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Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures

Phenoxazine

Cas:135-67-1

Min.Order:1 Kilogram

FOB Price: $10.0 / 20.0

Type:Lab/Research institutions

inquiry

Hangzhou Dingyan Chem Co., Ltd

Items Standard Result Assay (Ursolic acid) 98%min 98.22% ----------------------------------------------------------------

High purity 135-67-1 Phenoxazine

Cas:135-67-1

Min.Order:1 Gram

FOB Price: $100.0 / 500.0

Type:Trading Company

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Phenoxazine supplier in China

Cas:135-67-1

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:white powder Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

Phenoxazine

Cas:135-67-1

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Phenoxazine

Cas:135-67-1

Min.Order:1

Negotiable

Type:Other

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Puyang Huicheng Electronic Material Co., Ltd

Puyang Huicheng Electronic Material Co., Ltd was founded in 2002, which is focus on high complex new type intermediates and fine chemical custom synthesis, LED&OLED materials and related intermediates, catalyst design and synthesi

manufacturer of Phenoxazine professional supplier

Cas:135-67-1

Min.Order:100 Gram

Negotiable

Type:Manufacturers

inquiry

Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 135-67-1 Phenoxazine Manufacturer

Cas:135-67-1

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis

Phenoxazine

Cas:135-67-1

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Phenoxazine

Cas:135-67-1

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

135-67-1 Phenoxazine

Cas:135-67-1

Min.Order:1 Kilogram

FOB Price: $15.0 / 50.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Discount price CAS 135-67-1 with best quality

Cas:135-67-1

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Wuhan Fortuna Chemical Co.,Ltd

1.High quality : the purity is 99% min . through multiple producing procedures. 2.Competitive price : low price because of our skilled production technolpgy ,save the production cost at most , and give big profit room to our customers 3.Safe a

Phenoxazine

Cas:135-67-1

Min.Order:0 Metric Ton

Negotiable

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Phenoxazine 135-67-1

Cas:135-67-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

Product Name: Phenoxazine CAS: 135-67-1 MF: C12H9NO MW: 183.21 EINECS: 205-210-8 Mol File: 135-67-1.mol Phenoxazine Structure Phenoxazine Chemical Properties Melting point 156-159 °C (lit.) Boiling point 316.88°C (

Phenoxazine

Cas:135-67-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

PhenoxazineCAS: 135-67-1 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermediates,

PhenoxazineCAS: 135-67-1

Cas:135-67-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Phenoxazine

Cas:135-67-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

LIDE PHARMACEUTICALS LIMITED

Advantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the R&amp

Phenoxazine/ LIDE PHARMA- Factory supply / Best price

Cas:135-67-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Phenoxazine

Cas:135-67-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Triumph International Development Limilted

Triumph has the complete production of G- KG - MT service chain,we can make the new technology into productivity quickly in the research and development of new products. Main Service 1.Own made fine chemical products 2.Out sourcing and qua

Phenoxazine

Cas:135-67-1

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

superior quality Appearance:green gray powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Used as Pharmaceutical Intermediates Transportation

Phenoxazine

Cas:135-67-1

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Phenoxazine

Cas:135-67-1

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

Phenoxazine

Cas:135-67-1

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Phenoxazine

Cas:135-67-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products Phenoxazine

Cas:135-67-1

Min.Order:100 Gram

Negotiable

Type:Other

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality Phenoxazine

Cas:135-67-1

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Hangzhou Lingrui Chemical Co.,Ltd.

PhenoxazineAppearance:White fine powder Storage:Kept in a cool,dry and ventilated place Package:according to customers' requirements Application:Meets the requirements Transportation:By air(EMS or EUB or FedEx or TNT ect...) or by sea(FOB or CIF or C

Phenoxazine

Cas:135-67-1

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

Phenoxazine

Cas:135-67-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Siwei Development Group Ltd.

Product name: Phenoxazine CAS No.:135-67-1 Molecule Formula:C12H9NO Molecule Weight:183.21 Purity: 98.0% Package: 25kg/drum Description:White powder Manufacture Standards:Enterprise Standard TESTING ITEMS SPECIFIC

High Quality Phenoxazine on stock

Cas:135-67-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

Phenoxazine

Cas:135-67-1

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Suzhou Sinosun Imp.&Exp. Corporation

We're in good position to supply OLED intermediates . In the past 25 years, we have won technical support from several well-known universities and institutes. We have developed many chemicals together. It makes us capable of developing Cust

Phenoxazine

Cas:135-67-1

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Synthetic route

1-(10H-phenoxazin-10-yl)ethan-1-one
6192-43-4

1-(10H-phenoxazin-10-yl)ethan-1-one

phenoxazine
135-67-1

phenoxazine

Conditions
ConditionsYield
With sodium methylate Inert atmosphere;98%
Stage #1: 1-(10H-phenoxazin-10-yl)ethan-1-one With Triethoxysilane; sodium triethylborohydride In tert-butyl methyl ether at 80℃; for 24h;
Stage #2: With hydrogenchloride In tert-butyl methyl ether; water at 20℃; for 1h; chemoselective reaction;
69%
With triethyl borane; sodium hydroxide In tert-butyl methyl ether at 80℃; for 6h; Inert atmosphere; Sealed tube;63%
With sulfuric acid
Multi-step reaction with 2 steps
1: potassium hydroxide; triethyl borane / tetrahydrofuran / 24 h / 25 °C / Inert atmosphere; Schlenk technique; Sealed tube
2: sodium hydroxide; water / tetrahydrofuran / 1 h / 25 °C / Inert atmosphere; Schlenk technique; Sealed tube
View Scheme
N -(2-(2-fluorophenoxy)phenyl)acetamide

N -(2-(2-fluorophenoxy)phenyl)acetamide

phenoxazine
135-67-1

phenoxazine

Conditions
ConditionsYield
With caesium carbonate In N,N-dimethyl-formamide at 155℃; for 0.25h; Microwave irradiation; chemoselective reaction;90%
N -(2-(2-chlorophenoxy)phenyl)acetamide
873977-74-3

N -(2-(2-chlorophenoxy)phenyl)acetamide

phenoxazine
135-67-1

phenoxazine

Conditions
ConditionsYield
With caesium carbonate In N,N-dimethyl-formamide at 155℃; for 0.25h; Microwave irradiation; chemoselective reaction;85%
N-(2-(2-bromophenoxy)phenyl)acetamide
204847-21-2

N-(2-(2-bromophenoxy)phenyl)acetamide

phenoxazine
135-67-1

phenoxazine

Conditions
ConditionsYield
With caesium carbonate In N,N-dimethyl-formamide at 155℃; for 0.25h; Temperature; Solvent; Reagent/catalyst; Microwave irradiation; chemoselective reaction;83%
Multi-step reaction with 2 steps
1: caesium carbonate / N,N-dimethyl-formamide / 0.25 h / 100 °C / Microwave irradiation
2: caesium carbonate / N,N-dimethyl-formamide / 0.25 h / 155 °C / Microwave irradiation
View Scheme
N-(2-(2-iodophenoxy)phenyl)acetamide
1370030-52-6

N-(2-(2-iodophenoxy)phenyl)acetamide

phenoxazine
135-67-1

phenoxazine

Conditions
ConditionsYield
With caesium carbonate In N,N-dimethyl-formamide at 155℃; for 0.25h; Microwave irradiation; chemoselective reaction;74%
Multi-step reaction with 2 steps
1: potassium carbonate; N,N`-dimethylethylenediamine / toluene / 24 h / 135 °C / Inert atmosphere
2: sodium methylate / Inert atmosphere
View Scheme
C12H9NO(1+)*ClO4(1-)

C12H9NO(1+)*ClO4(1-)

phenoxazine
135-67-1

phenoxazine

Conditions
ConditionsYield
With zinc73%
cyclopentadienyliron hexafluorophosphate of phenoxazine

cyclopentadienyliron hexafluorophosphate of phenoxazine

phenoxazine
135-67-1

phenoxazine

Conditions
ConditionsYield
In N,N-dimethyl-formamide electrolysis in 0.2M KClO4 with mercury pool working electrode, Ag/0.1M AgNO3 reference electrode, Pt counter electrode, potential -1.90 V;73%
η6-phenoxazine-η5-cyclopentadienyliron hexafluorophosphate

η6-phenoxazine-η5-cyclopentadienyliron hexafluorophosphate

phenoxazine
135-67-1

phenoxazine

Conditions
ConditionsYield
at 200 - 250℃; under 1 Torr; for 1h;48%
N-(2-(2-bromophenoxy)phenyl)acetamide
204847-21-2

N-(2-(2-bromophenoxy)phenyl)acetamide

A

1-(10H-phenoxazin-10-yl)ethan-1-one
6192-43-4

1-(10H-phenoxazin-10-yl)ethan-1-one

B

phenoxazine
135-67-1

phenoxazine

Conditions
ConditionsYield
With sodium carbonate In N,N-dimethyl-formamide at 155℃; for 0.25h; Reagent/catalyst; Temperature; Microwave irradiation;A 27%
B 48%
10-(α-methylbenzyl)phenoxazine
113202-17-8

10-(α-methylbenzyl)phenoxazine

methyl iodide
74-88-4

methyl iodide

A

phenoxazine
135-67-1

phenoxazine

B

4-methyl-N-(α-phenylethyl)phenoxazine
113201-93-7

4-methyl-N-(α-phenylethyl)phenoxazine

C

4,6-dimethyl-N-(α-phenylethyl)phenoxazine
113202-08-7

4,6-dimethyl-N-(α-phenylethyl)phenoxazine

Conditions
ConditionsYield
With n-butyllithium Product distribution; other 10-alkylphenoxazines, other electrophiles, various ratios of reagents, regiospecifity of lithiation;A 2%
B 40%
C 5.5%
With n-butyllithium 1.) THF, hexane, 0 deg C, 3 h, 2.) -78 deg C, 15 min; Yield given. Multistep reaction. Yields of byproduct given;
2-amino-phenol
95-55-6

2-amino-phenol

A

phenoxazine
135-67-1

phenoxazine

B

2-(2-hydroxyphenlylamino)phenol
2391-71-1

2-(2-hydroxyphenlylamino)phenol

Conditions
ConditionsYield
With hydrogenchloride at 240℃; Condensation;A 8%
B 39%
Benzohydroxamic acid
495-18-1

Benzohydroxamic acid

A

N-phenyl benzoyl amide
93-98-1

N-phenyl benzoyl amide

B

phenoxazine
135-67-1

phenoxazine

C

4-amino-phenol
123-30-8

4-amino-phenol

D

aniline
62-53-3

aniline

E

2-amino-phenol
95-55-6

2-amino-phenol

F

benzil
134-81-6

benzil

Conditions
ConditionsYield
at 240℃; for 0.5h; Product distribution; Mechanism;A 11%
B 4%
C n/a
D 32%
E n/a
F 2%
2-phenoxyaniline
2688-84-8

2-phenoxyaniline

phenoxazine
135-67-1

phenoxazine

Conditions
ConditionsYield
With calcium oxide at 560℃;18%
cis-10-(1-Propenyl)phenoxazine
123703-96-8

cis-10-(1-Propenyl)phenoxazine

A

phenoxazine
135-67-1

phenoxazine

B

1-ethyl-2-methyl-1H-pyrido[3,2,1-k,l]phenoxazine
1186080-18-1

1-ethyl-2-methyl-1H-pyrido[3,2,1-k,l]phenoxazine

Conditions
ConditionsYield
With boron trifluoride diethyl etherate In ethyl acetate at 60℃; for 1.66667h;A n/a
B 13.5%
benzene-1,2-diol
120-80-9

benzene-1,2-diol

2-amino-phenol
95-55-6

2-amino-phenol

phenoxazine
135-67-1

phenoxazine

Conditions
ConditionsYield
at 260℃; im mit Kohlendioxyd gefuellten Rohr und Behandeln des Reaktionsprodukts mit Alkohol und verd. Salzsaeure;
With 2-aminophenol hydrochloride at 220 - 230℃;
at 270℃;
2-aminophenol hydrochloride
51-19-4

2-aminophenol hydrochloride

2-amino-phenol
95-55-6

2-amino-phenol

phenoxazine
135-67-1

phenoxazine

Conditions
ConditionsYield
at 200 - 240℃;
at 200 - 240℃;
2-amino-phenol
95-55-6

2-amino-phenol

phenoxazine
135-67-1

phenoxazine

Conditions
ConditionsYield
With iodine at 270℃;
With hydrogenchloride
10-Methyl-10H-phenoxazine
25782-99-4

10-Methyl-10H-phenoxazine

phenoxazine
135-67-1

phenoxazine

Conditions
ConditionsYield
With Pyridine hydrobromide at 200℃; for 0.666667h;
[1,2,3]triazolo[4,5,1-kl]phenoxazine
202-27-7

[1,2,3]triazolo[4,5,1-kl]phenoxazine

phenoxazine
135-67-1

phenoxazine

Conditions
ConditionsYield
With sulfuric acid; copper In ethanol Heating;
carbon dioxide
124-38-9

carbon dioxide

10-(tert-butyldimethylsilyl)-phenoxazine
113202-18-9

10-(tert-butyldimethylsilyl)-phenoxazine

A

phenoxazine
135-67-1

phenoxazine

B

methyl phenoxazine-4-carboxylate
100725-72-2

methyl phenoxazine-4-carboxylate

C

10-(tert-Butyl-dimethyl-silanyl)-10H-phenoxazine-4-carboxylic acid methyl ester
120033-13-8

10-(tert-Butyl-dimethyl-silanyl)-10H-phenoxazine-4-carboxylic acid methyl ester

D

dimethyl 10-(tert-butyldimethylsilyl)-phenoxazine-4,6-dicarboxylate
120033-18-3

dimethyl 10-(tert-butyldimethylsilyl)-phenoxazine-4,6-dicarboxylate

Conditions
ConditionsYield
Yield given. Multistep reaction. Yields of byproduct given;
carbon dioxide
124-38-9

carbon dioxide

10-(α-methylbenzyl)phenoxazine
113202-17-8

10-(α-methylbenzyl)phenoxazine

A

phenoxazine
135-67-1

phenoxazine

B

methyl phenoxazine-4-carboxylate
100725-72-2

methyl phenoxazine-4-carboxylate

C

methyl N-(α-phenylethyl)phenoxazine-4-carboxylate
113202-06-5

methyl N-(α-phenylethyl)phenoxazine-4-carboxylate

D

dimethyl 10-(α-methylbenzyl)phenoxazine-4,6-dicarboxylate
113202-07-6

dimethyl 10-(α-methylbenzyl)phenoxazine-4,6-dicarboxylate

Conditions
ConditionsYield
Yield given. Multistep reaction. Yields of byproduct given;
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

10-(tert-butyldimethylsilyl)-phenoxazine
113202-18-9

10-(tert-butyldimethylsilyl)-phenoxazine

A

phenoxazine
135-67-1

phenoxazine

B

10-(tert-Butyl-dimethyl-silanyl)-4-trimethylsilanyl-10H-phenoxazine
120033-12-7

10-(tert-Butyl-dimethyl-silanyl)-4-trimethylsilanyl-10H-phenoxazine

Conditions
ConditionsYield
With n-butyllithium 1.) THF, hexane, 0 deg C, 3 h, 2.) -78 deg C, 15 min; Yield given. Multistep reaction. Yields of byproduct given;
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

10-(tert-butyldimethylsilyl)-phenoxazine
113202-18-9

10-(tert-butyldimethylsilyl)-phenoxazine

A

phenoxazine
135-67-1

phenoxazine

B

10-(tert-Butyl-dimethyl-silanyl)-4,6-bis-trimethylsilanyl-10H-phenoxazine
120033-17-2

10-(tert-Butyl-dimethyl-silanyl)-4,6-bis-trimethylsilanyl-10H-phenoxazine

Conditions
ConditionsYield
With n-butyllithium 1.) THF, hexane, 0 deg C, 3 h, 2.) 0 deg C, 1 h; Yield given. Multistep reaction. Yields of byproduct given;
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

10-(α-methylbenzyl)phenoxazine
113202-17-8

10-(α-methylbenzyl)phenoxazine

A

phenoxazine
135-67-1

phenoxazine

B

10-(1-Phenyl-ethyl)-4-trimethylsilanyl-10H-phenoxazine
113201-94-8

10-(1-Phenyl-ethyl)-4-trimethylsilanyl-10H-phenoxazine

Conditions
ConditionsYield
With n-butyllithium 1.) THF, hexane, 0 deg C, 3 h, 2.) -78 deg C, 15 min; Yield given. Multistep reaction. Yields of byproduct given;
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

10-(α-methylbenzyl)phenoxazine
113202-17-8

10-(α-methylbenzyl)phenoxazine

A

phenoxazine
135-67-1

phenoxazine

B

10-(1-Phenyl-ethyl)-4-trimethylsilanyl-10H-phenoxazine
113201-94-8

10-(1-Phenyl-ethyl)-4-trimethylsilanyl-10H-phenoxazine

C

4,6-bis(trimethylsilyl)-10-(α-methylbenzyl)phenoxazine
120033-10-5

4,6-bis(trimethylsilyl)-10-(α-methylbenzyl)phenoxazine

Conditions
ConditionsYield
With n-butyllithium 1.) THF, hexane, 0 deg C, 3 h, 2.) 0 deg C, 1 h; Yield given. Multistep reaction. Yields of byproduct given;
Dimethyldisulphide
624-92-0

Dimethyldisulphide

10-(tert-butyldimethylsilyl)-phenoxazine
113202-18-9

10-(tert-butyldimethylsilyl)-phenoxazine

A

phenoxazine
135-67-1

phenoxazine

B

10-(tert-Butyl-dimethyl-silanyl)-4-methylsulfanyl-10H-phenoxazine
120033-11-6

10-(tert-Butyl-dimethyl-silanyl)-4-methylsulfanyl-10H-phenoxazine

C

10-(tert-Butyl-dimethyl-silanyl)-4,6-bis-methylsulfanyl-10H-phenoxazine
120033-15-0

10-(tert-Butyl-dimethyl-silanyl)-4,6-bis-methylsulfanyl-10H-phenoxazine

Conditions
ConditionsYield
With n-butyllithium 1.) THF, hexane, 0 deg C, 3 h, 2.) -78 deg C, 15 min; Yield given. Multistep reaction. Yields of byproduct given;
Dimethyldisulphide
624-92-0

Dimethyldisulphide

10-(α-methylbenzyl)phenoxazine
113202-17-8

10-(α-methylbenzyl)phenoxazine

A

phenoxazine
135-67-1

phenoxazine

B

4-(methylthio)phenoxazine
113201-99-3

4-(methylthio)phenoxazine

C

4,6-bis(methylthio)phenoxazine
113202-14-5

4,6-bis(methylthio)phenoxazine

D

4,6-dimethylthio-N-(α-phenylethyl)phenoxazine
113202-10-1

4,6-dimethylthio-N-(α-phenylethyl)phenoxazine

Conditions
ConditionsYield
With n-butyllithium 1.) THF, hexane, 0 deg C, 3 h, 2.) 0 deg C, 1 h; Yield given. Multistep reaction. Yields of byproduct given;
Dimethyldisulphide
624-92-0

Dimethyldisulphide

10-(α-methylbenzyl)phenoxazine
113202-17-8

10-(α-methylbenzyl)phenoxazine

A

phenoxazine
135-67-1

phenoxazine

B

4-(methylthio)-10-(α-methylbenzyl)phenoxazine
113201-95-9

4-(methylthio)-10-(α-methylbenzyl)phenoxazine

C

4,6-dimethylthio-N-(α-phenylethyl)phenoxazine
113202-10-1

4,6-dimethylthio-N-(α-phenylethyl)phenoxazine

Conditions
ConditionsYield
With n-butyllithium 1.) THF, hexane, 0 deg C, 3 h, 2.) -78 deg C, 15 min; Yield given. Multistep reaction. Yields of byproduct given;
carbon dioxide
124-38-9

carbon dioxide

10-(tert-butyldimethylsilyl)-phenoxazine
113202-18-9

10-(tert-butyldimethylsilyl)-phenoxazine

A

phenoxazine
135-67-1

phenoxazine

B

10H-phenoxazine-4-carboxylic acid
99847-07-1

10H-phenoxazine-4-carboxylic acid

C

10-(tert-Butyl-dimethyl-silanyl)-10H-phenoxazine-4-carboxylic acid
113201-97-1

10-(tert-Butyl-dimethyl-silanyl)-10H-phenoxazine-4-carboxylic acid

D

10-(tert-butyldimethylsilyl)-phenoxazine-4,6-dicarboxylic acid
263908-45-8

10-(tert-butyldimethylsilyl)-phenoxazine-4,6-dicarboxylic acid

Conditions
ConditionsYield
With n-butyllithium 1.) THF, hexane, 0 deg C, 3 h, 2.) -78 deg C, 15 min; Multistep reaction;
With n-butyllithium 1.) THF, hexane, 0 deg C, 3 h, 2.) 0 deg C, 1 h; Multistep reaction;
carbon dioxide
124-38-9

carbon dioxide

10-(α-methylbenzyl)phenoxazine
113202-17-8

10-(α-methylbenzyl)phenoxazine

A

phenoxazine
135-67-1

phenoxazine

B

10-(1-Phenyl-ethyl)-10H-phenoxazine-4-carboxylic acid
113202-20-3

10-(1-Phenyl-ethyl)-10H-phenoxazine-4-carboxylic acid

C

10-(α-methylbenzyl)phenoxazine-4,6-dicarboxylic acid
113202-09-8

10-(α-methylbenzyl)phenoxazine-4,6-dicarboxylic acid

Conditions
ConditionsYield
With n-butyllithium 1.) THF, hexane, 0 deg C, 3 h, 2.) -78 deg C, 15 min; Multistep reaction;
With n-butyllithium 1.) THF, hexane, 0 deg C, 3 h, 2.) -78 deg C, 15 min; Yield given. Multistep reaction. Yields of byproduct given;
1,3,5-Trioxan
110-88-3

1,3,5-Trioxan

phenoxazine
135-67-1

phenoxazine

10-Methyl-10H-phenoxazine
25782-99-4

10-Methyl-10H-phenoxazine

Conditions
ConditionsYield
With triethylsilane; trifluoroacetic acid In dichloromethane at 20℃; for 24h; Inert atmosphere; chemoselective reaction;99%
phenoxazine
135-67-1

phenoxazine

2-phenyl-4,6-bis(p-bromophenyl)pyrimidine
58536-47-3

2-phenyl-4,6-bis(p-bromophenyl)pyrimidine

4,6-bis(4-(10H-phenoxazin-10-yl)phenyl)-2-phenylpyrimidine

4,6-bis(4-(10H-phenoxazin-10-yl)phenyl)-2-phenylpyrimidine

Conditions
ConditionsYield
With palladium diacetate; sodium t-butanolate; tri tert-butylphosphoniumtetrafluoroborate In N,N-dimethyl-formamide at 130℃; for 48h; Inert atmosphere;98%
1,4-dibromo-butane
110-52-1

1,4-dibromo-butane

phenoxazine
135-67-1

phenoxazine

10-(4-bromobutyl)-10H-phenoxazine

10-(4-bromobutyl)-10H-phenoxazine

Conditions
ConditionsYield
With Aliquat 336; sodium hydroxide In water Heating;98%
phenoxazine
135-67-1

phenoxazine

2,4,6-tris(4-bromophenyl)-1,3,5-triazine
30363-03-2

2,4,6-tris(4-bromophenyl)-1,3,5-triazine

2,4,6-tri(4-(10H-phenoxazin-10H-yl)phenyl)-1,3,5-triazine

2,4,6-tri(4-(10H-phenoxazin-10H-yl)phenyl)-1,3,5-triazine

Conditions
ConditionsYield
With tri-tert-butyl phosphine; palladium diacetate; potassium carbonate In toluene for 24h; Reflux;97%
Stage #1: phenoxazine; 2,4,6-tris(4-bromophenyl)-1,3,5-triazine With potassium carbonate In toluene at 20℃; for 0.166667h; Inert atmosphere;
Stage #2: With tri-tert-butyl phosphine; palladium diacetate In toluene for 24h; Inert atmosphere; Reflux;
96.5%
phenoxazine
135-67-1

phenoxazine

4,6-bis(4-bromophenyl)-2-methylpyrimidine
204589-02-6

4,6-bis(4-bromophenyl)-2-methylpyrimidine

4,6-bis(4-(10H-phenoxazin-10-yl)phenyl)-2-methylpyrimidine

4,6-bis(4-(10H-phenoxazin-10-yl)phenyl)-2-methylpyrimidine

Conditions
ConditionsYield
With palladium diacetate; sodium t-butanolate; tri tert-butylphosphoniumtetrafluoroborate In N,N-dimethyl-formamide at 130℃; for 48h; Inert atmosphere;97%
phenoxazine
135-67-1

phenoxazine

7-bromo-2,3-diphenyl-5-azaquinoxaline
38870-31-4

7-bromo-2,3-diphenyl-5-azaquinoxaline

2,3-diphenyl-7-(10H-phenoxazin-10-yl)pyrido[2,3-b]pyrazine

2,3-diphenyl-7-(10H-phenoxazin-10-yl)pyrido[2,3-b]pyrazine

Conditions
ConditionsYield
With palladium diacetate; sodium t-butanolate; tri tert-butylphosphoniumtetrafluoroborate In toluene at 110℃; for 48h;97%
With tri-tert-butylphosphonium tetrafluoroborate; palladium diacetate; sodium t-butanolate In toluene Inert atmosphere; Reflux;97%
2-ethylhexyl bromide
18908-66-2

2-ethylhexyl bromide

phenoxazine
135-67-1

phenoxazine

10-(2-ethylhexyl)-10H-phenoxazine

10-(2-ethylhexyl)-10H-phenoxazine

Conditions
ConditionsYield
Stage #1: phenoxazine With tetraethylammonium bromide; potassium hydroxide In acetone at 50℃; for 1.5h; Inert atmosphere;
Stage #2: 3-bromomethylheptane In acetone at 60℃; Inert atmosphere;
97%
With potassium hydroxide
phenoxazine
135-67-1

phenoxazine

C20H10Br3FN2

C20H10Br3FN2

C56H34FN5O3

C56H34FN5O3

Conditions
ConditionsYield
With palladium diacetate; sodium t-butanolate; tri tert-butylphosphoniumtetrafluoroborate In toluene at 110℃; for 48h;97%
phenoxazine
135-67-1

phenoxazine

2,6 difluorobenzonitrile
1897-52-5

2,6 difluorobenzonitrile

2,6-di(10H-phenoxazin-10-yl)benzonitrile

2,6-di(10H-phenoxazin-10-yl)benzonitrile

Conditions
ConditionsYield
With sodium ethanolate In N,N-dimethyl-formamide at 70 - 150℃; for 48h;97%
With sodium hydride In hexane; N,N-dimethyl-formamide; mineral oil for 10h; Inert atmosphere;82%
phenoxazine
135-67-1

phenoxazine

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

4-(10H-phenoxazin-10-yl)benzaldehyde

4-(10H-phenoxazin-10-yl)benzaldehyde

Conditions
ConditionsYield
With potassium phosphate In N,N-dimethyl-formamide for 16h; Reflux; Inert atmosphere;97%
With potassium carbonate In N,N-dimethyl-formamide at 0.14℃; for 48h;31.9%
phenoxazine
135-67-1

phenoxazine

1-dodecylbromide
143-15-7

1-dodecylbromide

10-dodecyl-10H-phenoxazine
1083062-16-1

10-dodecyl-10H-phenoxazine

Conditions
ConditionsYield
With cetyltrimethylammonim bromide; sodium hydroxide In acetone Reflux;96%
phenoxazine
135-67-1

phenoxazine

1,3-bis-(4-bromobenzoyl)benzene
136039-69-5

1,3-bis-(4-bromobenzoyl)benzene

1,3-bis{4-(10H-phenoxazine-10-yl)benzoyl}benzene
1618669-36-5

1,3-bis{4-(10H-phenoxazine-10-yl)benzoyl}benzene

Conditions
ConditionsYield
With bis(tri-t-butylphosphine)palladium(0); potassium carbonate In toluene at 120℃; for 24h; Buchwald-Hartwig Coupling;96%
3,4-dimethoxyphenol
2033-89-8

3,4-dimethoxyphenol

phenoxazine
135-67-1

phenoxazine

C20H17NO4

C20H17NO4

Conditions
ConditionsYield
With dipotassium peroxodisulfate In acetonitrile at 20℃; for 12h; Irradiation;96%
With ammonium peroxydisulfate; 2,4,6-triphenylpyrylium tetrafluoroborate In dichloromethane at 20℃; Irradiation;92%
phenoxazine
135-67-1

phenoxazine

2,6-bis(4-chlorophenyl)isonicotinonitrile

2,6-bis(4-chlorophenyl)isonicotinonitrile

2,6-bis(4-(10H-phenoxazin-10-yl)phenyl)isonicotinonitrile

2,6-bis(4-(10H-phenoxazin-10-yl)phenyl)isonicotinonitrile

Conditions
ConditionsYield
With tri-tert-butyl phosphine; palladium diacetate; potassium carbonate In toluene for 22h; Buchwald-Hartwig Coupling; Inert atmosphere; Reflux;96%
With tri-tert-butyl phosphine; palladium diacetate; potassium carbonate In toluene at 110℃; for 25h; Inert atmosphere;96%
phenoxazine
135-67-1

phenoxazine

2,4,6-tris(3-bromophenyl)-1,3,5-triazine
890148-78-4

2,4,6-tris(3-bromophenyl)-1,3,5-triazine

2,4,6-tri(3-N-phenoxazylphenyl)-1,3,5-triazine

2,4,6-tri(3-N-phenoxazylphenyl)-1,3,5-triazine

Conditions
ConditionsYield
Stage #1: phenoxazine; 2,4,6-tris(3-bromophenyl)-1,3,5-triazine With potassium carbonate In toluene at 20℃; for 0.166667h; Inert atmosphere;
Stage #2: With tri-tert-butyl phosphine; palladium diacetate In toluene for 24h; Inert atmosphere; Reflux;
95.3%
bromobenzene
108-86-1

bromobenzene

phenoxazine
135-67-1

phenoxazine

10-phenyl-10H-phenoxazine
37832-25-0

10-phenyl-10H-phenoxazine

Conditions
ConditionsYield
With tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In toluene Reflux; Inert atmosphere;95%
With tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In toluene for 6h; Inert atmosphere; Reflux;95%
With tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In toluene at 120℃; for 48h; Inert atmosphere;76.8%
phenoxazine
135-67-1

phenoxazine

4,6-bis(4-bromophenyl)pyrimidine
141034-81-3

4,6-bis(4-bromophenyl)pyrimidine

4,6-bis(4-(10H-phenoxazin-10-yl)phenyl)pyrimidine

4,6-bis(4-(10H-phenoxazin-10-yl)phenyl)pyrimidine

Conditions
ConditionsYield
With palladium diacetate; sodium t-butanolate; tri tert-butylphosphoniumtetrafluoroborate In N,N-dimethyl-formamide at 130℃; for 48h; Inert atmosphere;95%
phenoxazine
135-67-1

phenoxazine

2,3-bis(4′-bromophenyl)-6,7-difluoroquinoxaline

2,3-bis(4′-bromophenyl)-6,7-difluoroquinoxaline

10,10'-((6,7-difluoroquinoxaline-2,3-diyl)bis(4,1-phenylene))bis(10H-phenoxazine)

10,10'-((6,7-difluoroquinoxaline-2,3-diyl)bis(4,1-phenylene))bis(10H-phenoxazine)

Conditions
ConditionsYield
With palladium diacetate; sodium t-butanolate; tri tert-butylphosphoniumtetrafluoroborate In toluene at 110℃; for 48h;95%
With palladium diacetate; sodium t-butanolate; tri tert-butylphosphoniumtetrafluoroborate In toluene Reflux; Inert atmosphere;93%
With tris-(dibenzylideneacetone)dipalladium(0); sodium t-butanolate; tri tert-butylphosphoniumtetrafluoroborate In toluene at 100℃; Inert atmosphere;80%
phenoxazine
135-67-1

phenoxazine

4-bromo-benzaldehyde
1122-91-4

4-bromo-benzaldehyde

4-(10H-phenoxazin-10-yl)benzaldehyde

4-(10H-phenoxazin-10-yl)benzaldehyde

Conditions
ConditionsYield
With tri-tert-butyl phosphine; palladium diacetate; potassium carbonate In toluene at 110 - 120℃; Inert atmosphere;95%
With palladium diacetate; caesium carbonate; triphenylphosphine In toluene at 110℃; for 24h; Inert atmosphere;82.6%
phenoxazine
135-67-1

phenoxazine

4-(4-chlorophenyl)-2,6-diphenylpyridine-3,5-dicarbonitrile

4-(4-chlorophenyl)-2,6-diphenylpyridine-3,5-dicarbonitrile

4-(4-(10H-phenoxazin-10-yl)phenyl)-2,6-diphenylpyridine-3,5-dicarbonitrile

4-(4-(10H-phenoxazin-10-yl)phenyl)-2,6-diphenylpyridine-3,5-dicarbonitrile

Conditions
ConditionsYield
With palladium diacetate; sodium t-butanolate; tri tert-butylphosphoniumtetrafluoroborate In toluene at 110℃; for 24h; Inert atmosphere;95%
4-(4-bromophenyl)-2,6-diphenylpyridine
1498-81-3

4-(4-bromophenyl)-2,6-diphenylpyridine

phenoxazine
135-67-1

phenoxazine

C35H24N2O

C35H24N2O

Conditions
ConditionsYield
Stage #1: 4-(4-bromophenyl)-2,6-diphenylpyridine; phenoxazine With potassium carbonate In toluene for 0.25h; Inert atmosphere;
Stage #2: With triisopropylamine; palladium diacetate In toluene for 48h; Reflux; Inert atmosphere;
94%
phenoxazine
135-67-1

phenoxazine

tri-p-tert-butylphenol phosphate ester
78-33-1

tri-p-tert-butylphenol phosphate ester

10-(4-(tert-butyl)phenyl)-10H-phenoxazine

10-(4-(tert-butyl)phenyl)-10H-phenoxazine

Conditions
ConditionsYield
With bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)]; N-[2-(di(1-adamantyl)phosphino)phenyl]morpholine; potassium carbonate at 130℃; for 4h; Schlenk technique; Inert atmosphere; Sealed tube;94%
With N-[2-(di(1-adamantyl)phosphino)phenyl]morpholine; [Pd(π-cinnamyl)Cl]2 at 130℃; for 4h; Schlenk technique; Inert atmosphere; Sealed tube;94%
phenoxazine
135-67-1

phenoxazine

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

methyl 4-(10H-phenoxazin-10-yl)benzoate

methyl 4-(10H-phenoxazin-10-yl)benzoate

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 220℃; for 6h; Inert atmosphere;94%
With copper(I) oxide In N,N-dimethyl acetamide at 160℃; for 24h; Inert atmosphere;90%
With copper(I) oxide In N,N-dimethyl acetamide at 160℃; for 8h;90%
phenoxazine
135-67-1

phenoxazine

2',7'-dibromospiro[fluorene-9,9'-thioxanthene]-10',10'-dioxide

2',7'-dibromospiro[fluorene-9,9'-thioxanthene]-10',10'-dioxide

2',7'-di(10H-phenoxazin-10-yl)spiro[fluorene-9,9'-thioxanthene]-10',10'-dioxide

2',7'-di(10H-phenoxazin-10-yl)spiro[fluorene-9,9'-thioxanthene]-10',10'-dioxide

Conditions
ConditionsYield
With tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate In toluene at 110℃; for 24h; Inert atmosphere;94%
With tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate In toluene at 110℃; for 24h; Buchwald-Hartwig Coupling; Inert atmosphere;76%
phenoxazine
135-67-1

phenoxazine

4-bromo-N,N-bis-(4-methoxyphenyl)aniline
194416-45-0

4-bromo-N,N-bis-(4-methoxyphenyl)aniline

C32H26N2O3

C32H26N2O3

Conditions
ConditionsYield
With tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate In toluene at 20 - 110℃; for 24h; Inert atmosphere;93.2%
phenoxazine
135-67-1

phenoxazine

5-bromo-10,15,20-tris(3,5-di-tert-butylphenyl)porphyrinato nickel(II)
262424-49-7

5-bromo-10,15,20-tris(3,5-di-tert-butylphenyl)porphyrinato nickel(II)

C74H79N5NiO

C74H79N5NiO

Conditions
ConditionsYield
With C40H57Cl2N3Pd; sodium t-butanolate In tetrahydrofuran at 60℃; for 13h; Buchwald-Hartwig Coupling; Inert atmosphere;93%
2-phenyl-indole
948-65-2

2-phenyl-indole

phenoxazine
135-67-1

phenoxazine

10-(2-phenyl-1H-indol-3-yl)-10H-phenoxazine

10-(2-phenyl-1H-indol-3-yl)-10H-phenoxazine

Conditions
ConditionsYield
With oxygen; potassium carbonate In 1,2-dichloro-benzene at 130℃; for 3h;93%
With oxygen; sodium nitrite In toluene at 0 - 20℃; Sealed tube;61%
phenoxazine
135-67-1

phenoxazine

C36H27Br2N

C36H27Br2N

C60H43N3O2

C60H43N3O2

Conditions
ConditionsYield
With palladium diacetate; sodium t-butanolate; tri tert-butylphosphoniumtetrafluoroborate In water; toluene at 120℃; for 24h; Glovebox; Inert atmosphere;93%
phenoxazine
135-67-1

phenoxazine

(1R,2S,6R)-2-(benzyloxy)-7-oxabicyclo[4.1.0]heptane

(1R,2S,6R)-2-(benzyloxy)-7-oxabicyclo[4.1.0]heptane

(1R,2S,6S)-2-(benzyloxy)-6-(10H-phenoxazin-10-yl)cyclohexan-1-ol

(1R,2S,6S)-2-(benzyloxy)-6-(10H-phenoxazin-10-yl)cyclohexan-1-ol

Conditions
ConditionsYield
With ytterbium(III) triflate In 1,2-dichloro-ethane93%
With ytterbium(III) triflate In 1,2-dichloro-ethane93%

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