Tridodecylamine supplier | CasNO.102-87-4

Name
TRIDODECYLAMINE
EINECS 203-063-4
CAS No. 102-87-4
Article Data13
CAS DataBase
Density 0.828 g/cm³
Solubility Not miscible or difficult to mix with water.
Melting Point 16 °C
Formula C₃₆H₇₅N
Boiling Point 544.6 °C at 760 mmHg
Molecular Weight 521.998
Flash Point 256.6 °C
Transport Information
Appearance clear slightly yellow liquid
Safety 26-36
Risk Codes 36/37/38
Molecular Structure
Hazard Symbols Xi
Synonyms Tridodecylamine(6CI,8CI);Adogen 360;Alamine 304;Alamine 304-1;Armeen 312;N,N-Didodecyl-1-dodecanamine;NSC 35134;Tri-n-dodecylamine;Trilaurylamine;Tris(dodecyl)amine;
PSA 3.24000
LogP 13.05110

Synthetic route

: 124-22-1
n-Dodecylamine

A: 3007-31-6
N,N-didodecylamine

B: 102-87-4
tridodecylamine

Conditions

Conditions	Yield
With Co2Rh2/C In toluene at 180℃; under 760.051 Torr; for 6h; Temperature; Time; Solvent; Autoclave; Inert atmosphere;	A 86% B 5%
With ruthenium trichloride; triphenylphosphine In tetrahydrofuran at 235℃; for 8h;	A 26 % Chromat. B 52%
With ruthenium trichloride; triphenylphosphine In tetrahydrofuran at 235℃; for 8h; Title compound not separated from byproducts;	A 67 % Chromat. B 30 % Chromat.
With tris(triphenylphosphine)ruthenium(II) chloride In methanol at 180℃; for 7h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

: 2437-25-4
undecyl cyanide

A: 3007-31-6
N,N-didodecylamine

B: 102-87-4
tridodecylamine

Conditions

Conditions	Yield
With hydrogen; silica gel; copper at 160℃; under 33002.6 Torr; for 2.69444h; Product distribution; Rate constant; other temperatures, other catalysts;	A 84% B n/a
With methanol; hydrogen at 249.9℃; under 37503 Torr; for 25h;	A 15% B 60 % Chromat.
With methanol; hydrogen; aluminum oxide; copper-chromium powder at 249.9℃; under 37503 Torr; for 25h;	A 48 % Chromat. B 5 % Chromat.

: 124-22-1
n-Dodecylamine

: 143-15-7
1-dodecylbromide

: 102-87-4
tridodecylamine

Conditions

Conditions	Yield
With sodium carbonate In ethanol for 144h; Heating;	22.6%

: 4292-19-7
1-Iodododecane

: 3007-31-6
N,N-didodecylamine

: 102-87-4
tridodecylamine

Conditions

Conditions	Yield
at 160 - 170℃;

: 4292-19-7
1-Iodododecane

A: 3007-31-6
N,N-didodecylamine

B: 102-87-4
tridodecylamine

Conditions

Conditions	Yield
With ammonia; water

: 3007-31-6
N,N-didodecylamine

: 112-52-7
1-chlorododecane

: 102-87-4
tridodecylamine

Conditions

Conditions	Yield
at 160 - 170℃;

: 67-56-1
methanol

: 111-82-0
methyl n-dodecanoate

A: 124-22-1
n-Dodecylamine

B: 112-18-5
N,N-dimethylaminododecane

C: 7311-30-0
N-methyldodecylamine

D: 3007-31-6
N,N-didodecylamine

E: 2915-90-4
N-methyldidodecylamine

F: 102-87-4
tridodecylamine

Conditions

Conditions	Yield
With ammonia; hydrogen; copper-chromium powder; titanium(IV) oxide at 250℃; under 37503 Torr; Product distribution; other catalyst; var. temp., pressure, and reagents ratio;	A 31.9 % Chromat. B 20.0 % Chromat. C 30.7 % Chromat. D 2.5 % Chromat. E 2.0 % Chromat. F 2.0 % Chromat.

...Expand

: 111-82-0
methyl n-dodecanoate

A: 124-22-1
n-Dodecylamine

B: 3007-31-6
N,N-didodecylamine

C: 102-87-4
tridodecylamine

Conditions

Conditions	Yield
With methanol; ammonia; hydrogen; copper-chromium powder; titanium(IV) oxide at 250℃; under 37503 Torr;	A 31.9 % Chromat. B 2.5 % Chromat. C 2.0 % Chromat.

...Expand

: 112-53-8
1-dodecyl alcohol

A: 102-87-4
tridodecylamine

B didodecylamine; dodecylamine: didodecylamine; dodecylamine

Conditions

Conditions	Yield
With aluminium silicate; ammonia at 350℃;

: tridodecyl-amine; compound with 2,4,6-trichloro-phenol

A: 102-87-4
tridodecylamine

B: 88-06-2
2,4,6-Trichlorophenol

Conditions

Conditions	Yield
In tetrachloromethane at 25℃; Equilibrium constant;

: tridodecyl-amine; compound with 2,4,6-trichloro-phenol

A: 102-87-4
tridodecylamine

B: 88-06-2
2,4,6-Trichlorophenol

Conditions

Conditions	Yield
In tetrachloromethane at 25℃; Equilibrium constant;

: 102-87-4
tridodecylamine

: 20587-64-8
tridodecylamine oxide

Conditions

Conditions	Yield
With dihydrogen peroxide In methanol; water	85%

: 102-87-4
tridodecylamine

: 2437-25-4
undecyl cyanide

Conditions

Conditions	Yield
With ammonium hydroxide; 1,3-Diiodo-5,5-dimethyl-2,4-imidazolidinedione at 60℃; for 6h;	84%
With ammonium hydroxide; 1,3-Diiodo-5,5-dimethyl-2,4-imidazolidinedione at 60℃; for 6h;	84%

: 937802-88-5
C22H17Cl2N2O5S(1-)*K(1+)

: 102-87-4
tridodecylamine

: 937802-92-1
C22H18Cl2N2O5S*C36H75N

Conditions

Conditions	Yield
With hydrogenchloride In methanol; water at 70℃; for 0.25h;	83%

: 102-87-4
tridodecylamine

: N,N-didodecylformamide

Conditions

Conditions	Yield
With manganese(IV) oxide; oxygen In chlorobenzene at 100℃; under 4500.45 Torr; for 4h; Autoclave; Green chemistry;	80%

: 102-87-4
tridodecylamine

: 4-bromomethyl-4'-methacrylamidocarbonylazobenzene

: C54H91N4O2(1+)*Br(1-)

Conditions

Conditions	Yield
In ethanol for 10h; Reflux;	73.5%

: 102-87-4
tridodecylamine

: C46H28N6O8

: europium(III) nitrate

: C46H24N6O8(4-)*Eu(3+)*C36H75N*H(1+)

Conditions

Conditions	Yield
In methanol at 20℃; for 4h; Inert atmosphere;	67.3%

...Expand

: 1120-71-4
1,3-propanesultone

: 102-87-4
tridodecylamine

: 103982-08-7
tridodecylammonium 3-propanesulfonate

Conditions

Conditions	Yield
In toluene at 110℃; for 3h;	62%

: 102-87-4
tridodecylamine

: 1670-14-0
benzamidine monohydrochloride

: 100-52-7
benzaldehyde

: 5-decyl-2,4-diphenylpyrimidine

Conditions

Conditions	Yield
With di-tert-butyl peroxide; iodine In chlorobenzene at 150℃; for 8h;	62%
With di-tert-butyl peroxide; iodine In chlorobenzene at 150℃; for 8h; Sealed tube;	62%

...Expand

: C24H19N2O5S(1-)*K(1+)

: 102-87-4
tridodecylamine

: C24H20N2O5S*C36H75N

Conditions

Conditions	Yield
With hydrogenchloride; water	61%

: 74-83-9
methyl bromide

: 102-87-4
tridodecylamine

: 29920-02-3
tridodecylmethylammonium chloride

Conditions

Conditions	Yield
In ethanol at 90 - 95℃; for 183h;	52%

: 98-01-1
furfural

: 102-87-4
tridodecylamine

: 696-62-8
para-iodoanisole

: C32H57NO2

Conditions

Conditions	Yield
With Wilkinson’s catalyst; 1,3-bis-(diphenylphosphino)propane; water In tetrahydrofuran at 140℃; for 12h; Inert atmosphere; Sealed tube;	52%

...Expand

: 102-87-4
tridodecylamine

: 70-11-1
α-bromoacetophenone

: 3-decyl-N,N-didodecyl-5-phenylfuran-2-amine

Conditions

Conditions	Yield
With [2,2]bipyridinyl; iron(III) chloride; di-tert-butyl peroxide In toluene at 135℃; for 14h; Sealed tube;	40%

: zinc perchlorate

: 102-87-4
tridodecylamine

: 1439241-70-9
C44H28N6O4

: europium(III) nitrate

: 2C44H26N6O4(2-)*Eu(3+)*Zn(2+)*2ClO4(1-)*C36H75N*H(1+)

Conditions

Conditions	Yield
Stage #1: tridodecylamine; C44H28N6O4; europium(III) nitrate In methanol at 20℃; for 4h; Stage #2: zinc perchlorate In methanol at 20℃; for 1h; Concentration;	36.9%

...Expand

: iron(II) tetrafluoroborate

: 102-87-4
tridodecylamine

: 1439241-70-9
C44H28N6O4

: europium(III) nitrate

: 2C44H26N6O4(2-)*C36H76N(1+)*Eu(3+)*Fe(2+)*2BF4(1-)

Conditions

Conditions	Yield
Stage #1: tridodecylamine; C44H28N6O4; europium(III) nitrate In methanol at 20℃; for 1h; Stage #2: iron(II) tetrafluoroborate In methanol at 20℃; for 1h;	35.8%

...Expand

: hydroxygallium naphthalocyaninetetrasulfonic acid

: 102-87-4
tridodecylamine

: 4C36H75N*C48H25GaN8O13S4

Conditions

Conditions	Yield
In methanol; water	32%

: 102-87-4
tridodecylamine

: S,S'-diethyl-S,S'-dimethyl-S,S'-cis-ethene-1,2-diyl-bis-sulfonium; bis-tetrafluoroborate

: C41H85NS(2+)*2BF4(1-)

: 102-87-4
tridodecylamine

: 74-88-4
methyl iodide

: 29710-98-3
tri-n-dodecylmethylammonium iodide

Conditions

Conditions	Yield
for 24h; Heating;

: 102-87-4
tridodecylamine

: 2486-89-7
tri-n-dodecylammonium chloride

Conditions

Conditions	Yield
With hydrogenchloride In water

: 102-87-4
tridodecylamine

: 2305-34-2
tridodecylamine; nitrate

Conditions

Conditions	Yield
With nitric acid In water

: 102-87-4
tridodecylamine

: 88-06-2
2,4,6-Trichlorophenol

: tridodecyl-amine; compound with 2,4,6-trichloro-phenol

Conditions

Conditions	Yield
In tetrachloromethane at 25℃; Equilibrium constant;

Tridodecylamine Specification

The 1-Dodecanamine,N,N-didodecyl-, with the CAS registry number 102-87-4, is also known as Tri-n-dodecylamine. Its EINECS registry number is 203-063-4. This chemical's molecular formula is C₃₆H₇₅N and molecular weight is 521.9874. Its IUPAC name is called N,N-didodecyldodecan-1-amine. This chemical is clear slightly yellow liquid.

Physical properties of 1-Dodecanamine,N,N-didodecyl-: (1)ACD/LogP: 17.60; (2)# of Rule of 5 Violations: 2; (3)ACD/LogD (pH 5.5): 14.52; (4)ACD/LogD (pH 7.4): 15.24; (5)ACD/BCF (pH 5.5): 1000000; (6)ACD/BCF (pH 7.4): 1000000; (7)ACD/KOC (pH 5.5): 10000000; (8)ACD/KOC (pH 7.4): 10000000; (9)#H bond acceptors: 1; (10)#Freely Rotating Bonds: 33; (11)Index of Refraction: 1.459; (12)Molar Refractivity: 172.55 cm³; (13)Molar Volume: 630 cm³; (14)Surface Tension: 31.2 dyne/cm; (15)Density: 0.828 g/cm³; (16)Flash Point: 256.6 °C; (17)Enthalpy of Vaporization: 82.33 kJ/mol; (18)Boiling Point: 544.6 °C at 760 mmHg; (19)Vapour Pressure: 6.41E-12 mmHg at 25°C.

Uses of 1-Dodecanamine,N,N-didodecyl-: it can be used to produce tridodecylamine oxide. This reaction will need reagent H₂O₂ and solvent H₂O, methanol. The yield is about 85%.

When you are using this chemical, please be cautious about it as the following:
This chemical may cause inflammation to the skin or other mucous membranes. It is irritating to eyes, respiratory system and skin. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. Whenever you will contact it, please wear suitable protective clothing.

You can still convert the following datas into molecular structure:
(1)Canonical SMILES: CCCCCCCCCCCCN(CCCCCCCCCCCC)CCCCCCCCCCCC
(2)InChI: InChI=1S/C36H75N/c1-4-7-10-13-16-19-22-25-28-31-34-37(35-32-29-26-23-20-17-14-11-8-5-2)36-33-30-27-24-21-18-15-12-9-6-3/h4-36H2,1-3H3
(3)InChIKey: SWZDQOUHBYYPJD-UHFFFAOYSA-N

Product Name

TRIDODECYLAMINE

Synthetic route

Tridodecylamine Specification

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