Silver mesylate supplier | CasNO.2386-52-9

Name
Silver mesylate
EINECS 219-199-2
CAS No. 2386-52-9
Article Data9
CAS DataBase
Density 1.511 g/cm3
Solubility Soluble in water, alcohol, ether and benzene. Slightly soluble in toluene, o-chlorotoluene and ethyl disulfide. Insoluble in hexane and methylcyclopentane.
Melting Point 252-256 °C(lit.)
Formula CH₃AgO₃S
Boiling Point
Molecular Weight 202.967
Flash Point
Transport Information UN 1759
Appearance white to beige or light grey crystalline powder
Safety 26-36-36/37/39-22
Risk Codes 36/37/38-20/21/22
Molecular Structure
Hazard Symbols Xn, Xi
Synonyms Methanesulfonicacid, silver(1+) salt (8CI,9CI);Silver methanesulfonate;Silvermethylsulfonate;Silver(I) methanesulfonate;
PSA 65.58000
LogP 0.24220

Synthetic route

: 75-75-2
methanesulfonic acid

: 20667-12-3
silver(l) oxide

: 2386-52-9
silver methanesulfonate

Conditions

Conditions	Yield
In water at 90℃; for 3h;	99%
In tetrahydrofuran at 20℃; for 1h;	95%
In water addn. of Ag2O to soln. of CH3SO3H in H2O; heating at 90°C for 3 h; cooling, filtration, evapn., washing with acetone, drying in vac.;	91%
In water at 90℃; for 3h;	91%

: 75-75-2
methanesulfonic acid

: silver carbonate

: 2386-52-9
silver methanesulfonate

Conditions

Conditions	Yield
In water (N2); addn. of aq. soln. of methanesulfonic acid to aq. suspn. of silvercompd. at 20°C, stirring for 1 h at 20°C; filtration through celite, evapn. at 50°C in vac.;	83%
In water byproducts: H2O, CO2; CH3SO3H reacted with Ag2CO3 in H2O (Y.Y.Zhang, Y.Wang, X.Tao, N.Wang, F.L.Du, Y.Z.Chen Polyhedron 27 (2008) 2501-2505);
In isopropyl alcohol at 0℃;	6.5 g
In acetonitrile at 20 - 60℃; for 1.25h;	1.1 g

: 75-75-2
methanesulfonic acid

: silver nitrate

: 2386-52-9
silver methanesulfonate

Conditions

Conditions	Yield
In water stoich. amts.; crystn. on slow evapn., manual sepn. of needles, washing (Me2CO, Et2O), drying (reduced pressure, over P2O5); elem. anal.;	25%

: [silver(I)(pyridine-N-oxide)3](methanesulfonate) monohydrate

: 2386-52-9
silver methanesulfonate

Conditions

Conditions	Yield
In neat (no solvent) at 250℃;

: 2386-52-9
silver methanesulfonate

: C22H26N3(1-)*Cl(1-)*Zn(2+)

: C22H26N3(1-)*CH3O3S(1-)*Zn(2+)

Conditions

Conditions	Yield
In ethanol	100%

: C64H104N5O6(1+)*I(1-)

: 2386-52-9
silver methanesulfonate

: C64H104N5O6(1+)*CH3O3S(1-)

Conditions

Conditions	Yield
In tetrahydrofuran; water for 2h;	100%

: C69H106N5O6(1+)*I(1-)

: 2386-52-9
silver methanesulfonate

: C69H106N5O6(1+)*CH3O3S(1-)

Conditions

Conditions	Yield
In tetrahydrofuran; water for 2h;	100%

: 725230-20-6
[Zn(II)Cl(2,8-diethyl-1,3,7,9-tetramethyl-5-(2-pyridyl)-dipyrromethene)]2

: 2386-52-9
silver methanesulfonate

: 725230-21-7
[Zn(II)(O3SMe)2(2,8-diethyl-1,3,7,9-tetramethyl-5-(2-pyridyl)-dipyrromethene)]2

Conditions

Conditions	Yield
In ethanol to soln. of Zn-complex added Ag-salt, stirred overnight; filtered, solvent removed from filtrate;	100%

: hexammine cobalt(III) chloride

: 2386-52-9
silver methanesulfonate

: hexaamminecobalt(III) methanesulfonate

Conditions

Conditions	Yield
In water byproducts: AgCl; Co complex and CH3SO3Ag (molar ratio 1:3.7) dissolved in hot H2O with stirring for 0.5 h; filtered; filtrate cooled slowly to room temp. for 3 d; crystals filtered off and dried in air; elem. anal.;	99%

: 162978-76-9
(2,2':6',2''-terpyridine)methylplatinum(II) chloride

: 2386-52-9
silver methanesulfonate

: 1127889-38-6
[Pt(CH3)(2,2':6',2''-terpyridine)]CH3SO3

Conditions

Conditions	Yield
In water byproducts: AgCl; Pt complex (0.21 mmol) treated with stoich. amt. of aq. soln. of AgCH3SO3; stirred in the dark (room temp., 1 h); AgCl filtered off; evapd. (vac.); recrystd. from 2,2,2-trifluoroethanol/Et2O; elem. anal.;	99%

: 694-59-7
pyridine N-oxide

: 2386-52-9
silver methanesulfonate

: [silver(I)(pyridine-N-oxide)2](methanesulfonate)

Conditions

Conditions	Yield
In acetonitrile at 20℃; for 1h;	99%

: 694-59-7
pyridine N-oxide

: 2386-52-9
silver methanesulfonate

: [silver(I)(pyridine-N-oxide)3](methanesulfonate) monohydrate

Conditions

Conditions	Yield
In acetonitrile at 20℃; for 1h;	99%

: 2386-52-9
silver methanesulfonate

: 15442-91-8
1,2,4,5-tetrabromomethylbenzene

: 1,2,4,5-tetrakis(methanesulfonyloxy)methylbenzene

Conditions

Conditions	Yield
In acetonitrile at 85℃; for 2h;	99%

: 1469468-10-7
C28H33ClIrNO2

: 2386-52-9
silver methanesulfonate

: pentamethylcyclopentadienyl[(3-methoxy-8-((4-methoxyphenyl)imino)-5,6,7,8-tetrahydronaphthalen-1-yl)]iridium(III) methanesulfonate

Conditions

Conditions	Yield
In chloroform at 23℃; Sealed tube;	99%

: 2386-52-9
silver methanesulfonate

: C25H27ClF2IrNO

: pentamethylcyclopentadienyl[(2,4-difluoro-6-(1-((4-methoxyphenyl)imino)ethyl)phenyl)]iridium(III) methanesulfonate

Conditions

Conditions	Yield
In chloroform at 23℃; Sealed tube;	99%

: 2386-52-9
silver methanesulfonate

: C22H25ClIrNO

: pentamethylcyclopentadienyl(5-methoxy-2-(pyridin-2-yl)phenyl)iridium(III) methanesulfonate

Conditions

Conditions	Yield
In chloroform at 23℃; Sealed tube;	99%

: 2386-52-9
silver methanesulfonate

: C21H27ClIrNO

: pentamethylcyclopentadienyl(2-(3,4-dihydro-2H-pyrrol-5-yl)-5-methoxyphenyl)iridium(III) methanesulfonate

Conditions

Conditions	Yield
In chloroform at 23℃; Sealed tube;	99%

: C26H31ClNO2Rh

: 2386-52-9
silver methanesulfonate

: pentamethylcyclopentadienyl[(5-methoxy-2-(1-((4-methoxyphenyl)imino)ethyl)phenyl)]rhodium(III) methanesulfonate

Conditions

Conditions	Yield
In chloroform at 23℃; Sealed tube;	99%

: 75-75-2
methanesulfonic acid

: 20667-12-3
silver(l) oxide

: 2386-52-9
silver methanesulfonate

Conditions

Conditions	Yield
In water at 90℃; for 3h;	99%
In tetrahydrofuran at 20℃; for 1h;	95%
In water addn. of Ag2O to soln. of CH3SO3H in H2O; heating at 90°C for 3 h; cooling, filtration, evapn., washing with acetone, drying in vac.;	91%
In water at 90℃; for 3h;	91%

: 75-75-2
methanesulfonic acid

: silver carbonate

: 2386-52-9
silver methanesulfonate

Conditions

Conditions	Yield
In water (N2); addn. of aq. soln. of methanesulfonic acid to aq. suspn. of silvercompd. at 20°C, stirring for 1 h at 20°C; filtration through celite, evapn. at 50°C in vac.;	83%
In water byproducts: H2O, CO2; CH3SO3H reacted with Ag2CO3 in H2O (Y.Y.Zhang, Y.Wang, X.Tao, N.Wang, F.L.Du, Y.Z.Chen Polyhedron 27 (2008) 2501-2505);
In isopropyl alcohol at 0℃;	6.5 g
In acetonitrile at 20 - 60℃; for 1.25h;	1.1 g

: 75-75-2
methanesulfonic acid

: silver nitrate

: 2386-52-9
silver methanesulfonate

Conditions

Conditions	Yield
In water stoich. amts.; crystn. on slow evapn., manual sepn. of needles, washing (Me2CO, Et2O), drying (reduced pressure, over P2O5); elem. anal.;	25%

: [silver(I)(pyridine-N-oxide)3](methanesulfonate) monohydrate

: 2386-52-9
silver methanesulfonate

Conditions

Conditions	Yield
In neat (no solvent) at 250℃;

: 2386-52-9
silver methanesulfonate

: C22H26N3(1-)*Cl(1-)*Zn(2+)

: C22H26N3(1-)*CH3O3S(1-)*Zn(2+)

Conditions

Conditions	Yield
In ethanol	100%

: C64H104N5O6(1+)*I(1-)

: 2386-52-9
silver methanesulfonate

: C64H104N5O6(1+)*CH3O3S(1-)

Conditions

Conditions	Yield
In tetrahydrofuran; water for 2h;	100%

: C69H106N5O6(1+)*I(1-)

: 2386-52-9
silver methanesulfonate

: C69H106N5O6(1+)*CH3O3S(1-)

Conditions

Conditions	Yield
In tetrahydrofuran; water for 2h;	100%

: 725230-20-6
[Zn(II)Cl(2,8-diethyl-1,3,7,9-tetramethyl-5-(2-pyridyl)-dipyrromethene)]2

: 2386-52-9
silver methanesulfonate

: 725230-21-7
[Zn(II)(O3SMe)2(2,8-diethyl-1,3,7,9-tetramethyl-5-(2-pyridyl)-dipyrromethene)]2

Conditions

Conditions	Yield
In ethanol to soln. of Zn-complex added Ag-salt, stirred overnight; filtered, solvent removed from filtrate;	100%

: hexammine cobalt(III) chloride

: 2386-52-9
silver methanesulfonate

: hexaamminecobalt(III) methanesulfonate

Conditions

Conditions	Yield
In water byproducts: AgCl; Co complex and CH3SO3Ag (molar ratio 1:3.7) dissolved in hot H2O with stirring for 0.5 h; filtered; filtrate cooled slowly to room temp. for 3 d; crystals filtered off and dried in air; elem. anal.;	99%

: 162978-76-9
(2,2':6',2''-terpyridine)methylplatinum(II) chloride

: 2386-52-9
silver methanesulfonate

: 1127889-38-6
[Pt(CH3)(2,2':6',2''-terpyridine)]CH3SO3

Conditions

Conditions	Yield
In water byproducts: AgCl; Pt complex (0.21 mmol) treated with stoich. amt. of aq. soln. of AgCH3SO3; stirred in the dark (room temp., 1 h); AgCl filtered off; evapd. (vac.); recrystd. from 2,2,2-trifluoroethanol/Et2O; elem. anal.;	99%

: 694-59-7
pyridine N-oxide

: 2386-52-9
silver methanesulfonate

: [silver(I)(pyridine-N-oxide)2](methanesulfonate)

Conditions

Conditions	Yield
In acetonitrile at 20℃; for 1h;	99%

: 694-59-7
pyridine N-oxide

: 2386-52-9
silver methanesulfonate

: [silver(I)(pyridine-N-oxide)3](methanesulfonate) monohydrate

Conditions

Conditions	Yield
In acetonitrile at 20℃; for 1h;	99%

: 2386-52-9
silver methanesulfonate

: 15442-91-8
1,2,4,5-tetrabromomethylbenzene

: 1,2,4,5-tetrakis(methanesulfonyloxy)methylbenzene

Conditions

Conditions	Yield
In acetonitrile at 85℃; for 2h;	99%

: 1469468-10-7
C28H33ClIrNO2

: 2386-52-9
silver methanesulfonate

: pentamethylcyclopentadienyl[(3-methoxy-8-((4-methoxyphenyl)imino)-5,6,7,8-tetrahydronaphthalen-1-yl)]iridium(III) methanesulfonate

Conditions

Conditions	Yield
In chloroform at 23℃; Sealed tube;	99%

: 2386-52-9
silver methanesulfonate

: C25H27ClF2IrNO

: pentamethylcyclopentadienyl[(2,4-difluoro-6-(1-((4-methoxyphenyl)imino)ethyl)phenyl)]iridium(III) methanesulfonate

Conditions

Conditions	Yield
In chloroform at 23℃; Sealed tube;	99%

: 2386-52-9
silver methanesulfonate

: C22H25ClIrNO

: pentamethylcyclopentadienyl(5-methoxy-2-(pyridin-2-yl)phenyl)iridium(III) methanesulfonate

Conditions

Conditions	Yield
In chloroform at 23℃; Sealed tube;	99%

: 2386-52-9
silver methanesulfonate

: C21H27ClIrNO

: pentamethylcyclopentadienyl(2-(3,4-dihydro-2H-pyrrol-5-yl)-5-methoxyphenyl)iridium(III) methanesulfonate

Conditions

Conditions	Yield
In chloroform at 23℃; Sealed tube;	99%

: C26H31ClNO2Rh

: 2386-52-9
silver methanesulfonate

: pentamethylcyclopentadienyl[(5-methoxy-2-(1-((4-methoxyphenyl)imino)ethyl)phenyl)]rhodium(III) methanesulfonate

Conditions

Conditions	Yield
In chloroform at 23℃; Sealed tube;	99%

: 2386-52-9
silver methanesulfonate

: 97513-90-1
1-methyl-3-(2-hydroxyethyl)imidazolium bromide

: 1502880-14-9
1-(2′-hydroxyethyl)-3-methylimidazolium mesylate

Conditions

Conditions	Yield
In water at 20℃; for 24h; Darkness;	98%

: 1259987-95-5
Mor-DaIPhos-AuCl

: 2386-52-9
silver methanesulfonate

: C31H45AuNO4PS

Conditions

Conditions	Yield
In dichloromethane at 20℃; for 0.5h;	98%

: 1601480-18-5
C48H20F14N8O4

: 2386-52-9
silver methanesulfonate

: 74-88-4
methyl iodide

: C52H32F14N8O4(4+)*4CH3O3S(1-)

Conditions

Conditions	Yield
Stage #1: C48H20F14N8O4; methyl iodide In methanol at 80℃; for 48h; Inert atmosphere; Schlenk technique; Stage #2: silver methanesulfonate In methanol at 20℃; for 12h; Inert atmosphere; Schlenk technique;	98%

...Expand

: C17H25N2O6(1+)*Br(1-)

: 2386-52-9
silver methanesulfonate

: C17H25N2O6(1+)*CH3O3S(1-)

Conditions

Conditions	Yield
In water at 20℃; for 24h; Darkness;	98%

: 64-69-7
Iodoacetic acid

: 2386-52-9
silver methanesulfonate

: 3586-50-3
(methanesulfonyloxy)acetic acid

Conditions

Conditions	Yield
In acetonitrile at 20℃; for 16h; Darkness;	97%
In acetonitrile	50%

: C92H106N6O8(4+)*4I(1-)

: 2386-52-9
silver methanesulfonate

: C92H106N6O8(4+)*4CH3O3S(1-)

Conditions

Conditions	Yield
In methanol at 20℃; for 3h;	97%

: 66062-59-7
N-(n-butyl)-N,N-dimethyl-N-[2-(methacryloyloxy)ethyl]ammoniumbromide

: 2386-52-9
silver methanesulfonate

: 1338564-41-2
2-(N-butyl-N,N-dimethylamino)ethyl methacrylate methanesulfonate

Conditions

Conditions	Yield
In water at 20℃; Darkness;	97%

: 39728-43-3
2,6-dimethyl-4-nitrobenzoic acid chloride

: 2386-52-9
silver methanesulfonate

: 85374-82-9
2,6-Dimethyl-4-nitrobenzoesaeure-methansulfonsaeure-anhydrid

Conditions

Conditions	Yield
Heating;	96%

: 5451-09-2
5-aminolevulinic acid hydrochloride

: 2386-52-9
silver methanesulfonate

: 5-amino-4-oxopentanoic acid methanesulfonate

Conditions

Conditions	Yield
In water	96%

: 143255-56-5
1,6-dichloro-1,6-dimethyl-1,6-distannacyclodecane

: 2386-52-9
silver methanesulfonate

: 143255-14-5
1,6-dimethyl-1,6-bis(methanesulfonyloxy)-1,6-distannacyclodecane

Conditions

Conditions	Yield
In dichloromethane byproducts: AgCl; to soln. of dichloro-compd. in CH2Cl2 is added AgSO3Me, mixt. is refluxed for 12 h; filtration, solvent is decanted, residue is washed with CH2Cl2 and then heated to 70°C at 0.01 mmHg, elem. anal.;	96%

: 2386-52-9
silver methanesulfonate

: 64099-50-9
-N,N,N-triethyl N-phthalidylammonium bromide

: 92641-14-0
N-(1,3-dihydro-3-oxoisobenzofuran-1-yl)-N,N,N-triethyl ammonium methanesulfonate

Conditions

Conditions	Yield
In acetonitrile	95%

: 2386-52-9
silver methanesulfonate

: C47H52N6O2(2+)*2ClH*2Cl(1-)

: C47H52N6O2(2+)*2CH4O3S*2CH3O3S(1-)

Conditions

Conditions	Yield
In diethyl ether; water Heating;	95%

: 2386-52-9
silver methanesulfonate

: C49H56N6O2(2+)*2ClH*2Cl(1-)

: C49H56N6O2(2+)*2CH4O3S*2CH3O3S(1-)

Conditions

Conditions	Yield
In diethyl ether; water Heating;	95%

: 1066-45-1
trimethyltin(IV)chloride

: 2386-52-9
silver methanesulfonate

: 44823-89-4
Trimethylstannylmethansulfonat

Conditions

Conditions	Yield
In dichloromethane to ClSnMe3 in CH2Cl2 is added AgSO3Me, mixt. is stirred at room temp. for 1 h; filtration, solvent is removed under reduced pressure, residue is heated at 0.01 mmHg, elem. anal.;	95%
(N2); stirring (25°C), according to P. A. Yeats, J. R. Sams and F. Aubke, Inorg. Chem. 1971, 10, 1877.; elem. anal.;

: 143255-51-0
1,3-dichloro-1,2,2,3-tetramethyl-1,3-distannacycloheptane

: 2386-52-9
silver methanesulfonate

: 143255-10-1
1,2,2,3-tetramethyl-1,3-bis(methanesulfonyloxy)-1,3-distannacycloheptane

Conditions

Conditions	Yield
In methanol byproducts: AgCl; to soln. of dichloro-compd. in dry MeOH under N2 is quickly added AgSO3Me, mixt. is stirred for 1 h at room temp.; filtration, MeOH is removed under reduced pressure, residue is heated to 70°C at 0.01 mmHg, elem. anal.;	95%

Silver mesylate Chemical Properties

IUPAC Name:  Silver methanesulfonate
Synonyms:  Methanesulfonic acid silver salt ; Methanesulfonic acid, silver salt ; Methanesulfonic acid, silver(1+) salt ; Silver methanesulfonate ; Silver methanesulfonate (Ag(CH₂SO₃)) ; Silver methanesulphonate ; Silver methylsulfonate
The Molecular Formula of Silver Methylsulfonate (CAS NO.2386-52-9):CH₃AgO₃S
The Molecular Weight of   Silver Methylsulfonate (CAS NO.2386-52-9):202.965920 g/mol
The Molecular Structure of Silver Methylsulfonate (CAS NO.2386-52-9):

Polar Surface Area: 62.75Å²
Polarizability: 10^-24cm³
Melting Point: 252-256 °C(lit.)
Appearance: white to beige or light grey crystalline powder

Silver mesylate Uses

Silver Methylsulfonate ,whose Cas Register Number is 2386-52-9, can be used in organic synthesis.

Silver mesylate Toxicity Data With Reference

ivn-mus LD50:18 mg/kg

CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) NX#00622 .

Silver mesylate Consensus Reports

Silver and its compounds are on the Community Right-To-Know List. Reported in EPA TSCA Inventory.

Silver mesylate Safety Profile

Poison by intravenous route. When heated to decomposition it emits toxic fumes of SO_x. See also SULFONATES and SILVER COMPOUNDS.
Hazard Codes: Irritant Xi, Harmful Xn
Risk Statements: 36/37/38-20/21/22
R36/37/38:Irritating to eyes, respiratory system and skin.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed.
Safety Statements: 26-36-36/37/39-22
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36:Wear suitable protective clothing.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S22:Do not breathe dust.
RIDADR: 1759
WGK Germany: 3
RTECS: PB2685000
HazardClass: 8
PackingGroup: III

Silver mesylate Standards and Recommendations

OSHA PEL: TWA 0.01 mg(Ag)/m³
ACGIH TLV: TWA 0.01 mg(Ag)/m³

Product Name

Silver mesylate

Synthetic route

Silver mesylate Chemical Properties

Silver mesylate Uses

Silver mesylate Toxicity Data With Reference

Silver mesylate Consensus Reports

Silver mesylate Safety Profile

Silver mesylate Standards and Recommendations

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