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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

4-Methoxy-2-methylaniline Manufacturer/High quality/Best price/In stock

Cas:102-50-1

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Wuhan Fortuna Chemical Co.,Ltd

Good quality 2-Methyl-4-methoxybenzenamine CAS 102-50-1 with cheap price Company profile Wuhan Fortuna Chemical Co.,Ltd established in 2006, is a big integrative chemical enterprise being engaged in Pharmaceutical & its intermediates, Food/F

Good quality 2-Methyl-4-methoxybenzenamine CAS 102-50-1 with cheap price

Cas:102-50-1

Min.Order:10 Kilogram

FOB Price: $10.0

Type:Trading Company

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2-Methyl-p-anisidine (NH2=1)

Cas:102-50-1

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

2-Methyl-4-methoxybenzenamine 102-50-1

Cas:102-50-1

Min.Order:1 Kilogram

FOB Price: $15.0 / 50.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 102-50-1 with best quality

Cas:102-50-1

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Product Name 4-Methoxy-2-methylaniline Synonyms 4-Amino-m-metylanisole CAS Registry Number 102-50-1 Molecular Structure

4-Methoxy-2-methylaniline CAS: 102-50-1

Cas:102-50-1

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

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Hangzhou Sartort Biopharma Co., Ltd

Appearance:brick red crystals or liquid Storage:room temperature Package:200kg/drum Application:Chemicals Transportation:Express/Sea/Air Port:any port in china

2-Methyl-4-Methoxyaniline

Cas:102-50-1

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Lab/Research institutions

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Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

4-Methoxy-2-methylaniline

Cas:102-50-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Hot Sell Factory Supply Raw Material CAS 102-50-1 ,2-Methyl-4-methoxybenzenamine

Cas:102-50-1

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

4-Methoxy-2-methylaniline

Cas:102-50-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

2-Methyl-4-methoxybenzenamine

Cas:102-50-1

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

4-Methoxy-2-methylaniline

Cas:102-50-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Lingrui Chemical Co.,Ltd.

M-CRESIDINEAppearance:Colorless transparent liquid Storage:Keep away of light, cool place Package:according to customers' requirements Application:pharmaceutical intermediates Transportation:By air(EMS or EUB or FedEx or TNT ect...) or by sea(FOB or

M-CRESIDINE

Cas:102-50-1

Min.Order:1 Gram

Negotiable

Type:Other

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providing h

Factory Supply 2-Methyl-4-Methoxyaniline

Cas:102-50-1

Min.Order:0

Negotiable

Type:Other

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

2-Methyl-4-methoxybenzenamine

Cas:102-50-1

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

2-Methyl-4-methoxybenzenamine Basic information Product Name: 2-Methyl-4-methoxybenzenamine Synonyms: AKOS 91136;6-AMINO-3-METHOXYTOLUENE;4-METHO

102-50-1 C8H11NO 2-Methyl-4-methoxybenzenamine

Cas:102-50-1

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

2-Methyl-4-methoxybenzenamine

Cas:102-50-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

2-Methyl-4-methoxybenzenamine

Cas:102-50-1

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

2-Methyl-4-methoxybenzenamine

Cas:102-50-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

2-Methyl-4-methoxybenzenamine

Cas:102-50-1

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

M-CRESIDINE

Cas:102-50-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratoryAppearance:Light tan to tan liquid Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

2-Methyl-4-methoxybenzenamine cas no. 102-50-1 97%

Cas:102-50-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

meta-Cresidine

Cas:102-50-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

2-Methyl-4-Methoxyaniline

Cas:102-50-1

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

2-Methyl-4-methoxybenzenamine

Cas:102-50-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hubei Taiho Chemical Co.,LTD

TAIHO Unique Advantages:1.We're factory2.Free samples available3.Commodity inspection can be done4.ISO9001,Kosher certifications5.10 years experiences Storage:Store in cool &dry place Package:aluminium foil bag/fiber can/plastic drum Application:comp

4-Methoxy-2-methylaniline

Cas:102-50-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Xi`an Eastling Biotech Co., Ltd.

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:Beijing or Guangzhou

2-Methyl-4-methoxybenzenamine

Cas:102-50-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

4-Methoxy-2-Methylaniline

Cas:102-50-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Ocean Chemical Co., Ltd.

★.Best quality according to requirement ★.Competitive price in China market ★.Mature Technical support ★.Professional logistic support

2-Methyl-4-methoxybenzenamine

Cas:102-50-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

We are a trading company aiming at providing high-quality services to customers. Established for many years, with good reputation in the industry Storage:Sealed and preserved Application:Fine chemical intermediates, used as the main raw material for

2-Methyl-4-methoxybenzenamine

Cas:102-50-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

5-methoxy-2-nitrotoluene
5367-32-8

5-methoxy-2-nitrotoluene

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

Conditions
ConditionsYield
With hydrogen; platinum(IV) oxide In isopropyl alcohol under 2327.2 Torr;98.5%
With sodium formate In ethanol at 85℃; for 1h;87%
With tetrahydroxydiboron; water at 80℃; for 8h;80%
4-methoxy-2-methylphenyl boronic acid
208399-66-0

4-methoxy-2-methylphenyl boronic acid

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

Conditions
ConditionsYield
With sodium hydroxide; hydroxylamine-O-sulfonic acid In acetonitrile at 20℃; for 16h;89%
4-bromo-3-methylanisole
27060-75-9

4-bromo-3-methylanisole

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

Conditions
ConditionsYield
With ammonium sulfate; (R)-(-)-1-[(SP)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine; bis(tri-ortho-tolylphosphine)palladium(0); sodium t-butanolate In 1,4-dioxane at 100℃; for 6h; Inert atmosphere; Glovebox;80%
With ammonium hydroxide; copper(l) iodide; potassium carbonate; 4R-4-hydroxyproline In dimethyl sulfoxide at 70℃; for 36h;77%
1-(4-methoxy-2-methylphenyl)-1,2-hydrazinedicarboxylic acid bis(2,2,2-trichloroethyl) ester
154876-10-5

1-(4-methoxy-2-methylphenyl)-1,2-hydrazinedicarboxylic acid bis(2,2,2-trichloroethyl) ester

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

Conditions
ConditionsYield
With acetic acid; zinc for 0.75h; Ambient temperature;76%
1-chloro-4-methoxy-2-methylbenzene
13334-71-9

1-chloro-4-methoxy-2-methylbenzene

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

Conditions
ConditionsYield
With ammonium hydroxide; potassium phosphate; copper(l) iodide; N1,N2-bis(2,4,6-trimethoxyphenyl)oxalamide In water; dimethyl sulfoxide at 120℃; for 48h; Inert atmosphere;64%
With bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)]; N-[2-(di(1-adamantyl)phosphino)phenyl]morpholine; ammonia; sodium t-butanolate In 1,4-dioxane at 65℃; for 24h; Inert atmosphere; chemoselective reaction;52%
N-(4-methoxy-2-methylphenyl)acetamide
31601-41-9

N-(4-methoxy-2-methylphenyl)acetamide

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

Conditions
ConditionsYield
With hydrogenchloride
methanol
67-56-1

methanol

N-(o-tolyl)hydroxylamine
611-22-3

N-(o-tolyl)hydroxylamine

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

Conditions
ConditionsYield
With sulfuric acid at 25℃; durch wochenlange Einw.;
para-methoxynitrobenzene
100-17-4

para-methoxynitrobenzene

methylmagnesium chloride
676-58-4

methylmagnesium chloride

A

N-methyl-N-(4-methoxyphenyl)amine
5961-59-1

N-methyl-N-(4-methoxyphenyl)amine

B

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

Conditions
ConditionsYield
With lithium aluminium tetrahydride; palladium on activated charcoal 1) THF, 20 min, -30 deg C, 2) 20 deg C, 2 h; Yield given. Multistep reaction. Yields of byproduct given;
4-methoxy-2-methyl-acetophenone oxime

4-methoxy-2-methyl-acetophenone oxime

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

Conditions
ConditionsYield
With hydrogenchloride
hydrogenchloride
7647-01-0

hydrogenchloride

1-(4-methoxy-2-methyl-phenyl)-ethanone oxime
75112-71-9

1-(4-methoxy-2-methyl-phenyl)-ethanone oxime

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

1-methoxy-3-methyl-benzene
100-84-5

1-methoxy-3-methyl-benzene

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 92 percent / ZnCl2 / diethyl ether; CH2Cl2 / 0.5 h / 25 °C
2: 76 percent / Zn, glacial acetic acid / 0.75 h / Ambient temperature
View Scheme
3-methyl-4-nitrophenol
2581-34-2

3-methyl-4-nitrophenol

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: potassium carbonate; xylene
2: tin (II)-chloride; hydrochloric acid
View Scheme
Multi-step reaction with 2 steps
1: alkaline solution
2: tin; hydrochloric acid; alcohol
View Scheme
Multi-step reaction with 2 steps
1: diethyl ether
2: tin; hydrochloric acid
View Scheme
Multi-step reaction with 2 steps
1: (methylation)
2: N2H4*H2O / Raney-Ni
View Scheme
4-acetamido-3-methylphenol
39495-15-3

4-acetamido-3-methylphenol

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: alkali
2: hydrochloric acid
View Scheme
3-methyl-phenol
108-39-4

3-methyl-phenol

KOH

KOH

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: HNO3, AcOH
2: (methylation)
3: N2H4*H2O / Raney-Ni
View Scheme
C8H10O2

C8H10O2

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

Conditions
ConditionsYield
With glycine ethyl ester hydrochloride; triethylamine In methanol; water at 40℃; Inert atmosphere;
ortho-cresol
95-48-7

ortho-cresol

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: [bis(acetoxy)iodo]benzene / 0 - 20 °C / Inert atmosphere
2: triethylamine; glycine ethyl ester hydrochloride / methanol; water / 40 °C / Inert atmosphere
View Scheme
Multi-step reaction with 3 steps
1.1: [bis(acetoxy)iodo]benzene / 0.53 h / 0 - 20 °C / Inert atmosphere
1.2: 1 h / 0 - 20 °C / Inert atmosphere
2.1: [bis(acetoxy)iodo]benzene / 0 - 20 °C / Inert atmosphere
3.1: triethylamine; glycine ethyl ester hydrochloride / methanol; water / 40 °C / Inert atmosphere
View Scheme
1-hydroxy-4-methoxy-2-methylbenzene
5307-05-1

1-hydroxy-4-methoxy-2-methylbenzene

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: [bis(acetoxy)iodo]benzene / 0 - 20 °C / Inert atmosphere
2: triethylamine; glycine ethyl ester hydrochloride / methanol; water / 40 °C / Inert atmosphere
View Scheme
4,4-dimethoxy-2-methylcyclohexane-2,5-dien-1-one
57197-11-2

4,4-dimethoxy-2-methylcyclohexane-2,5-dien-1-one

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

Conditions
ConditionsYield
With glycine ethyl ester hydrochloride; triethylamine In methanol; water at 40℃; Inert atmosphere;93 %Spectr.
4-chloro-3-nitropyridine
13091-23-1

4-chloro-3-nitropyridine

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

N-(4-methoxy-2-methylphenyl)-3-nitropyridin-4-amine
1513682-06-8

N-(4-methoxy-2-methylphenyl)-3-nitropyridin-4-amine

Conditions
ConditionsYield
With triethylamine In ethanol at 20℃; for 16h;100%
With triethylamine In ethanol at 20℃; for 16h;100%
With triethylamine In ethanol at 20℃; for 16h;100%
2,5-Dimethylpyrrole
625-84-3

2,5-Dimethylpyrrole

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

1-(4-methoxy-2-methyl-phenyl)-2,5-dimethyl-1H-pyrrole

1-(4-methoxy-2-methyl-phenyl)-2,5-dimethyl-1H-pyrrole

Conditions
ConditionsYield
In various solvent(s) at 110℃; pH=3;99%
phenyl chloroformate
1885-14-9

phenyl chloroformate

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

phenyl N-(4-methoxy-2-methylphenyl)carbamate
1378364-99-8

phenyl N-(4-methoxy-2-methylphenyl)carbamate

Conditions
ConditionsYield
With pyridine In tetrahydrofuran at 0 - 20℃;99%
With pyridine In tetrahydrofuran at 0 - 20℃;81.1%
BOC-glycine
4530-20-5

BOC-glycine

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

[(4-methoxy-2-methylphenylcarbamoyl)methyl]carbamic acid tert-butyl ester
1448525-54-9

[(4-methoxy-2-methylphenylcarbamoyl)methyl]carbamic acid tert-butyl ester

Conditions
ConditionsYield
With dmap; triethylamine In dichloromethane at 20℃; for 5h; Inert atmosphere;99%
With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine In dichloromethane at 20℃; for 5h;
acetic anhydride
108-24-7

acetic anhydride

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

N-(4-methoxy-2-methylphenyl)acetamide
31601-41-9

N-(4-methoxy-2-methylphenyl)acetamide

Conditions
ConditionsYield
With pyridine at 0 - 20℃; Inert atmosphere;98%
In dichloromethane at 25℃; for 3h; Large scale;91.8%
In dichloromethane at 20℃;82%
diethyl 2-ethoxymethylenemalonate
87-13-8

diethyl 2-ethoxymethylenemalonate

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

diethyl 2-((4-methoxy-2-methylphenylamino)methylene)malonate
384820-97-7

diethyl 2-((4-methoxy-2-methylphenylamino)methylene)malonate

Conditions
ConditionsYield
at 120℃; for 1h;98%
In toluene for 5h; Reflux;14.4 g
2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

(2-methyl-4-methoxyphenyl)diazonium tetrafluoroborate

(2-methyl-4-methoxyphenyl)diazonium tetrafluoroborate

Conditions
ConditionsYield
Stage #1: 2-methyl-4-methoxyaniline With tetrafluoroboric acid at 0℃;
Stage #2: With sodium nitrite at 0 - 20℃; for 3h; Further stages.;
98%
With tetrafluoroboric acid; sodium nitrite at 0℃;96%
Stage #1: 2-methyl-4-methoxyaniline With boron trifluoride diethyl etherate In tetrahydrofuran for 0.0833333h; Cooling with ice;
Stage #2: With tert.-butylnitrite In tetrahydrofuran at 0℃;
90%
Stage #1: 2-methyl-4-methoxyaniline With tetrafluoroboric acid In water at 20℃;
Stage #2: With sodium nitrite In water at 10℃; Cooling with ice;
78%
Stage #1: 2-methyl-4-methoxyaniline With tetrafluoroboric acid In water at 20℃; for 0.166667h;
Stage #2: With sodium nitrite In water at 0 - 20℃; for 1h;
2-bromo-4-methyl-1-(3-methylbut-1-enyl)benzene

2-bromo-4-methyl-1-(3-methylbut-1-enyl)benzene

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

4-methoxy-2-methyl-N-(5-methyl-2-(3-methylbut-1-enyl)phenyl)aniline

4-methoxy-2-methyl-N-(5-methyl-2-(3-methylbut-1-enyl)phenyl)aniline

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); sodium tert-pentoxide; XPhos In 1,4-dioxane at 110℃; for 12h; Buchwald-Hartwig Coupling; Inert atmosphere;98%
pivaloyl chloride
3282-30-2

pivaloyl chloride

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

4'-methoxy-2'-methylpivalanilide

4'-methoxy-2'-methylpivalanilide

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran at 0℃; for 0.5h;97%
With sodium carbonate In dichloromethane; water at 80℃; for 2h;93%
With triethylamine In ethyl acetate
1,3-diphenyl-2-propynone
7338-94-5

1,3-diphenyl-2-propynone

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

(Z)-3-(4-methoxy-2-methylphenylamino)-1,3-diphenylprop-2-en-1-one
1198463-75-0

(Z)-3-(4-methoxy-2-methylphenylamino)-1,3-diphenylprop-2-en-1-one

Conditions
ConditionsYield
In methanol at 80℃; for 1h; Sealed tube;96%
In ethanol Michael Addition; Reflux;96%
1,1,1,3,3,3-hexamethyl-disilazane
999-97-3

1,1,1,3,3,3-hexamethyl-disilazane

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

N-TMS-4-Methoxy-2-methylaniline
109463-66-3

N-TMS-4-Methoxy-2-methylaniline

Conditions
ConditionsYield
With cyclohexane-1,2-epoxide; lithium iodide; chloro-trimethyl-silane In neat (no solvent) for 1h; Heating;95%
(E)-N'-(2-cyano-4,5-dimethoxyphenyl)-N,N-dimethylformimidamide

(E)-N'-(2-cyano-4,5-dimethoxyphenyl)-N,N-dimethylformimidamide

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

(6,7-dimethoxyquinazolin-4-yl)-(4-methoxy-2-methylphenyl)amine

(6,7-dimethoxyquinazolin-4-yl)-(4-methoxy-2-methylphenyl)amine

Conditions
ConditionsYield
With acetic acid In acetonitrile at 160℃; for 0.166667h; microwave irradiation;95%
2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

(E)-N'-(2-cyano-4-nitrophenyl)-N,N'-dimethylformimidamide

(E)-N'-(2-cyano-4-nitrophenyl)-N,N'-dimethylformimidamide

(4-methoxy-2-methylphenyl)-(6-nitroquinazolin-4-yl)amine

(4-methoxy-2-methylphenyl)-(6-nitroquinazolin-4-yl)amine

Conditions
ConditionsYield
With acetic acid In acetonitrile at 160℃; for 0.166667h; microwave irradiation;95%
chlorobenzene
108-90-7

chlorobenzene

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

4-phenylamino-3-methyl-1-methoxybenzene
41317-15-1

4-phenylamino-3-methyl-1-methoxybenzene

Conditions
ConditionsYield
With potassium phosphate; DavePhos; tris(dibenzylideneacetone)dipalladium (0) In toluene at 110℃; for 8h; Buchwald-Hartwig amination;95%
With potassium phosphate; DavePhos; tris-(dibenzylideneacetone)dipalladium(0) In toluene Heating;95%
bromobenzene
108-86-1

bromobenzene

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

4-phenylamino-3-methyl-1-methoxybenzene
41317-15-1

4-phenylamino-3-methyl-1-methoxybenzene

Conditions
ConditionsYield
With caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; tris(dibenzylideneacetone)dipalladium (0) In toluene at 110℃; Buchwald-Hartwig amination;95%
With 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; tris-(dibenzylideneacetone)dipalladium(0) In toluene Heating;95%
With potassium phosphate; copper(l) iodide; C18H15N3O2 at 25℃; for 24h; Reagent/catalyst; Temperature; Sealed tube;93%
With potassium phosphate; copper(l) iodide In diethylene glycol at 70℃; for 14h; Sealed tube;93%
5-(4-benzyloxy-benzenesulfonyl)-4-chloro-2-methyl-pyrimidine
796048-82-3

5-(4-benzyloxy-benzenesulfonyl)-4-chloro-2-methyl-pyrimidine

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

[5-(4-Benzyloxybenzenesulfonyl)-2-methylpyrimidin-4-yl]-(4-methoxy-2-methylphenyl)-amine

[5-(4-Benzyloxybenzenesulfonyl)-2-methylpyrimidin-4-yl]-(4-methoxy-2-methylphenyl)-amine

Conditions
ConditionsYield
With toluene-4-sulfonic acid In toluene for 1h; Heating / reflux;95%
2-methylphenyl bromide
95-46-5

2-methylphenyl bromide

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

4-methoxy-2-methyl-N-(2-tolyl)aniline
100925-29-9

4-methoxy-2-methyl-N-(2-tolyl)aniline

Conditions
ConditionsYield
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; sodium t-butanolate In toluene at 100℃; for 4h;95%
2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

A

4-phenylamino-3-methyl-1-methoxybenzene
41317-15-1

4-phenylamino-3-methyl-1-methoxybenzene

B

phenol
108-95-2

phenol

Conditions
ConditionsYield
A n/a
B 94%
ethyl acetoacetate
141-97-9

ethyl acetoacetate

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

N-(4-methoxy-2-methylphenyl)-3-oxobutanamide

N-(4-methoxy-2-methylphenyl)-3-oxobutanamide

Conditions
ConditionsYield
With 1,1,1,3',3',3'-hexafluoro-propanol In acetonitrile at 80℃; for 12h; Sealed tube; Green chemistry;94%
2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

N'-(2-cyano-4-methylphenyl)-N,N-dimethylformamidine

N'-(2-cyano-4-methylphenyl)-N,N-dimethylformamidine

(4-methoxy-2-methylphenyl)-(6-methylquinazolin-4-yl)amine

(4-methoxy-2-methylphenyl)-(6-methylquinazolin-4-yl)amine

Conditions
ConditionsYield
With acetic acid In acetonitrile at 160℃; for 0.166667h; microwave irradiation;93%
2,2,2-trifluroethylamine hydrochloride
373-88-6

2,2,2-trifluroethylamine hydrochloride

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

4-methoxy-2-methyl-N-(2,2,2-trifluoroethyl)aniline

4-methoxy-2-methyl-N-(2,2,2-trifluoroethyl)aniline

Conditions
ConditionsYield
Stage #1: 2,2,2-trifluroethylamine hydrochloride With acetic acid; sodium nitrite In dichloromethane; water at 20℃; for 0.5h;
Stage #2: 2-methyl-4-methoxyaniline With C50H23Cl8FeN4O10 In dichloromethane; water for 12.5h;
93%
1,3-dimethoxy-2-hydroxy-benzene
91-10-1

1,3-dimethoxy-2-hydroxy-benzene

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

C16H17NO4

C16H17NO4

Conditions
ConditionsYield
With tert.-butylhydroperoxide; meso-tetraphenylporphyrin iron(III) chloride; 1,1,1,3',3',3'-hexafluoro-propanol at 20℃; regioselective reaction;93%
2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

N'-(2-cyano-3-methylphenyl)-N,N-dimethylformamidine

N'-(2-cyano-3-methylphenyl)-N,N-dimethylformamidine

(4-methoxy-2-methylphenyl)-(5-methylquinazolin-4-yl)amine

(4-methoxy-2-methylphenyl)-(5-methylquinazolin-4-yl)amine

Conditions
ConditionsYield
With acetic acid In acetonitrile at 160℃; for 0.166667h; microwave irradiation;92%
trifluoroacetic acid
76-05-1

trifluoroacetic acid

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

(Z)-2,2,2-trifluoro-N-(4-methoxy-2-methylphenyl)acetimidoyl chloride

(Z)-2,2,2-trifluoro-N-(4-methoxy-2-methylphenyl)acetimidoyl chloride

Conditions
ConditionsYield
With tetrachloromethane; triethylamine; triphenylphosphine for 3h; Heating;92%
With triethylamine; triphenylphosphine In tetrachloromethane for 3h; Heating;92%
Stage #1: trifluoroacetic acid With tetrachloromethane; triethylamine; triphenylphosphine at 0℃; for 0.166667h; Inert atmosphere;
Stage #2: 2-methyl-4-methoxyaniline at 0 - 85℃; Inert atmosphere;
89%
4-Chlorobutanoyl chloride
4635-59-0

4-Chlorobutanoyl chloride

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

1-[2-methyl-4-(methyloxy)phenyl]-2-pyrrolidinone
727993-66-0

1-[2-methyl-4-(methyloxy)phenyl]-2-pyrrolidinone

Conditions
ConditionsYield
Stage #1: 4-Chlorobutanoyl chloride; 2-methyl-4-methoxyaniline With triethylamine In tetrahydrofuran at 0 - 10℃; for 1.5h;
Stage #2: With potassium tert-butylate In tetrahydrofuran at 0 - 10℃; for 2h;
92%
2-azidobenzaldehyde
16714-25-3

2-azidobenzaldehyde

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

2-(4-methoxy-2-methylphenyl)-2H-indazole
1393125-78-4

2-(4-methoxy-2-methylphenyl)-2H-indazole

Conditions
ConditionsYield
at 100℃; under 10343.2 Torr; Microwave irradiation;92%
2,3-diethynylquinoxaline
91-19-0

2,3-diethynylquinoxaline

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

2-(4-methoxy-2-methylphenyl)quinoxaline

2-(4-methoxy-2-methylphenyl)quinoxaline

Conditions
ConditionsYield
Stage #1: 2-methyl-4-methoxyaniline With tetrafluoroboric acid; tert.-butylnitrite In ethanol; water at 0 - 20℃;
Stage #2: 2,3-diethynylquinoxaline With tetrabutylammonium tetrafluoroborate; trifluoroacetic acid In acetonitrile at 20℃; for 4.5h; Electrochemical reaction;
92%
allyl acetoacetate
1118-84-9

allyl acetoacetate

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

N-(4-methoxy-2-methylphenyl)-3-oxobutanamide

N-(4-methoxy-2-methylphenyl)-3-oxobutanamide

Conditions
ConditionsYield
With 1,1,1,3',3',3'-hexafluoro-propanol In acetonitrile at 80℃; for 12h; Sealed tube; Green chemistry;92%
sodium carbonate
497-19-8

sodium carbonate

chlorobenzene
108-90-7

chlorobenzene

2-methyl-4-methoxyaniline
102-50-1

2-methyl-4-methoxyaniline

2-(4-methoxy-2-methylphenylamino)benzoic acid

2-(4-methoxy-2-methylphenylamino)benzoic acid

Conditions
ConditionsYield
Stage #1: sodium carbonate; chlorobenzene With copper In N,N-dimethyl-formamide; toluene for 0.25h; Reflux;
Stage #2: 2-methyl-4-methoxyaniline In N,N-dimethyl-formamide; toluene under 760.051 Torr; for 10.6h; Reagent/catalyst; Solvent; Reflux;
91.47%

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