Triethylsilane supplier | CasNO.617-86-7

Name
Triethylsilane
EINECS 210-535-3
CAS No. 617-86-7
Article Data105
CAS DataBase
Density 0.728g/mLat 25°C(lit.)
Solubility Miscible with water.
Melting Point -157 °C
Formula C₆H₁₆Si
Boiling Point 107.499 °C at 760 mmHg
Molecular Weight 116.279
Flash Point 25°F
Transport Information UN 1993 3/PG 2
Appearance Clear liquid
Safety 9-16-29-33-37/39-26
Risk Codes 11-36/37/38
Molecular Structure
Hazard Symbols F, Xi
Synonyms Triethylsilyl hydride;
PSA 0.00000
LogP 2.27320

Synthetic route

: 2117-34-2
triethylmethoxysilane

: 617-86-7
triethylsilane

Conditions

Conditions	Yield
With N,N,N,N,N,N-hexamethylphosphoric triamide; sodium tetrahydroborate; ethyl bromide; tetraoctyl ammonium bromide In benzene-d6 at 20℃; for 24h; Reagent/catalyst; Solvent;	96%

: 13399-93-4
3-(trimethylsilyl)propane-1-thiol

: 4149-29-5
bis(triethylsilyl)mercury

A: 617-86-7
triethylsilane

B: 1-Triethylsilanylsulfanyl-3-trimethylsilanyl-propane

Conditions

Conditions	Yield
In benzene Heating;	A n/a B 89.5%

...Expand

: 994-30-9
triethylsilyl chloride

: 617-86-7
triethylsilane

Conditions

Conditions	Yield
With sodium tetrahydroborate In acetonitrile at 20℃; for 0.25h; Inert atmosphere;	88%
With lithium hydride In tetrahydrofuran at 20 - 60℃; Reagent/catalyst; Solvent;	82%
Stage #1: triethylsilyl chloride With magnesium In tetrahydrofuran at 75℃; for 12h; Inert atmosphere; Stage #2: Acidic conditions;	80%

: 7538-45-6
2-mercaptoethyl(trimethoxysilane)

: 4149-29-5
bis(triethylsilyl)mercury

A: 617-86-7
triethylsilane

B: C11H28O3SSi2

Conditions

Conditions	Yield
In benzene Heating;	A n/a B 87.3%

...Expand

: 30817-94-8
(mercaptomethyl)trimethoxysilane

: 4149-29-5
bis(triethylsilyl)mercury

A: 617-86-7
triethylsilane

B: triethyl(trimethoxysilylmethylthio)silane

Conditions

Conditions	Yield
In benzene at 50℃; for 0.25h;	A n/a B 80%

...Expand

: 109-65-9
1-bromo-butane

: 92465-73-1
triethylsilylcalcium chloride

A: 617-86-7
triethylsilane

B: 994-96-7
butyltriethylsilane

Conditions

Conditions	Yield
for 1h; Ambient temperature;	A 1.1% B 26%

...Expand

: 108-86-1
bromobenzene

: 92465-73-1
triethylsilylcalcium chloride

A: 617-86-7
triethylsilane

B: 2987-77-1
triethylphenylsilane

Conditions

Conditions	Yield
for 1h; Ambient temperature;	A 3% B 24%

...Expand

: 462-06-6
fluorobenzene

: 92465-73-1
triethylsilylcalcium chloride

A: 617-86-7
triethylsilane

B: 2987-77-1
triethylphenylsilane

Conditions

Conditions	Yield
for 1h; Ambient temperature;	A 15% B n/a

...Expand

: 92465-73-1
triethylsilylcalcium chloride

: 108-90-7
chlorobenzene

A: 617-86-7
triethylsilane

B: 2987-77-1
triethylphenylsilane

Conditions

Conditions	Yield
for 1h; Ambient temperature;	A 10% B 5%

...Expand

: 78-10-4
tetraethoxy orthosilicate

: 557-20-0
diethylzinc

: 617-86-7
triethylsilane

Conditions

Conditions	Yield
With sodium

: 358-43-0
triethylsilyl fluoride

: 617-86-7
triethylsilane

Conditions

Conditions	Yield
With diethylaluminium hydride
Multi-step reaction with 2 steps 1: I2; AlI3 View Scheme

: 597-67-1
ethoxytriethylsilane

: 557-20-0
diethylzinc

: 617-86-7
triethylsilane

Conditions

Conditions	Yield
With sodium
With Na In not given

: 994-49-0
hexaethyl disiloxane

: 617-86-7
triethylsilane

Conditions

Conditions	Yield
With triethylaluminum

: 925-90-6
ethylmagnesium bromide

: 617-86-7
triethylsilane

Conditions

Conditions	Yield
With diethyl ether; trichlorosilane
With trichlorosilane In diethyl ether

: 2386-64-3
ethylmagnesium chloride

: 617-86-7
triethylsilane

Conditions

Conditions	Yield
With diethyl ether; trichlorosilane

: 542-91-6
H2SiEt2

A: 617-86-7
triethylsilane

B: 2814-79-1
ethylsilane

Conditions

Conditions	Yield
With sulfur trioxide; zirconium(IV) oxide at 99.9℃; under 30 Torr; for 0.583333h; Product distribution; other alkylsilanes, var. temp., var. pretreatment of catalyst;

: 1112-48-7
triethyl-bromo-silane

: 617-86-7
triethylsilane

Conditions

Conditions	Yield
With N,N,N,N,N,N-hexamethylphosphoric triamide; ytterbium In tetrahydrofuran Yield given;

: 925-90-6
ethylmagnesium bromide

: 101519-12-4
sodiumtris(benzene-1,2 diolato)silicate

: 617-86-7
triethylsilane

Conditions

Conditions	Yield
With lithium aluminium tetrahydride Yield given. Multistep reaction;

: 101631-06-5
triethylsilyl hydrotrioxide

: 617-86-7
triethylsilane

Conditions

Conditions	Yield
In dichloromethane at -60℃; for 2.5h;

: 994-30-9
triethylsilyl chloride

: 71-43-2
benzene

A: 617-86-7
triethylsilane

B: 2987-77-1
triethylphenylsilane

Conditions

Conditions	Yield
With calcium 1) 900 deg C, 0.005 Torr, 2) 1 h, r.t., 0.005 Torr; Yield given. Multistep reaction. Yields of byproduct given;

...Expand

: 617-86-7
triethylsilane

: 111-87-5
octanol

: 17957-36-7
1-octyl triethylsilyl ether

Conditions

Conditions	Yield
cationic dirhodium(II) complex at 50℃; for 24h;	100%
With Rh/AlO(OH) In toluene at 25℃; for 24h; Inert atmosphere;	90%
dirhodium(II) tetrakis(perfluorobutyrate) In dichloromethane for 3h; Product distribution; Ambient temperature; var. alcohols; rel. reactivities for triethylsilane alcoholysis; var. catalysts;	86%

: 617-86-7
triethylsilane

: 597-52-4
Triethylsilanol

Conditions

Conditions	Yield
With 5%-palladium/activated carbon; water In ethyl acetate	100%
With water at 20℃; for 0.25h;	99%
With water In tetrahydrofuran at 25℃; for 0.0166667h; Catalytic behavior;	99%

: 617-86-7
triethylsilane

: 80-62-6
methacrylic acid methyl ester

: 18002-64-7
β-triethylsilanyl-isobutyric acid methyl ester

Conditions

Conditions	Yield
bis(benzonitrile)dichloroplatinum(II); triethylphosphine for 24h;	100%
With platinum on activated charcoal
With dihydrogen hexachloroplatinate

: 617-86-7
triethylsilane

: 65-85-0
benzoic acid

: 1018-20-8
triethylsilyl benzoate

Conditions

Conditions	Yield
With indium(III) bromide In dichloromethane-d2 at 20℃;	100%
With palladium diacetate In benzene-d6 for 4h; dehydrocoupling reaction; Heating;	95%
With zinc(II) chloride In N,N-dimethyl-formamide at 120℃; for 25h;	85%

: 292638-84-7
styrene

: 617-86-7
triethylsilane

: 14355-62-5
triethyl-2-phenylethylsilane

Conditions

Conditions	Yield
cerium(IV) oxide; gold In toluene at 70℃; for 8h;	100%
With tris(pentafluorophenyl)borate In dichloromethane at 20℃; for 12h;	96%
With dimanganese decacarbonyl; bis(3,5-bis(trifluoromethyl)phenyl)(2’,4’,6’-triisopropyl-3,6-dimethoxy-[1,1’-biphenyl]-2-yl)phosphine at 120℃; for 24h; Sealed tube;	83%

: 617-86-7
triethylsilane

: 592-41-6
1-hexene

: 13810-04-3
n-hexyltriethylsilane

Conditions

Conditions	Yield
at 90℃; for 5h; Inert atmosphere;	100%
at 90℃; for 5h; Inert atmosphere;	100%
With C26H31F5NZn(1+)*C24BF20(1-) In dichloromethane-d2 at 20℃; for 28h; Reagent/catalyst; Inert atmosphere; Glovebox;	100%

: 617-86-7
triethylsilane

: 100-52-7
benzaldehyde

: 13959-92-7
benzyl triethylsilyl ether

Conditions

Conditions	Yield
cerium(IV) oxide; gold In toluene at 70℃; for 8h;	100%
With C16H25AlBN6(1+)*C19H3BF15(1-) In chloroform-d1 at 75℃; for 0.5h;	99%
With (1,3-dimesityl-5-methyl-6-oxo-6H-pyrimidin-2-ylidene-4-olate)-copper(I) lithium(THF)2; sodium t-butanolate In tetrahydrofuran at 65℃; for 2h; Schlenk technique; Inert atmosphere;	98%

: 617-86-7
triethylsilane

: 98-86-2
acetophenone

: 112473-30-0, 18442-52-9
triethyl(1-phenylethoxy)silane

Conditions

Conditions	Yield
With (1,3-dimesityl-5-methyl-6-oxo-6H-pyrimidin-2-ylidene-4-olate)-copper(I) lithium(THF)2; sodium t-butanolate In tetrahydrofuran at 65℃; for 1h; Reagent/catalyst; Temperature; Time; Schlenk technique; Inert atmosphere;	100%
With C42H43BN3P2(1+)*C18HBF15(1-) In chloroform at 40℃; for 2h; Reagent/catalyst; Temperature; Schlenk technique; Glovebox;	99%
Stage #1: acetophenone With C8H10BiCl2N; C4H6AgN2(1+)*C24H12BCl8(1-) In dichloromethane-d2 at 25℃; Stage #2: triethylsilane In dichloromethane at 25℃;	99%

: 617-86-7
triethylsilane

: 821-10-3
1,4-Dichloro-2-butyne

1,4-dichloro 2-triethylsilylbut-2-ene: 108930-44-5
1,4-dichloro 2-triethylsilylbut-2-ene

Conditions

Conditions	Yield
With dihydrogen hexachloroplatinate In tetrahydrofuran at 85℃; for 4h;	100%
With platinum(IV) oxide In toluene at 100℃; for 24h; diastereoselective reaction;	75%
dihydrogen hexachloroplatinate
With dihydrogen hexachloroplatinate at 170℃; for 1h;

: 617-86-7
triethylsilane

: 100-51-6
benzyl alcohol

: 13959-92-7
benzyl triethylsilyl ether

Conditions

Conditions	Yield
{Rh2(OAc)3[(R)-PhCH2SCH(Me)C(O)OEt]2}BF4 In dichloromethane at 50℃; for 24h;	100%
With C23H26IrN2(1+)*C32H12BF24(1-) In 1,2-dichloro-ethane at 20℃; for 0.0166667h; Catalytic behavior; Schlenk technique; Inert atmosphere;	100%
With Pd/XC-72-700-Ar at 25℃; for 0.03h;	99%

: 109-99-9
tetrahydrofuran

: 617-86-7
triethylsilane

: 2751-87-3
n-butoxytriethylsilane

Conditions

Conditions	Yield
nickel at 100℃; for 1h;	100%
With [(POCOP)Ir(H)(acetone)]+[B(C6F5)4]- In dichloromethane-d2 at 22℃; for 3h;	100 %Spectr.

: 617-86-7
triethylsilane

: 622-97-9
1-ethenyl-4-methylbenzene

: 75476-54-9
(E)-1-(p-methylphenyl)-2-(triethylsilyl)ethylene

Conditions

Conditions	Yield
dodecacarbonyl-triangulo-triruthenium In benzene at 80℃; for 5h;	100%
With dimanganese decacarbonyl; N,N-bis(diphenylphosphino)isopropylamine at 140℃; for 24h; Sealed tube;	82%
With norborn-2-ene; chloro(1,5-cyclooctadiene)rhodium(I) dimer; triphenylphosphine In tetrahydrofuran at 100℃; for 2h; Schlenk technique; Inert atmosphere; Sealed tube;	82%

: 617-86-7
triethylsilane

: 141-79-7
4-methyl-pent-3-en-2-one

: 57137-74-3
(E)-4-methyl-2-(triethylsilyloxy)pent-2-ene

Conditions

Conditions	Yield
RhCl(PPh3)3 at 40℃;	100%

: 617-86-7
triethylsilane

: 4526-07-2
1,4-bis(trimethylsilyl)-1,3-butadiyne

: 103716-77-4
(E)-2-triethylsilyl-1,4-bis(trimethylsilyl)-1-buten-3-yne

Conditions

Conditions	Yield
With tetrakis(triphenylphosphine)platinum at 100℃; for 1h;	100%

: 617-86-7
triethylsilane

: 4526-07-2
1,4-bis(trimethylsilyl)-1,3-butadiyne

: 103716-76-3
1,3-bis(triethylsilyl)-1,4-bis(trimethylsilyl)-1,2-butadiene

Conditions

Conditions	Yield
dihydrogen hexachloroplatinate In isopropyl alcohol at 80℃; for 0.5h;	100%
With dihydrogen hexachloroplatinate In isopropyl alcohol at 80℃; for 0.5h;	100%

: 617-86-7
triethylsilane

: 123239-66-7
(3-methoxynaphthalen-2-yl)phenylmethanol

: Triethyl-[(3-methoxy-naphthalen-2-yl)-phenyl-methoxy]-silane

Conditions

Conditions	Yield
In dichloromethane at 0℃;	100%

: 617-86-7
triethylsilane

: 103716-81-0
(E)-2-dimethylphenylsilyl-1,4-bis(trimethylsilyl)-1-buten-3-yne

: 103716-84-3
3-dimethylphenylsilyl-1-triethylsilyl-1,4-bis(trimethylsilyl)-1,2-butadiene

Conditions

Conditions	Yield
With RhCl(PPh3)3 at 100℃; for 13h;	100%
dihydrogen hexachloroplatinate	93%

: 617-86-7
triethylsilane

: 104106-61-8
4aβ,8-dimethyl-4a,5,6,8aα-tetrahydro-2<1H>-naphthalenone

: 104504-88-3
7-triethylsilyloxy-1,4aβ-dimethyl-3,4,4a,5,8,8aα-hexahydronaphthalene

Conditions

Conditions	Yield
Wilkinson's catalyst for 6h; Ambient temperature;	100%

: 617-86-7
triethylsilane

: 151545-05-0
C72H140Si14

: 2-<2,4,6-trisphenyl>-1,1,1-triethyl-2-mesityldisilane

Conditions

Conditions	Yield
In toluene at 70℃;	100%
In tetrahydrofuran for 10h; Heating;	77%
In toluene at 60℃; Rate constant; Mechanism; Kinetics; energy data: Ea, ΔH(excit.), SDS(excit.); var. temp.;
In toluene at 81.3℃; Rate constant; Kinetics; Thermodynamic data; Ea, ΔH(excit.), SDS(excit.); var. temp.;

: 617-86-7
triethylsilane

: 98-83-9
isopropenylbenzene

: 17911-16-9
triethyl(2-phenylpropyl)silane

Conditions

Conditions	Yield
platinum(II) chloride at 24.9℃; for 96h;	100%
With fluorotris(pentafluorophenyl)phosphonium tetrakis(pentafluorophenyl)borate In dichloromethane at 20℃; for 1h; Inert atmosphere;	99%
With tris(pentafluorophenyl)borate In dichloromethane at 20℃;	97%

: 617-86-7
triethylsilane

: 536-74-3
phenylacetylene

: 21209-32-5
(E)-1-(triethylsilyl)-2-phenylethene

Conditions

Conditions	Yield
carbonylhydridetris(triphenylphosphine)rhodium(I) at 20℃; for 72h; magnetic field 40 Oe;	100%
With dicyclohexylphosphino-2′,4′,6′-triisopropylbiphenyl; platinum(II) chloride In tetrahydrofuran at 60℃; for 1.25h;	98%
With sodium iodide In tetrahydrofuran at 20℃; for 1h; Catalytic behavior; stereoselective reaction;	98%

: 617-86-7
triethylsilane

: (2RS,3RS,4RS,5RS,6RS,7RS)-3,6-dimesityl-3,6-bis<2,4,6-trisphenyl>-3,6-disilatetracyclo<6.4.02,4.05,7>dodeca-1(8),9,11-triene

A: 91-20-3
naphthalene

B: 2-<2,4,6-trisphenyl>-1,1,1-triethyl-2-mesityldisilane

Conditions

Conditions	Yield
In (2)H8-toluene at 120℃; for 30h;	A n/a B 100%

...Expand

: 617-86-7
triethylsilane

: (Z)-4,8-dimesityl-4,8-bis<2,4,6-trisphenyl>-4,8-disilabicyclo<5.1.0>octa-2,5-diene

A: 2-<2,4,6-trisphenyl>-1,1,1-triethyl-2-mesityldisilane

B: 71-43-2
benzene

Conditions

Conditions	Yield
In (2)H8-toluene at 120℃; for 30h;	A 100% B n/a

...Expand

: 617-86-7
triethylsilane

: 218937-15-6
2α,9α,10β,13α-tetraacetoxy-taxa-4(20),11-dien-5α-ol

: 325691-23-4
2α,9α,10β,13α-tetraacetoxy-5α-triethylsilyloxytaxa-4(20),11-diene

Conditions

Conditions	Yield
With 1H-imidazole In N,N-dimethyl-formamide at 20℃; for 2h;	100%

: 617-86-7
triethylsilane

: 51060-11-8
2,2,4-trimethyl-hept-6-yn-3-one

: (4RS,5SR)-4,6,6-trimethyl-5-phenyl-5-triethylsilyloxyhept-1-yne

Conditions

Conditions	Yield
With tris(pentafluorophenyl)borate In toluene at 0℃; for 1h;	100%

: 617-86-7
triethylsilane

: 552890-39-8
Acetic acid (2R,3S,5R,6S)-6-allyl-5-benzyloxy-2-phenylsulfanylethynyl-tetrahydro-pyran-3-yl ester

: 617673-36-6
Acetic acid (2R,3S,5R,6S)-6-allyl-5-benzyloxy-2-((Z)-2-phenylsulfanyl-2-triethylsilanyl-vinyl)-tetrahydro-pyran-3-yl ester

Conditions

Conditions	Yield
biscobalthexacarbonyl-2-methyl-but-3-yn-2-ol In 1,2-dichloro-ethane at 60℃; for 1.5h;	100%
biscobalthexacarbonyl-2-methyl-but-3-yn-2-ol In 1,2-dichloro-ethane

: 617-86-7
triethylsilane

: 109660-11-9
4,4-dimethyl-2-(naphthalen-2-yl)-4,5-dihydrooxazole

: 4,4-dimethyl-2-(3-triethylsilanylnaphthalen-2-yl)-4,5-dihydro-oxazole

Conditions

Conditions	Yield
With norborn-2-ene; dodecacarbonyl-triangulo-triruthenium In toluene for 20h; Heating;	100%

: 617-86-7
triethylsilane

: 3-methyl-2-(naphthalen-1-yl)pyridine

: 2-(2-(triethylsilyl)naphthalene-1-yl)-3-methylpyridine

Conditions

Conditions	Yield
With norborn-2-ene; dodecacarbonyl-triangulo-triruthenium In toluene for 20h; Heating;	100%
With norborn-2-ene; dodecacarbonyl-triangulo-triruthenium In toluene for 36h; Inert atmosphere; Schlenk technique; Reflux;	59.6 mg

: 617-86-7
triethylsilane

: 13019-22-2
9-Decen-1-ol

: 566189-62-6
1-(triethylsilyl)oxy-9-decene

Conditions

Conditions	Yield
AuCl(xanthphos) In acetone at 50℃; for 8h;	100%
With copper (I) tert-butoxide; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In toluene at 25℃; for 2h;	95%

: 617-86-7
triethylsilane

: 107-05-1
3-chloroprop-1-ene

: 2290-35-9
(3-chloropropyl)triethylsilane

Conditions

Conditions	Yield
copper dichloride at 200℃; for 45h;	100%
copper diacetate at 200℃; for 45h;	100%
copper(II) sulfate at 200℃; for 45h;	100%

Triethylsilane Specification

The Triethylsilane is an organic compound with the formula C₆H₁₆Si. The IUPAC name of this chemical is triethylsilicon. With the CAS registry number 617-86-7, it is also named as Silane, triethyl-. The product's categories are Other Reagents; Reduction; Si (Classes of Silicon Compounds); Si-H Compounds; Silicon Compounds (for Synthesis); Synthetic Organic Chemistry; Alkyl Silanes; Hydrogensilanes Hydrogensiloxanes; Reducing Agents; Chemistry; Silanes; Synthetic Reagents. Besides, it is clear liquid, which should be stored in a dark closed and dry place. It is often used in organic synthesis, specifically for the hydrosilation of olefins to give alkyl silanes. It can also be used as a reducing agent since it has an active hydride.

Physical properties about Triethylsilane are: (1)ACD/LogP: 3.65; (2)ACD/LogD (pH 5.5): 3.65; (3)ACD/LogD (pH 7.4): 3.65; (4)ACD/BCF (pH 5.5): 349.789; (5)ACD/BCF (pH 7.4): 349.789; (6)ACD/KOC (pH 5.5): 2303.888; (7)ACD/KOC (pH 7.4): 2303.888; (8)#Freely Rotating Bonds: 3; (9)Enthalpy of Vaporization: 33.2 kJ/mol; (10)Boiling Point: 107.499 °C at 760 mmHg; (11)Vapour Pressure: 31.55 mmHg at 25°C.

Uses of Triethylsilane: it can be used to produce ethoxy-triethyl-silane. It will need reagent NaOEt.

When you are using this chemical, please be cautious about it as the following:
It is highly flammable. Please keep away from sources of ignition - No smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Besides, this chemical is irritating to eyes, respiratory system and skin. When you are using it, wear suitable gloves and eye/face protection, do not breathe dust and take precautionary measures against static discharges.

You can still convert the following datas into molecular structure:
(1)SMILES: CC[SiH](CC)CC
(2)InChI: InChI=1/C6H16Si/c1-4-7(5-2)6-3/h7H,4-6H2,1-3H3
(3)InChIKey: AQRLNPVMDITEJU-UHFFFAOYAL
(4)Std. InChI: InChI=1S/C6H16Si/c1-4-7(5-2)6-3/h7H,4-6H2,1-3H3
(5)Std. InChIKey: AQRLNPVMDITEJU-UHFFFAOYSA-N

Product Name

Triethylsilane

Synthetic route

Triethylsilane Specification

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