedel-Crafts Acylation;	82.2%

: 622-85-5
propoxybenzene

: 140-10-3
(E)-3-phenylacrylic acid

: 64990-86-9
4'-propyloxy-trans-chalcone

Conditions

Conditions	Yield
With phosphoric acid; trifluoroacetic acid at 20℃; for 0.75h;	80%

: 622-85-5
propoxybenzene

: 10313-60-7
3,4-dimethoxyphenylacetyl chloride

: 2-(3,4-Dimethoxyphenyl)-1-(4-propoxyphenyl)ethanon

Conditions

Conditions	Yield
With aluminium trichloride In 1,2-dichloro-ethane at 40℃;	78%

: 622-85-5
propoxybenzene

: 75-36-5
acetyl chloride

: 4-propoxyphenacyl chloride

Conditions

Conditions	Yield
With aluminium trichloride at 40℃; for 3h;	66%

: 622-85-5
propoxybenzene

: 123-76-2
levulinic acid

: C14H18O3

Conditions

Conditions	Yield
With H-β zeolite In neat (no solvent) at 150℃; for 12h; regioselective reaction;	63%

: 622-85-5
propoxybenzene

: 872415-81-1
chloro(5,10,15,20-tetratolylporphyrinato)carbonyliridium(III)

: 100-66-3
methoxybenzene

: 386707-40-0
(5,10,15,20-tetrakis(p-tolyl)porphyrinato)(methyl)iridium(III)

: 872415-73-1
(5,10,15,20-tetra-p-tolylporphyrinato)propyliridium(III)

Conditions

Conditions	Yield
With potassium hydroxide at 150℃; for 2h; Inert atmosphere; Darkness;	A 23% B 61%

...Expand

: 26118-57-0
2-(4-(n-propoxy)phenyl)acetic acid

: 622-85-5
propoxybenzene

: 94686-48-3
4,4'-Dipropyloxy-deoxybenzoin

Conditions

Conditions	Yield
Stage #1: 2-(4-(n-propoxy)phenyl)acetic acid With thionyl chloride In chloroform at 0℃; Stage #2: propoxybenzene With aluminum (III) chloride In dichloromethane at 0 - 20℃; Stage #3: With water In dichloromethane Cooling;	51.86%

: 622-85-5
propoxybenzene

: 1597-49-5
trifluoroacetyl-DL-alanine

: 742095-38-1
(RS)-2-trifluoroacetamido-1-(4-propoxyphenyl)-1-propanone

Conditions

Conditions	Yield
With aluminium trichloride; oxalyl dichloride	50%

: 7790-94-5
chlorosulfonic acid

: 622-85-5
propoxybenzene

: 58076-32-7
4-n-propoxy-1-benzenesulfonyl chloride

Conditions

Conditions	Yield
In dichloromethane for 2h;	50%

: 622-85-5
propoxybenzene

: 872415-81-1
chloro(5,10,15,20-tetratolylporphyrinato)carbonyliridium(III)

: 103-73-1
Phenetole

: 872415-72-0
(5,10,15,20-tetra-p-tolylporphyrinato)ethyliridium(III)

: 872415-73-1
(5,10,15,20-tetra-p-tolylporphyrinato)propyliridium(III)

Conditions

Conditions	Yield
With potassium hydroxide at 150℃; for 2h; Inert atmosphere; Darkness;	A 25% B 46%

...Expand

: 622-85-5
propoxybenzene

: 386707-40-0
(5,10,15,20-tetrakis(p-tolyl)porphyrinato)(methyl)iridium(III)

: 872415-73-1
(5,10,15,20-tetra-p-tolylporphyrinato)propyliridium(III)

Conditions

Conditions	Yield
With potassium hydroxide at 150℃; for 17h; Inert atmosphere; Darkness;	5%

: 623-73-4
diazoacetic acid ethyl ester

: 622-85-5
propoxybenzene

: 4-propoxy-cyclohepta-1,3,6-trienecarboxylic acid

Conditions

Conditions	Yield
at 150℃; Erwaermen des Reaktionsprodukts mit methanol. KOH;

: 108-30-5
succinic acid anhydride

: 622-85-5
propoxybenzene

: 39496-82-7
4-oxo-4-(4-propoxyphenyl)butanoic acid

Conditions

Conditions	Yield
With aluminium trichloride; nitrobenzene

Propoxybenzene Chemical Properties

IUPAC Name: Propoxybenzene
Synonyms: Phenyl propyl ether ; Benzene, propoxy- ; Ether, phenyl propyl ; Ether, propyl phenyl ; Ether,propylphenyl ; Propoxy-benzen ; Propoxy-benzene ; Propoxyphenyl
Molecular Structure of Propyl phenyl ether (CAS NO. 622-85-5) :
Molecular Formula of Propyl phenyl ether (CAS NO. 622-85-5) : C₉H₁₂O
Molecular Weight of Propyl phenyl ether (CAS NO. 622-85-5) : 136.19
CAS NO: 622-85-5
EINECS: 210-756-5
Index of Refraction: 1.488
Surface Tension: 30.2 dyne/cm
Density: 0.929 g/cm³
Flash Point: 65 °C
Enthalpy of Vaporization: 40.87 kJ/mol
Boiling Point: 189.9 °C at 760 mmHg
Vapour Pressure: 0.77 mmHg at 25°C

Propoxybenzene Uses

Propyl phenyl ether (CAS NO. 622-85-5) is used as intermediate in organic synthesis .

Propoxybenzene Toxicity Data With Reference

orl-mus LD50:3400 mg/kg

JPETAB Journal of Pharmacology and Experimental Therapeutics. 88 (1946),400.

Propoxybenzene Consensus Reports

Reported in EPA TSCA Inventory.

Propoxybenzene Safety Profile

Moderately toxic by ingestion. When heated to decomposition it emits acrid smoke and irritating fumes. See also ETHERS.

Product Name

Propoxybenzene

Synthetic route

Propoxybenzene Chemical Properties

Propoxybenzene Uses

Propoxybenzene Toxicity Data With Reference

Propoxybenzene Consensus Reports

Propoxybenzene Safety Profile

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