Sodium thiophenolate supplier

Name
SODIUM THIOPHENOXIDE
EINECS 213-224-0
CAS No. 930-69-8
Article Data48
CAS DataBase
Density 1.079g/cm³
Solubility
Melting Point >300 °C
Formula C₆H₆S.Na
Boiling Point 169.1°C at 760mmHg
Molecular Weight 132.161
Flash Point 50.6°C
Transport Information UN 1759
Appearance
Safety 26-36/37/39-45
Risk Codes 34
Molecular Structure
Hazard Symbols C
Synonyms Benzenethiol,sodium deriv. (6CI);Benzenethiol, sodium salt (8CI,9CI);Sodium, (phenylthio)-(7CI);Sodium benzenethiolate;Sodium phenylmercaptide;Sodium phenylsulfide;Sodium phenylthiolate;Sodium thiophenate;Sodium thiophenolate;Sodiumthiophenoxide;Sodium thiophenylate;Thiophenol sodium salt;Thiophenyl sodiumsalt;
PSA 25.30000
LogP 2.24300

Synthetic route

: 108-98-5
thiophenol

: 930-69-8
sodium thiophenolate

Conditions

Conditions	Yield
With sodium methylate In methanol at 45℃;	97%
With sodium hydride In tetrahydrofuran; diethyl ether for 1.75h;	93%
With sodium In diethyl ether	90%

: 934-87-2
S-phenyl thioacetate

: 930-69-8
sodium thiophenolate

Conditions

Conditions	Yield
With sodium thiomethoxide In methanol at 23℃; for 0.5h;	81%

: 3019-20-3
isopropylthiobenzene

: 930-69-8
sodium thiophenolate

Conditions

Conditions	Yield
With sodium In N,N,N,N,N,N-hexamethylphosphoric triamide at 90℃;

: 108-98-5
thiophenol

A: 930-69-8
sodium thiophenolate

B: 882-33-7
diphenyldisulfane

Conditions

Conditions	Yield
With sodium hydroxide

: sodium fluorenone ketyl

: 882-33-7
diphenyldisulfane

A: 486-25-9
9-fluorenone

B: 930-69-8
sodium thiophenolate

Conditions

Conditions	Yield
In tetrahydrofuran at 23℃; Rate constant;

...Expand

: C22H12(1-)*Na(1+)

: 882-33-7
diphenyldisulfane

A: 191-24-2
Benzo[ghi]perylene

B: 930-69-8
sodium thiophenolate

Conditions

Conditions	Yield
In tetrahydrofuran at 23℃; Rate constant;

...Expand

: C13H8O3S(1-)*Na(1+)

: 882-33-7
diphenyldisulfane

A: 930-69-8
sodium thiophenolate

B: 3166-15-2
thioxanthen-9-one 10,10-dioxide

Conditions

Conditions	Yield
In tetrahydrofuran at 22.4 - 33.5℃; Rate constant; Thermodynamic data; Ea, ΔG, ΔS;

...Expand

: perylene radical anion; sodium salt

: 882-33-7
diphenyldisulfane

A: 198-55-0
PERYLENE

B: 930-69-8
sodium thiophenolate

Conditions

Conditions	Yield
In tetrahydrofuran at 23℃; Rate constant;

...Expand

: 882-33-7
diphenyldisulfane

: 930-69-8
sodium thiophenolate

Conditions

Conditions	Yield
With sodium tetrahydroborate In ethanol for 0.5h; Heating;
With sodium In ammonia
With sodium tetrahydroborate In ethanol
With sodium tetrahydroborate In ethanol Inert atmosphere;

: 5510-78-1
diphenylthiophosphinic acid-S-phenyl ester

A: 930-69-8
sodium thiophenolate

B: 22214-04-6
sodium diphenylphosphinate

Conditions

Conditions	Yield
With sodium hydroxide In water; acetonitrile at 25℃; Rate constant; effect of H2O-MeCN proportion; further base and solvent;

: 60-29-7
diethyl ether

: 882-33-7
diphenyldisulfane

monosodium-compound of 4-phenyl-benzophenone: monosodium-compound of 4-phenyl-benzophenone

: 930-69-8
sodium thiophenolate

...Expand

: 56-23-5
tetrachloromethane

: 882-33-7
diphenyldisulfane

sodium: sodium

: 930-69-8
sodium thiophenolate

...Expand

: 5535-49-9
2-Chloroethyl phenyl sulfide

: 108-88-3
toluene

sodium: sodium

A: 74-85-1
ethene

B: 622-20-8
1,2-bis(phenylthio)ethane

C: 930-69-8
sodium thiophenolate

...Expand

: 14633-31-9
1-chloro-4-(phenylthio)butane

: 108-88-3
toluene

sodium: sodium

A: 106-98-9
1-butylene

B: 74-85-1
ethene

C: 5330-89-2
1,4-bis-phenylsulfanyl-butane

D: 930-69-8
sodium thiophenolate

...Expand

: 4911-65-3
3-chloropropyl phenyl sulfide

: 108-88-3
toluene

sodium: sodium

A: 28118-53-8
1,3-bis(phenylthio)propane

B: 930-69-8
sodium thiophenolate

C: 75-19-4
cyclopropane

...Expand

: 139-66-2
diphenyl sulfide

: 7664-41-7
ammonia

sodium: sodium

A: 930-69-8
sodium thiophenolate

B: 62-53-3
aniline

...Expand

: 7440-23-5
sodium

: 108-98-5
thiophenol

: 930-69-8
sodium thiophenolate

Conditions

Conditions	Yield
With methanol
Stage #1: sodium With methanol Stage #2: thiophenol In methanol

4-Acetyloxy-3-[3-[N',N"-di(Cbz)guanidino]propyl]-2-azetidinone: 4-Acetyloxy-3-[3-[N',N"-di(Cbz)guanidino]propyl]-2-azetidinone

: 108-98-5
thiophenol

A trans-4-Phenylthio-3-[3-[N',N"-di(Cbz)guanidino]propyl]-2-azetidinone: trans-4-Phenylthio-3-[3-[N',N"-di(Cbz)guanidino]propyl]-2-azetidinone

B: 930-69-8
sodium thiophenolate

Conditions

Conditions	Yield
With NaH In tetrahydrofuran	A 450 mg (34%) B n/a

...Expand

: 7311-63-9
5-bromothiophene-2-carboxylic acid

: 930-69-8
sodium thiophenolate

Conditions

Conditions	Yield
In quinoline; dimethyl sulfoxide

3-nitrophthalic acid N-phenylimide: 3-nitrophthalic acid N-phenylimide

: 108-98-5
thiophenol

: 930-69-8
sodium thiophenolate

Conditions

Conditions	Yield
With acetic acid In methanol; water; dimethyl sulfoxide

: 16940-66-2
sodium tetrahydroborate

: 2127-03-9
2,2'-dipyridyldisulphide

: 930-69-8
sodium thiophenolate

Conditions

Conditions	Yield
With sodium hydroxide In ethanol Inert atmosphere;

: 62-53-3
aniline

: 930-69-8
sodium thiophenolate

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: acetic acid / ethanol / 3 h / Reflux; Inert atmosphere 2: acetic acid / water; dimethyl sulfoxide View Scheme

: 19065-85-1
3-nitro-N-phenylphthalimide

: 930-69-8
sodium thiophenolate

Conditions

Conditions	Yield
With acetic acid In water; dimethyl sulfoxide

: 108-86-1
bromobenzene

: 930-69-8
sodium thiophenolate

: 139-66-2
diphenyl sulfide

Conditions

Conditions	Yield
o-phenylene-bis-nickel(II) bromide In ethylene glycol at 200℃; for 24h;	100%
With 1,5-(2,9-dimethyl-1,10-phenanthroyl)-p-tert-butylcalix[8]arene; copper(l) chloride In toluene at 110℃; for 15h; Schlenk technique; Glovebox; Inert atmosphere;	95%
With tetra(n-butyl)ammonium hydroxide In ammonia at -45℃; for 1.5h; Irradiation; further catalyst (Et3N);	70%
With 2C21H11N3O6(4-)H(1+)2Ni(2+)14H2OCo(3+) In N,N-dimethyl-formamide at 80℃; for 6h; Reagent/catalyst; Inert atmosphere;	65 %Chromat.

: 930-68-7
cyclohexenone

: 930-69-8
sodium thiophenolate

: 35155-84-1
3-phenylthiocyclohexanone

Conditions

Conditions	Yield
In tetrahydrofuran Ambient temperature;	100%

: 20395-28-2
5-chloropentyl acetate

: 930-69-8
sodium thiophenolate

: 82777-33-1
5-(phenylthio)pentyl acetate

Conditions

Conditions	Yield
In ethanol at 80℃; for 2h;	100%

: 43205-82-9
carvotanacetone

: 930-69-8
sodium thiophenolate

: 115234-44-1
5-isopropyl-2-methyl-3-(phenylthio)cyclohexanone

Conditions

Conditions	Yield
In tetrahydrofuran Ambient temperature;	100%

: 31643-49-9
4-Nitrophthalonitrile

: 930-69-8
sodium thiophenolate

: 51762-68-6
3-(phenylthio)-phthalonitrile

Conditions

Conditions	Yield
In N,N-dimethyl-formamide	100%

: 18801-63-3
3,4,5,6-tetramethyl-1,2-dinitrobenzene

: 930-69-8
sodium thiophenolate

: 81064-19-9
1-nitro-2-(phenylthio)-3,4,5,6-tetramethylbenzene

Conditions

Conditions	Yield
In dimethyl sulfoxide at 120℃; for 0.25h;	100%

: 31515-43-2
1-nitro-2-(phenylsulfonyl)benzene

: 930-69-8
sodium thiophenolate

: 4171-83-9
2-nitrophenyl phenyl sulfide

Conditions

Conditions	Yield
In dimethyl sulfoxide at 120℃; for 3h;	100%

: 930-69-8
sodium thiophenolate

: 88626-31-7
E-(1-methyl 1,3-butadienyl) sulfonyl benzene

: 109628-69-5
E-(1-methyl 4-phenylthio 2-butenyl) sulfonyl benzene

Conditions

Conditions	Yield
In ethanol; benzene at 25℃; for 3h;	100%

: 930-69-8
sodium thiophenolate

: 144898-91-9
Methyl 2-cyclopentyl-6-bromo-4-hexenoate

: 144898-99-7
Methyl 2-cyclopentyl-6-phenylthio-4-hexenoate

Conditions

Conditions	Yield
In ethanol	100%

: 930-69-8
sodium thiophenolate

: 144898-96-4
Methyl trans-1-(4-bromo-2-butenyl)cyclohexanecarboxylate

: 144899-01-4
Methyl 1-(4-phenylthio-2-butenyl)-cyclohexanecarboxylate

Conditions

Conditions	Yield
In ethanol	100%

: 930-69-8
sodium thiophenolate

: 79433-13-9
acetic acid (2Z,6E)-8-bromo-3,7-dimethyl-octa-2,6-dienyl ester

: 79433-14-0
(2Z,6E)-3,7-dimethyl-8-phenylthio-2,6-octadien-1-ol

Conditions

Conditions	Yield
In methanol at 65℃; for 2h;	100%

: 930-69-8
sodium thiophenolate

: (1R,2R)-2-Chloromethyl-cyclobutanecarbonitrile

: (1R,2R)-2-Phenylsulfanylmethyl-cyclobutanecarbonitrile

Conditions

Conditions	Yield
In methanol for 2h; Heating;	100%

: 930-69-8
sodium thiophenolate

: 79306-31-3
1-bromo-2,2-dimethylcyclopropyl methyl sulfide

: 79306-55-1
(2,2-Dimethyl-1-methylsulfanyl-cyclopropylsulfanyl)-benzene

Conditions

Conditions	Yield
In N,N-dimethyl-formamide at 20℃;	100%

: 930-69-8
sodium thiophenolate

: C27H22NOPS

: (2-phenyl-4-thiazolyl)triphenylphosphonium perchlorate

Conditions

Conditions	Yield
With hydrogenchloride; sodium perchlorate In methanol at 20 - 25℃; for 24h;	100%

: 930-69-8
sodium thiophenolate

: C28H24NOPS

: Triphenyl-(2-p-tolyl-thiazol-4-yl)-phosphonium; perchlorate

Conditions

Conditions	Yield
With hydrogenchloride; sodium perchlorate In methanol at 20 - 25℃; for 24h;	100%

: 1112-67-0
tetrabutyl-ammonium chloride

: 930-69-8
sodium thiophenolate

: 4670-62-6
tetra-N-butylammonium benzenethiolate

Conditions

Conditions	Yield
In tetrahydrofuran for 4h; Inert atmosphere;	100%

: 930-69-8
sodium thiophenolate

: 156306-86-4
6,8-dibromo-1,4-dimethoxybenzocyclohepten-7-one

: 138147-86-1
6,8-bis(phenylthio)-1,4-dimethoxy-7H-benzocyclohepten-6-one

Conditions

Conditions	Yield
In N,N-dimethyl-formamide at 85℃; for 1h;	100%

: 930-69-8
sodium thiophenolate

: 128803-97-4
9-<2,3-anhydro-5-O-(tert-butyldimethylsilyl)-β-D-ribofuranosyl>adenine

: 440099-55-8
9-[5-O-(tert-butyldimethylsilyl)-3-deoxy-3-C-phenylthio-β-D-xylofuranosyl]adenine

Conditions

Conditions	Yield
In methanol for 6.5h; Heating;	100%

: 615-20-3
2-chlorobenzo[d][1,3]thiazole

: 930-69-8
sodium thiophenolate

: 4276-60-2
2-(phenylthio)benzothiazole

Conditions

Conditions	Yield
In ethanol for 5h; Heating;	100%

: 930-69-8
sodium thiophenolate

: 216172-10-0
4-[(tert-butyldimethylsilyl)oxy]but-2-yn-1-yl 4-methylbenzene-1-sulfonate

: 880885-70-1
tert-butyl-dimethyl-(4-phenylsulfanyl-but-2-ynyloxy)-silane

Conditions

Conditions	Yield
With 18-crown-6 ether In toluene at 20℃;	100%

: 1558-81-2
1-carbethoxy-1-cyanocyclopropane

: 930-69-8
sodium thiophenolate

poly(ethyl 1-cyanocyclopropanecarboxylate), degree of polymerization 41; monomer(s): ethyl 1-cyanocyclopropanecarboxylate; sodium thiophenolate: poly(ethyl 1-cyanocyclopropanecarboxylate), degree of polymerization 41; monomer(s): ethyl 1-cyanocyclopropanecarboxylate; sodium thiophenolate

Conditions

Conditions	Yield
In dimethyl sulfoxide at 60℃; for 4h;	100%

: 930-69-8
sodium thiophenolate

: 158109-81-0
cis-(2S,3S)-(+)-N-(p-toluenesulfonyl)-2-carbomethoxy-3-phenylaziridine

: C23H23NO4S2

Conditions

Conditions	Yield
	100%

: bis((cyclopentadienyl)(1,2-ethanedithiolate)titanium(IV) chloride)

: 930-69-8
sodium thiophenolate

: bis((cyclopentadienyl)(1,2-ethanedithiolate)(SPh)titanium(IV))

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: NaCl; a mixt. of Ti-compd. and NaSPh in THF is stirred for 1 h (N2); solvent is removed, residue is extd. into benzene, ppt. is filtered off, filtrate is kept for 1 week, elem. anal.;	100%

: 930-69-8
sodium thiophenolate

: 37026-88-3
N-methyl-tri-n-butyl-ammonium bromide

: 100-68-5
methyl-phenyl-thioether

Conditions

Conditions	Yield
In butan-1-ol at 115℃; for 5h;	99.5%

: 612-62-4
2-Chloroquinoline

: 930-69-8
sodium thiophenolate

: 22190-12-1
2-phenylsulfanyl-quinoline

Conditions

Conditions	Yield
In N,N,N,N,N,N-hexamethylphosphoric triamide at 90℃; for 0.00972222h; microwave irradiation;	99%
In ethanol Heating;	89%
In dimethyl sulfoxide at 150℃; for 0.25h; Microwave irradiation;	83%
With ethanol

: 5029-67-4
2-iodopyridine

: 930-69-8
sodium thiophenolate

: 3111-54-4
2-phenylsulfanylpyridine

Conditions

Conditions	Yield
In N,N,N,N,N,N-hexamethylphosphoric triamide at 100℃; for 0.00833333h; microwave irradiation;	99%
In N,N-dimethyl-formamide at 80℃; for 4h; Product distribution; Mechanism;	58 % Chromat.
In N,N-dimethyl-formamide at 80℃; for 4h;	58 % Chromat.

: 111-83-1
1-bromo-octane

: 930-69-8
sodium thiophenolate

: 13910-16-2
n-octylsulfanylbenzene

Conditions

Conditions	Yield
dodecyldimethylsulfonium methyl sulfate In water at 40℃; for 6h;	99%
polymer-supported polyether 6a In water; toluene at 25℃; Rate constant; other polymer-supported crown ethers and cryptands as phase-transfer catalysts;
hexadecyltetrabutylphosphonium bromide at 20℃; for 0.15h; Product distribution; further times and phase-transfer catalysts;	100 % Chromat.
Ph3S(1+)*X(1-); bromine; iodide; perchlorate(1-) In dichloromethane; water at 40℃; for 12h;

: 110637-93-9, 58324-83-7
p-(1-methyl-1-nitropropyl)nitrobenzene

: 930-69-8
sodium thiophenolate

A: 110637-97-3
2-(p-nitrophenyl)-2-butyl phenyl sulfide

B: 882-33-7
diphenyldisulfane

Conditions

Conditions	Yield
In dimethyl sulfoxide for 0.75h;	A 99% B 99%

...Expand

: 30491-96-4
2-(Chloromethyl)-cyclopropannitril

: 930-69-8
sodium thiophenolate

: 115373-45-0
2-Phenylsulfanylmethyl-cyclopropanecarbonitrile

Conditions

Conditions	Yield
In methanol for 16h; Heating;	99%

: 930-69-8
sodium thiophenolate

: 108661-89-8
(2-bromo-1,1-difluoro-ethyl)benzene

: 129973-38-2
2,2-Difluoro-2-phenylethyl phenyl sulfide

Conditions

Conditions	Yield
With N,N-dimethyl-formamide at 25℃; for 2h;	99%

Sodium thiophenolate Specification

The cas register number of Sodium thiophenolate is 930-69-8. It also can be called as Benzenethiol, sodium salt and the Systematic name about this chemical is sodium benzenethiolate.

Physical properties about Sodium thiophenolate are: (1)ACD/LogP: 2.52; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 2.49; (4)ACD/LogD (pH 7.4): 1.67; (5)ACD/BCF (pH 5.5): 44.97; (6)ACD/BCF (pH 7.4): 6.83; (7)ACD/KOC (pH 5.5): 519.58; (8)ACD/KOC (pH 7.4): 78.9; (9)#H bond acceptors: 0; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 1; (12)Polar Surface Area: 38.8Å²; (13)Flash Point: 50.6 °C; (14)Enthalpy of Vaporization: 39.93 kJ/mol; (15)Boiling Point: 169.1 °C at 760 mmHg; (16)Vapour Pressure: 2.07 mmHg at 25°C.

When you are using this chemical, please be cautious about it as the following:
It can causes burns. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. So people must wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)

People can use the following data to convert to the molecule structure.
1.SMILES: [Na+].[S-]c1ccccc1
2.InChI: InChI=1/C6H6S.Na/c7-6-4-2-1-3-5-6;/h1-5,7H;/q;+1/p-1
3.InChIKey: RZWQDAUIUBVCDD-REWHXWOFAQ
4.Std. InChI: InChI=1S/C6H6S.Na/c7-6-4-2-1-3-5-6;/h1-5,7H;/q;+1/p-1.

Product Name

SODIUM THIOPHENOXIDE

Synthetic route

Sodium thiophenolate Specification

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