Sodium tartrate supplier | CasNO.868-18-8

Name
Sodium tartrate
EINECS 212-773-3
CAS No. 868-18-8
Article Data58
CAS DataBase
Density 1.818 g/cm³
Solubility soluble in ~9 parts H2O, 2 parts boiling H2O; insoluble alcohol [MER06]
Melting Point 302oFoC
Formula C₄H₄Na₂O₆
Boiling Point 399.3 °C at 760 mmHg
Molecular Weight 194.052
Flash Point 209.4 °C
Transport Information
Appearance Colorless crystals or white crystal powder
Safety
Risk Codes
Molecular Structure
Hazard Symbols
Synonyms Butanedioicacid, 2,3-dihydroxy- (2R,3R)-, disodium salt (9CI);Butanedioic acid,2,3-dihydroxy-[R-(R*,R*)]-, disodium salt;Sodium tartrate (Na2(C4H4O6))(6CI,7CI);Tartaric acid, disodium salt (8CI);Bisodium tartrate;Disodium(+)-tartrate;Disodium L-(+)-tartrate;Disodium L-tartrate;L-Disodium tartrate;SodiumL-(+)-tartrate;
PSA 120.72000
LogP -4.79200

Synthetic route

: 50-99-7
D-glucose

A: 527-07-1
sodium D-gluconate

B: 868-18-8
sodium tartrate

C: D-glucaric acid disodium salt

Conditions

Conditions	Yield
With 2,2,6,6-tetramethyl-piperidine-N-oxyl; sodium hypochlorite; sodium bromide In water at 5℃; pH=11.7;	A n/a B n/a C 90%
With 2,2,6,6-tetramethyl-piperidine-N-oxyl; sodium hypochlorite; sodium bromide In water at 5℃; pH=11.2; Product distribution; Further Variations:; pH-values; Reaction partners;	A n/a B n/a C 64%
With 2,2,6,6-tetramethyl-piperidine-N-oxyl; sodium hypochlorite; sodium bromide In water at 5℃; pH=9.5;

...Expand

: Bi(3+)*OH(1-)*C4H4O6(2-)=Bi(OH)C4H4O6

A: 3Bi(3+)*7OH(1-)*C4H4O6(2-)=Bi(OH)*C4H4O6*2Bi(OH)3

B: 868-18-8
sodium tartrate

Conditions

Conditions	Yield
In sodium hydroxide solvation in aq. NaOH with formation of Na tartrate and the soluble coordination compound Bi(OH)C4H4O6*2Bi(OH)3;;

: sodium hydrogen tartrate *H2O

: 141-52-6
sodium ethanolate

: 868-18-8
sodium tartrate

Conditions

Conditions	Yield
In not given contact of NaOC2H5 with NaC4H5O6; slow reaction in the cold, fast reaction in the warmth;;
In not given contact of NaOC2H5 with NaC4H5O6; slow reaction in the cold, fast reaction in the warmth;;

: sodium arsenyl tartrate * 2.5H2O

: 1310-73-2
sodium hydroxide

A: arsenic(III) trioxide

B: 868-18-8
sodium tartrate

Conditions

Conditions	Yield
In not given formed when neutralized with NaOH; As2O3 pptd. and Na2C4H4O6 remained dissolved;;

...Expand

: sodium tartrate dihydrate

A: 497-19-8
sodium carbonate

B: 868-18-8
sodium tartrate

Conditions

Conditions	Yield
In neat (no solvent) byproducts: H2O, CO2, C; stepwise loss of H2O up to 154°C; decompn. of Na2C4H4O6 starting at 255°C; decompn. to Na2CO3 and C at 309°C: combustion of C up to 700°C; dissociation of Na2CO3 at 875°C;;
In neat (no solvent) byproducts: H2O, CO2, C; stepwise loss of H2O up to 154°C; decompn. of Na2C4H4O6 starting at 255°C; decompn. to Na2CO3 and C at 309°C: combustion of C up to 700°C; dissociation of Na2CO3 at 875°C;;

: 2Bi(3+)*4H(1+)*5C4H4O6(2-)=Bi2(C4H4O6)3*2C4H6O6

A: 3Bi(3+)*7OH(1-)*C4H4O6(2-)=Bi(OH)*C4H4O6*2Bi(OH)3

B: 868-18-8
sodium tartrate

Conditions

Conditions	Yield
With sodium hydroxide In water dissolution in aq. NaOH;;

: 87-69-4
tartaric acid

: 868-18-8
sodium tartrate

Conditions

Conditions	Yield
With sodium hydroxide pH=4.9;

: 62-76-0
sodium oxalate

: 868-18-8
sodium tartrate

Conditions

Conditions	Yield
With sodium cyanide Alkaline conditions;

: sodium dihydroxyfumarate

: 62-76-0
sodium oxalate

A: 526-94-3, 868-18-8, 4504-50-1, 14475-11-7, 21106-15-0, 21348-52-7, 21595-79-9, 22476-77-3, 25817-08-7, 51307-92-7, 60131-40-0, 64183-71-7, 109175-69-1
disodium meso-tartrate

B: 868-18-8
sodium tartrate

Conditions

Conditions	Yield
With sodium cyanide; sodium hydroxide for 24h; Aldol Condensation;

...Expand

: 868-18-8
sodium tartrate

: micafungin sodium

Conditions

Conditions	Yield
In ethanol; water	99.53%

: 67-66-3
chloroform

: ((C4NH2C(C6H4CH3))3H2(C(C6H4CH3)C4NH))2

: 5970-45-6
zinc(II) acetate dihydrate

: 868-18-8
sodium tartrate

: 71-43-2
benzene

: 2Zn(2+)*((CH3C6H4CN)4(CH)7C9H)2(2-)*(OOCCHOH)2(2-)*2C6H6*CHCl3=(Zn2((CH3C6H4CN)4(CH)7C9H)2(OOCCHOH)2)*2C6H6*CHCl3

Conditions

Conditions	Yield
In methanol; chloroform soln. Zn(AcO)2*2H2O in MeOH was added to soln. ligand in CHCl3, mixt. was stirred for 1 h and evapd. at room temp., solid was dissolved in CHCl3, filtered, filtrate volume was reduced, aq. soln. Na2tart was added, mixt. was stirred for 1 h; org. phase was isolated, washed with water, water phase was filtered, evapd. to dryness, solid was crystd. from benzene/CHCl3/hexane; elem. anal.;	80%

Yield

In methanol; chloroform soln. Zn(AcO)2*2H2O in MeOH was added to soln. ligand in CHCl3, mixt. was stirred for 1 h and evapd. at room temp., solid was dissolved in CHCl3, filtered, filtrate volume was reduced, aq. soln. Na2tart was added, mixt. was stirred for 1 h; org. phase was isolated, washed with water, water phase was filtered, evapd. to dryness, solid was crystd. from benzene/CHCl3/hexane; elem. anal.;

80%

...Expand

: 66-71-7
1,10-Phenanthroline

: cobalt(II) nitrate hexahydrate

: 7732-18-5
water

: 868-18-8
sodium tartrate

: [Co(tartrate)(1,10-phenanthroline)]*6H2O

Conditions

Conditions	Yield
In methanol; water aq. soln. of Co compd. (1 mmol) and H2O/MeOH (1:2) soln. of phen (1 mmol) and sodium tartrate (1 mmol); crystd. on storage for 2 wk, elem. anal.;	74%

...Expand

: 366-18-7
[2,2]bipyridinyl

: cobalt(II) nitrate hexahydrate

: 7732-18-5
water

: 868-18-8
sodium tartrate

: [Co(tartrate)(2,2'-bipyridine)]*5H2O

Conditions

Conditions	Yield
In methanol; water aq. soln. of Co compd. (1 mmol) and H2O/MeOH (1:2) soln. of phen (1 mmol) and sodium tartrate (1 mmol); crystd. on storage for 2 wk, elem. anal.;	70%

...Expand

: Pt(2+)*C12H12N2*2NO3(1-)

: 7732-18-5
water

: 868-18-8
sodium tartrate

: C28H26N4O6Pt2*4H2O

Conditions

Conditions	Yield
for 6h; Reflux;	68%

...Expand

: (R)-8-Fluoro-5-methoxycarbonyl-3-(N,N-di-n-propylamino)chroman

: 79-37-8
oxalyl dichloride

: 868-18-8
sodium tartrate

: (R)-8-Fluoro-5-formyl-3-(N,N-dipropylamino)-chroman

Conditions

Conditions	Yield
With sodium hydroxide; diisobutylaluminium hydride; sodium hydrogencarbonate; triethylamine In tetrahydrofuran; diethyl ether; dichloromethane; dimethyl sulfoxide	60%

...Expand

: 54822-51-4
Pt(2,2`-bipyridine)(ONO2)2

: 7732-18-5
water

: 868-18-8
sodium tartrate

: [{2,2’-bipyridine platinum(II)}2(μ-D-tart)][{2,2’-bipyridine platinum(II)}2(μ-L-tart)]*4H2O

: [2,2’-bipyridine platinum(II)(D-tartH2)][2,2’-bipyridine platinum(II)(L-tartH2)]*4H2O

Conditions

Conditions	Yield
In water at 20℃; for 24h;	A 54% B 0.5%

...Expand

: 503590-72-5
di(hexamethyleneimine)(sulfato)aquoplatinum(II)

: 868-18-8
sodium tartrate

: di(hexamethyleneimine)(tartronato)platinum(II)

Conditions

Conditions	Yield
In water 2 equiv. of Na salt, stirred for 24 h; filtered, concd. (vac.), cooled to 0°C for 24 h, ppt. filtered, washed (cold water), dried (vac.); elem. anal.;	53.48%

: 4916-57-8
1,2-bis(4'-pyridyl)ethane

: Cu(2+)*2NO3(1-)*8H2O=Cu(NO3)2*8H2O

: 868-18-8
sodium tartrate

: [Cu3(tartaric acid)(tartaric acid)-(H2O)(1,2-bis(4-pyridyl)ethane)] · 3H2O

Conditions

Conditions	Yield
With potassium iodide; sodium hydroxide In methanol; water at 150℃; for 96h; Sealed tube;	52%

...Expand

: copper(II) nitrate trihydrate

: cucurbit[6]uril

: 7732-18-5
water

: 868-18-8
sodium tartrate

: C36H36N24O12*C18H28N4(2+)*4C4H2O6(4-)*19H2O*7Cu(2+)

Conditions

Conditions	Yield
In water at 120℃; for 48h; Autoclave;	44%

...Expand

: copper(II) choride dihydrate

: cucurbit[6]uril

: 868-18-8
sodium tartrate

: C36H36N24O12*C18H26N4*2C4H4O6(2-)*2Cl(1-)*2H2O*3Cu(2+)

Conditions

Conditions	Yield
In water at 120℃; for 48h; Autoclave;	40.6%

...Expand

: C29H54N3O(1+)*Br(1-)

: 868-18-8
sodium tartrate

: C29H54N3O(1+)*0.5C4H4O6(2-)

Conditions

Conditions	Yield
In dichloromethane	25%

: C27H50N3O(1+)*Br(1-)

: 868-18-8
sodium tartrate

: C27H50N3O(1+)*0.5C4H4O6(2-)

Conditions

Conditions	Yield
In dichloromethane	21%

: C26H48N3O(1+)*Br(1-)

: 868-18-8
sodium tartrate

: C26H48N3O(1+)*0.5C4H4O6(2-)

Conditions

Conditions	Yield
In dichloromethane	20%

: C25H46N3O(1+)*Br(1-)

: 868-18-8
sodium tartrate

: C25H46N3O(1+)*0.5C4H4O6(2-)

Conditions

Conditions	Yield
In dichloromethane	20%

: C26H48N3O(1+)*Br(1-)

: 868-18-8
sodium tartrate

: C26H48N3O(1+)*0.5C4H4O6(2-)

Conditions

Conditions	Yield
In dichloromethane	20%

: C24H44N3O(1+)*Br(1-)

: 868-18-8
sodium tartrate

: C24H44N3O(1+)*0.5C4H4O6(2-)

Conditions

Conditions	Yield
In dichloromethane	18%

: C26H48N3O(1+)*Br(1-)

: 868-18-8
sodium tartrate

: C26H48N3O(1+)*0.5C4H4O6(2-)

Conditions

Conditions	Yield
In dichloromethane	18%

: C22H40N3O(1+)*Br(1-)

: 868-18-8
sodium tartrate

: C22H40N3O(1+)*0.5C4H4O6(2-)

Conditions

Conditions	Yield
In dichloromethane	17%

: C25H46N3O(1+)*Br(1-)

: 868-18-8
sodium tartrate

: C25H46N3O(1+)*0.5C4H4O6(2-)

Conditions

Conditions	Yield
In dichloromethane	16%

: 868-18-8
sodium tartrate

: C4(2)H6O6

Conditions

Conditions	Yield
With sodium hydroxide; water-d2 for 4h; Heating;

: 64-17-5
ethanol

: 96-10-6
diethylaluminium chloride

: 868-18-8
sodium tartrate

: 105-36-2
ethyl bromoacetate

: 55854-89-2
8-methyl-7-propionylindolizino[1,2-b]quinoline-9(11H)-one

: ethyl 3-hydroxy-3-(8-methyl-9-oxo-9,11-dihydroindolizino[1,2-b]quinolin-7-yl)pentanoate

Conditions

Conditions	Yield
With silver(I) acetate; potassium In tetrahydrofuran; dichloromethane
With silver(I) acetate; potassium In tetrahydrofuran; dichloromethane

...Expand

: 329270-46-4
2S-2-tert-butoxycarbonylamino-4-(2S-3,3-dimethyl-oxiranyl)-butyric acid methyl ester

: 329270-45-3
2S-2-tert-butoxycarbonylamino-4-(2R-3,3-dimethyl-oxiranyl)-butyric acid methyl ester

: 13283-01-7
tungsten(VI) chloride

: 868-18-8
sodium tartrate

: 329270-44-2
(2S)-2-tert-Butoxycarbonylamino-6-methylhept-5-enoic acid methyl ester

Conditions

Conditions	Yield
With sodium hydroxide; n-butyllithium In tetrahydrofuran

...Expand

: methyl N-(pyridin-4-yl)isonipecotate

: 868-18-8
sodium tartrate

: potassium tartrate

A: 130658-67-2
4-hydroxymethyl-1-(pyridin-4-yl)piperidine

B: 166954-15-0
C-(3,4,5,6-tetrahydro-2H-[1,4']bipyridinyl-4-yl)-methylamine

Conditions

Conditions	Yield
With sodium hydroxide In tetrahydrofuran; water; ethyl acetate

...Expand

: methyl N-(pyridin-4-yl)isonipecotate

: 868-18-8
sodium tartrate

: potassium tartrate

A: 725683-58-9
N-(5-chloropyridin-2-yl)-2-[[1-(4-pyridinyl)piperidin-4-yl]methoxy]benzamide

B: 130658-67-2
4-hydroxymethyl-1-(pyridin-4-yl)piperidine

Conditions

Conditions	Yield
With sodium hydroxide In tetrahydrofuran; water; ethyl acetate

...Expand

: 22889-78-7
3,5-dichloro-4-aminopyridine

sodium diethylaluminate: sodium diethylaluminate

: 1'-benzotriazolyl 7-methoxy-2-methoxymethyl-3H-benzimidazole-4-carboxylate

: 868-18-8
sodium tartrate

: 201284-92-6
N-(3,5-dichloro-pyridin-4-yl)-7-methoxy-2-methoxymethyl-3H-benzimidazole-4-carboxamide

Conditions

Conditions	Yield
In tetrahydrofuran; toluene

...Expand

: methyl N-(pyridin-4-yl)isonipecotate

: 868-18-8
sodium tartrate

: potassium tartrate

: 130658-67-2
4-hydroxymethyl-1-(pyridin-4-yl)piperidine

Conditions

Conditions	Yield
With sodium hydroxide In tetrahydrofuran; water; ethyl acetate	357 mg (68%)
With sodium hydroxide In tetrahydrofuran; water; ethyl acetate

...Expand

: 868-18-8
sodium tartrate

: 220495-70-5
1-phenylbenzimidazole-5-carboxylic acid methyl ester

: 5-(hydroxymethyl)-1-phenylbenzimidazole

Conditions

Conditions	Yield
With diisobutylaluminium hydride In methanol; dichloromethane

Sodium tartrate Consensus Reports

Reported in EPA TSCA Inventory.

Sodium tartrate Specification

The CAS registry number of Sodium tartrate is 868-18-8. Its EINECS registry number is 212-773-3. The systematic name is disodium (2R,3R)-2,3-dihydroxybutanedioate. In addition, the molecular formula is C₄H₄Na₂O₆ and the molecular weight is 194.05. Its crystal structure captures a very precise amount of water. And it is also a common primary standard for Karl Fischer titration. What's more, it should be stored in sealed container, and put in a cool and dry place.

Physical properties about this chemical are: (1)ACD/LogP: -1.43; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -5.86; (4)ACD/LogD (pH 7.4): -6.18; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 1; (8)ACD/KOC (pH 7.4): 1; (9)#H bond acceptors: 6; (10)#H bond donors: 4; (11)#Freely Rotating Bonds: 5; (12)Polar Surface Area: 93.06 Å²; (13)Flash Point: 209.4 °C; (14)Enthalpy of Vaporization: 75.13 kJ/mol; (15)Boiling Point: 399.3 °C at 760 mmHg; (16)Vapour Pressure: 4.93E-08 mmHg at 25°C.

Preparation and uses of Sodium tartrate: it can be prepared by L-tartaric acid. Heat the L-tartaric acid at first. And then after a series of neutralization by sodium hydroxide, condensation and crystallization you can get the desired product. In addition, it is used as an emulsifier and a binding agent in food products such as jellies, margarine, and sausage casings. And it also can be used as a food additive, slow granule, emulsion salt, antioxidants, antioxidant synergistic agent and chelating agent.

You can still convert the following datas into molecular structure:
(1)SMILES: [Na+].[Na+].O=C([O-])[C@H](O)[C@@H](O)C([O-])=O
(2)InChI: InChI=1/C4H6O6.2Na/c5-1(3(7)8)2(6)4(9)10;;/h1-2,5-6H,(H,7,8)(H,9,10);;/q;2*+1/p-2/t1-,2-;;/m1../s1
(3)InChIKey: HELHAJAZNSDZJO-NMAATZGSBY

The toxicity data is as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Source
mouse	LD10	oral	3686mg/kg (3686mg/kg)	Journal of the American Pharmaceutical Association, Scientific Edition. Vol. 31, Pg. 12, 1942.
rabbit	LDLo	oral	5290mg/kg (5290mg/kg)	FAO Nutrition Meetings Report Series. Vol. 53A, Pg. 512, 1974.
rat	LDLo	oral	7500mg/kg (7500mg/kg)	National Technical Information Service. Vol. OTS0555808,

Product Name

Sodium tartrate

Synthetic route

Sodium tartrate Consensus Reports

Sodium tartrate Specification

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