Tetradecane supplier | CasNO.629-59-4

Name
n-Tetradecane
EINECS 211-096-0
CAS No. 629-59-4
Article Data145
CAS DataBase
Density 0.764 g/cm³
Solubility insoluble in water
Melting Point 5.8 °C
Formula C₁₄H₃₀
Boiling Point 253.9 °C at 760 mmHg
Molecular Weight 198.392
Flash Point 99.4 °C
Transport Information
Appearance Colorless liquid
Safety 23-24-62-24/25
Risk Codes 65-67
Molecular Structure
Hazard Symbols Xn
Synonyms CactusNormal Paraffin N 14;Linpar 14;N 14;NSC 72440;Rubitherm RT 2;n-Tetradecane;
PSA 0.00000
LogP 5.70740

Synthetic route

: 1120-36-1
1-tetradecene

: 629-59-4
tetradecane

Conditions

Conditions	Yield
With hydrogen; In dichloromethane at 65℃; for 18h; same yield with a similar catalyst; Pressure (range begins): 120 ;	100%
With hydrogen In methanol at 20℃; under 2068.65 Torr; for 2h;	98%
With 3-methyllumiflavin; oxygen; hydrazine hydrate In acetonitrile at 30℃; under 760.051 Torr; for 24h;	96%

: 41320-43-8
S-methyl O-tetradecyl dithiocarbonate

: 629-59-4
tetradecane

Conditions

Conditions	Yield
With sodium formate; (Bu4N)2S2O8 In N,N-dimethyl-formamide at 50℃; for 0.5h; Barton-McCombie deoxygenation;	100%
With 2,2'-azobis(isobutyronitrile); tetraphenyldisilane In ethyl acetate for 16h; Reduction; Heating;	51%
With triethyl borane; tri-n-butyl-tin hydride In hexane; benzene at 20℃; for 0.333333h;	18%

: 334-68-9
1-fluorododecane

: 629-59-4
tetradecane

Conditions

Conditions	Yield
With triethylaluminum; 1,2-dibromomethane In hexane at 20℃; for 24h; Solvent;	99%

: 10374-74-0
tetradec-7-ene

: 629-59-4
tetradecane

Conditions

Conditions	Yield
With platinum on activated charcoal; C24H16N2O4 In ethanol at 50℃; for 18h; Glovebox;	99%

: 1002-69-3
decyl chloride

: 92273-73-9
n-butylzinc bromide

: 629-59-4
tetradecane

Conditions

Conditions	Yield
With 1-methyl-1H-imidazole; tris(dibenzylideneacetone)dipalladium (0) In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 80℃; for 40h; Negishi cross-coupling;	97%

: 140479-90-9
tetradecyl (pentafluorophenyl)thionocarbonate

: 629-59-4
tetradecane

Conditions

Conditions	Yield
With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; 1-hydroxy-pyrrolidine-2,5-dione In toluene for 0.0833333h; Product distribution; Mechanism; Heating; other thionocarbonates, other solvents and reaction times, or diphenylsilane, phenylsilane, triphenylsilane in combination with benzoyl peroxide;	95%
With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride In toluene for 0.0833333h; Heating;	95 % Chromat.

: 1243-66-9
N-tetradecyl-p-toluenesulfonamide

: 629-59-4
tetradecane

Conditions

Conditions	Yield
With potassium hydroxide; chloroamine In methanol; diethyl ether Heating;	93%

: 544-63-8
n-tetradecanoic acid

: 629-59-4
tetradecane

Conditions

Conditions	Yield
With hydrogen In hexane at 160℃; under 22502.3 Torr; for 18h; Molecular sieve; chemoselective reaction;	90%
With hydrogen In neat (no solvent) at 250℃; under 6000.6 Torr; for 24h; Catalytic behavior; Autoclave; High pressure;	89%
With Hexadecane; hydrogen at 50 - 200℃; under 5931.67 - 21446.5 Torr; Reagent/catalyst; Sealed tube; Inert atmosphere;	30.14%

: 112-29-8
1-bromo dodecane

: 92273-73-9
n-butylzinc bromide

: 629-59-4
tetradecane

Conditions

Conditions	Yield
With 1-methyl-1H-imidazole; tris(dibenzylideneacetone)dipalladium (0) In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 80℃; for 40h; Negishi cross-coupling;	90%

: 124-07-2
Octanoic acid

: 629-59-4
tetradecane

Conditions

Conditions	Yield
With piperidine; silica gel In methanol; acetonitrile Kolbe electrolytic synthesis; Electrolysis; cooling;	90%
With pyridine; potassium hydroxide In methanol; cyclohexane; acetonitrile Kolbe electrolysis; Electrolysis;	95 %Spectr.

: 1002-84-2
palmitic acid

A: 629-59-4
tetradecane

B: 201230-82-2
carbon monoxide

Conditions

Conditions	Yield
With hydrogen at 200℃; under 7500.75 Torr; for 24h; Microwave irradiation;	A 90% B n/a

: 112-72-1
1-Tetradecanol

A: 629-50-5
Tridecane

B: 629-59-4
tetradecane

Conditions

Conditions	Yield
With hydrogen; Ni-2549 P at 240℃; under 15001.5 Torr; for 12h;	A 89% B 2.1%
With hydrogen In n-heptane at 199.84℃; under 22502.3 Torr; Kinetics; Autoclave;

: 51354-26-8
Acetic acid 1-pentyl-nonyl ester

: 629-59-4
tetradecane

Conditions

Conditions	Yield
With di-tert-butyl peroxide; HSiPh3 at 140℃; for 15h;	88%
With di-tert-butyl peroxide; (4-diphenylsilylphenyl)diphenylsilane at 140℃; for 15h; Product distribution; alcohol deoxygenation via acetate; reaction with Ph3SiH;	70%

: 51354-26-8
Acetic acid 1-pentyl-nonyl ester

: 789-25-3
HSiPh3

A: 629-59-4
tetradecane

B: 1929-33-5
triphenylsilyl acetate

Conditions

Conditions	Yield
With di-tert-butyl peroxide at 140℃; for 12h;	A 88% B n/a

...Expand

: 4282-40-0
1-Iodoheptane

: 629-59-4
tetradecane

Conditions

Conditions	Yield
With manganese; copper dichloride In water for 16h; Ambient temperature;	87%
With pyridine; manganese; trifluoroacetic acid; cobalt(II) bromide In acetonitrile at 50℃;	60%
With CuI*P(Et)3; lithium dihydronaphthylide radical 1. THF/DMF, 0 deg C; 2. 25 deg C; Yield given. Multistep reaction;

: 2425-54-9
myristyl chloride

: 629-59-4
tetradecane

Conditions

Conditions	Yield
With cyclohexa-1,4-diene; 9-ethyl-N3,N3,N6,N6,-tetramethyl-9H-carbazole-3,6-diamine; N-ethyl-N,N-diisopropylamine In N,N-dimethyl acetamide at 23℃; for 36h; Reagent/catalyst; Solvent; Inert atmosphere; UV-irradiation; Schlenk technique;	87%
With lithium-trihydroborate In tetrahydrofuran for 48h; Ambient temperature;	42%
With [((Me)NN2)NiCl]; diphenylsilane; sodium isopropylate In toluene for 6.5h; Inert atmosphere;	98 %Chromat.

: 2050-77-3
Iododecane

: 92273-73-9
n-butylzinc bromide

: 629-59-4
tetradecane

Conditions

Conditions	Yield
With 1-methyl-1H-imidazole; tris(dibenzylideneacetone)dipalladium (0) In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 80℃; for 40h; Negishi cross-coupling;	87%

: 111-25-1
1-bromo-hexane

: 17049-49-9
octylmagnesium bromide

A: 629-59-4
tetradecane

B: 544-76-3
Hexadecane

Conditions

Conditions	Yield
With silver(I) 4-methylbenzenesulfonate; ethylene dibromide In tetrahydrofuran at 20℃; for 30h;	A 2% B 86%

...Expand

: 629-04-9
1-Bromoheptane

A: 629-59-4
tetradecane

B further product(s): the corresponding alkane and/oralkene: further product(s): the corresponding alkane and/oralkene

Conditions

Conditions	Yield
With tetrabutylammonium tetrafluoroborate; nickel(0) 2,2'-bipyridyl complex Product distribution; electrochemical reduction;;	A 85% B n/a

: 146404-39-9
C21H38N2O2S

: 629-59-4
tetradecane

Conditions

Conditions	Yield
With potassium tert-butylate In tetrahydrofuran Heating;	83%

: 13125-66-1
n-heptylmagnesium bromide

: 89228-81-9
buta-2,3-dien-1-yl diethyl phosphate

A: 44993-36-4
2-heptyl-buta-1,3-diene

B: 629-59-4
tetradecane

Conditions

Conditions	Yield
In tetrahydrofuran for 0.5h; Ambient temperature; Yields of byproduct given;	A 80% B n/a

...Expand

: 86436-68-2
5-Bromo-tetradecane

: 629-59-4
tetradecane

Conditions

Conditions	Yield
With sodium tetrahydroborate In various solvent(s) at 70℃; for 12h;	80%

: 112-29-8
1-bromo dodecane

: 693-04-9
butyl magnesium bromide

: 629-59-4
tetradecane

Conditions

Conditions	Yield
With buta-1,3-diene; copper dichloride In tetrahydrofuran at 30℃; for 48h; Schlenk technique; Inert atmosphere;	80%
With buta-1,3-diene; nickel dichloride In tetrahydrofuran at 0℃; for 0.5h;	100 % Chromat.
With 1-Phenylprop-1-yne; copper dichloride In tetrahydrofuran for 0.5h; Heating;	98 % Chromat.

: 24767-82-6
1-heptyl 4-methylbenzenesulfonate

: 629-59-4
tetradecane

Conditions

Conditions	Yield
With pyridine; manganese; trifluoroacetic acid; sodium iodide; cobalt(II) bromide In acetonitrile at 50℃;	80%

: 505-54-4
thapsic acid

: 629-59-4
tetradecane

Conditions

Conditions	Yield
With whole cells of Escherichia coli overexpressed short-length Chlorella variabillis photodecarboxylase In dimethyl sulfoxide at 30℃; for 6h; pH=8.5; Concentration; Sealed tube; Irradiation; Microbiological reaction;	79%

: 26072-89-9
1-Tetradecene sulfide

A: 1120-36-1
1-tetradecene

B: 629-59-4
tetradecane

C: 35953-54-9
trans-2-tetradecene

Conditions

Conditions	Yield
With nickel In ethanol at 90℃; for 0.5h;	A 74% B 16% C 4%

...Expand

: 18451-85-9
15-(methoxycarbonyl)pentadecanoic acid

: 124-07-2
Octanoic acid

A: 629-59-4
tetradecane

B: 929-77-1
behenic acid methyl ester

C: 24397-43-1
triacontanedioic acid dimethyl ester

Conditions

Conditions	Yield
With sodium methylate In methanol at 27℃; Kolbe coupling; Electrochemical reaction; Pt anode; graphite cathode;	A n/a B 72% C n/a

...Expand

: 629-06-1
1-Chloroheptane

: 629-59-4
tetradecane

Conditions

Conditions	Yield
With pyridine; manganese; trifluoroacetic acid; sodium iodide; cobalt(II) bromide In acetonitrile at 80℃; for 72h; Reagent/catalyst;	70%
With tetrabutylammonium tetrafluoroborate; nickel(0) 2,2'-bipyridyl complex In N,N-dimethyl-formamide at 20℃; Rate constant; electrochemical reduction;

: 6294-17-3
1-bromo-6-chlorohexane

: 92273-73-9
n-butylzinc bromide

: 629-59-4
tetradecane

Conditions

Conditions	Yield
With 1-methyl-1H-imidazole; tris(dibenzylideneacetone)dipalladium (0) In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 80℃; for 40h; Negishi cross-coupling;	70%

: 555-44-2
glyceroltripalmitate

: 629-59-4
tetradecane

Conditions

Conditions	Yield
With tris(pentafluorophenyl)borate In cyclohexane at 20℃; for 6h; Schlenk technique; Inert atmosphere; Green chemistry;	70%

2'-(2'-hydroxy-4-methylphenyl)-2',4',4',7'-tetramethylchroman: 2'-(2'-hydroxy-4-methylphenyl)-2',4',4',7'-tetramethylchroman

: 629-59-4
tetradecane

: 108-39-4
3-methyl-phenol

: 19814-64-3
3,6,9,9-tetramethylxanthene

Conditions

Conditions	Yield
With methanesulfonic acid	90%

...Expand

: 629-59-4
tetradecane

: 108-39-4
3-methyl-phenol

A 4,4,4'4'7,7'-hexamethyl-2,2'-spirobichroman: 4,4,4'4'7,7'-hexamethyl-2,2'-spirobichroman

B: 19814-64-3
3,6,9,9-tetramethylxanthene

Conditions

Conditions	Yield
With methanesulfonic acid In acetone	A 73% B n/a

...Expand

Tetradecane Specification

The IUPAC name of this chemical is tetradecane. With the CAS registry number 629-59-4, it is also named as n-Tetradecane. The product's categories are Analytical Chemistry; n-Paraffins (GC Standard); Standard Materials for GC; Acyclic; Alkanes; Organic Building Blocks; Alpha Sort; Chemical Class; Hydrocarbons; NeatsVolatiles / Semivolatiles; TA - TE; T-ZAlphabetic. It is colorless liquid which is flammable by fire, heat and oxidants. When heated to decomposition it emits acrid smoke and irritating fumes. In addition, Tetradecane may be incompatible with strong oxidizing agents like nitric acid. So the storage environment should be ventilate, low-temperature and dry.

The other characteristics of this product can be summarized as: (1)ACD/LogP: 8.19; (2)# of Rule of 5 Violations: 1; (3)ACD/LogD (pH 5.5): 8.19; (4)ACD/LogD (pH 7.4): 8.19; (5)ACD/BCF (pH 5.5): 994777.5; (6)ACD/BCF (pH 7.4): 994777.5; (7)ACD/KOC (pH 5.5): 683503.31; (8)ACD/KOC (pH 7.4): 683503.31; (9)#H bond acceptors: 0; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 11; (12)Index of Refraction: 1.428; (13)Molar Refractivity: 66.9 cm³; (14)Molar Volume: 259.6 cm³; (15)Polarizability: 26.52×10^-24 cm³; (16)Surface Tension: 26.5 dyne/cm; (17)Enthalpy of Vaporization: 47.14 kJ/mol; (18)Vapour Pressure: 0.0285 mmHg at 25°C; (19)Rotatable Bond Count: 11; (20)Exact Mass: 198.234751; (21)MonoIsotopic Mass: 198.234751; (22)Heavy Atom Count: 14; (23)Complexity: 74.

Preparation of Tetradecane: It can be obtained by 1-iodo-heptane. This reaction needs reagent CuCl2 and Mn and solvent H2O at ambient temperature. The reaction time is 16 hours. The yield is 87%.

Uses of Tetradecane: It is mainly used in organic synthesis and can be used as solvents and standards hydrocarbon. It is also used as standard material in chromatographic analysis.

When you are using this chemical, please be cautious about it as the following:
It may cause lung damage if swallowed and vapours may cause drowsiness and dizziness, so people should not breathe vapour and avoid contact with skin and eyes. If swallowed, do not induce vomitting; seek medical advice immediately and show this container or label.

People can use the following data to convert to the molecule structure.
1. SMILES:C(CCCCC)CCCCCCCC
2. InChI: InChI=1/C14H30/c1-3-5-7-9-11-13-14-12-10-8-6-4-2/h3-14H2,1-2H3

The following are the toxicity data which has been tested.

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
mouse	LDLo	intravenous	5800mg/kg (5800mg/kg)	BEHAVIORAL: ALTERED SLEEP TIME (INCLUDING CHANGE IN RIGHTING REFLEX)	Acta Pharmacologica et Toxicologica. Vol. 37, Pg. 56, 1975.

Product Name

n-Tetradecane

Synthetic route

Tetradecane Specification

Related Products

Hot Products