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Inner Mongolia CAMO Rare Earth Co.,Ltd

#Gadolinium Chloride Anhydrous# is a white powder, also known as gadolinium chloride (anhydrous), ultra dry gadolinium chloride and gadolinium trichloride. This product is an inorganic compound of high-purity gadolinium prepared for the pharmaceutica

Gadolinium Chloride Anhydrous(High quality)

Cas:10138-52-0

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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

Gadolinium chloride(GdCl3)

Cas:10138-52-0

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Henan Tianfu Chemical Co., Ltd.

Now we would like to update our product list for you, kindly check the below information: 1. Catalyst series ( such as Noble Metal Catalyst, Phosphorous ligand, etc ) 2. Pharmaceutical Intermediate ( such as diabtes series, Anti

10138-52-0

Cas:10138-52-0

Min.Order:1 Kilogram

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 10138-52-0 with best quality

Cas:10138-52-0

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

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Shanghai Minstar Chemical Co., Ltd

Product Name: GADOLINIUM CHLORIDE CAS: 10138-52-0 MF: Cl3Gd MW: 263.61 EINECS: 233-386-6 Mol File: 10138-52-0.mol GADOLINIUM CHLORIDE Structure GADOLINIUM CHLORIDE Chemical Properties Melting point 609°C density 4,52 g

GADOLINIUM CHLORIDE

Cas:10138-52-0

Min.Order:1 Gram

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Qingdao Beluga Import and Export Co., LTD

GADOLINIUM CHLORIDE CAS:10138-52-0 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic inte

GADOLINIUM CHLORIDE CAS:10138-52-0

Cas:10138-52-0

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Gadolinium chloride(GdCl3)

Cas:10138-52-0

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:10138-52-0

Cas:10138-52-0

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Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

GADOLINIUM CHLORIDE

Cas:10138-52-0

Min.Order:1 Gram

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Gadolinium chloride(GdCl3)

Cas:10138-52-0

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Gadolinium(III) chloride manufacturer

Cas:10138-52-0

Min.Order:10 Gram

FOB Price: $100.0

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providing h

Factory Supply Gadolinium chloride

Cas:10138-52-0

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Type:Other

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Henan Kanbei Chemical Co.,LTD

High quality, competitive price, fast delivery and first-class service we possesses have won the trust and praise of customers. Standard: BP/USP/EP The purity is equal or greater than 99%. As a supplier, we can provide high-quality products. Cle

Gadolinium Chloride Anhydrous

Cas:10138-52-0

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Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

Gadolinium(III) chloride

Cas:10138-52-0

Min.Order:1 Gram

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Shanghai Seasonsgreen Chemical Co.,Ltd

Shanghai Seasonsgreen Chemical is a high-tech research and development, production, sale and custom synthesis set in one high-tech chemical products enterprises. Our sales and marketing division is located in Shanghai, serving international pharmaceu

lower price High quality GADOLINIUM CHLORIDE

Cas:10138-52-0

Min.Order:1 Kilogram

FOB Price: $1.0

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Gadolinium chloride

Cas:10138-52-0

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Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec Gadolinium(III) chloride G24750 100g

Cas:10138-52-0

Min.Order:1 bottle

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Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

GADOLINIUM CHLORIDE

Cas:10138-52-0

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Gadolinium chloride(GdCl3)

Cas:10138-52-0

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Hangzhou Ocean Chemical Co., Ltd.

1.Quality control, test sample before shipping and keep sample for 3 years after shipping;2. Prompt shipment with professional documents;3. Packing as your request, with photo before shipment;454. Mixed container, we can mix different items in one co

Gadolinium (III) Chloride Anhydrous

Cas:10138-52-0

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Wuhan Circle Star Chem-medical Technology co.,Ltd.

good quality, competitive price, thoughtful after sale serviceAppearance:white powder Storage:Keep it in dry,shady and cool place Package:25kg,50kg,180kg,200kg,250kg,1000kg,customization Application:Pharma;Industry;Agricultural;chemical reaserch Tran

Gadolinium chloride

Cas:10138-52-0

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BOC Sciences

We are committed to providing our customers with the best products and services at the most competitive prices.Appearance:powder Storage:Room temperature with sealed well Package:according to the clients requirement Application:Use as primary and sec

Gadolinium chloride

Cas:10138-52-0

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Hangzhou Fandachem Co.,Ltd

Gadolinium chloride(GdCl3) cas 10138-52-0Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

Gadolinium chloride(GdCl3) cas 10138-52-0

Cas:10138-52-0

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Hunan Russell Chemicals Technology Co.,Ltd

low price and high purityAppearance:solid or liquid Storage:in sealed air resistant place Package:As customer require Application:Pharma;Industry;Agricultural Transportation:by sea or by airplane Port:any port in China

Shanghai Yuanye Bio-Technology Co., Ltd.

Known for its best quality and competitve price, this chemicals we offered is widely appreciated by our customers.Appearance:White powder Storage:keep sealed and keep from direct light Package:According client's requirements Application:pharmaceutica

Gadolinium(III) chloride manufacturer

Cas:10138-52-0

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ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

Gadolinium(III) chloride

Cas:10138-52-0

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LEAP CHEM Co., Ltd.

Best Seller, High Quality, Competitive Price, Fast Delivery, Quick ResponseAppearance:powder, or liquid Storage:Stored in room temperature, ventilated place Package:Bottle, barrel, cargo, container, etc. Application:Pharmaceuticals, intermediates, AP

Gadolinium(III)chloride

Cas:10138-52-0

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NUTROCHEM- MANUFACTURE PLACE

best seller Application:API

Gadolinium(III) chloride

Cas:10138-52-0

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HWRK Chem

in store Package:100g Application:Organic Chemicals

GADOLINIUM CHLORIDE

Cas:10138-52-0

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Shaanxi Mingqi Chemical Co., Ltd

Known for its best quality and competitve price, this chemicals we offered is widely appreciated by our customers. Our advantages:1, High quality with competitive price:1) Standard:BP/USP/EP/Enterprise standard2) All Purity≥99%3) We are manufacturer

Gadolinium(III) chloride manufacturer

Cas:10138-52-0

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Synthetic route

[Gd(chloride)2(water)6]Cl

[Gd(chloride)2(water)6]Cl

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

Conditions
ConditionsYield
In neat (no solvent, solid phase) byproducts: H2O; Schlenk techniques; heating Gd compd. under vacuum (1E-3 Torr);99%
gadolinium(III) oxide

gadolinium(III) oxide

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

Conditions
ConditionsYield
With HCl; NH4Cl In hydrogenchloride soln. evapd. at 80°C in vac.; residue heated at 1E-3 Torr to 430°C; distn. (1E-5 Torr, Ta vessel);90%
With hydrogenchloride In hydrogenchloride Gd2O3 dissolved in concd. HCl; soln. evapd., residual chloride purified by high-temperature react. with NH4Cl (J.Kutscher and A.Schneider, Z.Anorg.Allg.Chem., 389 (1972) 157);
In not given
J.F. Desreux, in Lanthanide Probes in Life, Chemical and Earth Science. Theory and Practice, ed. J.-C. G. Buenzli and G.R. Choppin, Elsevier Science Publ. B.V. Amsterdam, 1989, ch. 2, pp. 43-64;
hydrogenchloride
7647-01-0

hydrogenchloride

gadolinium(III) oxide

gadolinium(III) oxide

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

Conditions
ConditionsYield
In hydrogenchloride metal oxide treated with 1:1 hydrochloric acid; soln. filtered, evapd. to dryness, crystals dried in vaccum dessicator over CaCl2;85%
In water dissolving of Gd2O3 in a slight excess of concd. HCl in doubly distd. water; evapn. of excess HCl;
In neat (no solvent) oxide was treated with concd. HCl; evapd.; residue dissolved in H2O; evapd.;
gadolinium(III) oxide

gadolinium(III) oxide

erbium(III) oxide

erbium(III) oxide

potassium chloride

potassium chloride

chlorine
7782-50-5

chlorine

A

erbium(III) chloride
10138-41-7

erbium(III) chloride

B

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

Conditions
ConditionsYield
With pyrographite In gas byproducts: CO; by chlorination-chem. vapor transport react.; mixt. of Er2O3 and Gd2O3 with carbon and KCl (1:1:6:1 at. ratio) placed in alumina reactor and chlorinated with dry Cl2 (20 cm**3/min) at 800 K for 2 h; gas replace by Ar:Cl2 at 800-1300 K; detn. of separation factor;A 40.58%
B 14.91%
gadolinium(III) oxide

gadolinium(III) oxide

aluminium chloride dimer

aluminium chloride dimer

A

aluminum oxochloride

aluminum oxochloride

B

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

Conditions
ConditionsYield
In neat (no solvent) Al2Cl6 prepd. from Al and Cl2; in Duran tube, at 400°C (Cl2); chemical vapour phase transport with Al2Cl6 from 400 to 310°C, 24 h;A n/a
B 14%
gadolinium(III) oxide

gadolinium(III) oxide

ammonium chloride

ammonium chloride

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

Conditions
ConditionsYield
according to Meyer, G., Ax, P., Mater. Res. Bull. 1982, 17, 1447.;
In neat (no solvent) byproducts: NH3, H2O; (Ar); excess of NH4Cl; 520 K for 4 h; removal of excess of NH4Cl at 700 K in vac.; sublimation (1250 K);
gadolinium(III) chloride hydrate

gadolinium(III) chloride hydrate

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

Conditions
ConditionsYield
With NH4Cl In neat (no solvent) heating of GdCl3*99H2O in the presence of NH4Cl (Handbuch der preparativen anorganischen Chemie, Herausg. G. Brauer, Studgardt, 1975);
With NH4Cl; chlorine byproducts: H2O; crystalline hydrate mixt. with ammonium chloride dehydration in chlorinestream;
gadolinium(III) oxide

gadolinium(III) oxide

thionyl chloride
7719-09-7

thionyl chloride

A

gadolinium(III) oxochloride

gadolinium(III) oxochloride

B

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

Conditions
ConditionsYield
In neat (no solvent)
In neat (no solvent)
gadolinium(III) oxide

gadolinium(III) oxide

aluminium trichloride
7446-70-0

aluminium trichloride

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

Conditions
ConditionsYield
In neat (no solvent) absence of moisture; large excess AlCl3, evacuated quartz tube, 573 K; fractional sublimation over 450 to 650 K gradient, removal of residual AlCl3 on heating in Cl2/N2 stream;
tetrachloromethane
56-23-5

tetrachloromethane

gadolinium(III) oxide

gadolinium(III) oxide

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

Conditions
ConditionsYield
dry box, nitrogen stream; direct chlorination using CCl4;
at 550°C, 15 h;
In neat (no solvent) heating to 825 K in 4 - 5 h, chlorination by isothermal treatment in a stream of CCl4 at 825 K for 5 - 6 h; elem. anal.;
gadolinium(III) oxide

gadolinium(III) oxide

chlorine
7782-50-5

chlorine

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

Conditions
ConditionsYield
With pyrographite In solid byproducts: CO; at 800°C for 2 h;
With aluminium trichloride; pyrographite In neat (no solvent) byproducts: CO; chlorination at 800 K for 2 h, heating up to 1300 K in CO-HCl mixt., CVTalong temp. gradient at 1300 K for 6 h;
With aluminium trichloride; pyrographite In neat (no solvent) chlorinating of rare earth/carbon (molar ration 3/1) mixt. (Cl2 flow rate 20 ml/min, 800 K, 2 h), heating in CO/HCl flow (800-1200 K), chemical vapor transport (AlCl3, 1300 K, 6 h, CO carrier gas, 40 ml/min); atomic emission spectrometric monitoring;
gadolinium(III) chloride hexahydrate

gadolinium(III) chloride hexahydrate

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

Conditions
ConditionsYield
In neat (no solvent) byproducts: water; dehydration in an HCl-stream;
With SOCl2 In neat (no solvent) refluxed for 24 h;
hydrogenchloride
7647-01-0

hydrogenchloride

Gd2O3

Gd2O3

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

Conditions
ConditionsYield
In hydrogenchloride Gd2O3 was dissolved in 35% HCl;
hydrogenchloride
7647-01-0

hydrogenchloride

gadolinium

gadolinium

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

Conditions
ConditionsYield
In not given
gadolinium

gadolinium

chlorine
7782-50-5

chlorine

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

Conditions
ConditionsYield
In solid matrix Gd is volatilised by radiation heating (1350-1500°C), a mixt. ofchlorine and argon was passed to a support cooled to 12-15 K; the matrice is formed over 1-2,5 h;
Irradiation (UV/VIS); Gd evapn. (tantalum cell, ca. 2000 K) into argon matrix containing 5 % Cl2, irradiation (GE medium pressure mercury lamp (100 W) with glass envelope removed); trapping of molecules in solid Ar or Ne matrix;
gadolinium trichloride hydrate

gadolinium trichloride hydrate

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

Conditions
ConditionsYield
With ammonium chloride In neat (no solvent) heating of mixt. of GdCl3-hydrate and NH4Cl in Cl2/HCl stream;
3NH4(1+)*Gd(3+)*6Cl(1-)=(NH4)3GdCl6

3NH4(1+)*Gd(3+)*6Cl(1-)=(NH4)3GdCl6

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

Conditions
ConditionsYield
Thermal decompn. of starting material above 400°C.; X-ray diffraction, thermal anal.;
gadolinium(III) bis(4-N-(4'antipyrylmethylidene)aminoantipyrine) perchlorate

gadolinium(III) bis(4-N-(4'antipyrylmethylidene)aminoantipyrine) perchlorate

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

Conditions
ConditionsYield
In neat (no solvent) Kinetics; sample heating in thermal analyser in N2 at 20 K/min up to 800°C; TG, DTG;
gadolinium(III) trifluoromethanesulfonate

gadolinium(III) trifluoromethanesulfonate

A

Carbonyl fluoride
353-50-4

Carbonyl fluoride

B

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

Conditions
ConditionsYield
byproducts: SO2; above 400°C;
byproducts: SO2; above 400°C;
gadolinium(III) trifluoromethanesulfonate

gadolinium(III) trifluoromethanesulfonate

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

Conditions
ConditionsYield
thermal decompn. at 500-1000°C;
thermal decompn. at 500-1000°C;
thermal decompn. at 500-1000°C;
GdCl3*2(acetylacetone imine)

GdCl3*2(acetylacetone imine)

A

4-amino-3-penten-2-one
1118-66-7

4-amino-3-penten-2-one

B

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

Conditions
ConditionsYield
In neat (no solvent) 320°C; thermogravimetric anal.;
GdCl3*H2O
114364-08-8

GdCl3*H2O

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

Conditions
ConditionsYield
In neat (no solvent) byproducts: H2O; sample heating at 150-160°C till the weight loss reached the calculated value; gravimetric monitoring;
GdClH0.91

GdClH0.91

A

gadolinium

gadolinium

B

Gd2Cl3

Gd2Cl3

C

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

Conditions
ConditionsYield
In neat (no solvent) byproducts: H2; decompn. 290 h at 1123 K in a Ta capsule in a Pt ampoule (under 1 bar O2); detn. by TG;
1.33Gd(3+)*0.67Y(3+)*6NH2CH2COOH*9H2O*6ClO4(1-)=Gd1.33Y0.67(NH2CH2COOH)6(H2O)4(ClO4)6*5H2O

1.33Gd(3+)*0.67Y(3+)*6NH2CH2COOH*9H2O*6ClO4(1-)=Gd1.33Y0.67(NH2CH2COOH)6(H2O)4(ClO4)6*5H2O

A

yttrium(III) chloride
10361-92-9

yttrium(III) chloride

B

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

Conditions
ConditionsYield
In neat (no solvent, solid phase) heating of metal complex;
N-tris(2-aminoethyl)amine-N',N', N'', N'', N''', N'''-hexaacetic acid

N-tris(2-aminoethyl)amine-N',N', N'', N'', N''', N'''-hexaacetic acid

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

sodium hydroxide
1310-73-2

sodium hydroxide

2Na(1+)*H(1+)*[GdC18H24N4O12](3-)*3.5H2O=Na2H[Gd(C18H24N4O12)]*3.5H2O

2Na(1+)*H(1+)*[GdC18H24N4O12](3-)*3.5H2O=Na2H[Gd(C18H24N4O12)]*3.5H2O

Conditions
ConditionsYield
In water equimolar ratio Gd:ligand, pH 7, stirring; evapn. (vac.), drying (3 h, 200°C), ; elem. anal.;100%
water
7732-18-5

water

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

gadolinium(III)(OH)(C6H4(COO)2)(H2O)4*gadolinium(III)(C6H4(COO)2)(C6H4(COOH)(H2O)4*6H2O

gadolinium(III)(OH)(C6H4(COO)2)(H2O)4*gadolinium(III)(C6H4(COO)2)(C6H4(COOH)(H2O)4*6H2O

Conditions
ConditionsYield
In water GdCl3 mixed with disodium salt of isophthalic acid in water at room temp.; pptd.; filtered; dried in air; elem. anal.; XRD;100%
gadolinium

gadolinium

graphite

graphite

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

10Gd(3+)*6C2(4-)*6Cl(1-)=Gd10(C2)6Cl6

10Gd(3+)*6C2(4-)*6Cl(1-)=Gd10(C2)6Cl6

Conditions
ConditionsYield
(Ar); Schlenk techniques; GdCl3, Gd, C in 2:8:12 ratio closed in Ta capsule; closed in silica tube; heated at 1170°C for 39 d; detn. by XRD;100%
gadolinium(III) isopropoxide

gadolinium(III) isopropoxide

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

Gd(3+)*Cl(1-)*2OCH(CH3)2(1-)=GdCl(OCH(CH3)2)2

Gd(3+)*Cl(1-)*2OCH(CH3)2(1-)=GdCl(OCH(CH3)2)2

Conditions
ConditionsYield
In isopropyl alcohol byproducts: isopropyl acetate; molar ratio chloride:isopropoxide=1:2, refluxing; solvent removal (reduced pressure), drying (28°C, 0.1 torr); elem. anal.;99.7%
gadolinium(III) isopropoxide

gadolinium(III) isopropoxide

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

Gd(3+)*2Cl(1-)*OCH(CH3)2(1-)=GdCl2(OCH(CH3)2)

Gd(3+)*2Cl(1-)*OCH(CH3)2(1-)=GdCl2(OCH(CH3)2)

Conditions
ConditionsYield
In isopropyl alcohol byproducts: isopropyl acetate; molar ratio chloride:isopropoxide=2:1, refluxing; solvent removal (reduced pressure), drying (28°C, 0.1 torr); elem. anal.;99.6%
sodium peroxide

sodium peroxide

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

chromium(III) chloride
10025-73-7

chromium(III) chloride

gadolinium orthochromite

gadolinium orthochromite

Conditions
ConditionsYield
In neat (no solvent, solid phase) byproducts: NaCl2, O2; 800°C (10 min); washing (H2O), filtering;99%
benzene 1,3,5-tricarboxylic acid, ammonium salt

benzene 1,3,5-tricarboxylic acid, ammonium salt

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

gadolinium(III) 1,3,5-benzenetricarboxylate hexahydrate

gadolinium(III) 1,3,5-benzenetricarboxylate hexahydrate

Conditions
ConditionsYield
In not given hot soln.;99%
In not given hot soln.;99%
gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

potassium cyanide copper (I)-cyanide (1:1)

potassium cyanide copper (I)-cyanide (1:1)

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

(Gd2(dimethylformamide)8Cu4(CN)10)

(Gd2(dimethylformamide)8Cu4(CN)10)

Conditions
ConditionsYield
In N,N-dimethyl-formamide byproducts: KCl, CuCN; (N2), mixed, stirred at room temp. over 7 days; filtered, concd.(vac.), washed (hexane), dried.(vac.) for 30 min, elem. anal.;99%
In N,N-dimethyl-formamide byproducts: KCl, CuCN;
potassium cyanide

potassium cyanide

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

copper(l) cyanide

copper(l) cyanide

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

Gd(dimethylformamide)8Cu6(CN)9 * 2 dimethylformamide

Gd(dimethylformamide)8Cu6(CN)9 * 2 dimethylformamide

Conditions
ConditionsYield
In N,N-dimethyl-formamide byproducts: KCl; (N2), mixed, stirred at room temp. for 14 d; filtered, crystd.(three weeks);99%
In N,N-dimethyl-formamide byproducts: KCl; react. of GdCl3, CuCN and KCN in DMF;
K6[W4(μ3-Te)4(CN)12] * 5 H2O

K6[W4(μ3-Te)4(CN)12] * 5 H2O

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

[tetraaquadimetylformamidegadolinium(III)][tetraaquabis(dimethylformamide)gadolinium(III)][dodecylcyanotetra-mu.3-tellurotetratungstate(W-W)] dimethylformamide solvate hydrate

[tetraaquadimetylformamidegadolinium(III)][tetraaquabis(dimethylformamide)gadolinium(III)][dodecylcyanotetra-mu.3-tellurotetratungstate(W-W)] dimethylformamide solvate hydrate

Conditions
ConditionsYield
In water aq. soln. of metal chloride and 3-4 drops of DMF added to aq. soln. of K6W4Te4(CN)12*5H2O; after 3 ds ppt. filtered; washed (EtOH); dried (air) for 1 h; elem. anal.;98%
5-aminoisophthalic acid, ammonium salt

5-aminoisophthalic acid, ammonium salt

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

gadolinium(III) 5-aminoisophthalate tridecahydrate

gadolinium(III) 5-aminoisophthalate tridecahydrate

Conditions
ConditionsYield
In water ligand added to aq. soln. of metal salt with stirring; mixt. stirred for1 h at room temp.; filtered; washed (hot water); dried at 30°C for 2 ds; elem. anal.;98%
hexaammonium heptamolybdate tetrahydrate

hexaammonium heptamolybdate tetrahydrate

D-tartaric acid
147-71-7

D-tartaric acid

water
7732-18-5

water

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

NH4(1+)*2Mo(6+)*4O(2-)*Gd(3+)*10H2O*2(OCHCO2)2(4-)=NH4[Mo2O4Gd(H2O)6((OCHCO2)2)2]*4H2O

NH4(1+)*2Mo(6+)*4O(2-)*Gd(3+)*10H2O*2(OCHCO2)2(4-)=NH4[Mo2O4Gd(H2O)6((OCHCO2)2)2]*4H2O

Conditions
ConditionsYield
With HCl In water pH of soln. adjusted to 0.80 by HCl (10 %), 2 wk; elem. anal.;97.9%
(E)-3-phenylacrylic acid
140-10-3

(E)-3-phenylacrylic acid

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

[Gd(trans-cinnamate)3]

[Gd(trans-cinnamate)3]

Conditions
ConditionsYield
With NaOH In water cinnamic acid dispersed in water; treated with equimolar aq. NaOH; pH adjusted by dropwise addition of aq. HCl to 7-8; soln. added to metal chloride soln. in 3:1 molar ratio; pH adjusted to 5; stirred for 1 h; collected; washed with EtOH followed by H2O; dried in vacuum desiccator for 2 days; elem. anal.;96%
gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

warfarin
129-06-6

warfarin

Gd(3+)*3C19H15O4(1-)*6H2O=Gd(C19H15O4)3*6H2O

Gd(3+)*3C19H15O4(1-)*6H2O=Gd(C19H15O4)3*6H2O

Conditions
ConditionsYield
In water dropwise addn. of soln. of Ln-salt to soln. of ligand salt (pptn.), stirring (0.5 h); filtration, washing (H2O), drying (vac. desiccator); elem. anal.;93%
meso-trans-di(hexadecyl)tetrabenzoporphyrin

meso-trans-di(hexadecyl)tetrabenzoporphyrin

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

chlorogadolinium meso-trans-di(hexadecyl)tetrabenzoporphyrinate
1379531-29-9

chlorogadolinium meso-trans-di(hexadecyl)tetrabenzoporphyrinate

Conditions
ConditionsYield
In N,N-dimethyl-formamide benzoporphyrin dissolved in DMF; metal chloride added; mixt. heated for 16 h at reflux; cooled; diluted (H2O); extd. (CHCl3); extract washed (H2O); solvent distd. off; residue washed (aq. EtOH); dried; elem. anal.;92%
gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

triethylentetramine
112-24-3

triethylentetramine

oxalic acid diethyl ester
95-92-1

oxalic acid diethyl ester

Gd(C8H16O2N4)Cl2(H2O)2(1+)*Cl(1-)=[Gd(C8H20Cl2N4O4)]Cl
257926-44-6

Gd(C8H16O2N4)Cl2(H2O)2(1+)*Cl(1-)=[Gd(C8H20Cl2N4O4)]Cl

Conditions
ConditionsYield
With acetonitrile In methanol refluxing (3 h), stirring, refluxing (2 h), acetonitrile addn., crystn.; filtration, washing (acetonitrile-ethanol), drying (red. pressure); elem. anal.;90%
6-[bis[(carboxymethyl)]amino]-6-[5-(didecylamino)-5-oxopent-1-yl]-tetrahydro-1H-1,4-diazepine-1,4(5H)-diacetic acid

6-[bis[(carboxymethyl)]amino]-6-[5-(didecylamino)-5-oxopent-1-yl]-tetrahydro-1H-1,4-diazepine-1,4(5H)-diacetic acid

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

[6-[bis[(carboxymethyl)]amino]-6-[5-(didecylamino)-5-oxopent-1-yl]tetrahydro-1H-1,4-diazepine-1,4( 5H )-diacetate[(4-)]gadolinate( 1-)]sodium

[6-[bis[(carboxymethyl)]amino]-6-[5-(didecylamino)-5-oxopent-1-yl]tetrahydro-1H-1,4-diazepine-1,4( 5H )-diacetate[(4-)]gadolinate( 1-)]sodium

Conditions
ConditionsYield
With sodium hydroxide In water at 20℃; pH=6.5-7;90%
methyl 2-(1-ferrocenylethylidene)hydrazinecarbodithioate

methyl 2-(1-ferrocenylethylidene)hydrazinecarbodithioate

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

Gd(C5H5FeC5H4C(CH3)NNCSSCH3)3

Gd(C5H5FeC5H4C(CH3)NNCSSCH3)3

Conditions
ConditionsYield
In ethanol dissolution of ligand in anhyd. ethanol, dropwise addn. of lanthanide(III) chloride in anhyd. ethanol into ligand soln., maintaining under reflux for 7 h; concn. of mixt. to a reduced volume, filtn., washing several times with cold ethanol and ether, elem. anal.;89%
10-[2-(didecylamino)-2-oxoethyl]-1,4,7,10-tetraazacyclododecane-1,4,7-triacetic acid
1579956-47-0

10-[2-(didecylamino)-2-oxoethyl]-1,4,7,10-tetraazacyclododecane-1,4,7-triacetic acid

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

[10-[2-(didecylamino)-2-oxoethyl]-1,4,7 ,10-tetraazacyclododecane-1,4,7-triacetate (3-) ]gadolinium
1579960-68-1

[10-[2-(didecylamino)-2-oxoethyl]-1,4,7 ,10-tetraazacyclododecane-1,4,7-triacetate (3-) ]gadolinium

Conditions
ConditionsYield
With sodium hydrogencarbonate; sodium hydroxide In water at 20℃; pH=5-7.5;89%
gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

urea
57-13-6

urea

2Gd(3+)*3CO3(2-)*3H2O = Gd2(CO3)3*3H2O

2Gd(3+)*3CO3(2-)*3H2O = Gd2(CO3)3*3H2O

Conditions
ConditionsYield
In water byproducts: NH4Cl, CO2, NH3; aq. solns. GdCl3 and urea were mixed and heated to 90°C for 2-4 h; ppt. was filtered, washed with hot water, dried at 75°C in oven for 3 h and in vacuo over silica; elem. anal.;88%
exo-Li(N,N,N',N'-tetramethylethylenediamine)-1-Li(N,N,N',N'-tetramethylethylenediamine)-2,3-(SiMe3)2-2,3-C2B4H4

exo-Li(N,N,N',N'-tetramethylethylenediamine)-1-Li(N,N,N',N'-tetramethylethylenediamine)-2,3-(SiMe3)2-2,3-C2B4H4

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

[Li(TMEDA)2][1-Cl-1-(μ-Cl)-2,2',3,3'-(SiMe3)4-5,6-[(μ-H)3Li(TMEDA)]-1,1'-commo-Gd(2,3-C2B4H4)2]

[Li(TMEDA)2][1-Cl-1-(μ-Cl)-2,2',3,3'-(SiMe3)4-5,6-[(μ-H)3Li(TMEDA)]-1,1'-commo-Gd(2,3-C2B4H4)2]

Conditions
ConditionsYield
In benzene byproducts: LiCl; stirring (0°C, 2 - 3 h, room temp., 36 h); filtering, washing (C6H6), crystn. on slow evapn.; elem. anal.;88%
C48H68N12O16

C48H68N12O16

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

C48H62Gd2N12O16

C48H62Gd2N12O16

Conditions
ConditionsYield
In water at 80℃; for 24h; pH=7; pH-value;88%
sodium tetrahydroborate
16940-66-2

sodium tetrahydroborate

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

gadolinium tetraborate*2tetrahydrofuran

gadolinium tetraborate*2tetrahydrofuran

Conditions
ConditionsYield
In tetrahydrofuran byproducts: NaCl; stirring (air and moisture exclusion, room tempo., 30 h); IR spectroscopy;86%
With tetrahydrofuran In tetrahydrofuran
K7[Mo4(μ3-Te)4(CN)12] * 12 H2O

K7[Mo4(μ3-Te)4(CN)12] * 12 H2O

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

[tetraaquadimetylformamidegadolinium(III)][tetraaquabis(dimethylformamide)gadolinium(III)][dodecylcyanotetra-mu.3-tellurotetramolybdate(Mo-Mo)] dimethylformamide solvate hexahydrate

[tetraaquadimetylformamidegadolinium(III)][tetraaquabis(dimethylformamide)gadolinium(III)][dodecylcyanotetra-mu.3-tellurotetramolybdate(Mo-Mo)] dimethylformamide solvate hexahydrate

Conditions
ConditionsYield
With air In water aq. soln. of metal chloride and 3-4 drops of DMF added to aq. soln. of K7Mo4Te4(CN)12*12H2O; after 3 ds ppt. filtered; washed (EtOH); dried (air) for 1 h; elem. anal.;86%
closo-exo-5,6-[(μ-H)2Na(THF)2]-1-Na(THF)2-2,4-(SiMe3)2-2,4-C2B4H4

closo-exo-5,6-[(μ-H)2Na(THF)2]-1-Na(THF)2-2,4-(SiMe3)2-2,4-C2B4H4

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

2,2',4,4'-(SiMe3)4-3,5',6'-[(μ-H)3Na(tetrahydrofuran)3]-1,1'-commo-Gd(η5-2,4-C2B4H4)2

2,2',4,4'-(SiMe3)4-3,5',6'-[(μ-H)3Na(tetrahydrofuran)3]-1,1'-commo-Gd(η5-2,4-C2B4H4)2

Conditions
ConditionsYield
In benzene under N2 atm. closo-exo-5,6-Na(THF)2-1-Na(THF)2-2,4-(SiMe3)-2,4-C2B4H4 and LnCl3 (2:1) were mixed in benzene and stirred at 0°C for 2-3 h, react. mixt. was warmed to room temp., raised to 60°C and stirred for 24 h; soln. was filtered and evapd., residue was recrystd. from n-hexane-benzene; elem. anal.;86%
tetrahydrofuran
109-99-9

tetrahydrofuran

5,10,15,20-tetraphenyl-21H,23H-porphine
917-23-7

5,10,15,20-tetraphenyl-21H,23H-porphine

sodium (η5-cyclopentadienyl)tris(dimethylphosphito)cobaltate(I)

sodium (η5-cyclopentadienyl)tris(dimethylphosphito)cobaltate(I)

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

lithium hexamethyldisilazane
4039-32-1

lithium hexamethyldisilazane

[(C5H5)Co(OP(OCH3)2)3Gd[5,10,15,20-tetraphenylporphyrinate]]

[(C5H5)Co(OP(OCH3)2)3Gd[5,10,15,20-tetraphenylporphyrinate]]

Conditions
ConditionsYield
In dichloromethane; toluene Ar, GdCl3 (THF) reacted with Li salt (3 equiv.), solvent removed (vac.),dissolved (CH2Cl2), added to a porphyrin (toluene), refluxed for 48 h, Co compd. added, heatd for 12 h; cooled to room temp., solvent removed (vac.), dissolved (CH2Cl2), filtered, chromy. (silica gel, CHCl3/petroleum ether), recrystd. (CH2Cl2); elem. anal.;86%
water
7732-18-5

water

gadolinium(III) chloride
10138-52-0

gadolinium(III) chloride

copper dichloride

copper dichloride

[Gd(CuC2H3N2(CH2C6H5)O2)5](3+)*3Cl(1-)*14H2O=[Gd(CuC2H3N2(CH2C6H5)O2)5]Cl3*14H2O

[Gd(CuC2H3N2(CH2C6H5)O2)5](3+)*3Cl(1-)*14H2O=[Gd(CuC2H3N2(CH2C6H5)O2)5]Cl3*14H2O

Conditions
ConditionsYield
With sodium hydroxide In methanol; water stirring of (S)-phenylalaninehydroxamic acid (5 equiv.) in MeOH, treatment with 2 equiv. of 1 M aq. NaOH (10 equiv.), stirring, sequential addn.of GdCl3 (1 equiv.) and CuCl2 (5 equiv.), stirring overnight; adjusting pH to 7, stirring for 20 min, filtration, addn. of 0.5 M aq. NaCl, slow evapn., crystn., filtration, rinsing with cold water, drying in air; elem. anal.;86%
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