Triethylene glycol diacrylate supplier

Name
Triethylene glycol diacrylate
EINECS 216-853-9
CAS No. 1680-21-3
Article Data7
CAS DataBase
Density 1.092 g/cm³
Solubility
Melting Point 125℃/2mm
Formula C₁₂H₁₈O₆
Boiling Point 338.876 °C at 760 mmHg
Molecular Weight 258.271
Flash Point 146.608 °C
Transport Information
Appearance
Safety 26-36/37/39-28
Risk Codes 36/37/38-43
Molecular Structure
Hazard Symbols Xi
Synonyms Triethylene glycol, diacrylate (8CI);Kayarad PEG 100DA;Light Acrylate 3EG-A;SR 272;2-Propenoicacid, 1,2-ethanediylbis(oxy-2,1-ethanediyl) ester (9CI);Acrylic acid, diesterwith triethylene glycol (6CI,7CI,8CI);
PSA 71.06000
LogP 0.47800

Synthetic route

: 814-68-6
acryloyl chloride

: 112-27-6
2,2'-[1,2-ethanediylbis(oxy)]bisethanol

: 1680-21-3
2-propenoic acid 1,2 ethanediylbis(oxy-2,1-ethanediyl) ester

Conditions

Conditions	Yield
With triethylamine In dichloromethane at 20℃; for 1h;	99%
Stage #1: 2,2'-[1,2-ethanediylbis(oxy)]bisethanol With triethylamine In dichloromethane at 0℃; Inert atmosphere; Stage #2: acryloyl chloride In dichloromethane at 0 - 20℃; for 1h; Inert atmosphere;	57%

: 1680-21-3
2-propenoic acid 1,2 ethanediylbis(oxy-2,1-ethanediyl) ester

: 654636-62-1
N-(2-methyl-2-propyl)-N-(1-diethylphosphono-2,2-dimethylpropyl)-O-(2-carboxyprop-2-yl)hydroxylamide

: 871982-25-1
C46H90O18N2P2

Conditions

Conditions	Yield
In tert-butyl alcohol at 100℃; for 1h;	70%

: 1680-21-3
2-propenoic acid 1,2 ethanediylbis(oxy-2,1-ethanediyl) ester

polymer, photopolymerization; monomer(s): triethylene glycol diacrylate: polymer, photopolymerization; monomer(s): triethylene glycol diacrylate

Conditions

Conditions	Yield
With 2,2-dimethoxy-2-phenylacetophenone under 3750.3 Torr; for 0.0216667h; Kinetics; Product distribution; UV-irradiation;	63.6%

: 628-92-2
Cycloheptene

: 1680-21-3
2-propenoic acid 1,2 ethanediylbis(oxy-2,1-ethanediyl) ester

: (12E,19E)-1,4,7,10-Tetraoxa-cyclohenicosa-12,19-diene-11,21-dione

Conditions

Conditions	Yield
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride In dichloromethane for 12h; Heating;	63%

: 931-88-4, 931-87-3
(Z)-Cyclooctene

: 1680-21-3
2-propenoic acid 1,2 ethanediylbis(oxy-2,1-ethanediyl) ester

: (12E,20E)-1,4,7,10-Tetraoxa-cyclodocosa-12,20-diene-11,22-dione

Conditions

Conditions	Yield
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride In dichloromethane for 12h; Heating;	59%

: 1680-21-3
2-propenoic acid 1,2 ethanediylbis(oxy-2,1-ethanediyl) ester

: 1501-82-2
cyclododecene

: (12E,24E)-1,4,7,10-Tetraoxa-cyclohexacosa-12,24-diene-11,26-dione

Conditions

Conditions	Yield
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride In dichloromethane for 12h; Heating;	55%

: 1680-21-3
2-propenoic acid 1,2 ethanediylbis(oxy-2,1-ethanediyl) ester

: 142-29-0
cyclopentene

: (12E,17E)-1,4,7,10-Tetraoxa-cyclononadeca-12,17-diene-11,19-dione

Conditions

Conditions	Yield
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride In dichloromethane for 12h; Heating;	52%

: 1680-21-3
2-propenoic acid 1,2 ethanediylbis(oxy-2,1-ethanediyl) ester

: 1120-62-3
3-methyl-1-cyclopentene

: (12E,17E)-14-Methyl-1,4,7,10-tetraoxa-cyclononadeca-12,17-diene-11,19-dione

Conditions

Conditions	Yield
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride In dichloromethane for 12h; Heating;	50%

: 1680-21-3
2-propenoic acid 1,2 ethanediylbis(oxy-2,1-ethanediyl) ester

: 110-83-8
cyclohexene

: (12E,18E)-1,4,7,10-Tetraoxa-cycloicosa-12,18-diene-11,20-dione

Conditions

Conditions	Yield
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride In dichloromethane for 12h; Heating;	39%

: 591-47-9
4-methylcyclohexene

: 1680-21-3
2-propenoic acid 1,2 ethanediylbis(oxy-2,1-ethanediyl) ester

: (12E,18E)-15-Methyl-1,4,7,10-tetraoxa-cycloicosa-12,18-diene-11,20-dione

Conditions

Conditions	Yield
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride In dichloromethane for 12h; Heating;	37%

: 1680-21-3
2-propenoic acid 1,2 ethanediylbis(oxy-2,1-ethanediyl) ester

: 18728-47-7
N,N-dihydroxybenzene-1,3-dicarboximidoyl dichloride

: C20H22N2O8

Conditions

Conditions	Yield
With triethylamine In ethanol at 20℃; for 10h;	30%

: 1680-21-3
2-propenoic acid 1,2 ethanediylbis(oxy-2,1-ethanediyl) ester

: 13533-12-5
N,N-dihydroxybenzene-1,4-dicarboximidoyl dichloride

: C40H44N4O16

Conditions

Conditions	Yield
With triethylamine In ethanol at 20℃; for 10h;	27%
With triethylamine In ethanol for 14h; Ambient temperature; Yield given;

: 1680-21-3
2-propenoic acid 1,2 ethanediylbis(oxy-2,1-ethanediyl) ester

: 65823-19-0
N,N-dihydroxypyridine-1,3-dicarboximidoyl dichloride

: C19H21N3O8

Conditions

Conditions	Yield
With triethylamine In ethanol at 20℃; for 10h;	17%

: 1680-21-3
2-propenoic acid 1,2 ethanediylbis(oxy-2,1-ethanediyl) ester

: 18728-47-7
N,N-dihydroxybenzene-1,3-dicarboximidoyl dichloride

: C20H22N2O8

Conditions

Conditions	Yield
With triethylamine In ethanol for 14h; Ambient temperature; Yield given;

: 1680-21-3
2-propenoic acid 1,2 ethanediylbis(oxy-2,1-ethanediyl) ester

: 65823-19-0
N,N-dihydroxypyridine-1,3-dicarboximidoyl dichloride

: C19H21N3O8

Conditions

Conditions	Yield
With triethylamine In ethanol for 14h; Ambient temperature; Yield given;

: 1680-21-3
2-propenoic acid 1,2 ethanediylbis(oxy-2,1-ethanediyl) ester

polymer; monomer(s): acrylic acid 2-[2-(2-acryloyloxyethoxy)ethoxy]ethyl ester: polymer; monomer(s): acrylic acid 2-[2-(2-acryloyloxyethoxy)ethoxy]ethyl ester

Conditions

Conditions	Yield
With tetraethylammonium perchlorate In N,N-dimethyl-formamide Electrochemical reaction;

: 110-85-0
piperazine

: 1680-21-3
2-propenoic acid 1,2 ethanediylbis(oxy-2,1-ethanediyl) ester

polymer, Mw = 14800, PDI = 1.98; monomer(s): acrylic acid 2-[2-(2-acryloyloxy-ethoxy)-ethoxy]-ethyl ester; piperazine: polymer, Mw = 14800, PDI = 1.98; monomer(s): acrylic acid 2-[2-(2-acryloyloxy-ethoxy)-ethoxy]-ethyl ester; piperazine

Conditions

Conditions	Yield
In dichloromethane at 45℃; for 120h;

: 27578-60-5
1-(2-aminoethyl)piperidine

: 1680-21-3
2-propenoic acid 1,2 ethanediylbis(oxy-2,1-ethanediyl) ester

polymer, Mw = 3230, PDI = 1.82; monomer(s): acrylic acid 2-[2-(2-acryloyloxy-ethoxy)-ethoxy]-ethyl ester; (2-aminoethyl)piperidine: polymer, Mw = 3230, PDI = 1.82; monomer(s): acrylic acid 2-[2-(2-acryloyloxy-ethoxy)-ethoxy]-ethyl ester; (2-aminoethyl)piperidine

Conditions

Conditions	Yield
In dichloromethane at 45℃; for 120h;

: 2038-03-1
4-(2-AMINOETHYL)MORPHOLINE

: 1680-21-3
2-propenoic acid 1,2 ethanediylbis(oxy-2,1-ethanediyl) ester

polymer, Mw = 6830, PDI = 1.93; monomer(s): acrylic acid 2-[2-(2-acryloyloxy-ethoxy)-ethoxy]-ethyl ester; 4-(2-aminoethyl)morpholine: polymer, Mw = 6830, PDI = 1.93; monomer(s): acrylic acid 2-[2-(2-acryloyloxy-ethoxy)-ethoxy]-ethyl ester; 4-(2-aminoethyl)morpholine

Conditions

Conditions	Yield
In dichloromethane at 45℃; for 120h;

: 5036-48-6
3-(1H-imidazol-1-yl)propan-1-amine

: 1680-21-3
2-propenoic acid 1,2 ethanediylbis(oxy-2,1-ethanediyl) ester

polymer, Mw = 1752, PDI = 1.46; monomer(s): acrylic acid 2-[2-(2-acryloyloxy-ethoxy)-ethoxy]-ethyl ester; 1-(3-aminopropyl)imidazole: polymer, Mw = 1752, PDI = 1.46; monomer(s): acrylic acid 2-[2-(2-acryloyloxy-ethoxy)-ethoxy]-ethyl ester; 1-(3-aminopropyl)imidazole

Conditions

Conditions	Yield
In dichloromethane at 45℃; for 120h;

: 111-26-2
hexan-1-amine

: 1680-21-3
2-propenoic acid 1,2 ethanediylbis(oxy-2,1-ethanediyl) ester

polymer, Mw = 5640, PDI = 1.85; monomer(s): acrylic acid 2-[2-(2-acryloyloxy-ethoxy)-ethoxy]-ethyl ester; hexylamine: polymer, Mw = 5640, PDI = 1.85; monomer(s): acrylic acid 2-[2-(2-acryloyloxy-ethoxy)-ethoxy]-ethyl ester; hexylamine

Conditions

Conditions	Yield
In dichloromethane at 45℃; for 120h;

: 13325-10-5
4-Aminobutanol

: 1680-21-3
2-propenoic acid 1,2 ethanediylbis(oxy-2,1-ethanediyl) ester

polymer, Mw = 15300, PDI = 3.92; monomer(s): acrylic acid 2-[2-(2-acryloyloxy-ethoxy)-ethoxy]-ethyl ester; 4-amino-butan-1-ol: polymer, Mw = 15300, PDI = 3.92; monomer(s): acrylic acid 2-[2-(2-acryloyloxy-ethoxy)-ethoxy]-ethyl ester; 4-amino-butan-1-ol

Conditions

Conditions	Yield
In dichloromethane at 45℃; for 120h;

: 1680-21-3
2-propenoic acid 1,2 ethanediylbis(oxy-2,1-ethanediyl) ester

: 16898-52-5
1,3-di(piperidin-4-yl)propane

polymer, Mw = 18700, PDI = 2.72; monomer(s): acrylic acid 2-[2-(2-acryloyloxy-ethoxy)-ethoxy]-ethyl ester; 1,3-bispiperidine-4-yl-propan: polymer, Mw = 18700, PDI = 2.72; monomer(s): acrylic acid 2-[2-(2-acryloyloxy-ethoxy)-ethoxy]-ethyl ester; 1,3-bispiperidine-4-yl-propan

Conditions

Conditions	Yield
In dichloromethane at 45℃; for 120h;

: 1680-21-3
2-propenoic acid 1,2 ethanediylbis(oxy-2,1-ethanediyl) ester

: 141-43-5
ethanolamine

polymer, Mw = 7940, PDI = 3.25; monomer(s): acrylic acid 2-[2-(2-acryloyloxy-ethoxy)-ethoxy]-ethyl ester; 2-amino-ethanol: polymer, Mw = 7940, PDI = 3.25; monomer(s): acrylic acid 2-[2-(2-acryloyloxy-ethoxy)-ethoxy]-ethyl ester; 2-amino-ethanol

Conditions

Conditions	Yield
In dichloromethane at 45℃; for 120h;

: 1680-21-3
2-propenoic acid 1,2 ethanediylbis(oxy-2,1-ethanediyl) ester

: 109-73-9
N-butylamine

polymer, Mw = 5220, PDI = 1.95; monomer(s): acrylic acid 2-[2-(2-acryloyloxy-ethoxy)-ethoxy]-ethyl ester; butylamine: polymer, Mw = 5220, PDI = 1.95; monomer(s): acrylic acid 2-[2-(2-acryloyloxy-ethoxy)-ethoxy]-ethyl ester; butylamine

Conditions

Conditions	Yield
In dichloromethane at 45℃; for 120h;

: 1680-21-3
2-propenoic acid 1,2 ethanediylbis(oxy-2,1-ethanediyl) ester

: 929-06-6
2-(2-Aminoethoxy)ethanol

polymer, Mw = 15500, PDI = 4.89; monomer(s): acrylic acid 2-[2-(2-acryloyloxy-ethoxy)-ethoxy]-ethyl ester; 2-(2-aminoethoxy)ethanol: polymer, Mw = 15500, PDI = 4.89; monomer(s): acrylic acid 2-[2-(2-acryloyloxy-ethoxy)-ethoxy]-ethyl ester; 2-(2-aminoethoxy)ethanol

Conditions

Conditions	Yield
In dichloromethane at 45℃; for 120h;

: 15214-89-8
2-acrylamido-2-methylpropanesulfonic acid

: 1680-21-3
2-propenoic acid 1,2 ethanediylbis(oxy-2,1-ethanediyl) ester

polymer, low hydrophobic, prepared by photocopolymerization of monomer and cross-linker; monomer(s): 2-acrylamido-2-methyl-1-propanesulfonic acid; poly(ethylene glycol) diacrylate: polymer, low hydrophobic, prepared by photocopolymerization of monomer and cross-linker; monomer(s): 2-acrylamido-2-methyl-1-propanesulfonic acid; poly(ethylene glycol) diacrylate

Conditions

Conditions	Yield
With 2,2-dimethoxy-2-phenylacetophenone In methanol; diethyl ether; water for 0.05h; UV-irradiation;

: 15214-89-8
2-acrylamido-2-methylpropanesulfonic acid

: 1680-21-3
2-propenoic acid 1,2 ethanediylbis(oxy-2,1-ethanediyl) ester

polymer, low hydrophobic, prepared by photocopolymerization of monomer (25 wt %) and cross-linker (75 wt %); monomer(s): 2-acrylamido-2-methyl-1-propanesulfonic acid; poly(ethylene glycol) diacrylate: polymer, low hydrophobic, prepared by photocopolymerization of monomer (25 wt %) and cross-linker (75 wt %); monomer(s): 2-acrylamido-2-methyl-1-propanesulfonic acid; poly(ethylene glycol) diacrylate

Conditions

Conditions	Yield
With 2,2-dimethoxy-2-phenylacetophenone In methanol; diethyl ether; water for 0.05h; UV-irradiation;

: 10595-80-9
2-Methacryloyloxyethyl-1-sulfonic acid

: 1680-21-3
2-propenoic acid 1,2 ethanediylbis(oxy-2,1-ethanediyl) ester

polymer, low hydrophobic, prepared by photocopolymerization of monomer, cross-linker and porogen; monomer(s): sulfoethyl methacrylate; poly(ethylene glycol) diacrylate: polymer, low hydrophobic, prepared by photocopolymerization of monomer, cross-linker and porogen; monomer(s): sulfoethyl methacrylate; poly(ethylene glycol) diacrylate

Conditions

Conditions	Yield
With 2,2-dimethoxy-2-phenylacetophenone In diethyl ether for 0.5h; UV-irradiation;

Triethylene glycol diacrylate Chemical Properties

IUPAC Name: 2-[2-(2-prop-2-enoyloxyethoxy)ethoxy]Ethyl prop-2-enoate (1680-21-3)
Synonyms: 1,2-Ethanediylbis(oxy-2,1-ethanediyl) Diacrylate
Molecular Structure :
Molecular Formula: C₁₂H₁₈O₆
Molecular Weight: 258.27
CAS Registry Number: 1680-21-3
EINECS : 216-853-9
Surface Tension: 35.2 dyne/cm
Density: 1.092 g/cm³
Flash Point: 146.6 °C
Enthalpy of Vaporization: 58.23 kJ/mol
Boiling Point: 338.9 °C at 760 mmHg
Vapour Pressure: 9.54E-05 mmHg at 25°C
Melting point:266°C
Stability: Triethylene glycol diacrylate (1680-21-3) is stable,combustible, incompatible with strong oxidizing agents.

Triethylene glycol diacrylate Uses

Triethylene glycol diacrylate (1680-21-3) is used in photographic film.

Triethylene glycol diacrylate Toxicity Data With Reference

1.	skn-rbt 500 mg/2H4 SEV	EPASR* United States Environmental Protection Agency, Office of Pesticides and Toxic Substances. (U.S. Environmental Protection Agency, 401M St., S.W., Washington, DC 20460) History Unknown 8EHQ-0981-0410 .
2.	eye-rbt 100 mg SEV	EPASR* United States Environmental Protection Agency, Office of Pesticides and Toxic Substances. (U.S. Environmental Protection Agency, 401M St., S.W., Washington, DC 20460) History Unknown 8EHQ-0981-0410 .
3.	orl-rat LD50:500 mg/kg	85GMAT Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure Izmerov, N.F., et al.,Moscow, USSR.: Centre of International Projects, GKNT,1982,115.
4.	orl-mus LD50:700 mg/kg	85GMAT Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure Izmerov, N.F., et al.,Moscow, USSR.: Centre of International Projects, GKNT,1982,115.
5.	skn-rbt LD50:1900 mg/kg	EPASR* United States Environmental Protection Agency, Office of Pesticides and Toxic Substances. (U.S. Environmental Protection Agency, 401M St., S.W., Washington, DC 20460) History Unknown 8EHQ-0981-0410 .

Triethylene glycol diacrylate Consensus Reports

Reported in EPA TSCA Inventory.

Triethylene glycol diacrylate Safety Profile

Hazard Codes Xi
Risk Statements 36/37/38-43
43: Triethylene glycol diacrylate (1680-21-3) may cause sensitization by skin contact
36/37/38: Irritating to eyes, respiratory system and skin
Safety Statements 26-36/37/39-28
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
28: After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer)
36/37/39: Wear suitable protective clothing, gloves and eye/face protection

Product Name

Triethylene glycol diacrylate

Synthetic route

Triethylene glycol diacrylate Chemical Properties

Triethylene glycol diacrylate Uses

Triethylene glycol diacrylate Toxicity Data With Reference

Triethylene glycol diacrylate Consensus Reports

Triethylene glycol diacrylate Safety Profile

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