Tributyl(1-ethoxyvinyl)stannane supplier

Name
TRIBUTYL(1-ETHOXYVINYL)TIN
EINECS
CAS No. 97674-02-7
Article Data4
CAS DataBase
Density 1.069 g/cm³ at 25 °C(lit.)
Solubility
Melting Point <0 °C
Formula C₁₆H₃₄OSn
Boiling Point 319.2 °C at 760 mmHg
Molecular Weight 361.155
Flash Point 160.3 °C
Transport Information UN 2788 6.1/PG 3
Appearance Clear colorless liquid
Safety 35-36/37/39-45-60-61
Risk Codes 21-25-36/38-48/23/25-50/53
Molecular Structure
Hazard Symbols T,N
Synonyms (1-Ethoxyethenyl)tributyltin;(1-Ethoxyvinyl)tributyltin;(1-Ethoxyvinyl)tri-n-butyltin;(1-Ethoxyvinyl)tributylstannane;1-(Tributylstannyl)-1-ethoxyethene;Tri-n-butyl(1-ethoxyvinyl)tin;Tributyl(1-((ethyl)oxy)vinyl)tin;Tributyl(1-ethoxyethenyl)stannane;Tributyl(1-ethoxyvinyl)tin;Tributyl(a-ethoxyvinyl)tin;(a-Ethoxyvinyl)tributyltin;AC1Q2UOW;
PSA 9.23000
LogP 5.92490

Synthetic route

: 1461-22-9
tributyltin chloride

: 109-92-2
ethyl vinyl ether

: 97674-02-7
tributyl(1-ethoxyvinyl)stannane

Conditions

Conditions	Yield
Stage #1: ethyl vinyl ether With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; potassium tert-butylate In tetrahydrofuran; hexane at -40 - -30℃; for 1.5h; Inert atmosphere; Stage #2: tributyltin chloride In tetrahydrofuran; hexane; water at -78℃; for 10h; Stille Carbonyl Synthesis;	81.03%
With tert.-butyl lithium at -78℃;
Stage #1: ethyl vinyl ether With tert.-butyl lithium In tetrahydrofuran; pentane at -78 - 0℃; for 0.25h; Inert atmosphere; Stage #2: tributyltin chloride In tetrahydrofuran; pentane at -78 - 20℃; for 0.5h; Inert atmosphere;

: 1333-74-0
hydrogen

: 137344-20-8
ethoxy(tributylstannyl)acetylene

: 97674-02-7
tributyl(1-ethoxyvinyl)stannane

Conditions

Conditions	Yield
With tributylphosphine In toluene toluene, 5 mol% Ru-complex, tributylphosphine (30 mol %) under 1 atm. ofH2, 80°C, 6 h;	65%

: 571189-53-2
{1-[6-(6-bromo-8-cyclopentyl-5-methyl-7-oxo-7,8-dihydropyrido[2,3-d]pyrimidin-2-ylamino)pyridin-3-yl]pyrrolidin-3-yl}carbamic acid tert-butyl ester

: 97674-02-7
tributyl(1-ethoxyvinyl)stannane

: 571189-52-1
(1-{6-[8-cyclopentyl-6-(1-ethoxyvinyl)-5-methyl-7-oxo-7,8-dihydropyrido[2,3-d]pyrimidin-2-ylamino]pyridin-3-yl}pyrrolidin-3-yl)carbamic acid tert-butyl ester

Conditions

Conditions	Yield
With tetrakis(triphenylphosphine) palladium(0) In toluene at 110℃; for 12h; Stille coupling;	100%

: 1435-52-5
2,5-dibromofluorobenzene

: 97674-02-7
tributyl(1-ethoxyvinyl)stannane

: 380608-27-5
1-(4-acetyl-2-fluorophenyl)ethan-1-one

Conditions

Conditions	Yield
bis-triphenylphosphine-palladium(II) chloride In tetrahydrofuran for 18h; Heating / reflux;	100%

: 927389-54-6
6-bromo-2-cyclopropyl-7-methoxy-5-methyl-1,3-benzoxazole-4-carbonitrile

: 97674-02-7
tributyl(1-ethoxyvinyl)stannane

: 927389-55-7
2-cyclopropyl-6-[1-(ethoxy)ethenyl]-7-methoxy-5-methyl-1,3-benzoxazole-4-carbonitrile

Conditions

Conditions	Yield
bis-triphenylphosphine-palladium(II) chloride; 2,6-di-tert-butyl-4-methyl-phenol In toluene for 22h; Heating / reflux;	100%

: 927389-91-1
6-bromo-2-[2-methoxy-1,1-dimethylethyl]-7-fluoro-5-methyl-1,3-benzoxazole-4-carbonitrile

: 97674-02-7
tributyl(1-ethoxyvinyl)stannane

: 927389-93-3
C18H21FN2O3

Conditions

Conditions	Yield
bis-triphenylphosphine-palladium(II) chloride; 2,6-di-tert-butyl-4-methyl-phenol In toluene for 6h; Heating / reflux;	100%

: 927389-32-0
6-bromo-2-cyclopropyl-7-fluoro-5-methyl-1,3-benzoxazole-4-carbonitrile

: 97674-02-7
tributyl(1-ethoxyvinyl)stannane

: 927389-44-4
2-cyclopropyl-6-[1-(ethoxy)ethenyl]-7-fluoro-5-methyl-1,3-benzoxazole-4-carbonitrile

Conditions

Conditions	Yield
bis-triphenylphosphine-palladium(II) chloride; 2,6-di-tert-butyl-4-methyl-phenol In toluene for 17h; Heating / reflux;	100%

: 15862-46-1
N-(5-bromo-pyridin-3-yl)-acetamide

: 97674-02-7
tributyl(1-ethoxyvinyl)stannane

: 1035234-81-1
N-[5-(1-ethoxyvinyl)pyridin-3-yl]acetamide

Conditions

Conditions	Yield
Stage #1: N-(5-bromo-pyridin-3-yl)-acetamide; tributyl(1-ethoxyvinyl)stannane With bis-triphenylphosphine-palladium(II) chloride In N,N-dimethyl-formamide at 80℃; for 24h; Stage #2: With potassium fluoride In water; N,N-dimethyl-formamide at 20℃; for 0.5h;	100%

: 1296271-35-6
8-bromo-2-morpholino-4-oxo-4H-chromene-6-carboxylic acid

: 97674-02-7
tributyl(1-ethoxyvinyl)stannane

: 1296271-36-7
8-acetyl-2-morpholino-4-oxo-4H-chromene-6-carboxylic acid

Conditions

Conditions	Yield
Stage #1: 8-bromo-2-morpholino-4-oxo-4H-chromene-6-carboxylic acid; tributyl(1-ethoxyvinyl)stannane; bis-triphenylphosphine-palladium(II) chloride In 1,4-dioxane at 100℃; for 3h; Inert atmosphere; Stage #2: With hydrogenchloride; water In 1,4-dioxane at 50℃; for 0.416667h;	100%
Stage #1: 8-bromo-2-morpholino-4-oxo-4H-chromene-6-carboxylic acid; tributyl(1-ethoxyvinyl)stannane; bis-triphenylphosphine-palladium(II) chloride In 1,4-dioxane at 100℃; for 3h; Stille Coupling; Inert atmosphere; Stage #2: With hydrogenchloride In 1,4-dioxane at 50℃; for 0.416667h;	100%
Stage #1: 8-bromo-2-morpholino-4-oxo-4H-chromene-6-carboxylic acid; tributyl(1-ethoxyvinyl)stannane With bis-triphenylphosphine-palladium(II) chloride In 1,4-dioxane at 100℃; for 3h; Stille Cross Coupling; Inert atmosphere; Stage #2: With hydrogenchloride In 1,4-dioxane; water at 50℃; for 0.416667h; Stille Cross Coupling; Inert atmosphere;	200 mg

: 552331-06-3
6-bromo-3-chloro-isoquinoline

: 97674-02-7
tributyl(1-ethoxyvinyl)stannane

: 1381812-85-6
3-chloro-6-(1-ethoxyvinyl)isoquinoline

Conditions

Conditions	Yield
With bis-triphenylphosphine-palladium(II) chloride In toluene at 50℃; for 18h; Stille Cross Coupling; Inert atmosphere;	100%
Stage #1: 6-bromo-3-chloro-isoquinoline; tributyl(1-ethoxyvinyl)stannane In toluene for 0.5h; Inert atmosphere; Stage #2: With bis-triphenylphosphine-palladium(II) chloride In toluene at 60℃; for 20h;	92%
With bis-triphenylphosphine-palladium(II) chloride In toluene at 60℃; for 20h; Inert atmosphere;	92%
With bis-triphenylphosphine-palladium(II) chloride In toluene at 60℃; for 20h; Inert atmosphere;	92%
bis-triphenylphosphine-palladium(II) chloride In toluene at 50℃; for 18h; Inert atmosphere;

: 1261072-54-1
methyl {(2S)-1-[(2S)-2-{5-[4-(6-bromoquinoxalin-2-yl)phenyl]-1H-imidazol-2-yl}pyrrolidin-1-yl]-3-methyl-1-oxobutan-2-yl}carbamate

: 97674-02-7
tributyl(1-ethoxyvinyl)stannane

: 1399845-38-5
methyl (S)-1-((S)-2-(5-(4-(6-(1-ethoxyvinyl)quinoxalin-2-yl)phenyl)-1H-imidazol-2-yl)pyrrolidin-1-yl)-3-methyl-1-oxobutan-2-ylcarbamate

Conditions

Conditions	Yield
dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2 In 1,4-dioxane at 80℃; for 6h; Inert atmosphere;	100%

: 1552315-38-4
8-chloro-N-(2-methylallyl)quinoxalin-2-amine

: 97674-02-7
tributyl(1-ethoxyvinyl)stannane

: 1552315-40-8
8-(1-ethoxyvinyl)-N-(2-methylallyl)quinoxalin-2-amine

Conditions

Conditions	Yield
With tris-(dibenzylideneacetone)dipalladium(0); copper(l) iodide; cesium fluoride; XPhos at 120℃; Sealed tube; Inert atmosphere;	100%

: 1622880-49-2
C14H14BrN3O4

: 97674-02-7
tributyl(1-ethoxyvinyl)stannane

: C16H17N3O5

Conditions

Conditions	Yield
Stage #1: C14H14BrN3O4; tributyl(1-ethoxyvinyl)stannane With bis-triphenylphosphine-palladium(II) chloride In 1,4-dioxane at 100℃; for 18h; Stille Cross-Coupling (Migita-Kosugi-Stille Coupling); Stage #2: With hydrogenchloride In water for 0.166667h;	100%

: 4-[(4-bromo-3,3,7-trifluoro-2-oxo-2,3-dihydro-1H-indol-1-yl)methyl]pyridine-2-carbonitrile

: 97674-02-7
tributyl(1-ethoxyvinyl)stannane

: 4-[(4-acetyl-3,3,7-trifluoro-2-oxo-2,3-dihydro-1H-indol-1-yl)methyl]pyridine-2-carbonitrile

Conditions

Conditions	Yield
Stage #1: 4-[(4-bromo-3,3,7-trifluoro-2-oxo-2,3-dihydro-1H-indol-1-yl)methyl]pyridine-2-carbonitrile; tributyl(1-ethoxyvinyl)stannane With tetrakis(triphenylphosphine) palladium(0) In N,N-dimethyl-formamide at 120℃; for 3h; Stage #2: With hydrogenchloride In water; N,N-dimethyl-formamide at 20℃; for 1h;	100%

: 1262412-30-5
5-bromo-3-fluoro-2-(trifluoromethyl)pyridine

: 97674-02-7
tributyl(1-ethoxyvinyl)stannane

: 1-[5-fluoro-6-(trifluoromethyl)-3-pyridyl]ethanone

Conditions

Conditions	Yield
Stage #1: 5-bromo-3-fluoro-2-(trifluoromethyl)pyridine; tributyl(1-ethoxyvinyl)stannane With tetrakis(triphenylphosphine) palladium(0); trimethylamine In 1,4-dioxane at 100℃; for 4h; Inert atmosphere; Stage #2: With hydrogenchloride; water In 1,4-dioxane at 20℃;	100%

: 97674-02-7
tributyl(1-ethoxyvinyl)stannane

: 69034-12-4
2-chloro-5-(trifluoromethyl)pyrimidine

: 2-(1-ethoxyethenyl)-5-(trifluoromethyl)pyrimidine

Conditions

Conditions	Yield
With bis-triphenylphosphine-palladium(II) chloride In N,N-dimethyl-formamide at 100℃; for 3h; Inert atmosphere;	100%

: 571189-69-0
4-[6-(6-bromo-8-cyclopentyl-5-methyl-7-oxo-7,8-dihydropyrido[2,3-d]pyrimidin-2-ylamino)pyridin-3-yl]-2,2-dimethylpiperazine-1-carboxylic acid tert-butyl ester

: 97674-02-7
tributyl(1-ethoxyvinyl)stannane

: 571189-71-4
4-{6-[8-cyclopentyl-6-(1-ethoxyvinyl)-5-methyl-7-oxo-7,8-dihydropyrido[2,3-d]pyrimidin-2-ylamino]pyridin-3-yl}-2,2-dimethylpiperazine-1-carboxylic acid tert-butyl ester

Conditions

Conditions	Yield
With tetrakis(triphenylphosphine) palladium(0) In toluene for 1h; Stille coupling; Heating;	99%

: 571189-69-0
4-[6-(6-bromo-8-cyclopentyl-5-methyl-7-oxo-7,8-dihydropyrido[2,3-d]pyrimidin-2-ylamino)pyridin-3-yl]-2,2-dimethylpiperazine-1-carboxylic acid tert-butyl ester

: 97674-02-7
tributyl(1-ethoxyvinyl)stannane

A: 571189-71-4
4-{6-[8-cyclopentyl-6-(1-ethoxyvinyl)-5-methyl-7-oxo-7,8-dihydropyrido[2,3-d]pyrimidin-2-ylamino]pyridin-3-yl}-2,2-dimethylpiperazine-1-carboxylic acid tert-butyl ester

B 4-16-[8-Cyclopentyl-6-(1-ethoxy-vin l)-5-methyl-7-oxo-7,8-dihydro-pyrido[2,3-d]pyrimidin-2-ylamino]-pyridin-3-yl-2,2-dimethyl-piperazine-1-carboxylic Acid Tert-butyl Ester: 4-16-[8-Cyclopentyl-6-(1-ethoxy-vin l)-5-methyl-7-oxo-7,8-dihydro-pyrido[2,3-d]pyrimidin-2-ylamino]-pyridin-3-yl-2,2-dimethyl-piperazine-1-carboxylic Acid Tert-butyl Ester

Conditions

Conditions	Yield
tetrakis(triphenylphosphine) palladium(0) In dichloromethane; toluene	A n/a B 99%

...Expand

: 67460-09-7
benzyl 2-bromobenzoate

: 97674-02-7
tributyl(1-ethoxyvinyl)stannane

: 267647-97-2
2-(1-Ethoxyethenyl)benzoic acid phenylmethyl ester

Conditions

Conditions	Yield
dichlorobis(triphenylphosphine)palladium[II] In 1,4-dioxane	99%

: 943025-87-4
1,1-dimethylethyl [2-chloro-5-fluoro-6-(methyloxy)-3-pyridinyl]carbamate

: 97674-02-7
tributyl(1-ethoxyvinyl)stannane

: 943025-88-5
1,1-dimethylethyl [2-[1-(ethyloxy)ethenyl]-5-fluoro-6-(methyloxy)-3-pyridinyl]carbamate

Conditions

Conditions	Yield
Stage #1: 1,1-dimethylethyl [2-chloro-5-fluoro-6-(methyloxy)-3-pyridinyl]carbamate; tributyl(1-ethoxyvinyl)stannane With cesium fluoride; bis(tri-t-butylphosphine)palladium(0) In 1,4-dioxane at 100℃; Stage #2: With potassium fluoride In 1,4-dioxane; water for 0.5h;	99%
Stage #1: 1,1-dimethylethyl [2-chloro-5-fluoro-6-(methyloxy)-3-pyridinyl]carbamate; tributyl(1-ethoxyvinyl)stannane With cesium fluoride; bis(tri-t-butylphosphine)palladium(0) In dioxane,1,4 at 100℃; Stage #2: With potassium fluoride In dioxane,1,4-; water	99%

: 757234-77-8
methyl 1-chloro-N-(methoxymethyl)pyrido[3,4-b]indole-3-carboxylate

: 97674-02-7
tributyl(1-ethoxyvinyl)stannane

: 66154-37-8
methyl 1-acetyl-9H-pyrido[3,4-b]indole-3-carboxylate

Conditions

Conditions	Yield
Stage #1: methyl 1-chloro-N-(methoxymethyl)pyrido[3,4-b]indole-3-carboxylate; tributyl(1-ethoxyvinyl)stannane With bis-triphenylphosphine-palladium(II) chloride; tetraethylammonium chloride In N,N-dimethyl-formamide at 100℃; for 3h; Inert atmosphere; Stage #2: With hydrogenchloride In methanol; N,N-dimethyl-formamide at 20℃; for 1h; Inert atmosphere;	99%
Stage #1: methyl 1-chloro-N-(methoxymethyl)pyrido[3,4-b]indole-3-carboxylate; tributyl(1-ethoxyvinyl)stannane With bis-triphenylphosphine-palladium(II) chloride; C8H20N(1+)*ClH In N,N-dimethyl-formamide at 100℃; for 2h; Stille Carbonyl Synthesis; Stage #2: With hydrogenchloride; methanol at 20℃; for 1h; Stille Carbonyl Synthesis;	99%

: 1253575-82-4
4-(5-chloro-2-fluoropyridin-3-yl)-6-methyl-1,3,5-triazin-2-amine

: 97674-02-7
tributyl(1-ethoxyvinyl)stannane

: 4-(5-(1-ethoxyvinyl)-2-fluoropyridin-3-yl)-6-methyl-1,3,5-triazin-2-amine

Conditions

Conditions	Yield
With palladium diacetate; cesium fluoride; XPhos In 1,4-dioxane; N,N-dimethyl-formamide at 110℃; for 1.5h; Stille Cross Coupling;	99%

: 2-benzyl-5-bromo-6-phenyl-2,3-dihydropyridazin-3-one

: 97674-02-7
tributyl(1-ethoxyvinyl)stannane

: 2-benzyl-5-(1-ethoxyethenyl)-6-phenyl-2,3-dihydropyridazin-3-one

Conditions

Conditions	Yield
With bis-triphenylphosphine-palladium(II) chloride In toluene for 2h; Reflux;	99%

: 127827-52-5
6-bromo-7-fluoroquinoline

: 97674-02-7
tributyl(1-ethoxyvinyl)stannane

: 1-(7-fluoroquinolin-6-yl)ethan-1-one

Conditions

Conditions	Yield
Stage #1: 6-bromo-7-fluoroquinoline; tributyl(1-ethoxyvinyl)stannane With bis-triphenylphosphine-palladium(II) chloride In 1,4-dioxane at 90℃; Inert atmosphere; Stage #2: With potassium fluoride In 1,4-dioxane; water at 20℃; for 2h; Inert atmosphere;	99%
With bis-triphenylphosphine-palladium(II) chloride In 1,4-dioxane at 110℃; for 4h;	87%
With bis-triphenylphosphine-palladium(II) chloride In 1,4-dioxane at 110℃; for 4h;

: 4-chloro-N-(tetrahydro-2H-pyran-4-yl)pyrimidin-2-amine

: 97674-02-7
tributyl(1-ethoxyvinyl)stannane

: 4-(1-ethoxyvinyl)-N-(tetrahydro-2H-pyran-4-yl)pyrimidin-2-amine

Conditions

Conditions	Yield
Stage #1: 4-chloro-N-(tetrahydro-2H-pyran-4-yl)pyrimidin-2-amine; tributyl(1-ethoxyvinyl)stannane With bis-triphenylphosphine-palladium(II) chloride In N,N-dimethyl-formamide at 25 - 100℃; for 12h; Inert atmosphere; Stage #2: With potassium fluoride In ethyl acetate; N,N-dimethyl-formamide at 20℃; for 2h;	99%

: 23056-36-2
2-chloro-4-nitropyridine

: 97674-02-7
tributyl(1-ethoxyvinyl)stannane

: C7H6N2O3

Conditions

Conditions	Yield
Stage #1: 2-chloro-4-nitropyridine; tributyl(1-ethoxyvinyl)stannane With bis-triphenylphosphine-palladium(II) chloride In N,N-dimethyl-formamide at 85℃; for 3h; Inert atmosphere; Stage #2: With hydrogenchloride In water at 20℃; Solvent; Temperature; Reagent/catalyst;	99%

: 97674-02-7
tributyl(1-ethoxyvinyl)stannane

: tert-butyl N-(8-bromoimidazo[1,2-b]pyridazin-7-yl)carbamate

: tert-butyl N-[8-(1-ethoxyvinyl)imidazo[1,2-b]pyridazin-7-yl]carbamate

Conditions

Conditions	Yield
With bis-triphenylphosphine-palladium(II) chloride In N,N-dimethyl-formamide at 100℃; for 3h; Inert atmosphere;	99%

: 133059-44-6
4-bromo-3-fluorobenzonitrile

: 97674-02-7
tributyl(1-ethoxyvinyl)stannane

: 1352144-78-5
4-acetyl-3-fluorobenzonitrile

Conditions

Conditions	Yield
With bis-triphenylphosphine-palladium(II) chloride; triethylamine In toluene Heating;	98.1%
Stage #1: 4-bromo-3-fluorobenzonitrile; tributyl(1-ethoxyvinyl)stannane With bis-triphenylphosphine-palladium(II) chloride In toluene at 20℃; Inert atmosphere; Reflux; Stage #2: With potassium fluoride In toluene for 0.5h; Inert atmosphere; Stage #3: With hydrogenchloride In water; toluene at 70℃; for 2h;	88%
With dichlorobis(triphenylphosphine)palladium(II) In toluene at 110℃; for 4h;	70.5%

: 623-12-1
4-chloromethoxybenzene

: 97674-02-7
tributyl(1-ethoxyvinyl)stannane

: 66821-19-0
1-(1'-ethoxyvinyl)-4-methoxybenzene

Conditions

Conditions	Yield
With tri-tert-butyl phosphine; cesium fluoride; tris(dibenzylideneacetone)dipalladium (0) In 1,4-dioxane at 100℃; for 48h; Substitution; Stille cross-coupling reaction;	98%
With P(i-BuNCH2CH2)3N; cesium fluoride; tris(dibenzylideneacetone)dipalladium (0) In 1,4-dioxane at 100 - 110℃; Stille reaction;	97%
With tris(dibenzylideneacetone)dipalladium (0); cesium fluoride; 2,8,9-tris(2-methylpropyl)-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane In 1,4-dioxane at 110℃; for 48h; Stille cross-coupling;	97%
With tris(dibenzylideneacetone)dipalladium (0); tri-tert-butyl phosphine; cesium fluoride In 1,4-dioxane at 100℃; for 48h; Stille cross-coupling;	97%

: 95-46-5
2-methylphenyl bromide

: 97674-02-7
tributyl(1-ethoxyvinyl)stannane

: 31732-33-9
1-(1-ethoxyvinyl)-2-methylbenzene

Conditions

Conditions	Yield
With tris(dibenzylideneacetone)dipalladium (0); tri-tert-butyl phosphine; cesium fluoride In 1-methyl-pyrrolidin-2-one; hexane at 20℃; for 3h; Stille cross-coupling;	98%

: 97674-02-7
tributyl(1-ethoxyvinyl)stannane

: 247158-79-8
5-Bromo-2-methoxymethyl-6-phenylpyridazin-3-one

: 617693-71-7
2-methoxymethyl-6-phenyl-5-[(1'-ethoxy)vinyl]-3-pyridazinone

Conditions

Conditions	Yield
With bis-triphenylphosphine-palladium(II) chloride In toluene for 2h; Stille reaction; Heating;	98%

: 1123194-98-8
6-bromo-2-methoxy-3-(4-methyl-1H-imidazol-1-yl)pyridine

: 97674-02-7
tributyl(1-ethoxyvinyl)stannane

: 1241428-42-1
6-(1-ethoxyvinyl)-2-methoxy-3-(4-methyl-1H-imidazol-1-yl)pyridine

Conditions

Conditions	Yield
With bis-triphenylphosphine-palladium(II) chloride In 1,4-dioxane at 100℃; for 18h; Inert atmosphere;	98%
bis-triphenylphosphine-palladium(II) chloride In 1,4-dioxane at 100℃; for 5.75h;
bis-triphenylphosphine-palladium(II) chloride In 1,4-dioxane at 100℃; for 5.75h;

Tributyl(1-ethoxyvinyl)stannane Specification

The Stannane,tributyl(1-ethoxyethenyl)- with CAS registry number of 97674-02-7 is also known as (1-Ethoxyethenyl)tributyltin. The IUPAC name is Tributyl(1-ethoxyethenyl)stannane. It belongs to product categories of Organometallic Reagents; Organotin; Organotins; Stannanes. In addition, the formula is C₁₆H₃₄OSn and the molecular weight is 361.15. This chemical is a clear colorless liquid and should be sealed in cool, dry place.

Physical properties about Stannane,tributyl(1-ethoxyethenyl)- are: (1)ACD/LogP: 9.37; (2)# of Rule of 5 Violations: 1; (3)ACD/LogD (pH 5.5): 9.37; (4)ACD/LogD (pH 7.4): 9.37; (5)ACD/BCF (pH 5.5): 1000000; (6)ACD/BCF (pH 7.4): 1000000; (7)ACD/KOC (pH 5.5): 2981317; (8)ACD/KOC (pH 7.4): 2981317; (9)#H bond acceptors: 1; (10)#Freely Rotating Bonds: 12; (11)Flash Point: 160.3 °C; (12)Enthalpy of Vaporization: 53.85 kJ/mol; (13)Boiling Point: 319.2 °C at 760 mmHg; (14)Vapour Pressure: 0.000641 mmHg at 25 °C.

Uses of Stannane,tributyl(1-ethoxyethenyl)-: it is used to produce 1-(4-nitro-phenyl)-ethanone by reaction with 1-bromo-4-nitro-benzene. The reaction occurs with reagent 5percent HCl and solvent PdCl₂(PPh₃)₂ at the temperature of 100 °C for 20 hours. The yield is about 91%.

Stannane,tributyl(1-ethoxyethenyl)- is used to produce 1-(4-nitro-phenyl)-ethanone by reaction with 1-bromo-4-nitro-benzene.

When you are using this chemical, please be cautious about it. As a chemical, it is irritating to eyes and skin and it is harmful in contact with skin. This chemical has danger of serious damage to health by prolonged exposure through inhalation and if swallowed. What's more, it is very toxic to aquatic organisms that may cause long-term adverse effects in the aquatic environment. During using it, wear suitable protective clothing, gloves and eye/face protection. Avoid release to the environment. This material and its container must be disposed of as hazardous waste in a safe way. In case of accident or if you feel unwell seek medical advice immediately.

You can still convert the following datas into molecular structure:
1. Canonical SMILES: CCCC[Sn](CCCC)(CCCC)C(=C)OCC
2. InChI: InChI=1S/C4H7O.3C4H9.Sn/c1-3-5-4-2;3*1-3-4-2;/h1,4H2,2H3;3*1,3-4H2,2H3;
3. InChIKey: HGXJOXHYPGNVNK-UHFFFAOYSA-N

Product Name

TRIBUTYL(1-ETHOXYVINYL)TIN

Synthetic route

Tributyl(1-ethoxyvinyl)stannane Specification

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