Triaminomonochloro platinum (II) chloride supplier

Name
Triaminomonochloro platinum (II) chloride
EINECS
CAS No. 13815-16-2
Article Data34
CAS DataBase
Density g/cm³
Solubility
Melting Point
Formula ClH₆N₃Pt-₃
Boiling Point °Cat760mmHg
Molecular Weight 317.078
Flash Point °C
Transport Information
Appearance
Safety
Risk Codes
Molecular Structure
Hazard Symbols
Synonyms 2,3,4-triaminopyridine;triaminopyridine;Pyridin-2,3,4-triyltriamin;2,3,4-pyridinetriamine;pyridine-2,3,4-triyltriamine;
PSA 78.06000
LogP 1.01610

Synthetic route

: 26035-31-4, 14913-33-8, 15663-27-1
transplatin

: 13815-16-2
triamminechloroplatinum(II) chloride

Conditions

Conditions	Yield
With hydrogenchloride; ammonium hydroxide; silver nitrate In water; N,N-dimethyl-formamide byproducts: AgCl; Pt-complex reacted with a soln. of AgNO3 in DMF overnight; filtered; aq. NH4OH added; evapd. to dryness; dissolved in aq. HCl; concentrated; ethanol added; cooled to -20°C; pptd.; recrystd. from 0.1 M HCl/ethanol; elem. anal.;	47%

: 15663-27-1
cisplatin

: tetrammineplatinum(II) chloride

: 13815-16-2
triamminechloroplatinum(II) chloride

Conditions

Conditions	Yield
With ammonia In water effect of NH3 forms a small amount of (Pt(NH3)3Cl)Cl and a great amount of (Pt(NH3)4)Cl2;;
With NH3 In water effect of NH3 forms a small amount of (Pt(NH3)3Cl)Cl and a great amount of (Pt(NH3)4)Cl2;;
With NH3 In water dropwise addn. of NH3-soln. to a cis-(Pt(NH3)2Cl2)-soln. heated at 95-98°C;;

: 15663-27-1
cisplatin

: 13815-16-2
triamminechloroplatinum(II) chloride

Conditions

Conditions	Yield
With potassium cyanate In water byproducts: NH3; effect of KCNO;;
With water In not given formation at heating of cis-(Pt(NH3)2Cl2) in presence of H2O at 100°C under a pressure of 4250 atm;;	<1
With H2O In not given formation at heating of cis-(Pt(NH3)2Cl2) in presence of H2O at 100°C under a pressure of 4250 atm;;	<1
With KCNO In water byproducts: NH3; effect of KCNO;;

: tetrammineplatinum(II) chloride

: chloro-triammine-platinum(II) tetrachloro-platinate(II)

: 13815-16-2
triamminechloroplatinum(II) chloride

Conditions

Conditions	Yield
In not given formation at reaction of (Pt(NH3)3Cl)2(PtCl4) with (Pt(NH3)4)Cl2;; recrystallization in dild. alcohol;;
In not given formation at reaction of (Pt(NH3)3Cl)2(PtCl4) with (Pt(NH3)4)Cl2;; recrystallization in dild. alcohol;;

: 15663-27-1
cisplatin

: tetrammineplatinum(II) chloride

: 13815-16-2
triamminechloroplatinum(II) chloride

Conditions

Conditions	Yield
With hydrogenchloride; potassium cyanate; potassium tetrachloroplatinate In water byproducts: [Pt(NH3)4][PtCl4], [Pt(NH3)3Cl]2[PtCl4]; cis-(Pt(NH3)2Cl2) and KNCO boiled in water for 1 min, concd. HCl added,unreacted Pt-complex filtered off, K2PtCl4 added, (PtNH3)4)(PtCl4) and (Pt(NH3)3Cl)2(PtCl4) sepd., the filtrate yielded a solid, dissolved in aq. HCl, treated with (Pt(NH3)4)Cl2; the product was obtained by leaving the soln. over P2O5 in a dessicator;

Yield

With hydrogenchloride; potassium cyanate; potassium tetrachloroplatinate In water byproducts: [Pt(NH3)4][PtCl4], [Pt(NH3)3Cl]2[PtCl4]; cis-(Pt(NH3)2Cl2) and KNCO boiled in water for 1 min, concd. HCl added,unreacted Pt-complex filtered off, K2PtCl4 added, (PtNH3)4)(PtCl4) and (Pt(NH3)3Cl)2(PtCl4) sepd., the filtrate yielded a solid, dissolved in aq. HCl, treated with (Pt(NH3)4)Cl2; the product was obtained by leaving the soln. over P2O5 in a dessicator;

: 7647-01-0
hydrogenchloride

: tetrammineplatinum(II) chloride

: 13815-16-2
triamminechloroplatinum(II) chloride

Conditions

Conditions	Yield
In hydrogenchloride formation at effect of HCl-soln. on (Pt(NH3)4)Cl2;;
In hydrogenchloride formation at effect of HCl-soln. on (Pt(NH3)4)Cl2;;

: chloro-triammine-platinum(II) tetrachloro-platinate(II)

: tetraammineplatinum(II) chloride monohydrate

: 13815-16-2
triamminechloroplatinum(II) chloride

Conditions

Conditions	Yield
In hydrogenchloride formation at boiling of (Pt(NH3)4)Cl2*H2O with 8% excess (Pt(NH3)3Cl)2(PtCl4) and H2O containing HCl for 3 min; cooling down; concn. in vac.; filtration; evaporation in vac. over H2SO4 and storing over sodium lime;;

: potassium amminetrichloroplatinate

: 15663-27-1
cisplatin

: tetrammineplatinum(II) chloride

: 13815-16-2
triamminechloroplatinum(II) chloride

Conditions

Conditions	Yield
With ammonia In ammonia
With NH3 In ammonia aq. ammonia=NH3;
In ammonia

...Expand

: 15663-27-1
cisplatin

: 7664-41-7
ammonia

: 13815-16-2
triamminechloroplatinum(II) chloride

Conditions

Conditions	Yield
In not given formation at addn. of NH3 to cis-(Pt(NH3)2Cl2);;
In not given formation at addn. of NH3 to cis-(Pt(NH3)2Cl2);;
In ammonia aq. ammonia=NH3; formation from cis-(Pt(NH3)2Cl2) and NH3-soln.;; not isolated;;

: 26035-31-4, 14913-33-8, 15663-27-1
transplatin

: tetrammineplatinum(II) chloride

: 13815-16-2
triamminechloroplatinum(II) chloride

Conditions

Conditions	Yield
With ammonia In ammonia effect of NH3;;
With NH3 In ammonia aq. ammonia=NH3; effect of NH3;;

: 26035-31-4, 14913-33-8, 15663-27-1
transplatin

: 7664-41-7
ammonia

: 13815-16-2
triamminechloroplatinum(II) chloride

Conditions

Conditions	Yield
In not given formation at addn. of NH3 to trans-(Pt(NH3)2Cl2);;
In not given formation at addn. of NH3 to trans-(Pt(NH3)2Cl2);;

: 7647-01-0
hydrogenchloride

: {Pta3NO3}NO3

: 13815-16-2
triamminechloroplatinum(II) chloride

Conditions

Conditions	Yield
In hydrogenchloride formation at effect of HCl-soln. on a concd. (Pt(NH3)3NO3)NO3-soln.;;
In hydrogenchloride formation at effect of HCl-soln. on a concd. (Pt(NH3)3NO3)NO3-soln.;;

: {Pta3NO3}NO3*1/2H2O

: 13815-16-2
triamminechloroplatinum(II) chloride

Conditions

Conditions	Yield
With hydrogenchloride In hydrogenchloride effect of concd. HCl-soln.;;
With HCl In hydrogenchloride effect of concd. HCl-soln.;;

: {Pta4mc}Cl2

: 13815-16-2
triamminechloroplatinum(II) chloride

Conditions

Conditions	Yield
With hydrogenchloride In hydrogenchloride effect of boiling HCl-soln.;;
With HCl In hydrogenchloride effect of boiling HCl-soln.;;

: {Pta3mc*a}Cl2

: 13815-16-2
triamminechloroplatinum(II) chloride

Conditions

Conditions	Yield
With hydrogenchloride In hydrogenchloride byproducts: CH3CN, NH3; effect of boiling HCl-soln.;;
In hydrogenchloride

: Pt(NH3)5Br(3+)*3ClO4(1-)*3H2O = [Pt(NH3)5Br](ClO4)3*3H2O

: 13815-16-2
triamminechloroplatinum(II) chloride

Conditions

Conditions	Yield
With chloride; lithium perchlorate Kinetics; 25°C;

: 13815-16-2
triamminechloroplatinum(II) chloride

: silver nitrate

: 17902-23-7
tegafur

: 462658-07-7
(N(1)-(2'-tetrahydrofuranyl)-5-fluorouracilato)triammineplatinum(II) nitrate

Conditions

Conditions	Yield
With Ag2O In water byproducts: AgCl; equimol.; to a soln. of Pt compd. and AgNO3 added at room temp. a soln. of ligand and Ag2O, stirred at room temp. for several h, heated on waterbath for 1 h; cooled, filtered, evapd. (vac., 35-40°C), added alcohol and ether, dried at 100°C; elem. anal.;	83%

...Expand

: 13815-16-2
triamminechloroplatinum(II) chloride

: 75-08-1
ethanethiol

: {PtSC2H5Cl}

Conditions

Conditions	Yield
In ethanol reaction with ethylmercaptane in dild. alcohol;;
In not given formation on effect of HSC2H5 on (Pt(NH3)3Cl)Cl;;

: 13815-16-2
triamminechloroplatinum(II) chloride

: 7732-18-5
water

: silver nitrate

: {Pta3aq}(NO3)2

Conditions

Conditions	Yield
In not given formation at heating of a (Pta3Cl)Cl-soln. with AgNO3;;

...Expand

: 5456-21-3
ammonium hydrazine dithiocarbonate

: 13815-16-2
triamminechloroplatinum(II) chloride

: {Pt(SC2N2H3)2}

Conditions

Conditions	Yield
In not given reaction in cold soln. with NH4-hydrazine dithiocarbonate;;
In water pptn. on mixing of solns. of (Pt(NH3)3Cl)Cl in H2O and NH4-hydrazinedithiocarbonate in H2O;;
In not given reaction in cold soln. with NH4-hydrazine dithiocarbonate;;
In water pptn. on mixing of solns. of (Pt(NH3)3Cl)Cl in H2O and NH4-hydrazinedithiocarbonate in H2O;;

: 13815-16-2
triamminechloroplatinum(II) chloride

: silver nitrate

: {Pta3aq}(NO3)2

Conditions

Conditions	Yield
In not given heating with AgNO3-soln.;;

: 13815-16-2
triamminechloroplatinum(II) chloride

: 108-98-5
thiophenol

: {Pt(SC6H5)2}

Conditions

Conditions	Yield
In ethanol reaction with excess phenylmercaptane in dild. alcohol;;

: 13815-16-2
triamminechloroplatinum(II) chloride

: tetrammineplatinum(II) chloride

Conditions

Conditions	Yield
With ammonia In ammonia reaction with NH3-soln.;;
With NH3 In ammonia aq. ammonia=NH3; reaction with NH3-soln.;;

: 13815-16-2
triamminechloroplatinum(II) chloride

: 26035-31-4, 14913-33-8, 15663-27-1
transplatin

: tetrammineplatinum(II) chloride

Conditions

Conditions	Yield
In neat (no solvent) decomposition at heating in a closed tube; begin of the decomposition at 170-172°C;;
In neat (no solvent) decomposition at heating in a closed tube; begin of the decomposition at 170-172°C;;

: 13815-16-2
triamminechloroplatinum(II) chloride

: 15663-27-1
cisplatin

Conditions

Conditions	Yield
With hydrogenchloride In hydrogenchloride effect of HCl-soln.;;
With HCl In hydrogenchloride effect of HCl-soln.;;

: 13815-16-2
triamminechloroplatinum(II) chloride

: 26035-31-4, 14913-33-8, 15663-27-1
transplatin

Conditions

Conditions	Yield
With HCl In hydrogenchloride heating with HCl-soln.;;
In water complex in H2O was dissolved in H2O and kept in a 40°C water bath for 24 h, then at room temp. for 2 more weeks; ppt. was filtered off, treated with DMF;

: 13815-16-2
triamminechloroplatinum(II) chloride

: 16893-07-5, 16893-08-6, 17030-08-9
{Pt(a3Cl)Cl2}Cl

Conditions

Conditions	Yield
With chlorine In not given oxidation with Cl2;;
With Cl2 In not given oxidation with Cl2;;

: 13815-16-2
triamminechloroplatinum(II) chloride

: {Pta3aq}Cl2

Conditions

Conditions	Yield
With silver nitrate In not given effect of AgNO3-soln. at low temperature;;
With AgNO3 In not given effect of AgNO3-soln. at low temperature;;

: sodium hexachloroplatinate

: 13815-16-2
triamminechloroplatinum(II) chloride

: {Pta3Cl}2{PtCl6}

Conditions

Conditions	Yield
In not given reaction with Na2(PtCl6);;
In not given reaction with Na2(PtCl6);;

: 13815-16-2
triamminechloroplatinum(II) chloride

: 118-00-3
G

: cis-[(NH3)2Pt(guanosine)Cl]Cl

Conditions

Conditions	Yield
In water Kinetics; 5-50-fold excess of the amine at different concns. of Pt complex and chloride ion; 60°C; conductometry; IR monitoring (Pt-Cl streching vibration bands at 334-336 cm**-1);

: 15191-27-2
1,2,3,4,5,6-hexahydro-1,5-methano-pyrido[1,2-a][1,5]diazocin-8-one

: 13815-16-2
triamminechloroplatinum(II) chloride

: Pt(2+)*2NH3*(HOCH2((C4H4O)(OH)2)(C4H2N2O)NH2)*2Cl(1-) = [Pt(NH3)2(HOCH2((C4H4O)(OH)2)(C4H2N2O)NH2)Cl]Cl

Conditions

Conditions	Yield
In water Kinetics; 5-50-fold excess of the amine at different concns. of Pt complex and chloride ion; 60°C; conductometry; IR monitoring (Pt-Cl streching vibration bands at 334-336 cm**-1);