Conditions | Yield |
---|---|
With alkaline glycerol at 200℃; for 3h; Heating / reflux; |
Conditions | Yield |
---|---|
Stage #1: safflower oil With alkaline glycerol at 80℃; for 0.333333h; Heating / reflux; Stage #2: With phosphoric acid at 100℃; pH=3; Heating / reflux; |
methanol
A
Methyl oleate
B
Methyl linoleate
C
methyl linolenate
D
hexadecanoic acid methyl ester
E
Methyl stearate
F
methyl arachidate
Conditions | Yield |
---|---|
With potassium hydroxide for 14h; |
Conditions | Yield |
---|---|
With sodium ethanolate In ethanol at 78℃; for 1h; Heating / reflux; |
Conditions | Yield |
---|---|
With sodium methylate In methanol at 65℃; for 2h; Industry scale; |
Conditions | Yield |
---|---|
With potassium hydroxide In PEG 300 at 120 - 180℃; Continous process; |
Conditions | Yield |
---|---|
With potassium hydroxide In propylene glycol; water at 140℃; for 2h; |
Conditions | Yield |
---|---|
With potassium hydroxide In PEG 300; water at 140℃; for 2h; |
Conditions | Yield |
---|---|
With potassium hydroxide In PEG 300; propylene glycol; water at 140℃; for 2h; |
Conditions | Yield |
---|---|
With potassium hydroxide In Isopropyl-idene-rac-glycerol; water at 150℃; for 2h; |
Conditions | Yield |
---|---|
With potassium hydroxide In PEG 200; water at 140℃; for 2h; |
Conditions | Yield |
---|---|
With potassium hydroxide In PEG 300; water at 180℃; for 4h; |
Conditions | Yield |
---|---|
With potassium hydroxide In PEG 300; water at 140℃; for 2h; |
Conditions | Yield |
---|---|
With potassium hydroxide In PEG 600; water at 140℃; for 2h; |
Conditions | Yield |
---|---|
With potassium hydroxide In PEG 300; water at 140℃; for 2h; |
A
cis-9-hexadecenoic acid
B
cis-Octadecenoic acid
C
Elaidic acid
D
(9Z,12Z)-octadeca-9,11-dienoic acid
E
cis-9,trans-11-octadecadienoic acid
F
(10Z,12Z)-10,12-Octadecadienoic acid
G
trans-10,cis-12-octadecadienoic acid
H
linoleic acid
I
(9E,12E)-Octadeca-9,12-dienoic acid
J
gadoleic acid
K
Arachidic acid
L
n-docosanoic acid
M
n-tetradecanoic acid
N
1-hexadecylcarboxylic acid
O
stearic acid
P
octadeca-11Z,13Z-dienoic acid
Conditions | Yield |
---|---|
With sodium hydroxide; ethanol; water at 150 - 215℃; under 7500.75 - 24002.4 Torr; for 0 - 6h; Product distribution / selectivity; | |
With potassium hydroxide; ethanol; water at 150℃; under 7500.75 - 9000.9 Torr; for 0 - 6h; Product distribution / selectivity; | |
With potassium hydroxide; water In propylene glycol at 150℃; under 7500.75 - 9000.9 Torr; for 0 - 6h; Product distribution / selectivity; |
A
cis-9-hexadecenoic acid
B
cis-Octadecenoic acid
C
cis-9,trans-11-octadecadienoic acid
D
trans-9,trans-11-octadecadienoic acid
E
trans-10,cis-12-octadecadienoic acid
F
stearic acid
Conditions | Yield |
---|---|
Stage #1: safflower oil With sodium hydroxide; propylene glycol at 50 - 175℃; Stage #2: With phosphoric acid at 50℃; pH=1; |
Conditions | Yield |
---|---|
xKOH*K(z)Glyceroxide at 20℃; for 6h; Product distribution / selectivity; |
ethanol
Conditions | Yield |
---|---|
Stage #1: ethanol With potassium hydroxide Stage #2: safflower oil at 20℃; for 2h; |
methanol
Conditions | Yield |
---|---|
Stage #1: methanol With potassium hydroxide Stage #2: safflower oil at 20℃; for 2h; |
1. | skn-hmn 300 mg/3D-I MLD | 85DKA8 Cutaneous Toxicity Drill, V.A. andP. Lazar, eds.,New York, NY.: Academic Press,1977,127. | ||
2. | eye-rbt 100 mg/24H MLD | JACTDZ Journal of the American College of Toxicology. 4 (5)(1985),171. | ||
3. | ipr-mus LD50:>50 g/kg | NTIS** National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) AD691-490 . |
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