Vinyl chlorocarbonate supplier

Name
VINYL CHLOROFORMATE
EINECS 225-874-2
CAS No. 5130-24-5
Article Data10
CAS DataBase
Density 1.21 g/cm³
Solubility
Melting Point
Formula C₃H₃ClO₂
Boiling Point 72.1 °C at 760 mmHg
Molecular Weight 106.509
Flash Point 24 °F
Transport Information UN 3390 6
Appearance clear colourless liquid
Safety 16-26-36-45-36/37
Risk Codes 23/24/25-34-11
Molecular Structure
Hazard Symbols F；T
Synonyms Formicacid, chloro-, vinyl ester (7CI,8CI);Vinyl chlorocarbonate;Vinylchloroformate;Vinyloxycarbonyl chloride;ethenyl carbonochloridate;carbonochloridic acid, ethenyl ester;
PSA 26.30000
LogP 1.50530

Synthetic route

: 75-44-5
phosgene

: 6213-94-1
trimethylsiloxyethene

: 5130-24-5
Vinyl chloroformate

Conditions

Conditions	Yield
palladium diacetate In hexanedinitrile at -2 - 2℃; for 63h; Product distribution / selectivity;	85.2%
With palladium diacetate In acetonitrile

: 124-05-0
ethylenebis(chloroformate)

: 5130-24-5
Vinyl chloroformate

Conditions

Conditions	Yield
at 425 - 460℃; Pyrolysis;

: 124-05-0
ethylenebis(chloroformate)

A: 75-34-3
1,1-dichloroethane

B: 5130-24-5
Vinyl chloroformate

C: 50893-53-3
carbonochloridic acid 1-chloro-ethyl ester

D: 627-11-2
2-Chloroethyl chloroformate

Conditions

Conditions	Yield
at 460℃; Produkt 5: 1.2-Dichlor-aethan.Pyrolysis;

...Expand

: 627-11-2
2-Chloroethyl chloroformate

: 5130-24-5
Vinyl chloroformate

Conditions

Conditions	Yield
Pyrolysis;
at 425 - 460℃; Pyrolysis;

: 75-44-5
phosgene

: 4387-13-7
bis(formylmethyl)mercury

: 5130-24-5
Vinyl chloroformate

Conditions

Conditions	Yield
In diethyl ether; diethylene glycol dimethyl ether

: 75-44-5
phosgene

: 557-75-5
ethenol

: 5130-24-5
Vinyl chloroformate

Conditions

Conditions	Yield
With pyridine In diethyl ether 1.) 1 h, 0 deg C, 2.) 8 h, 25 deg C;

: 5130-24-5
Vinyl chloroformate

: 203570-57-4
2-Benzyl-4,4-diphenyl-octahydro-2-aza-4-sila-inden-7-one

: 203570-62-1
7-Oxo-4,4-diphenyl-octahydro-2-aza-4-sila-indene-2-carboxylic acid vinyl ester

Conditions

Conditions	Yield
With triethylamine In 1,2-dichloro-ethane for 2.5h; Ambient temperature;	100%

: 5130-24-5
Vinyl chloroformate

: 189363-85-7
2-(3,4-dimethoxyphenyl)-2-cyclohexen-1-ol

: carbonic acid 2-(3,4-dimethoxy-phenyl)-cyclohex-2-enyl ester vinyl ester

Conditions

Conditions	Yield
With pyridine In dichloromethane at 0℃;	100%

: 5130-24-5
Vinyl chloroformate

: 215609-91-9
2-(3,4-methylenedioxyphenyl)-2-cyclohexen-1-ol

: 335371-05-6
carbonic acid 2-benzo[1,3]dioxol-5-yl-cyclohex-2-enyl ester vinyl ester

Conditions

Conditions	Yield
With pyridine In dichloromethane at 0℃;	100%

: 719-80-2
Ethyl diphenylphosphinite

: 5130-24-5
Vinyl chloroformate

: 1237132-78-3
diphenylvinyloxycarbonylphosphinoxide

Conditions

Conditions	Yield
at 0 - 20℃; for 3.25h; Michaelis-Arbuzov reaction;	99%

: 5130-24-5
Vinyl chloroformate

: 144152-46-5
3-(tbutyldimethylsilyl)-14-acetoxy-7,8-dihydromorphinone

: 144152-44-3
N-vinyloxycarbonyl-3-(tbutyldimethylsilyl)-14-acetoxy-7,8-dihydromorphinone

Conditions

Conditions	Yield
In 1,2-dichloro-ethane for 72h; Heating;	98%

: 5130-24-5
Vinyl chloroformate

: 14β-methoxy-7,8-dihydrocodeinone

: 14β-methoxy-7,8-dihydro-N-<(vinyloxy)carbonyl>norcodeinone

Conditions

Conditions	Yield
In 1,2-dichloro-ethane at 50℃; for 120h;	97%

: 5130-24-5
Vinyl chloroformate

: 57822-91-0
2,2,4,4-Tetramethyl-1,3-oxazolidine

: vinyl 2,2,4,4-tetramethyl-1,3-oxazolidine-3-carboxylate

Conditions

Conditions	Yield
With sodium carbonate In dichloromethane at 20℃; for 5h;	97%

: 126811-06-1
(1R)-9-methyl-9-azabicyclo[4.2.1]nonan-2-one

: 5130-24-5
Vinyl chloroformate

: 200402-26-2
(1R,6R)-2-Oxo-9-aza-bicyclo[4.2.1]nonane-9-carboxylic acid vinyl ester

Conditions

Conditions	Yield
With potassium carbonate In dichloromethane	96%

: 5130-24-5
Vinyl chloroformate

: 9-methyl-9-aza-bicyclo[4.2.1]nonan-2-one

: 2-oxo-9-aza-bicyclo[4.2.1]nonane-9-carboxylic acid vinyl ester

Conditions

Conditions	Yield
With potassium carbonate In dichloromethane Substitution;	96%

: 5130-24-5
Vinyl chloroformate

: 350678-19-2
2-[(tert-butyldimethylsiloxy)methyl]cyclohex-2-enol

: 335371-10-3
1-tert-butyldimethylsilanyloxymethyl-6-vinyloxycarbonyloxy-1-cyclohexene

Conditions

Conditions	Yield
With pyridine In dichloromethane at 0℃; for 1h;	96%

: 5130-24-5
Vinyl chloroformate

: 110-70-3
N,N`-dimethylethylenediamine

: 1158919-28-8
C10H16N2O4

Conditions

Conditions	Yield
With sodium carbonate In dichloromethane; water at 0 - 20℃; for 2.66667h; Inert atmosphere;	96%

: 5130-24-5
Vinyl chloroformate

: 872-36-6
vinylene carbonate

Conditions

Conditions	Yield
With triethylamine at 34 - 49℃; for 0.0555556h; Temperature; Flow reactor; Sonication; Inert atmosphere;	95.6%

: 5130-24-5
Vinyl chloroformate

: trans-decahydro-4a-(3-methoxyphenyl)-2-methyl-6-methyleneisoquinoline

: 137517-94-3
ethenyl (+/-)-trans-3,4,4a,5,8,8a-hexahydro-4a-(3-methoxyphenyl)-2(1H)-isoquinolinecarboxylate

Conditions

Conditions	Yield
With potassium carbonate In 1,2-dichloro-ethane for 1.5h; Heating;	95%

: 5130-24-5
Vinyl chloroformate

: C12H18N2O

: C14H18N2O3

Conditions

Conditions	Yield
With potassium carbonate In dichloromethane Heating;	95%

: 5130-24-5
Vinyl chloroformate

: C12H18N2O

: C14H18N2O3

Conditions

Conditions	Yield
With potassium carbonate In dichloromethane Heating;	95%

: 5130-24-5
Vinyl chloroformate

: C12H18N2O

: C14H18N2O3

Conditions

Conditions	Yield
With potassium carbonate In dichloromethane Heating;	95%

: 143-28-2
oleoyl alcohol

: 5130-24-5
Vinyl chloroformate

: 1188536-57-3
cis-octadec-9-enyl vinyl carbonate

Conditions

Conditions	Yield
With pyridine at 0 - 50℃; Inert atmosphere;	95%

: 70423-78-8
9-methyl-9-azabicyclo[4.2.1]nonan-2-one

: 5130-24-5
Vinyl chloroformate

: 284039-55-0
9-vinyloxycarbonyl-9-azabicyclo[4.2.1]nonan-2-one

Conditions

Conditions	Yield
Stage #1: 9-methyl-9-azabicyclo[4.2.1]nonan-2-one With potassium carbonate In dichloromethane at 20℃; for 1h; Stage #2: Vinyl chloroformate In dichloromethane at 20℃; for 48h; Further stages.;	94%

: 5130-24-5
Vinyl chloroformate

: 192803-37-5
3-tert-butyl-2,5-dihydroxybenzaldehyde

: 3-tert-butyl-4-hydroxy-5-oxomethylphenyl vinyl carbonate

Conditions

Conditions	Yield
With pyridine In chloroform at 20℃; for 4h;	94%

: 950676-27-4
3-{4,5-dimethoxy-2-[2-(4-methylbenzenesulfonylamino)ethyl]phenyl}prop-2-enol

: 5130-24-5
Vinyl chloroformate

: ethenyl (Z)-3-{4,5-dimethoxy-2-[2-(4-methylbenzenesulfonylamino)ethyl]phenyl}prop-2-enyl carbonate

Conditions

Conditions	Yield
With pyridine In dichloromethane at 0℃; for 3h;	94%

: 110-63-4
Butane-1,4-diol

: 5130-24-5
Vinyl chloroformate

: 1158919-26-6
1,4-bis(vinyloxycarbonyloxy)butane

Conditions

Conditions	Yield
With pyridine at 0 - 50℃; Inert atmosphere;	94%

: 5130-24-5
Vinyl chloroformate

: 151562-12-8
(+/-)-6-methoxydimetindene

: 173070-30-9
{2-[6-Methoxy-3-(1-pyridin-2-yl-ethyl)-1H-inden-2-yl]-ethyl}-methyl-carbamic acid vinyl ester

Conditions

Conditions	Yield
With N,N,N',N'-tetramethyl-1,8-diaminonaphthalene In 1,2-dichloro-ethane 15 min, -5 to -10 deg C; 30 min, 60-70 deg C;	93%

: 5130-24-5
Vinyl chloroformate

: 640727-43-1
(Z)-3-{4,5-dimethoxy-2-[2-(trifluoroacetylamino)ethyl]phenyl}prop-2-enol

: 950676-31-0
ethenyl (Z)-3-{4,5-dimethoxy-2-[2-(trifluoroacetylamino)ethyl]phenyl}prop-2-enyl carbonate

Conditions

Conditions	Yield
With pyridine In dichloromethane at 0℃; for 3h;	93%

: 872036-41-4
(S)-(-)-4-chloro-2-(1-hydroxyethyl)pyridine

: 5130-24-5
Vinyl chloroformate

: 1207742-70-8
(1S)-(-)-1-(4-chloropyridin-2-yl)ethyl vinyl carbonate

Conditions

Conditions	Yield
With pyridine In dichloromethane at 0 - 20℃;	93%

: 5130-24-5
Vinyl chloroformate

: 1332523-77-9
(Z)-3-{4,6-dimethoxy-2-[2-(trifluoroacetylamino)ethyl]phenyl}prop-2-enol

: 1332523-71-3
ethenyl (Z)-3-{4,6-dimethoxy-2-[2-(trifluoroacetylamino)-ethyl]phenyl}prop-2-enyl carbonate

Conditions

Conditions	Yield
With pyridine In dichloromethane at 0℃; for 3h; Inert atmosphere;	93%

: 5130-24-5
Vinyl chloroformate

: 1314093-93-0
1,3-bis(4-methoxybenzyloxy)-6-[(Z)-3-hydroxyprop-1-enyl]5-[2-(trifluoroacetamido)ethyl]benzene

: 1,3-bis(4-methoxybenzyloxy)-4-(3-ethenyloxycarbonyloxyprop-1-enyl)-5-[ 2-(trifluoroacetamido)ethyl]benzene

Conditions

Conditions	Yield
With pyridine at 0℃; for 3h;	93%

: 6246-48-6, 35278-77-4, 36615-19-7
geranylamine

: 5130-24-5
Vinyl chloroformate

: 7647-14-5
sodium chloride

Conditions

Conditions	Yield
With triethylamine	93%

: 5130-24-5
Vinyl chloroformate

: 193538-84-0
(2S,3R)-3-methylsulfanylmethyl-1-(1-phenylethyl)-pyrrolidine-2-carboxylic acid ethyl ester

: 193538-86-2
(2S,3R)-3-methylsulfanylmethyl-1-(1-phenylethyl)-pyrrolidine-1,2-carboxylic acid 2-ethyl ester 1-vinyl ester

Conditions

Conditions	Yield
In 1,2-dichloro-ethane for 192h; Heating;	92%

: 5130-24-5
Vinyl chloroformate

: 169437-96-1
(3S,5S)-1-ethynyl-3,5-dihydroxy-2-methylcyclohex-1-ene

: 797037-97-9
(3S,5S)-1-ethynyl-2-methyl-3,5-bis[(vinyloxy)carbonyloxy]-1-cyclohexene

Conditions

Conditions	Yield
With pyridine In dichloromethane for 1h;	92%

: 5130-24-5
Vinyl chloroformate

: 25-ethoxymethyloxyvitamin D3

: 3-O-(vinyloxy)carbonyl-25-ethoxymethyloxyvitamin D3

Conditions

Conditions	Yield
With pyridine at 0℃;	92%
With triethylamine In dichloromethane at 0 - 20℃; for 12h;	92%

Vinyl chlorocarbonate Specification

The Vinyl chlorocarbonate, with the CAS registry number 5130-24-5 and EINECS registry number 225-874-2, has the systematic name and IUPAC name of ethenyl carbonochloridate. It is a kind of clear colourless liquid, and belongs to the followiing product categories: Monomers; Polymer Science; Vinyl Esters. And the molecular formula of the chemical is C₃H₃ClO₂. What' s more, it should bestored at 2-8°C.

The characteristics of Vinyl chlorocarbonate are as followings: (1)ACD/LogP: 1.51; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 1.51; (4)ACD/LogD (pH 7.4): 1.51; (5)ACD/BCF (pH 5.5): 8.24; (6)ACD/BCF (pH 7.4): 8.24; (7)ACD/KOC (pH 5.5): 157.52; (8)ACD/KOC (pH 7.4): 157.52; (9)#H bond acceptors: 2; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 2; (12)Polar Surface Area: 26.3 Å²; (13)Index of Refraction: 1.42; (14)Molar Refractivity: 22.29 cm³; (15)Molar Volume: 88 cm³; (16)Polarizability: 8.83×10^-24cm³; (17)Surface Tension: 28.6 dyne/cm; (18)Density: 1.21 g/cm³; (19)Enthalpy of Vaporization: 31.35 kJ/mol; (20)Boiling Point: 72.1 °C at 760 mmHg; (21)Vapour Pressure: 120 mmHg at 25°C.

Uses of Vinyl chlorocarbonate: It can react with diazomethane to produce vinyl diazoacetate, and the yield is about 92%.

You should be cautious while dealing with this chemical. It is highly flammable chemical which may cause burns. And it is toxic by inhalation, in contact with skin and if swallowed. Therefore, you had better take the following instructions: Keep away from sources of ignition - No smoking; Wear suitable protective clothing and gloves, and if in case of contacting with eyes, rinse immediately with plenty of water and seek medical advice; In case of accident or if you feel unwell, seek medical advice immediately (show label where possible).

Addtionally, the following datas could be converted into the molecular structure:
(1)SMILES: ClC(=O)O\C=C
(2)InChI: InChI=1/C3H3ClO2/c1-2-6-3(4)5/h2H,1H2
(3)InChIKey: PQLFROTZSIMBKR-UHFFFAOYAD

Product Name

VINYL CHLOROFORMATE

Synthetic route

Vinyl chlorocarbonate Specification

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