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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

4'-Methylacetophenone Manufacturer/High quality/Best price/In stock

Cas:122-00-9

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 4'-Methylacetophenone supplier in China

Cas:122-00-9

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Jinan Finer Chemical Co., Ltd

Product Description Product Name 4'-Methylacetophenone CAS No. 122-00-9 Appearance Colorless to yellowish liquid Assay ≥99% Capacity 200mt/year Min.packing 100g

4'-Methylacetophenone

Cas:122-00-9

Min.Order:1 Gram

FOB Price: $12.0

Type:Lab/Research institutions

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

4’-methylacetophenone

Cas:122-00-9

Min.Order:1 Gram

Negotiable

Type:Manufacturers

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EAST CHEMSOURCES LIMITED

4'-Methylacetophenone CAS: 122-00-9 EINECS No.: 204-514-8 Molecular formula: C9H10O Molecular weight: 134.1751 Properties: Density: 1.005 Melting point: 22-24°C Boiling point: 226°C Refractive index: 1.532-1.535 Flash point:

4'-Methylacetophenone

Cas:122-00-9

Min.Order:1 Kilogram

FOB Price: $2.0 / 3.0

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 4'-methylacetophenone

Cas:122-00-9

Min.Order:1

Negotiable

Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High Quality Oled CAS 122-00-9 Ethanone,1-(4-methylphenyl)-

Cas:122-00-9

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new api, intermedi

4'-Methylacetophenone

Cas:122-00-9

Min.Order:1 Kilogram

FOB Price: $5.0

Type:Manufacturers

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ANQING CHICO PHARMACEUTICAL CO.,LTD.

High quality. Factory supply. In stock. Best price.1.Quick response within 24 hours;2.Best quality in your requirement;?3.We pay more attention on delivery time, and usually ship on time;4.Under the premise of safety and effectiveness, we can produce

4'-Methylacetophenone

Cas:122-00-9

Min.Order:0

Negotiable

Type:Trading Company

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COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

P-methyl Acetophenone

Cas:122-00-9

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

4'-Methylacetophenone

Cas:122-00-9

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

4'-Methylacetophenone 122-00-9

Cas:122-00-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

4'-Methylacetophenone

Cas:122-00-9

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Top quality CAS 122-00-9 with fast shipping

Cas:122-00-9

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

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Hubei Langyou International Trading Co., Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:off-white to similar to white powder Storage:Store in sealed

High Purity Raw Material 4'-Methylacetophenone CAS 122-00-9 in Cosmetics.

Cas:122-00-9

Min.Order:100 Gram

Negotiable

Type:Other

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Hangzhou Sartort Biopharma Co., Ltd

Appearance:colorless to pale yellow liquid Storage:Store below +30°C. Package:200kg/Drum Application:Chemicals Transportation:Express/Sea/Air Port:Any port in China

4'-Methylacetophenone with high quality

Cas:122-00-9

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Lab/Research institutions

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Shanghai Minstar Chemical Co., Ltd

Product Name: 4'-Methylacetophenone CAS: 122-00-9 MF: C9H10O MW: 134.18 EINECS: 204-514-8 Mol File: 122-00-9.mol 4'-Methylacetophenone Structure 4'-Methylacetophenone Chemical Properties Melting point 22-24 °C (

4'-Methylacetophenone

Cas:122-00-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Ethanone,1-(4-methylphenyl)-

Cas:122-00-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Hangzhou Maytime Bio-Tech Co.,Ltd.

Best service,high quality,competitive price,prompt delivery. Package:200kgs/drum Application:Used as intermediate,like celecoxib. Port:shanghai seaport ,Hangzhou airport

4'-Methylacetophenon

Cas:122-00-9

Min.Order:1 Kilogram

Negotiable

Type:Other

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

4'-Methylacetophenone with CAS: 122-00-9

Cas:122-00-9

Min.Order:1 Kilogram

FOB Price: $31.0 / 46.0

Type:Trading Company

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Qingdao Beluga Import and Export Co., LTD

4'-Methylacetophenone CAS:122-00-9 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic i

4'-Methylacetophenone CAS:122-00-9

Cas:122-00-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

1-(4-Methylpheyl)ethanone

Cas:122-00-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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LIDE PHARMACEUTICALS LIMITED

Advantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the R&amp

Ethanone,1-(4-methylphenyl)-/ LIDE PHARMA- Factory supply / Best price

Cas:122-00-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Mojin Biotechnology Co.,Ltd

Company information: Hebei Mojin Biotechnology Co., Ltd, Our company is a professional in carbomer,carbopol,lead acetate,meglumine diphenyl ethylamine and other chemical raw materials and chemical reagents research and development production ente

4'-Methylacetophenone CAS 122-00-9

Cas:122-00-9

Min.Order:1 Kilogram

FOB Price: $30.0 / 40.0

Type:Trading Company

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Shanxi Ankesi Biotechnology Co., Ltd

Our Advantage 1. Rich experience We specialize in this filed for many years, our APIs exported to all over the world and and we established long friendly relations of cooperation with our clients. 2. Great quality,purity and favorable Good qual

4'-Methylacetophenone CAS 122-00-9 AKS

Cas:122-00-9

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Shanghai Terui OP New Material Technology Co., Ltd.

We have overseas warehouses in California, Nuevo Laredo, Mexico, Vancouver, Canada, Amsterdam, The Netherlands and Melbourne, Australia. Overseas warehouses can provide some of the best selling products. We look forward to cooperating with strong loc

Factory price supply 4'-Methylacetophenone cas 122-00-9

Cas:122-00-9

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Ethanone,1-(4-methylphenyl)-

Cas:122-00-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

4-Methyl Acetophenone

Cas:122-00-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Triumph International Development Limilted

Triumph has the complete production of G- KG - MT service chain,we can make the new technology into productivity quickly in the research and development of new products. Main Service 1.Own made fine chemical products 2.Out sourcing and qua

4'-Methylacetophenone

Cas:122-00-9

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We have s

4'-Methylacetophenone

Cas:122-00-9

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Synthetic route

4-(bromoacetyl)toluene
619-41-0

4-(bromoacetyl)toluene

para-methylacetophenone
122-00-9

para-methylacetophenone

Conditions
ConditionsYield
With AcrH2; perchloric acid; tris(2,2’-bipyridine)ruthenium(II) In acetonitrile at 298℃; for 8h; Irradiation;100%
With AcrH2; perchloric acid; tris(2,2’-bipyridine)ruthenium(II) In acetonitrile at 298℃; for 8h; Quantum yield; Mechanism; Irradiation; Electron-Transfer Rate Constants ;;100%
With ammonium chloride; zinc In ethanol at 80℃; for 0.00833333h; microwave irradiation;99%
4-n-methylphenylacetylene
766-97-2

4-n-methylphenylacetylene

para-methylacetophenone
122-00-9

para-methylacetophenone

Conditions
ConditionsYield
With gold(III) tribromide; water at 200℃; for 0.333333h; microwave irradiation;100%
With water at 59.84℃; for 24h; Ionic liquid;100%
With iron(III) chloride; air; water; 1,2-dichloro-ethane at 75℃; for 30h; regioselective reaction;99%
4-methyl-N'-(1-(p-tolyl)ethylidene)benzenesulfonohydrazide

4-methyl-N'-(1-(p-tolyl)ethylidene)benzenesulfonohydrazide

para-methylacetophenone
122-00-9

para-methylacetophenone

Conditions
ConditionsYield
With tert.-butylhydroperoxide In acetone for 10h; Heating;100%
With phosphoric acid for 0.0166667h; microwave irradiation;76%
4-methylethylbenzene
622-96-8

4-methylethylbenzene

para-methylacetophenone
122-00-9

para-methylacetophenone

Conditions
ConditionsYield
With potassium permanganate; iron(III) chloride In acetone at -78 - 20℃; for 16h;100%
With tert.-butylhydroperoxide; 1-n-butyl-3-methylimidazolim bromide In water at 20℃; for 12h;92%
With oxygen In water for 4h; Reflux;90%
dimethyl zinc(II)
544-97-8

dimethyl zinc(II)

para-bromoacetophenone
99-90-1

para-bromoacetophenone

para-methylacetophenone
122-00-9

para-methylacetophenone

Conditions
ConditionsYield
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride In 1,4-dioxane for 1h; Heating;100%
CH3C6H4CH(CH3)OH
536-50-5

CH3C6H4CH(CH3)OH

para-methylacetophenone
122-00-9

para-methylacetophenone

Conditions
ConditionsYield
With iodine; potassium carbonate In tert-butyl alcohol at 90℃; for 5h;99%
With silica-supported Jones reagent In dichloromethane for 0.00269444h;99.5%
With C53H46ClN3P2Ru; potassium tert-butylate; acetone at 56℃; under 750.075 Torr; for 0.166667h; Oppenauer Oxidation;99%
acetyl chloride
75-36-5

acetyl chloride

toluene
108-88-3

toluene

para-methylacetophenone
122-00-9

para-methylacetophenone

Conditions
ConditionsYield
With aluminum (III) chloride In chloroform at 0 - 20℃; Inert atmosphere;99%
With iron(III) oxide at 20℃; for 0.133333h; Friedel Crafts acylation; regioselective reaction;96%
With iron oxide In neat (no solvent) at 20℃; for 0.05h; Friedel-Crafts Acylation; Green chemistry;96%
1-ethenyl-4-methylbenzene
622-97-9

1-ethenyl-4-methylbenzene

para-methylacetophenone
122-00-9

para-methylacetophenone

Conditions
ConditionsYield
With water; oxygen In methanol; dimethyl sulfoxide at 80℃; under 1520.1 Torr; for 20h; Wacker Oxidation; Autoclave;98%
With tert.-butylhydroperoxide; C21H19N5Pd(2+)*2BF4(1-) In decane; acetonitrile at 45℃; for 12h; Wacker Oxidation;98%
With dihydrogen peroxide In water; acetonitrile at 55℃; for 12h; Wacker Oxidation;97%
acetyl chloride
75-36-5

acetyl chloride

toluene
108-88-3

toluene

A

para-methylacetophenone
122-00-9

para-methylacetophenone

B

2-Methylacetophenone
577-16-2, 122382-54-1

2-Methylacetophenone

Conditions
ConditionsYield
With aluminium trichloride; 1-ethyl-3-methyl-1H-imidazol-3-ium chloride at 20℃; for 1h;A 98%
B 1%
iron oxide for 6h; Ambient temperature; Yield given;A n/a
B 3%
With silver trifluoromethanesulfonate 1) CH2Cl2, -50 deg C, 15 h, 2) CH2Cl2, -40 deg C, 2,5 h; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
4-methylacethophenone oxime
2089-33-0

4-methylacethophenone oxime

para-methylacetophenone
122-00-9

para-methylacetophenone

Conditions
ConditionsYield
With water; oxygen In acetonitrile at 60℃; under 760.051 Torr; for 2h; Autoclave; Green chemistry;97%
With sodium nitrite In water; acetonitrile at 40℃; for 1.33333h;97%
With Dess-Martin periodane In dichloromethane; water for 0.25h;96%
Acetyl bromide
506-96-7

Acetyl bromide

toluene
108-88-3

toluene

A

para-methylacetophenone
122-00-9

para-methylacetophenone

B

2-Methylacetophenone
577-16-2, 122382-54-1

2-Methylacetophenone

C

3-Methylacetophenone
585-74-0

3-Methylacetophenone

Conditions
ConditionsYield
With iron(II) sulfate for 2h; Product distribution; Ambient temperature; other aromatic hydrocarbon, acetylating reagents, catalyst, reaction times and temperature;A 97%
B 2%
C 1%
CH3C6H4CH(CH3)OH
536-50-5

CH3C6H4CH(CH3)OH

3,3-dimethyldioxirane
74087-85-7

3,3-dimethyldioxirane

A

2-hydroxy-1-p-tolyl-ethanone
4079-54-3

2-hydroxy-1-p-tolyl-ethanone

B

para-methylacetophenone
122-00-9

para-methylacetophenone

Conditions
ConditionsYield
In acetone at 25℃; for 3h;A 2%
B 97%
In acetone at 25℃; for 3h; Thermodynamic data; Rate constant; Ea, ΔH(excit.), ΔS(excit.), ΔG(excit.);A 2%
B 97%
p-methyl acetophenone semicarbazone
3352-98-5

p-methyl acetophenone semicarbazone

para-methylacetophenone
122-00-9

para-methylacetophenone

Conditions
ConditionsYield
With CuCl2*2H2O for 0.00166667h; microwave irradiation;96%
With potassium permanganate; montmorillonite K-10 for 0.166667h;95%
With 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione; water; silica gel In dichloromethane at 20℃; for 2h;92%
1-(4-methylphenyl)ethyl trimethylsilyl ether
128816-30-8

1-(4-methylphenyl)ethyl trimethylsilyl ether

para-methylacetophenone
122-00-9

para-methylacetophenone

Conditions
ConditionsYield
With N-benzyl-N,N-dimethyl anilinium peroxodisulfate In acetonitrile for 0.166667h; Reflux;96%
toluene-4-sulfonic acid hydrazide
1576-35-8

toluene-4-sulfonic acid hydrazide

acetonitrile
75-05-8

acetonitrile

para-methylacetophenone
122-00-9

para-methylacetophenone

Conditions
ConditionsYield
With 1,10-Phenanthroline; water; palladium diacetate at 100℃; under 760.051 Torr; for 6h;96%
-butyl vinyl ether
111-34-2

-butyl vinyl ether

para-bromotoluene
106-38-7

para-bromotoluene

para-methylacetophenone
122-00-9

para-methylacetophenone

Conditions
ConditionsYield
Stage #1: -butyl vinyl ether; para-bromotoluene With meso-2,4-bis(diphenylphosphino)pentane; triethylamine; palladium diacetate In dimethyl sulfoxide at 115℃; for 36h; Heck arylation;
Stage #2: With hydrogenchloride In dimethyl sulfoxide at 20℃;
95%
Stage #1: -butyl vinyl ether; para-bromotoluene With palladium diacetate; 1,3-bis-(diphenylphosphino)propane; triethylamine In various solvent(s) at 120℃; for 36h; Heck reaction;
Stage #2: With hydrogenchloride Further stages.;
88%
With 1,3-bis-(diphenylphosphino)propane; diisopropylamine; 1-butyl-3-methylimidazolium Tetrafluoroborate; palladium diacetate In dimethyl sulfoxide at 115℃; for 24h; Heck arylation;87%
With hydrogenchloride; palladium diacetate; 1,3-bis-(diphenylphosphino)propane; thallium(I) acetate; triethylamine 1) DMF, 100 deg C, 6 h; 2) room temp., 1 h; Yield given. Multistep reaction;
C21H18N6
111508-08-8

C21H18N6

para-methylacetophenone
122-00-9

para-methylacetophenone

Conditions
ConditionsYield
With hydrogenchloride In tetrahydrofuran for 10h; Ambient temperature;95%
(Z)-2-(4,5-Dihydro-oxazol-2-yl)-1-p-tolyl-vinylamine
143407-58-3

(Z)-2-(4,5-Dihydro-oxazol-2-yl)-1-p-tolyl-vinylamine

para-methylacetophenone
122-00-9

para-methylacetophenone

Conditions
ConditionsYield
With sulfuric acid at 100℃; for 6h;95%
4-methylacetophenone hydrazone
64252-53-5

4-methylacetophenone hydrazone

para-methylacetophenone
122-00-9

para-methylacetophenone

Conditions
ConditionsYield
With ammonium dichromate(VI); water; silica gel; zirconium(IV) chloride at 80℃; for 0.583333h;95%
With [(NO3)3Ce]3.H2IO6 In acetonitrile for 0.5h; Heating;85%
With water; silica gel; iodic acid for 0.166667h;73%
1-methyl-4-isopropenylbenzene
1195-32-0

1-methyl-4-isopropenylbenzene

para-methylacetophenone
122-00-9

para-methylacetophenone

Conditions
ConditionsYield
With monoethylene glycol diethyl ether at 90℃; for 12h; Green chemistry;95%
With 4,4'-dimethoxyphenyl disulfide; oxygen In acetonitrile at 25℃; under 750.075 Torr; for 16h; Irradiation;90.7%
With tert.-butylhydroperoxide; 2.9-dimethyl-1,10-phenanthroline; copper(II) choride dihydrate In water at 20℃; for 0.5h; Green chemistry;89%
lithium methyltriolborate

lithium methyltriolborate

para-bromoacetophenone
99-90-1

para-bromoacetophenone

para-methylacetophenone
122-00-9

para-methylacetophenone

Conditions
ConditionsYield
With palladium diacetate; ruphos In methanol; water at 80℃; for 12h; Inert atmosphere;95%
trimethyl indium
3385-78-2

trimethyl indium

4-methyl-benzoyl chloride
874-60-2

4-methyl-benzoyl chloride

para-methylacetophenone
122-00-9

para-methylacetophenone

Conditions
ConditionsYield
With mesoporous MCM-41-immobilized phosphine-free heterogeneous palladium(0)-schiff base complex In tetrahydrofuran at 68℃; for 2h; Inert atmosphere; Green chemistry;95%
4-methyl-1-methoxyethylbenzene
79744-75-5

4-methyl-1-methoxyethylbenzene

para-methylacetophenone
122-00-9

para-methylacetophenone

Conditions
ConditionsYield
With dihydrogen peroxide; bromine In dichloromethane; water at 20℃; for 24h;94%
With 3,3-dimethyldioxirane In acetone at 25℃; Rate constant;84 % Spectr.
para-bromoacetophenone
99-90-1

para-bromoacetophenone

trimethyl indium
3385-78-2

trimethyl indium

para-methylacetophenone
122-00-9

para-methylacetophenone

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride In tetrahydrofuran for 1h; Heating;94%
methylmagnesium bromide
75-16-1

methylmagnesium bromide

p-Toluic acid
99-94-5

p-Toluic acid

para-methylacetophenone
122-00-9

para-methylacetophenone

Conditions
ConditionsYield
Stage #1: p-Toluic acid With N,O-dimethylhydroxylamine*hydrochloride; N-ethyl-N,N-diisopropylamine; (bis-(2-methoxyethyl)amino)sulfur trufluoride In tetrahydrofuran; dichloromethane at 20℃; for 0.25h;
Stage #2: methylmagnesium bromide In tetrahydrofuran; diethyl ether; dichloromethane at 0℃; for 2h;
94%
1-ethenyl-2-pyrrolidinone
88-12-0

1-ethenyl-2-pyrrolidinone

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

para-methylacetophenone
122-00-9

para-methylacetophenone

Conditions
ConditionsYield
Stage #1: 1-ethenyl-2-pyrrolidinone; 4-methylphenylboronic acid With 2.9-dimethyl-1,10-phenanthroline; p-benzoquinone; palladium diacetate In acetonitrile at 100℃; for 0.166667h; Heck reaction; microwave irradiation;
Stage #2: With silica gel In ethyl acetate Further stages.;
94%
2-(dimethylamino)-1-(p-tolyl)ethan-1-one
80354-58-1

2-(dimethylamino)-1-(p-tolyl)ethan-1-one

para-methylacetophenone
122-00-9

para-methylacetophenone

Conditions
ConditionsYield
With acetic acid; zinc at 20℃; for 1h;94%
2-phenoxy-1-p-tolylethanone
19513-79-2

2-phenoxy-1-p-tolylethanone

para-methylacetophenone
122-00-9

para-methylacetophenone

Conditions
ConditionsYield
With 2,6-bis[1-(2,6-dimethylphenylimino)ethyl]pyridine cobalt(II)dichloride; bis(pinacol)diborane; sodium t-butanolate In tetrahydrofuran; methanol at 65℃; for 3h; Schlenk technique; Inert atmosphere;94%
1-p-tolyl-ethanone-E-semicarbazone
120445-91-2

1-p-tolyl-ethanone-E-semicarbazone

para-methylacetophenone
122-00-9

para-methylacetophenone

Conditions
ConditionsYield
With hydrogenchloride; Tonsil In ethyl acetate for 1.5h; Heating;93.3%
bismuth(III) chloride In tetrahydrofuran; water for 0.166667h; catalysed cleavage; microwave irradiation;80%
With ammonium persulfate; montmorrilonite K10 clay In solid for 0.0333333h; Irradiation; microwave irradiation;69%
para-methylacetophenone
122-00-9

para-methylacetophenone

1,3,5-tris(4-methyl-phenyl)-benzene
50446-43-0

1,3,5-tris(4-methyl-phenyl)-benzene

Conditions
ConditionsYield
With trichloro(trifluoromethanesulfonato)titanium(IV) at 90 - 100℃; for 10h;100%
With [Cp2Zr(OSO2C8F17)2]*3H2O*THF In toluene at 110℃; for 3.5h;95%
With trifluorormethanesulfonic acid; oxygen In neat (no solvent) at 120℃; for 12h; Green chemistry; chemoselective reaction;93%
para-methylacetophenone
122-00-9

para-methylacetophenone

1-p-tolylethanone oxime
54582-23-9

1-p-tolylethanone oxime

Conditions
ConditionsYield
With hydroxylamine hydrochloride; sodium acetate In methanol Heating;100%
With hydroxylamine hydrochloride; sodium acetate In methanol; water Reflux;100%
With hydroxylamine hydrochloride; sodium acetate In ethanol; water Reflux;99%
para-methylacetophenone
122-00-9

para-methylacetophenone

(S)-1-(4-Methylphenyl)ethanol
536-50-5, 5788-09-0, 42070-92-8, 51154-54-2

(S)-1-(4-Methylphenyl)ethanol

Conditions
ConditionsYield
With Trimethyl borate; dimethylsulfide borane complex; (R)-α,α-diphenylprolinol In toluene at 20℃; for 9h; Inert atmosphere;100%
With bis(1,5-cyclooctadiene)diiridium(I) dichloride; (R)-N-(3-methylpyridine-2-methyl)-7-bis-(3,5-di-tert-butylphenyl)phosphino-7′-amino-1,1′-spirodihydroindane; potassium tert-butylate; hydrogen In ethanol at 25 - 30℃; under 7600.51 Torr; for 0.833333h; Autoclave; optical yield given as %ee; enantioselective reaction;99%
With bis(1,5-cyclooctadiene)diiridium(I) dichloride; (R)-7′-bis-(3,5-di-tert-butylphenyl)phosphino-7′-amino-1,1′-spiroindene; potassium tert-butylate; hydrogen In propan-1-ol at 25 - 30℃; under 4560.31 Torr; for 3h; Autoclave; optical yield given as %ee; enantioselective reaction;99%
ethyl trifluoroacetate,
383-63-1

ethyl trifluoroacetate,

para-methylacetophenone
122-00-9

para-methylacetophenone

4,4,4-trifluoro-1-(4-methylphenyl)butane-1,3-dione
720-94-5

4,4,4-trifluoro-1-(4-methylphenyl)butane-1,3-dione

Conditions
ConditionsYield
With sodium In ethanol at 20℃; for 3.2h; Temperature;100%
With potassium carbonate In isopropyl alcohol; acetonitrile at 40℃; for 24h; Temperature; Solvent;99.08%
With tert-butyl methyl ether; sodium ethanolate In ethanol at 25℃; for 24h; Claisen Condensation; Inert atmosphere;99.8%
para-methylacetophenone
122-00-9

para-methylacetophenone

4-methylacethophenone oxime
2089-33-0

4-methylacethophenone oxime

Conditions
ConditionsYield
With hydroxylamine hydrochloride; sodium acetate In ethanol; water Reflux;100%
With hydroxylamine hydrochloride; sodium acetate In ethanol; water at 95℃;100%
With hydroxylamine hydrochloride; sodium acetate In ethanol; water at 20℃; for 1.5h; Reflux;100%
tetraallyl tin
7393-43-3

tetraallyl tin

para-methylacetophenone
122-00-9

para-methylacetophenone

2-(4-methylphenyl)-4-penten-2-ol
110577-96-3, 110577-98-5, 99288-98-9

2-(4-methylphenyl)-4-penten-2-ol

Conditions
ConditionsYield
2,6-dimethylpyridine; zinc trifluoromethanesulfonate In dichloromethane at 20℃; for 24h;100%
polyaniline-supported Sc In dichloromethane at 20℃; for 3.66667h;95%
With gadolinium(III) chloride In acetonitrile at 20℃; for 3h;88%
With C20H32N2O10 In water at 25℃; for 24h;72%
para-methylacetophenone
122-00-9

para-methylacetophenone

(R)-1-(4-methylphenyl)ethanol
42070-92-8

(R)-1-(4-methylphenyl)ethanol

Conditions
ConditionsYield
With formic acid; C37H38ClN2O2RhS; triethylamine In neat (no solvent) at 24 - 30℃; for 22h; Reagent/catalyst; Inert atmosphere; enantioselective reaction;100%
With dimethylsulfide borane complex; (S)-1-methyl-3,3-diphenyl-hexahydropyrrolo[1,2-c][1,3,2]oxazaborole In tetrahydrofuran; toluene at 0 - 20℃; for 1h;100%
With potassium tert-butylate; hydrogen; [bis(2-methylallyl)cycloocta-1,5-diene]ruthenium(II); (R)-Ph-BINAN-H-Py In isopropyl alcohol at 25℃; under 38000 Torr; for 15h;99%
para-methylacetophenone
122-00-9

para-methylacetophenone

trifluoroacetic acid
76-05-1

trifluoroacetic acid

4,4,4-trifluoro-1-(4-methylphenyl)butane-1,3-dione
720-94-5

4,4,4-trifluoro-1-(4-methylphenyl)butane-1,3-dione

Conditions
ConditionsYield
Stage #1: para-methylacetophenone With sodium hydride In tetrahydrofuran; mineral oil at 0℃; for 0.5h; Inert atmosphere;
Stage #2: trifluoroacetic acid In tetrahydrofuran; mineral oil at 20℃; for 5h; Inert atmosphere;
100%
With sodium In methanol at 20 - 80℃; for 10h;95%
para-methylacetophenone
122-00-9

para-methylacetophenone

methylamine
74-89-5

methylamine

N-methyl-[1-(4'-methylphenyl)ethylidene]amine
53370-98-2

N-methyl-[1-(4'-methylphenyl)ethylidene]amine

Conditions
ConditionsYield
In ethanol at 20℃; for 48h; Molecular sieve; Inert atmosphere;100%
In ethanol at 20℃; for 48h; Inert atmosphere; Molecular sieve;
In ethanol at 20℃; Molecular sieve; Inert atmosphere; Schlenk technique;
In ethanol at 125℃; for 1.25h; Microwave irradiation;
In ethanol at 20℃; for 96h; Schlenk technique; Sealed tube; Inert atmosphere; Molecular sieve;
4,7-dichloroisatin
18711-13-2

4,7-dichloroisatin

para-methylacetophenone
122-00-9

para-methylacetophenone

4,7-dichloro-3-hydroxyl-3-(2-oxo-2-p-tolylethyl)-1,3-dihydroindol-2-one
1037184-43-2

4,7-dichloro-3-hydroxyl-3-(2-oxo-2-p-tolylethyl)-1,3-dihydroindol-2-one

Conditions
ConditionsYield
With diethylamine In methanol at 20℃;100%
N-butylamine
109-73-9

N-butylamine

para-methylacetophenone
122-00-9

para-methylacetophenone

C13H19N

C13H19N

Conditions
ConditionsYield
With titanium tetrachloride In diethyl ether; dichloromethane at 20℃;100%
In benzene at 70℃; for 6h; Molecular sieve;
trimethylsilyl cyanide
7677-24-9

trimethylsilyl cyanide

aniline
62-53-3

aniline

para-methylacetophenone
122-00-9

para-methylacetophenone

α,4-dimethyl-α-(phenylamino)benzeneacetonitrile

α,4-dimethyl-α-(phenylamino)benzeneacetonitrile

Conditions
ConditionsYield
With polymer-supported gallium(III) bis(trifluoromethanesulfonate) In dichloromethane at 40℃; under 15001.5 Torr; for 1h; Strecker reaction; Microreactor;99.6%
With sulfated tungstate at 20℃; for 6h; Strecker reaction; Neat (no solvent);96%
With {Cd2(5-(1-{[4-(3,5-dicarboxylatophenyl)-3,5-dimethyl-1H-pyrazol-1-yl]methyl}-3,5-dimethyl-1H-pyrazol-4-yl)benzene-1,3-dicarboxylate)*x(N,N-dimethylformamide)*yH2O}n at 25℃; for 4h; Inert atmosphere; Schlenk technique;94%
4-methyl-benzaldehyde
104-87-0

4-methyl-benzaldehyde

para-methylacetophenone
122-00-9

para-methylacetophenone

4,4'-Dimethylchalcon
21551-47-3

4,4'-Dimethylchalcon

Conditions
ConditionsYield
With sodium hydroxide for 0.0833333h; Product distribution; Ambient temperature;99%
With sodium hydroxide In ethanol at 5 - 10℃;95%
With sulfuric acid In 1,4-dioxane at 90℃; for 2h; Inert atmosphere;91%
para-methylacetophenone
122-00-9

para-methylacetophenone

benzyl alcohol
100-51-6

benzyl alcohol

4-methylphenyl phenethyl ketone
5012-90-8

4-methylphenyl phenethyl ketone

Conditions
ConditionsYield
With potassium phosphate tribasic trihydrate; C39H32Cl2N5PRu In tert-Amyl alcohol at 120℃; for 4h; Inert atmosphere; Schlenk technique;99%
With (1,4-dimethyl-5,7-diphenyl-1,2,3,4-tetrahydro-6H-cyclopenta[b]pyrazin-6-one)(triphenylphosphine)(dicarbonyl)iron; caesium carbonate In toluene at 90℃; for 16h; Schlenk technique; Inert atmosphere;98%
With lithium hydroxide at 140℃; for 48h; Reagent/catalyst; Inert atmosphere;98%
para-methylacetophenone
122-00-9

para-methylacetophenone

CH3C6H4CH(CH3)OH
536-50-5

CH3C6H4CH(CH3)OH

Conditions
ConditionsYield
With LaCu0.67Si1.33; hydrogen In methanol at 120℃; under 22502.3 Torr; for 10h; Autoclave;99%
With formic acid; C18H24ClIrN3 In water at 80℃; for 4h; Schlenk technique; Inert atmosphere; chemoselective reaction;99%
With hydrogen In ethanol at 20℃; for 5h;99%
para-methylacetophenone
122-00-9

para-methylacetophenone

4-methylethylbenzene
622-96-8

4-methylethylbenzene

Conditions
ConditionsYield
With palladium dichloride In methanol at 40℃; for 24h; Inert atmosphere; Green chemistry; chemoselective reaction;99%
With hydrogen In 1,4-dioxane at 200℃; under 15001.5 Torr;98.9%
Stage #1: para-methylacetophenone With iron(III) chloride In methanol at 20℃; for 0.05h;
Stage #2: In methanol at 20℃; for 0.166667h; chemoselective reaction;
98%
para-methylacetophenone
122-00-9

para-methylacetophenone

p-Toluic acid
99-94-5

p-Toluic acid

Conditions
ConditionsYield
With oxygen; copper(II) nitrate In acetonitrile at 120℃; under 4500.45 Torr; for 10h;99%
With copper(II) nitrate trihydrate; oxygen In acetonitrile at 120℃; under 4500.45 Torr; for 10h; Autoclave;97%
With sodium hydroxide; sodium bromite; sodium bromide In water for 6h; Ambient temperature;96%
4-methylbenzoic acid ethyl ester
94-08-6

4-methylbenzoic acid ethyl ester

para-methylacetophenone
122-00-9

para-methylacetophenone

1,3-bis(p-methylphenyl)-1,3-propanedione
3594-36-3

1,3-bis(p-methylphenyl)-1,3-propanedione

Conditions
ConditionsYield
With sodium hydroxide99%
With sodium hydride In tetrahydrofuran; mineral oil at 0 - 40℃; for 17h; Inert atmosphere;80%
With sodium hydride In benzene for 10h;66%
With sodium hydride In tetrahydrofuran; mineral oil Inert atmosphere; Reflux;33%
Claisen condensation;
Methyltriphenylphosphonium bromide
1779-49-3

Methyltriphenylphosphonium bromide

para-methylacetophenone
122-00-9

para-methylacetophenone

1-methyl-4-isopropenylbenzene
1195-32-0

1-methyl-4-isopropenylbenzene

Conditions
ConditionsYield
Stage #1: Methyltriphenylphosphonium bromide With n-butyllithium In tetrahydrofuran at 0℃; for 1h; Inert atmosphere;
Stage #2: para-methylacetophenone In tetrahydrofuran at 20℃; Inert atmosphere;
99%
Stage #1: Methyltriphenylphosphonium bromide With n-butyllithium In tetrahydrofuran; hexane at 0℃; for 1h; Wittig Olefination; Inert atmosphere;
Stage #2: para-methylacetophenone In tetrahydrofuran; hexane at 0 - 23℃; for 18h; Wittig Olefination; Inert atmosphere;
88%
Stage #1: Methyltriphenylphosphonium bromide With sodium hydride In tetrahydrofuran at 70℃; for 0.8h;
Stage #2: para-methylacetophenone In tetrahydrofuran at 75℃; for 10h; Temperature; Cooling with ice;
80%
para-methylacetophenone
122-00-9

para-methylacetophenone

p-methylphenacyl chloride
4209-24-9

p-methylphenacyl chloride

Conditions
ConditionsYield
With N,N,N-trimethylbenzenemethanaminium dichloroiodate In methanol; 1,2-dichloro-ethane for 3h; Heating;99%
With 1,3-dichloro-5,5-dimethylhydantoin; silica gel In methanol for 1h; Reflux;92%
With tetrachlorosilane; urea hydrogen peroxide adduct In dichloromethane at 0℃; for 1h;92%
[bis(acetoxy)iodo]benzene
3240-34-4

[bis(acetoxy)iodo]benzene

para-methylacetophenone
122-00-9

para-methylacetophenone

2-oxo-2-(4-tolyl)ethyl acetate
65143-37-5

2-oxo-2-(4-tolyl)ethyl acetate

Conditions
ConditionsYield
With acetic acid; scandium tris(trifluoromethanesulfonate) at 50℃; for 48h;99%
With acetic anhydride; acetic acid
trimethylsilyl cyanide
7677-24-9

trimethylsilyl cyanide

para-methylacetophenone
122-00-9

para-methylacetophenone

2-(4-tolyl)-2-(trimethylsiloxy)propanenitrile
69813-79-2

2-(4-tolyl)-2-(trimethylsiloxy)propanenitrile

Conditions
ConditionsYield
With MgAlCO3-HT In n-heptane for 0.0833333h; Ambient temperature;99%
With [(3,5-di-tert-Bu,2-OH)-C6H2-CH=N-CH2]2*Ti(O-i-Pr)4; N,N-dimethylaniline N-oxide In dichloromethane at 23℃; for 9h;99%
With C29H46LaN3Si2 at 15℃; for 1h; Inert atmosphere; Glovebox; Schlenk technique;99%
toluene-4-sulfonic acid
104-15-4

toluene-4-sulfonic acid

para-methylacetophenone
122-00-9

para-methylacetophenone

1-(4-methylphenyl)-2-(p-tolylsulfonyloxy)ethanone
98475-04-8

1-(4-methylphenyl)-2-(p-tolylsulfonyloxy)ethanone

Conditions
ConditionsYield
With potassium peroxymonosulfate; 4-tolyl iodide In water; acetonitrile at 60℃; for 1h; Inert atmosphere;99%
With Dess-Martin periodane In acetonitrile for 3.5h; Reflux;92%
With [bis(acetoxy)iodo]benzene Microwave irradiation;85%
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