Trimethoxypropylsilane supplier

Name
Trimethoxypropylsilane
EINECS 213-926-7
CAS No. 1067-25-0
Article Data11
CAS DataBase
Density 0.9 g/cm³
Solubility Reacts with water.
Melting Point
Formula C₆H₁₆O₃Si
Boiling Point 142 ºC at 760 mmHg
Molecular Weight 164.277
Flash Point 40.6 ºC
Transport Information UN 1993 3/PG 3
Appearance colorless or yellowish clear liquid
Safety 26-36
Risk Codes 10-36/37/38
Molecular Structure
Hazard Symbols Xi
Synonyms AY 43-203M;Dynasylan BSM;Dynasylan PTMO;JH-N 313;KBM 3033;N 313;P 810;Propyltrimethoxysilane;Silan 103;Z 6265;n-Propyltrimethoxysilane;
PSA 27.69000
LogP 1.27450

Synthetic route

: 3775-28-8
2-methylene-1,3-diglycidoxypropane

: 2487-90-3
trimethoxysilane

: 1067-25-0
n-propyltrimethoxysilane

Conditions

Conditions	Yield
chloroplatinic acid In isopropyl alcohol	85%

: 2487-90-3
trimethoxysilane

: 107-05-1
3-chloroprop-1-ene

A: bis(trimethoxysilyl)propane

B: 253586-30-0
3-chloropropyltrichlorosilane

C: 4668-00-2
chlorotrimethoxysilane

D: 681-84-5
tetramethylorthosilicate

E: 540-54-5
1-Chloropropane

F: 1067-25-0
n-propyltrimethoxysilane

G: 2530-87-2
3-Chloropropyltrimethoxysilan

Conditions

Conditions	Yield
With toluene; ruthenium trichloride In methanol at 20 - 83℃; for 2h; Product distribution / selectivity;
[ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 In dichloromethane at 20 - 83℃; for 2h; Product distribution / selectivity;
ruthenium trichloride In methanol at 75 - 169℃; for 18h; Product distribution / selectivity; Continuous operation;

...Expand

: 2487-90-3
trimethoxysilane

: 107-05-1
3-chloroprop-1-ene

A: 253586-30-0
3-chloropropyltrichlorosilane

B: 4668-00-2
chlorotrimethoxysilane

C: 681-84-5
tetramethylorthosilicate

D: 540-54-5
1-Chloropropane

E: 1067-25-0
n-propyltrimethoxysilane

F: 2530-87-2
3-Chloropropyltrimethoxysilan

Conditions

Conditions	Yield
With toluene; ruthenium trichloride In methanol at 20 - 83℃; for 2h; Product distribution / selectivity;
Stage #1: trimethoxysilane; ruthenium trichloride In methanol; toluene at 20 - 80℃; Heating / reflux; Stage #2: 3-chloroprop-1-ene at 78 - 83℃; for 2h;

...Expand

: 1438-82-0
1,1,1,3,3-pentamethyl-1,3-disiloxane

: C13H22OSi

A: 1067-25-0
n-propyltrimethoxysilane

B: 1254985-33-5
C11H30O5Si3

C: C12H22O2Si2

Conditions

Conditions	Yield
With tris(pentafluorophenyl)borate In hexane; toluene at 20℃;

...Expand

: 1438-82-0
1,1,1,3,3-pentamethyl-1,3-disiloxane

: C9H24O4Si2

A: 1,1,1,5,5,5-hexamethyl-3-propyl-3-[(trimethylsilyl)oxy]trisiloxane

B: 107-51-7
Octamethyltrisiloxane

C: 1067-25-0
n-propyltrimethoxysilane

D: 1254985-33-5
C11H30O5Si3

Conditions

Conditions	Yield
With tris(pentafluorophenyl)borate In hexane; toluene at 20℃; for 0.0833333h;

...Expand

: 67-56-1
methanol

: 141-57-1
n-propyltrichlorosilane

: 1067-25-0
n-propyltrimethoxysilane

Conditions

Conditions	Yield
at 20℃; pH=5.6; pH-value;

: 1067-25-0
n-propyltrimethoxysilane

: potassium propyl silicate

Conditions

Conditions	Yield
With hydrogenchloride; methanol; potassium chloride In water at 32 - 35℃; for 3.03h;	95.1%

: 1067-25-0
n-propyltrimethoxysilane

: 1365801-87-1
1-oxo-1-methyl-4-ethyl-4-hydroxymethyl-2,6-dioxa-1-phosphacyclohexane

: C12H27O6PSi

Conditions

Conditions	Yield
In 1,4-dioxane at 90℃; for 11h; Solvent; Temperature; Inert atmosphere;	94.7%

: 1067-25-0
n-propyltrimethoxysilane

: 92-44-4
2,3-naphthalenediol

: Potassium; 3-(2-propyl-1,3-dioxa-2-sila-cyclopenta[b]naphthalen-2-yloxy)-naphthalen-2-olate

Conditions

Conditions	Yield
With potassium ethoxide In ethanol Heating;	94%

: 107-46-0
Hexamethyldisiloxane

: 1067-25-0
n-propyltrimethoxysilane

A: 1,1,1,5,5,5-hexamethyl-3-propyl-3-[(trimethylsilyl)oxy]trisiloxane

B: n-PrSi(OMe)(OSiMe3)2

C: n-PrSi(OH)(OSiMe3)2

Conditions

Conditions	Yield
Stage #1: Hexamethyldisiloxane With methanol; sulfuric acid at 5 - 10℃; for 1h; Stage #2: n-propyltrimethoxysilane at 5 - 10℃; for 1.75h; Stage #3: With sulfuric acid; water more than 3 stages;	A 93.8% B n/a C n/a

...Expand

: 17455-13-9
18-crown-6 ether

: 1067-25-0
n-propyltrimethoxysilane

: 120-80-9
benzene-1,2-diol

: C15H15O4Si(1-)*C12H24KO6(1+)

Conditions

Conditions	Yield
With potassium methanolate In methanol at 20℃; for 3h; Schlenk technique; Inert atmosphere;	91%

...Expand

: 1067-25-0
n-propyltrimethoxysilane

: 824-11-3
ethriol phosphite

: C24H49O12P3Si

Conditions

Conditions	Yield
With dimethyl sulfate at 140 - 160℃; for 16h; Concentration; Temperature; Reagent/catalyst; Solvent; Inert atmosphere;	90.4%

: 107-46-0
Hexamethyldisiloxane

: 1067-25-0
n-propyltrimethoxysilane

: 1,1,1,5,5,5-hexamethyl-3-propyl-3-[(trimethylsilyl)oxy]trisiloxane

Conditions

Conditions	Yield
Stage #1: Hexamethyldisiloxane With sulfonic acid In methanol at 5 - 10℃; Stage #2: n-propyltrimethoxysilane In methanol at 5 - 10℃; for 1.75h; Stage #3: With water In methanol at 5 - 25℃; for 5h;	90%
Stage #1: Hexamethyldisiloxane With methanol; sulfuric acid at -10 - 10℃; for 1h; Stage #2: n-propyltrimethoxysilane at 5 - 10℃; for 1.75h; Stage #3: With water at 5 - 25℃; for 4h;	88.2%

: 1067-25-0
n-propyltrimethoxysilane

: C3H7F4Si(1-)*K(1+)

Conditions

Conditions	Yield
With potassium hydrogen bifluoride In water; acetone at 20℃; for 0.166667h;	89%

: 1067-25-0
n-propyltrimethoxysilane

: C3H9KO2Si

Conditions

Conditions	Yield
With water; potassium hydroxide In methanol at 40 - 110℃; for 1.5h;	78%

: 621-23-8
1,2,3-trimethoxybenzene

: 1067-25-0
n-propyltrimethoxysilane

: dimethoxy(2,4,6-trimethoxyphenyl)propylsilane

Conditions

Conditions	Yield
Stage #1: 1,2,3-trimethoxybenzene With n-butyllithium; N,N,N,N,-tetramethylethylenediamine In hexane; pentane at 20℃; for 17h; Stage #2: n-propyltrimethoxysilane In diethyl ether; hexane; pentane at 20℃; for 17h;	72%

: 1067-25-0
n-propyltrimethoxysilane

: trisodium tri-n-propylcyclotrisiloxanolate

Conditions

Conditions	Yield
With sodium hydroxide In ethanol; water for 0.5h; Reflux;	71%

: 1067-25-0
n-propyltrimethoxysilane

: 13139-86-1
4-methoxyphenyl magnesium bromide

: dimethoxy(4-methoxyphenyl)propylsilane

Conditions

Conditions	Yield
In tetrahydrofuran; diethyl ether at 20℃; for 19h;	67%

: 1067-25-0
n-propyltrimethoxysilane

: C3H7F4Si(1-)*H3N*H(1+)

Conditions

Conditions	Yield
With ammonium hydrogen difluoride In water; acetone at 20℃; Solvent;	67%

: 1067-25-0
n-propyltrimethoxysilane

: 151-10-0
1,3-Dimethoxybenzene

: dimethoxy(2,6-dimethoxyphenyl)propylsilane

Conditions

Conditions	Yield
Stage #1: 1,3-Dimethoxybenzene With n-butyllithium; N,N,N,N,-tetramethylethylenediamine In hexane; pentane at 20℃; for 17h; Stage #2: n-propyltrimethoxysilane In diethyl ether; hexane; pentane at 20℃; for 17h;	58%

: 307531-92-6
1,3,5,7,9,11,14-heptaisobutyltricyclo[7.3.3.15,11]heptasiloxane-endo-3,7,14-triol

: 1067-25-0
n-propyltrimethoxysilane

: C31H70O12Si8

Conditions

Conditions	Yield
In hexane	48%

: 150-25-4
N,N-bis-(2-hydroxyethyl)glycine

: 1067-25-0
n-propyltrimethoxysilane

: 85462-12-0
1-propyl-2,8,9-trioxa-5-aza-1-sila-bicyclo[3.3.3]undecan-3-one

Conditions

Conditions	Yield
In N,N-dimethyl-formamide; benzene

: 4420-74-0
3-(trimethoxysilyl)-1-propanethiol

: 1067-25-0
n-propyltrimethoxysilane

A: 18971-71-6
octa-n-propylsilsesquioxane

B: 161678-45-1
Si8O12(CH2CH2CH3)6((CH2)3SH)2

C: C24H56O12S2Si8

D: 161678-44-0
Si8O12(CH2CH2CH3)7(CH2)3SH

Conditions

Conditions	Yield
With hydrogenchloride In methanol at 20℃; for 504h; Yield given. Further byproducts given. Yields of byproduct given;

...Expand

: 4420-74-0
3-(trimethoxysilyl)-1-propanethiol

: 1067-25-0
n-propyltrimethoxysilane

A: 18971-71-6
octa-n-propylsilsesquioxane

B: C24H56O12S2Si8

C: C24H56O12S2Si8

D: 161678-44-0
Si8O12(CH2CH2CH3)7(CH2)3SH

Conditions

Conditions	Yield
With hydrogenchloride In methanol at 20℃; for 504h; Yield given. Further byproducts given. Yields of byproduct given;

...Expand

: 1067-25-0
n-propyltrimethoxysilane

A: 18971-71-6
octa-n-propylsilsesquioxane

B: 161678-45-1
Si8O12(CH2CH2CH3)6((CH2)3SH)2

C: C24H56O12S2Si8

D: 161678-44-0
Si8O12(CH2CH2CH3)7(CH2)3SH

Conditions

Conditions	Yield
With hydrogenchloride; 3-(trimethoxysilyl)-1-propanethiol In methanol at 20℃; for 504h; Yield given. Further byproducts given. Yields of byproduct given;

...Expand

: 1067-25-0
n-propyltrimethoxysilane

: propyl silanetriol

Conditions

Conditions	Yield
With acetic acid In isopropyl alcohol pH=3.5-5.5;
With water

: 1067-25-0
n-propyltrimethoxysilane

: 14684-31-2
methyl hypophosphite

Conditions

Conditions	Yield
With anilinium hypophosphorous salt In acetonitrile for 3h; Heating;	100 % Spectr.
With hypophosphorous acid In water; acetonitrile for 3h; Reflux; Inert atmosphere;

: 1067-25-0
n-propyltrimethoxysilane

: C5H14O3Si

Conditions

Conditions	Yield
With hydrogenchloride In acetone at 29.85℃; pH=4; Kinetics; Further Variations:; pH-values; Reagents;

: 1067-25-0
n-propyltrimethoxysilane

: 100-58-3
phenylmagnesium bromide

: (phenyl)-propyl-dimethoxysilane

: 17715-69-4
1-Bromo-2,4-dimethoxybenzene

: 1067-25-0
n-propyltrimethoxysilane

: 344927-18-0
(2,4-dimethoxyphenyl)-propyl-dimethoxysilane

Conditions

Conditions	Yield
With n-butyllithium In ethanol; hexane

Trimethoxypropylsilane Specification

The IUPAC name of n-Propyltrimethoxysilane is trimethoxy(propyl)silane. With the CAS registry number 1067-25-0, it is also named as Silane, trimethoxypropyl-. The product's categories are Alkyl; Organics; Functional Materials; Si (Classes of Silicon Compounds); Silane Coupling Agents; Silane Coupling Agents (Intermediates); Si-O Compounds; Trialkoxysilanes; Alkoxy Silanes; Crosslinkers; Crosslinking Agents, and the other registry number is 77030-43-4. Besides, it is colorless or yellowish clear liquid, which should be stored in dry inert gas in closed, cool and dry place. This chemical is stable, but reacts with moisture. Furthermore, it is incompatible with strong oxidizing agents, acids, alcohols, bases, water. In addition, its molecular formula is C₆H₁₆O₃Si and molecular weight is 164.28.

The other characteristics of this product can be summarized as: (1)EINECS: 213-926-7; (2)ACD/LogP: 1.20; (3)# of Rule of 5 Violations: 0; (4)ACD/LogD (pH 5.5): 1.2; (5)ACD/LogD (pH 7.4): 1.2; (6)ACD/BCF (pH 5.5): 4.8; (7)ACD/BCF (pH 7.4): 4.8; (8)ACD/KOC (pH 5.5): 106.98; (9)ACD/KOC (pH 7.4): 106.98; (10)H bond acceptors: 3; (11)H bond donors: 0; (12)Freely Rotating Bonds: 5; (13)Index of Refraction: 1.395; (14)Molar Refractivity: 43.79 cm³; (15)Molar Volume: 182.3 cm³; (16)Surface Tension: 20.6 dyne/cm; (17)Density: 0.9 g/cm³; (18)Flash Point: 40.6 °C; (19)Enthalpy of Vaporization: 36.35 kJ/mol; (20)Boiling Point: 142 °C at 760 mmHg; (21)Vapour Pressure: 7.14 mmHg at 25 °C.

Uses of n-Propyltrimethoxysilane: this chemical is an important material in sol-gel production. It may provide a hydrophobic surface treatment for inorganic powders or filler materials. And it is one of the catalyst components for polyolefin production with Ziegler-Natta catalysts. Additionally, it can react with Naphthalene-2,3-diol to get C₂₃H₁₉O₄Si(1-)*K(1+).

This reaction needs KOEt and Ethanol by heating. The yield is 94 %.

When you are using this chemical, please be cautious about it as the following: n-Propyltrimethoxysilane is flammable and irritating to eyes, respiratory system and skin. You should wear suitable protective clothing when use it. Moreover, in case of contact with eyes, please rinse immediately with plenty of water and seek medical advice.

People can use the following data to convert to the molecule structure.
(1)SMILES:O(C)[Si](OC)(OC)CCC
(2)InChI:InChI=1/C6H16O3Si/c1-5-6-10(7-2,8-3)9-4/h5-6H2,1-4H3
(3)InChIKey:HQYALQRYBUJWDH-UHFFFAOYAI
(4)Std. InChI:InChI=1S/C6H16O3Si/c1-5-6-10(7-2,8-3)9-4/h5-6H2,1-4H3
(5)Std. InChIKey:HQYALQRYBUJWDH-UHFFFAOYSA-N

Product Name

Trimethoxypropylsilane

Synthetic route

Trimethoxypropylsilane Specification

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