Trimethylene sulfate supplier

Name
1,3,2-DIOXATHIANE 2,2-DIOXIDE
EINECS 214-022-5
CAS No. 1073-05-8
Article Data20
CAS DataBase
Density 1.452 g/cm³
Solubility
Melting Point 58-62ºC
Formula C3H6 O4 S
Boiling Point 240.4ºC at 760 mmHg
Molecular Weight 138.144
Flash Point 99.2ºC
Transport Information
Appearance White Crystal Powder
Safety Mutation data reported. When heated to decomposition it emits toxic fumes of SO_x. See also SULFATES.
Risk Codes 40
Molecular Structure
Hazard Symbols
Synonyms 1,3-Propanediol,cyclic sulfate (8CI); Trimethylene sulfate (6CI,7CI); 1,3-Propylene sulfate;NSC 526595; Propano-1,3-diyl sulfate
PSA 60.98000
LogP 0.74890

Synthetic route

: sulfuric acid mono-(3-hydroxy-propyl) ester

: 1073-05-8
1,3,2-dioxathiane 2,2-dioxide

Conditions

Conditions	Yield
With modified ZSM-5 molecular sieve catalyst In toluene at 105 - 115℃; Temperature; Solvent; Reagent/catalyst; Inert atmosphere; Sealed tube;	92%

: 4176-55-0
2-oxo-1,3,2-dioxathiane

: 1073-05-8
1,3,2-dioxathiane 2,2-dioxide

Conditions

Conditions	Yield
With ruthenium tetroxide In chloroform; water at 0℃; for 0.0125h;	87%
With potassium permanganate In acetic acid for 1h; Ambient temperature;	20%
With ruthenium trichloride; sodium periodate; sodium hydrogencarbonate In tetrachloromethane; water; acetonitrile at 20℃; for 0.5h;	890 mg

: 504-63-2
trimethyleneglycol

: 1073-05-8
1,3,2-dioxathiane 2,2-dioxide

Conditions

Conditions	Yield
Stage #1: trimethyleneglycol With thionyl chloride In tetrachloromethane for 1.5h; Heating; Stage #2: With ruthenium trichloride; sodium periodate In water; acetonitrile at 20℃; for 1.5h; Further stages.;	87%
Stage #1: trimethyleneglycol With sodium methylate In toluene for 15h; Reflux; Stage #2: With fluorosulfonyl fluoride In dichloromethane; toluene at -10 - 0℃; for 2h; Autoclave; Inert atmosphere;	82.7%
Stage #1: trimethyleneglycol With fluorosulfonyl fluoride; sodium sulfate; cetyltrimethylammonim bromide; N-ethyl-N,N-diisopropylamine In acetonitrile at 5 - 10℃; for 1.5h; Inert atmosphere; Stage #2: With 15-crown-5; 18-crown-6 ether Reflux;	68%
With ruthenium trichloride; sodium periodate; thionyl chloride 1) CCl4, 45 min, reflux, 2) H2O, CCl4, acetonitrile, RT, 2 h; Yield given. Multistep reaction;
With sodium periodate; thionyl chloride; ruthenium trichloride Yield given. Multistep reaction;

: ruthenium (III) chloride hydrate

: 504-63-2
trimethyleneglycol

: 1073-05-8
1,3,2-dioxathiane 2,2-dioxide

Conditions

Conditions	Yield
With sodium periodate; thionyl chloride In carbon tetrachloride (CCl4); diethyl ether; water	87%

: 628-66-0
1,3-diacetoxypropane

: 77-78-1
dimethyl sulfate

: 1073-05-8
1,3,2-dioxathiane 2,2-dioxide

Conditions

Conditions	Yield
130 deg C oil bath;	56%

: 1,3-bis-sulfooxy-propane; barium compound

: 1073-05-8
1,3,2-dioxathiane 2,2-dioxide

Conditions

Conditions	Yield
at 180 - 190℃; under 4 Torr;

: 109-64-8
1,3-dibromo-propane

: 1073-05-8
1,3,2-dioxathiane 2,2-dioxide

Conditions

Conditions	Yield
With silver sulfate; xylene
With silver sulfate In xylene

barium salt of/the/ trimethylenedisulfuric acid: barium salt of/the/ trimethylenedisulfuric acid

: 1073-05-8
1,3,2-dioxathiane 2,2-dioxide

Conditions

Conditions	Yield
at 180 - 190℃; under 4 Torr;

: 504-63-2
trimethyleneglycol

oleum: oleum

A: 79431-21-3
1,3-bis-sulfooxy-propane

B: 1073-05-8
1,3,2-dioxathiane 2,2-dioxide

Conditions

Conditions	Yield
With chloroform at 60℃;

...Expand

: 37480-93-6, 54481-30-0, 59571-05-0
sodium salt of 1,3-propane-diol

: 1073-05-8
1,3,2-dioxathiane 2,2-dioxide

Conditions

Conditions	Yield
Stage #1: sodium salt of 1,3-propane-diol With sodium methylate In toluene at -10 - 10℃; for 2h; Inert atmosphere; Stage #2: With 15-crown-5 In toluene at 20℃; for 1h;	41.5 g

: 1073-05-8
1,3,2-dioxathiane 2,2-dioxide

: 872-71-9
sodium pyrrolidine-N-carbodithioate

: C13H20NO7S3(1-)*Na(1+)

Conditions

Conditions	Yield
In methanol at 20℃;	99%

: 148-18-5
sodium N,N-diethyldithiocarbamate

: 1073-05-8
1,3,2-dioxathiane 2,2-dioxide

: C13H22NO7S3(1-)*Na(1+)

Conditions

Conditions	Yield
In methanol at 20℃;	97%

: 5390-04-5
pent-1-yn-5-ol

: 1073-05-8
1,3,2-dioxathiane 2,2-dioxide

: 1383982-25-9
sodium 3-[4-(3-hydroxypropyl)-1H-1,2,3-triazol-1-yl]propyl sulfate

Conditions

Conditions	Yield
With sodium azide In water; tert-butyl alcohol at 60℃; for 0.25h; Microwave irradiation; regioselective reaction;	96%

: 148-18-5
sodium N,N-diethyldithiocarbamate

: 1073-05-8
1,3,2-dioxathiane 2,2-dioxide

: Na(1+)*C8H16NO4S3(1-)

Conditions

Conditions	Yield
In methanol at 20℃;	96%

: 1073-05-8
1,3,2-dioxathiane 2,2-dioxide

: 872-71-9
sodium pyrrolidine-N-carbodithioate

: C15H24NO8S3(1-)*Na(1+)

Conditions

Conditions	Yield
In methanol at 20℃;	95%

: 148-18-5
sodium N,N-diethyldithiocarbamate

: 1073-05-8
1,3,2-dioxathiane 2,2-dioxide

: C15H26NO8S3(1-)*Na(1+)

Conditions

Conditions	Yield
In methanol at 20℃;	92%

: 100-46-9
benzylamine

: 1073-05-8
1,3,2-dioxathiane 2,2-dioxide

: 1198271-81-6
3-(benzylammonio)propyl sulfate

Conditions

Conditions	Yield
In acetonitrile at 80℃;	91%

: 65279-33-6
C5H10NS2(1-)*Na(1+)

: 1073-05-8
1,3,2-dioxathiane 2,2-dioxide

: C13H22NO7S3(1-)*Na(1+)

Conditions

Conditions	Yield
In methanol at 20℃;	91%

: 65279-33-6
C5H10NS2(1-)*Na(1+)

: 1073-05-8
1,3,2-dioxathiane 2,2-dioxide

: C15H26NO8S3(1-)*Na(1+)

Conditions

Conditions	Yield
In methanol at 20℃;	91%

: 2510-23-8
3-Ethynylpyridine

: 1073-05-8
1,3,2-dioxathiane 2,2-dioxide

: 1383982-26-0
sodium 3-[4-(pyridin-3-yl)-1H-1,2,3-triazol-1-yl]propyl sulfate

Conditions

Conditions	Yield
With sodium azide In water; tert-butyl alcohol at 60℃; for 0.25h; Microwave irradiation; regioselective reaction;	90%

: 1073-05-8
1,3,2-dioxathiane 2,2-dioxide

: 623-47-2
propynoic acid ethyl ester

: 1383982-27-1
sodium 3-[4-(ethoxycarbonyl)-1H-1,2,3-triazol-1-yl]propyl sulfate

Conditions

Conditions	Yield
With sodium azide In water; tert-butyl alcohol at 60℃; for 0.25h; Microwave irradiation; regioselective reaction;	90%

: 1135256-40-4
C5H9NO2S2

: 1073-05-8
1,3,2-dioxathiane 2,2-dioxide

: Na(1+)*C8H14NO6S3(1-)

Conditions

Conditions	Yield
With sodium hydrogencarbonate In methanol at 20℃;	90%

: 75-64-9
tert-butylamine

: 1073-05-8
1,3,2-dioxathiane 2,2-dioxide

: 1198271-85-0
3-(tert-butylammonio)propyl sulfate

Conditions

Conditions	Yield
In acetonitrile at 80℃;	89%

: 5205-93-6
2-methyl-acrylic acid 3-dimethylamino-propyl amide

: 1073-05-8
1,3,2-dioxathiane 2,2-dioxide

: 3-((3-methacrylamidopropyl)dimethylammonio)propyl sulfate

Conditions

Conditions	Yield
With nitrobenzene In acetonitrile at 50℃; for 24h; Schlenk technique; Inert atmosphere;	88.8%

: 124-22-1
n-Dodecylamine

: 1073-05-8
1,3,2-dioxathiane 2,2-dioxide

: 1198271-83-8
3-(dodecylammonio)propyl sulfate

Conditions

Conditions	Yield
In acetonitrile at 80℃;	88%

: 1135256-40-4
C5H9NO2S2

: 1073-05-8
1,3,2-dioxathiane 2,2-dioxide

: C15H24NO10S3(1-)*Na(1+)

Conditions

Conditions	Yield
With sodium hydrogencarbonate In methanol at 20℃;	88%

: 34274-05-0
4-(3,4,5-trimethoxybenzyl)morpholine

: 1073-05-8
1,3,2-dioxathiane 2,2-dioxide

: 1529658-14-7
C17H27NO8S

Conditions

Conditions	Yield
In acetonitrile at 40℃; for 49h;	88%

: 83476-52-2
propargyl 2,3,4,6-tetra-O-acetyl-α-D-mannopyranoside

: 1073-05-8
1,3,2-dioxathiane 2,2-dioxide

: 1383982-28-2
sodium 3-[4-(2',3',4',6'-tetra-O-acetyl-α-D-mannopyranosyloxymethyl)-1H-1,2,3-traizol-1-yl]propyl sulfate

Conditions

Conditions	Yield
With sodium azide In water; tert-butyl alcohol at 60℃; for 0.25h; Microwave irradiation; regioselective reaction;	87%

: 108-91-8
cyclohexylamine

: 1073-05-8
1,3,2-dioxathiane 2,2-dioxide

: 747374-68-1
3-(cyclohexylammonio)propyl sulfate

Conditions

Conditions	Yield
In acetonitrile at 80℃;	86%

: 1135256-40-4
C5H9NO2S2

: 1073-05-8
1,3,2-dioxathiane 2,2-dioxide

: C13H20NO9S3(1-)*Na(1+)

Conditions

Conditions	Yield
With sodium hydrogencarbonate In methanol at 20℃;	85%

: 65567-06-8, 4541-02-0
lithium diphenylphosphide

: 1073-05-8
1,3,2-dioxathiane 2,2-dioxide

: C15H16O4PS(1-)*Li(1+)

Conditions

Conditions	Yield
In tetrahydrofuran at 0 - 5℃;	84%

: 75-15-0
carbon disulfide

: 109-89-7
diethylamine

: 1073-05-8
1,3,2-dioxathiane 2,2-dioxide

: Na(1+)*C8H16NO4S3(1-)

Conditions

Conditions	Yield
With β‐cyclodextrin; sodium hydroxide In water at 35 - 65℃; Microwave irradiation;	84%

...Expand

: 1003-03-8
Cyclopentamine

: 1073-05-8
1,3,2-dioxathiane 2,2-dioxide

: 1198271-86-1
3-(cyclopentylammonio)propyl sulfate

Conditions

Conditions	Yield
In acetonitrile at 80℃;	83%

: 1073-05-8
1,3,2-dioxathiane 2,2-dioxide

: 872-71-9
sodium pyrrolidine-N-carbodithioate

: Na(1+)*C8H14NO4S3(1-)

Conditions

Conditions	Yield
In methanol at 20℃;	82%

: 123-75-1
pyrrolidine

: 75-15-0
carbon disulfide

: 1073-05-8
1,3,2-dioxathiane 2,2-dioxide

: Na(1+)*C8H14NO4S3(1-)

Conditions

Conditions	Yield
With β‐cyclodextrin; sodium hydroxide In water at 35 - 65℃; Microwave irradiation;	80%

...Expand

Trimethylene sulfate Chemical Properties

IUPAC Name:1,3,2-Dioxathiane 2,2-dioxide (1073-05-8)
Synonyms: 1,3-Propanediol, cyclic sulphate ; 1,3-Propylene sulfate ; 1,3-Propylenesulfate ; Trimethylene sulfate ; Trimethylenesulfate ; 1,3,2-Dioxathiane 2,2-dioxide ; 1,3-Propanediol cyclic sulfate ; 1,3-Propylenesulphate
CAS: 1073-05-8
MF: C₃H₆O₄S
MW: 138.14
MS:
EINECS: 214-022-5
Product Categories: Heterocyclic Compounds
Mol File: 1073-05-8.mol
Surface Tension: 41.8 dyne/cm
Density: 1.452 g/cm³
Flash Point: 99.2 °C
Melting point:58-62°C
Enthalpy of Vaporization: 45.8 kJ/mol
Boiling Point: 240.4 °C at 760 mmHg
Vapour Pressure: 0.0589 mmHg at 25°C
Appearance: Trimethylene sulfate (1073-05-8) is white solid.

Trimethylene sulfate Uses

1.Trimethylene sulfate (1073-05-8) is used in lithium secondary battery electrolyte additive ，can improve the electrolyte at low temperature performance while preventing PC molecules embedded in the graphite electrode;
2.Trimethylene sulfate (1073-05-8) is used in organic synthesis, pharmaceutical intermediates.

Trimethylene sulfate Toxicity Data With Reference

1.		dnr-omi 690 µg/plate		BIZNAT Biologisches Zentralblatt. 95 (1976),463.
2.		mmo-sat 100 nmol/plate		CBINA8 Chemico-Biological Interactions. 19 (1977),241.

Trimethylene sulfate Consensus Reports

Reported in EPA TSCA Inventory.

Trimethylene sulfate Safety Profile

Hazard Codes Xn
Risk Statements 40
40: Limited evidence of a carcinogenic effect
Safety Statements 22-36
22: Do not breathe dust
36: Wear suitable protective clothing
RTECS TY4560000

Product Name

1,3,2-DIOXATHIANE 2,2-DIOXIDE

Synthetic route

Trimethylene sulfate Chemical Properties

Trimethylene sulfate Uses

Trimethylene sulfate Toxicity Data With Reference

Trimethylene sulfate Consensus Reports

Trimethylene sulfate Safety Profile

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