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Cas:122-00-9
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Cas:122-00-9
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inquiryProduct Description Product Name 4'-Methylacetophenone CAS No. 122-00-9 Appearance Colorless to yellowish liquid Assay ≥99% Capacity 200mt/year Min.packing 100g
Cas:122-00-9
Min.Order:1 Gram
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inquiryhigh quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai
4'-Methylacetophenone CAS: 122-00-9 EINECS No.: 204-514-8 Molecular formula: C9H10O Molecular weight: 134.1751 Properties: Density: 1.005 Melting point: 22-24°C Boiling point: 226°C Refractive index: 1.532-1.535 Flash point:
Cas:122-00-9
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inquiryThe above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
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Cas:122-00-9
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Cas:122-00-9
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inquiryOur company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O
Cas:122-00-9
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Cas:122-00-9
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Cas:122-00-9
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Cas:122-00-9
Min.Order:100 Gram
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inquiryAppearance:colorless to pale yellow liquid Storage:Store below +30°C. Package:200kg/Drum Application:Chemicals Transportation:Express/Sea/Air Port:Any port in China
Cas:122-00-9
Min.Order:1 Kilogram
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inquiryProduct Name: 4'-Methylacetophenone CAS: 122-00-9 MF: C9H10O MW: 134.18 EINECS: 204-514-8 Mol File: 122-00-9.mol 4'-Methylacetophenone Structure 4'-Methylacetophenone Chemical Properties Melting point 22-24 °C (
Cas:122-00-9
Min.Order:1 Gram
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inquiry1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ
Cas:122-00-9
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inquiryBest service,high quality,competitive price,prompt delivery. Package:200kgs/drum Application:Used as intermediate,like celecoxib. Port:shanghai seaport ,Hangzhou airport
Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present
Cas:122-00-9
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inquiry4'-Methylacetophenone CAS:122-00-9 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic i
Cas:122-00-9
Min.Order:1 Gram
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inquiryHello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai
Cas:122-00-9
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Cas:122-00-9
Min.Order:1 Kilogram
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Cas:122-00-9
Min.Order:1 Kilogram
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Cas:122-00-9
Min.Order:100 Gram
Negotiable
Type:Lab/Research institutions
inquiryOur advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We have s
Conditions | Yield |
---|---|
With AcrH2; perchloric acid; tris(2,2’-bipyridine)ruthenium(II) In acetonitrile at 298℃; for 8h; Irradiation; | 100% |
With AcrH2; perchloric acid; tris(2,2’-bipyridine)ruthenium(II) In acetonitrile at 298℃; for 8h; Quantum yield; Mechanism; Irradiation; Electron-Transfer Rate Constants ;; | 100% |
With ammonium chloride; zinc In ethanol at 80℃; for 0.00833333h; microwave irradiation; | 99% |
Conditions | Yield |
---|---|
With gold(III) tribromide; water at 200℃; for 0.333333h; microwave irradiation; | 100% |
With water at 59.84℃; for 24h; Ionic liquid; | 100% |
With iron(III) chloride; air; water; 1,2-dichloro-ethane at 75℃; for 30h; regioselective reaction; | 99% |
para-methylacetophenone
Conditions | Yield |
---|---|
With tert.-butylhydroperoxide In acetone for 10h; Heating; | 100% |
With phosphoric acid for 0.0166667h; microwave irradiation; | 76% |
Conditions | Yield |
---|---|
With potassium permanganate; iron(III) chloride In acetone at -78 - 20℃; for 16h; | 100% |
With tert.-butylhydroperoxide; 1-n-butyl-3-methylimidazolim bromide In water at 20℃; for 12h; | 92% |
With oxygen In water for 4h; Reflux; | 90% |
Conditions | Yield |
---|---|
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride In 1,4-dioxane for 1h; Heating; | 100% |
Conditions | Yield |
---|---|
With iodine; potassium carbonate In tert-butyl alcohol at 90℃; for 5h; | 99% |
With silica-supported Jones reagent In dichloromethane for 0.00269444h; | 99.5% |
With C53H46ClN3P2Ru; potassium tert-butylate; acetone at 56℃; under 750.075 Torr; for 0.166667h; Oppenauer Oxidation; | 99% |
Conditions | Yield |
---|---|
With aluminum (III) chloride In chloroform at 0 - 20℃; Inert atmosphere; | 99% |
With iron(III) oxide at 20℃; for 0.133333h; Friedel Crafts acylation; regioselective reaction; | 96% |
With iron oxide In neat (no solvent) at 20℃; for 0.05h; Friedel-Crafts Acylation; Green chemistry; | 96% |
Conditions | Yield |
---|---|
With water; oxygen In methanol; dimethyl sulfoxide at 80℃; under 1520.1 Torr; for 20h; Wacker Oxidation; Autoclave; | 98% |
With tert.-butylhydroperoxide; C21H19N5Pd(2+)*2BF4(1-) In decane; acetonitrile at 45℃; for 12h; Wacker Oxidation; | 98% |
With dihydrogen peroxide In water; acetonitrile at 55℃; for 12h; Wacker Oxidation; | 97% |
acetyl chloride
toluene
A
para-methylacetophenone
B
2-Methylacetophenone
Conditions | Yield |
---|---|
With aluminium trichloride; 1-ethyl-3-methyl-1H-imidazol-3-ium chloride at 20℃; for 1h; | A 98% B 1% |
iron oxide for 6h; Ambient temperature; Yield given; | A n/a B 3% |
With silver trifluoromethanesulfonate 1) CH2Cl2, -50 deg C, 15 h, 2) CH2Cl2, -40 deg C, 2,5 h; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts; |
Conditions | Yield |
---|---|
With water; oxygen In acetonitrile at 60℃; under 760.051 Torr; for 2h; Autoclave; Green chemistry; | 97% |
With sodium nitrite In water; acetonitrile at 40℃; for 1.33333h; | 97% |
With Dess-Martin periodane In dichloromethane; water for 0.25h; | 96% |
Acetyl bromide
toluene
A
para-methylacetophenone
B
2-Methylacetophenone
C
3-Methylacetophenone
Conditions | Yield |
---|---|
With iron(II) sulfate for 2h; Product distribution; Ambient temperature; other aromatic hydrocarbon, acetylating reagents, catalyst, reaction times and temperature; | A 97% B 2% C 1% |
CH3C6H4CH(CH3)OH
3,3-dimethyldioxirane
A
2-hydroxy-1-p-tolyl-ethanone
B
para-methylacetophenone
Conditions | Yield |
---|---|
In acetone at 25℃; for 3h; | A 2% B 97% |
In acetone at 25℃; for 3h; Thermodynamic data; Rate constant; Ea, ΔH(excit.), ΔS(excit.), ΔG(excit.); | A 2% B 97% |
Conditions | Yield |
---|---|
With CuCl2*2H2O for 0.00166667h; microwave irradiation; | 96% |
With potassium permanganate; montmorillonite K-10 for 0.166667h; | 95% |
With 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione; water; silica gel In dichloromethane at 20℃; for 2h; | 92% |
1-(4-methylphenyl)ethyl trimethylsilyl ether
para-methylacetophenone
Conditions | Yield |
---|---|
With N-benzyl-N,N-dimethyl anilinium peroxodisulfate In acetonitrile for 0.166667h; Reflux; | 96% |
Conditions | Yield |
---|---|
With 1,10-Phenanthroline; water; palladium diacetate at 100℃; under 760.051 Torr; for 6h; | 96% |
Conditions | Yield |
---|---|
Stage #1: -butyl vinyl ether; para-bromotoluene With meso-2,4-bis(diphenylphosphino)pentane; triethylamine; palladium diacetate In dimethyl sulfoxide at 115℃; for 36h; Heck arylation; Stage #2: With hydrogenchloride In dimethyl sulfoxide at 20℃; | 95% |
Stage #1: -butyl vinyl ether; para-bromotoluene With palladium diacetate; 1,3-bis-(diphenylphosphino)propane; triethylamine In various solvent(s) at 120℃; for 36h; Heck reaction; Stage #2: With hydrogenchloride Further stages.; | 88% |
With 1,3-bis-(diphenylphosphino)propane; diisopropylamine; 1-butyl-3-methylimidazolium Tetrafluoroborate; palladium diacetate In dimethyl sulfoxide at 115℃; for 24h; Heck arylation; | 87% |
With hydrogenchloride; palladium diacetate; 1,3-bis-(diphenylphosphino)propane; thallium(I) acetate; triethylamine 1) DMF, 100 deg C, 6 h; 2) room temp., 1 h; Yield given. Multistep reaction; |
C21H18N6
para-methylacetophenone
Conditions | Yield |
---|---|
With hydrogenchloride In tetrahydrofuran for 10h; Ambient temperature; | 95% |
(Z)-2-(4,5-Dihydro-oxazol-2-yl)-1-p-tolyl-vinylamine
para-methylacetophenone
Conditions | Yield |
---|---|
With sulfuric acid at 100℃; for 6h; | 95% |
4-methylacetophenone hydrazone
para-methylacetophenone
Conditions | Yield |
---|---|
With ammonium dichromate(VI); water; silica gel; zirconium(IV) chloride at 80℃; for 0.583333h; | 95% |
With [(NO3)3Ce]3.H2IO6 In acetonitrile for 0.5h; Heating; | 85% |
With water; silica gel; iodic acid for 0.166667h; | 73% |
Conditions | Yield |
---|---|
With monoethylene glycol diethyl ether at 90℃; for 12h; Green chemistry; | 95% |
With 4,4'-dimethoxyphenyl disulfide; oxygen In acetonitrile at 25℃; under 750.075 Torr; for 16h; Irradiation; | 90.7% |
With tert.-butylhydroperoxide; 2.9-dimethyl-1,10-phenanthroline; copper(II) choride dihydrate In water at 20℃; for 0.5h; Green chemistry; | 89% |
Conditions | Yield |
---|---|
With palladium diacetate; ruphos In methanol; water at 80℃; for 12h; Inert atmosphere; | 95% |
Conditions | Yield |
---|---|
With mesoporous MCM-41-immobilized phosphine-free heterogeneous palladium(0)-schiff base complex In tetrahydrofuran at 68℃; for 2h; Inert atmosphere; Green chemistry; | 95% |
4-methyl-1-methoxyethylbenzene
para-methylacetophenone
Conditions | Yield |
---|---|
With dihydrogen peroxide; bromine In dichloromethane; water at 20℃; for 24h; | 94% |
With 3,3-dimethyldioxirane In acetone at 25℃; Rate constant; | 84 % Spectr. |
Conditions | Yield |
---|---|
With bis-triphenylphosphine-palladium(II) chloride In tetrahydrofuran for 1h; Heating; | 94% |
Conditions | Yield |
---|---|
Stage #1: p-Toluic acid With N,O-dimethylhydroxylamine*hydrochloride; N-ethyl-N,N-diisopropylamine; (bis-(2-methoxyethyl)amino)sulfur trufluoride In tetrahydrofuran; dichloromethane at 20℃; for 0.25h; Stage #2: methylmagnesium bromide In tetrahydrofuran; diethyl ether; dichloromethane at 0℃; for 2h; | 94% |
1-ethenyl-2-pyrrolidinone
4-methylphenylboronic acid
para-methylacetophenone
Conditions | Yield |
---|---|
Stage #1: 1-ethenyl-2-pyrrolidinone; 4-methylphenylboronic acid With 2.9-dimethyl-1,10-phenanthroline; p-benzoquinone; palladium diacetate In acetonitrile at 100℃; for 0.166667h; Heck reaction; microwave irradiation; Stage #2: With silica gel In ethyl acetate Further stages.; | 94% |
2-(dimethylamino)-1-(p-tolyl)ethan-1-one
para-methylacetophenone
Conditions | Yield |
---|---|
With acetic acid; zinc at 20℃; for 1h; | 94% |
2-phenoxy-1-p-tolylethanone
para-methylacetophenone
Conditions | Yield |
---|---|
With 2,6-bis[1-(2,6-dimethylphenylimino)ethyl]pyridine cobalt(II)dichloride; bis(pinacol)diborane; sodium t-butanolate In tetrahydrofuran; methanol at 65℃; for 3h; Schlenk technique; Inert atmosphere; | 94% |
1-p-tolyl-ethanone-E-semicarbazone
para-methylacetophenone
Conditions | Yield |
---|---|
With hydrogenchloride; Tonsil In ethyl acetate for 1.5h; Heating; | 93.3% |
bismuth(III) chloride In tetrahydrofuran; water for 0.166667h; catalysed cleavage; microwave irradiation; | 80% |
With ammonium persulfate; montmorrilonite K10 clay In solid for 0.0333333h; Irradiation; microwave irradiation; | 69% |
para-methylacetophenone
1,3,5-tris(4-methyl-phenyl)-benzene
Conditions | Yield |
---|---|
With trichloro(trifluoromethanesulfonato)titanium(IV) at 90 - 100℃; for 10h; | 100% |
With [Cp2Zr(OSO2C8F17)2]*3H2O*THF In toluene at 110℃; for 3.5h; | 95% |
With trifluorormethanesulfonic acid; oxygen In neat (no solvent) at 120℃; for 12h; Green chemistry; chemoselective reaction; | 93% |
para-methylacetophenone
1-p-tolylethanone oxime
Conditions | Yield |
---|---|
With hydroxylamine hydrochloride; sodium acetate In methanol Heating; | 100% |
With hydroxylamine hydrochloride; sodium acetate In methanol; water Reflux; | 100% |
With hydroxylamine hydrochloride; sodium acetate In ethanol; water Reflux; | 99% |
para-methylacetophenone
(S)-1-(4-Methylphenyl)ethanol
Conditions | Yield |
---|---|
With Trimethyl borate; dimethylsulfide borane complex; (R)-α,α-diphenylprolinol In toluene at 20℃; for 9h; Inert atmosphere; | 100% |
With bis(1,5-cyclooctadiene)diiridium(I) dichloride; (R)-N-(3-methylpyridine-2-methyl)-7-bis-(3,5-di-tert-butylphenyl)phosphino-7′-amino-1,1′-spirodihydroindane; potassium tert-butylate; hydrogen In ethanol at 25 - 30℃; under 7600.51 Torr; for 0.833333h; Autoclave; optical yield given as %ee; enantioselective reaction; | 99% |
With bis(1,5-cyclooctadiene)diiridium(I) dichloride; (R)-7′-bis-(3,5-di-tert-butylphenyl)phosphino-7′-amino-1,1′-spiroindene; potassium tert-butylate; hydrogen In propan-1-ol at 25 - 30℃; under 4560.31 Torr; for 3h; Autoclave; optical yield given as %ee; enantioselective reaction; | 99% |
ethyl trifluoroacetate,
para-methylacetophenone
4,4,4-trifluoro-1-(4-methylphenyl)butane-1,3-dione
Conditions | Yield |
---|---|
With sodium In ethanol at 20℃; for 3.2h; Temperature; | 100% |
With potassium carbonate In isopropyl alcohol; acetonitrile at 40℃; for 24h; Temperature; Solvent; | 99.08% |
With tert-butyl methyl ether; sodium ethanolate In ethanol at 25℃; for 24h; Claisen Condensation; Inert atmosphere; | 99.8% |
Conditions | Yield |
---|---|
With hydroxylamine hydrochloride; sodium acetate In ethanol; water Reflux; | 100% |
With hydroxylamine hydrochloride; sodium acetate In ethanol; water at 95℃; | 100% |
With hydroxylamine hydrochloride; sodium acetate In ethanol; water at 20℃; for 1.5h; Reflux; | 100% |
tetraallyl tin
para-methylacetophenone
2-(4-methylphenyl)-4-penten-2-ol
Conditions | Yield |
---|---|
2,6-dimethylpyridine; zinc trifluoromethanesulfonate In dichloromethane at 20℃; for 24h; | 100% |
polyaniline-supported Sc In dichloromethane at 20℃; for 3.66667h; | 95% |
With gadolinium(III) chloride In acetonitrile at 20℃; for 3h; | 88% |
With C20H32N2O10 In water at 25℃; for 24h; | 72% |
para-methylacetophenone
(R)-1-(4-methylphenyl)ethanol
Conditions | Yield |
---|---|
With formic acid; C37H38ClN2O2RhS; triethylamine In neat (no solvent) at 24 - 30℃; for 22h; Reagent/catalyst; Inert atmosphere; enantioselective reaction; | 100% |
With dimethylsulfide borane complex; (S)-1-methyl-3,3-diphenyl-hexahydropyrrolo[1,2-c][1,3,2]oxazaborole In tetrahydrofuran; toluene at 0 - 20℃; for 1h; | 100% |
With potassium tert-butylate; hydrogen; [bis(2-methylallyl)cycloocta-1,5-diene]ruthenium(II); (R)-Ph-BINAN-H-Py In isopropyl alcohol at 25℃; under 38000 Torr; for 15h; | 99% |
para-methylacetophenone
trifluoroacetic acid
4,4,4-trifluoro-1-(4-methylphenyl)butane-1,3-dione
Conditions | Yield |
---|---|
Stage #1: para-methylacetophenone With sodium hydride In tetrahydrofuran; mineral oil at 0℃; for 0.5h; Inert atmosphere; Stage #2: trifluoroacetic acid In tetrahydrofuran; mineral oil at 20℃; for 5h; Inert atmosphere; | 100% |
With sodium In methanol at 20 - 80℃; for 10h; | 95% |
para-methylacetophenone
methylamine
N-methyl-[1-(4'-methylphenyl)ethylidene]amine
Conditions | Yield |
---|---|
In ethanol at 20℃; for 48h; Molecular sieve; Inert atmosphere; | 100% |
In ethanol at 20℃; for 48h; Inert atmosphere; Molecular sieve; | |
In ethanol at 20℃; Molecular sieve; Inert atmosphere; Schlenk technique; | |
In ethanol at 125℃; for 1.25h; Microwave irradiation; | |
In ethanol at 20℃; for 96h; Schlenk technique; Sealed tube; Inert atmosphere; Molecular sieve; |
4,7-dichloroisatin
para-methylacetophenone
4,7-dichloro-3-hydroxyl-3-(2-oxo-2-p-tolylethyl)-1,3-dihydroindol-2-one
Conditions | Yield |
---|---|
With diethylamine In methanol at 20℃; | 100% |
Conditions | Yield |
---|---|
With titanium tetrachloride In diethyl ether; dichloromethane at 20℃; | 100% |
In benzene at 70℃; for 6h; Molecular sieve; |
Conditions | Yield |
---|---|
With polymer-supported gallium(III) bis(trifluoromethanesulfonate) In dichloromethane at 40℃; under 15001.5 Torr; for 1h; Strecker reaction; Microreactor; | 99.6% |
With sulfated tungstate at 20℃; for 6h; Strecker reaction; Neat (no solvent); | 96% |
With {Cd2(5-(1-{[4-(3,5-dicarboxylatophenyl)-3,5-dimethyl-1H-pyrazol-1-yl]methyl}-3,5-dimethyl-1H-pyrazol-4-yl)benzene-1,3-dicarboxylate)*x(N,N-dimethylformamide)*yH2O}n at 25℃; for 4h; Inert atmosphere; Schlenk technique; | 94% |
Conditions | Yield |
---|---|
With sodium hydroxide for 0.0833333h; Product distribution; Ambient temperature; | 99% |
With sodium hydroxide In ethanol at 5 - 10℃; | 95% |
With sulfuric acid In 1,4-dioxane at 90℃; for 2h; Inert atmosphere; | 91% |
Conditions | Yield |
---|---|
With potassium phosphate tribasic trihydrate; C39H32Cl2N5PRu In tert-Amyl alcohol at 120℃; for 4h; Inert atmosphere; Schlenk technique; | 99% |
With (1,4-dimethyl-5,7-diphenyl-1,2,3,4-tetrahydro-6H-cyclopenta[b]pyrazin-6-one)(triphenylphosphine)(dicarbonyl)iron; caesium carbonate In toluene at 90℃; for 16h; Schlenk technique; Inert atmosphere; | 98% |
With lithium hydroxide at 140℃; for 48h; Reagent/catalyst; Inert atmosphere; | 98% |
Conditions | Yield |
---|---|
With LaCu0.67Si1.33; hydrogen In methanol at 120℃; under 22502.3 Torr; for 10h; Autoclave; | 99% |
With formic acid; C18H24ClIrN3 In water at 80℃; for 4h; Schlenk technique; Inert atmosphere; chemoselective reaction; | 99% |
With hydrogen In ethanol at 20℃; for 5h; | 99% |
Conditions | Yield |
---|---|
With palladium dichloride In methanol at 40℃; for 24h; Inert atmosphere; Green chemistry; chemoselective reaction; | 99% |
With hydrogen In 1,4-dioxane at 200℃; under 15001.5 Torr; | 98.9% |
Stage #1: para-methylacetophenone With iron(III) chloride In methanol at 20℃; for 0.05h; Stage #2: In methanol at 20℃; for 0.166667h; chemoselective reaction; | 98% |
Conditions | Yield |
---|---|
With oxygen; copper(II) nitrate In acetonitrile at 120℃; under 4500.45 Torr; for 10h; | 99% |
With copper(II) nitrate trihydrate; oxygen In acetonitrile at 120℃; under 4500.45 Torr; for 10h; Autoclave; | 97% |
With sodium hydroxide; sodium bromite; sodium bromide In water for 6h; Ambient temperature; | 96% |
4-methylbenzoic acid ethyl ester
para-methylacetophenone
1,3-bis(p-methylphenyl)-1,3-propanedione
Conditions | Yield |
---|---|
With sodium hydroxide | 99% |
With sodium hydride In tetrahydrofuran; mineral oil at 0 - 40℃; for 17h; Inert atmosphere; | 80% |
With sodium hydride In benzene for 10h; | 66% |
With sodium hydride In tetrahydrofuran; mineral oil Inert atmosphere; Reflux; | 33% |
Claisen condensation; |
Methyltriphenylphosphonium bromide
para-methylacetophenone
1-methyl-4-isopropenylbenzene
Conditions | Yield |
---|---|
Stage #1: Methyltriphenylphosphonium bromide With n-butyllithium In tetrahydrofuran at 0℃; for 1h; Inert atmosphere; Stage #2: para-methylacetophenone In tetrahydrofuran at 20℃; Inert atmosphere; | 99% |
Stage #1: Methyltriphenylphosphonium bromide With n-butyllithium In tetrahydrofuran; hexane at 0℃; for 1h; Wittig Olefination; Inert atmosphere; Stage #2: para-methylacetophenone In tetrahydrofuran; hexane at 0 - 23℃; for 18h; Wittig Olefination; Inert atmosphere; | 88% |
Stage #1: Methyltriphenylphosphonium bromide With sodium hydride In tetrahydrofuran at 70℃; for 0.8h; Stage #2: para-methylacetophenone In tetrahydrofuran at 75℃; for 10h; Temperature; Cooling with ice; | 80% |
Conditions | Yield |
---|---|
With N,N,N-trimethylbenzenemethanaminium dichloroiodate In methanol; 1,2-dichloro-ethane for 3h; Heating; | 99% |
With 1,3-dichloro-5,5-dimethylhydantoin; silica gel In methanol for 1h; Reflux; | 92% |
With tetrachlorosilane; urea hydrogen peroxide adduct In dichloromethane at 0℃; for 1h; | 92% |
[bis(acetoxy)iodo]benzene
para-methylacetophenone
2-oxo-2-(4-tolyl)ethyl acetate
Conditions | Yield |
---|---|
With acetic acid; scandium tris(trifluoromethanesulfonate) at 50℃; for 48h; | 99% |
With acetic anhydride; acetic acid |
trimethylsilyl cyanide
para-methylacetophenone
2-(4-tolyl)-2-(trimethylsiloxy)propanenitrile
Conditions | Yield |
---|---|
With MgAlCO3-HT In n-heptane for 0.0833333h; Ambient temperature; | 99% |
With [(3,5-di-tert-Bu,2-OH)-C6H2-CH=N-CH2]2*Ti(O-i-Pr)4; N,N-dimethylaniline N-oxide In dichloromethane at 23℃; for 9h; | 99% |
With C29H46LaN3Si2 at 15℃; for 1h; Inert atmosphere; Glovebox; Schlenk technique; | 99% |
toluene-4-sulfonic acid
para-methylacetophenone
1-(4-methylphenyl)-2-(p-tolylsulfonyloxy)ethanone
Conditions | Yield |
---|---|
With potassium peroxymonosulfate; 4-tolyl iodide In water; acetonitrile at 60℃; for 1h; Inert atmosphere; | 99% |
With Dess-Martin periodane In acetonitrile for 3.5h; Reflux; | 92% |
With [bis(acetoxy)iodo]benzene Microwave irradiation; | 85% |
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