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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

2-Methylthiazole

Cas:3581-87-1

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 2-Methylthiazole supplier in China

Cas:3581-87-1

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Tengzhou Runlong Fragrance Co., Ltd.

1、Our factory passed ISO 9001, ISO 14001, ISO 22000 system certification; HALAL 、KOSHER、FCC AND FDA certificate are available. We can provide customers with better prices, and the supply is stable. 2、We founded in 2004,10% of the staff have more tha

CAS 3581-87-1 high purity 2-Methylthiazole

Cas:3581-87-1

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

2-Methyl Thiazole

Cas:3581-87-1

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

2-Methylthiazole CAS: 3581-87-1

Cas:3581-87-1

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 3581-87-1 with best quality

Cas:3581-87-1

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

2-Methylthiazole 3581-87-1

Cas:3581-87-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

2-Methylthiazole CAS:3581-87-1 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermed

2-Methylthiazole CAS:3581-87-1

Cas:3581-87-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

2-Methylthiazole

Cas:3581-87-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Changchun Artel lmport and Export trade company

Product Detail Minimum Order Qty. 10 Gram

Factory Supply food grade 99% 2-Methylthiazole in stock CAS NO.3581-87-1

Cas:3581-87-1

Min.Order:10 Gram

Negotiable

Type:Trading Company

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:3581-87-1

Cas:3581-87-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Factory Supply High Quality CAS 3581-87-1 ,2-Methyl thiazole

Cas:3581-87-1

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Lonwin Chemical Group Limited

2-Methyl thiazole CAS: 3581-87-1 Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard Shelf life 2 years Storage should be stored in a well-clo

Factory supply 2-Methyl thiazole

Cas:3581-87-1

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

2-Methyl Thiazole

Cas:3581-87-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

superior quality moderate price & quick delivery Appearance:powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Used to make other chemic

2-Methylthiazole

Cas:3581-87-1

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

2-Methyl thiazole

Cas:3581-87-1

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

2-Methylthiazole

Cas:3581-87-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 2-Methylthiazole

Cas:3581-87-1

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 2-Methylthiazole

Cas:3581-87-1

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

2-Methyl thiazole

Cas:3581-87-1

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

2-Methylthiazole

Cas:3581-87-1

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

2-Methyl thiazole

Cas:3581-87-1

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

2-Methyl thiazole

Cas:3581-87-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

2-Methyl thiazole

Cas:3581-87-1

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as

2-Methylthiazole

Cas:3581-87-1

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

2-Methylthiazole Cas no.3581-87-1 98%

Cas:3581-87-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

2-Methyl thiazole

Cas:3581-87-1

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Hubei Vanz Pharm Co.,Ltd

ISO/factory/goodqualityAppearance:off white Storage:Dry,cool place Package:drum Application:active pharmaceutical ingredients Transportation:by air/sea/express Port:shenzhen/shanghai

2-Methylthiazole

Cas:3581-87-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

2-Methyl thiazole

Cas:3581-87-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

2-Methylthiazole

Cas:3581-87-1

Min.Order:0

Negotiable

Type:Other

inquiry

Synthetic route

2-bromo-1,3-thiazole
3034-53-5

2-bromo-1,3-thiazole

[3-(dimethylamino)propyl]dimethylindium

[3-(dimethylamino)propyl]dimethylindium

2-methylthiazole
3581-87-1

2-methylthiazole

Conditions
ConditionsYield
bis-triphenylphosphine-palladium(II) chloride In benzene at 80℃; for 19h;94%
2-(methanesulfonyl)thiazole
69749-91-3

2-(methanesulfonyl)thiazole

methyl iodide
74-88-4

methyl iodide

2-methylthiazole
3581-87-1

2-methylthiazole

Conditions
ConditionsYield
Stage #1: methyl iodide With magnesium In tetrahydrofuran at 10 - 30℃; for 2h; Inert atmosphere;
Stage #2: 2-(methanesulfonyl)thiazole In tetrahydrofuran at 0 - 20℃; for 1h; Inert atmosphere;
86%
2-bromo-1,3-thiazole
3034-53-5

2-bromo-1,3-thiazole

bis(μ-[2-(dimethylamino)ethanolato-N,O:O]tetramethyldiindium

bis(μ-[2-(dimethylamino)ethanolato-N,O:O]tetramethyldiindium

2-methylthiazole
3581-87-1

2-methylthiazole

Conditions
ConditionsYield
bis-triphenylphosphine-palladium(II) chloride In benzene at 80℃; for 24h;84%
2-methyl-4,5-dihydro-thiazole
2346-00-1

2-methyl-4,5-dihydro-thiazole

2-methylthiazole
3581-87-1

2-methylthiazole

Conditions
ConditionsYield
With sulfur at 100 - 110℃;
2-methyl-2,5-dihydro-thiazole
66867-06-9

2-methyl-2,5-dihydro-thiazole

2-methylthiazole
3581-87-1

2-methylthiazole

Conditions
ConditionsYield
With ethanol; iron(III) chloride
2-chloroethanal
107-20-0

2-chloroethanal

thioacetamide
62-55-5

thioacetamide

2-methylthiazole
3581-87-1

2-methylthiazole

1,2-dichloro-2-ethoxyethane
623-46-1

1,2-dichloro-2-ethoxyethane

thioacetamide
62-55-5

thioacetamide

2-methylthiazole
3581-87-1

2-methylthiazole

Conditions
ConditionsYield
With ethanol
monochloroacetaldehyde hydrate
15873-56-0

monochloroacetaldehyde hydrate

thioacetamide
62-55-5

thioacetamide

2-methylthiazole
3581-87-1

2-methylthiazole

Conditions
ConditionsYield
With acetic anhydride; benzene
2-bromo-1,3-thiazole
3034-53-5

2-bromo-1,3-thiazole

dimethyl sulfate
77-78-1

dimethyl sulfate

2-methylthiazole
3581-87-1

2-methylthiazole

Conditions
ConditionsYield
(i) nBuLi, Et2O, (ii) /BRN= 635994/; Multistep reaction;
N-thiazol-2-ylmethyl-aniline; hydrochloride

N-thiazol-2-ylmethyl-aniline; hydrochloride

2-methylthiazole
3581-87-1

2-methylthiazole

Conditions
ConditionsYield
With hydrogenchloride (electrolysis);
3-methylisothiazole
693-92-5

3-methylisothiazole

2-methylthiazole
3581-87-1

2-methylthiazole

Conditions
ConditionsYield
In ethanol Ambient temperature; Irradiation;
In ethanol Mechanism; Ambient temperature; Irradiation; other substrates, other solvents;
3-((7-(diethylamino)-3-iodo-2-oxo-2H-chromen-4-yl)methyl)-2-methylthiazol-3-ium bromide

3-((7-(diethylamino)-3-iodo-2-oxo-2H-chromen-4-yl)methyl)-2-methylthiazol-3-ium bromide

2-methylthiazole
3581-87-1

2-methylthiazole

Conditions
ConditionsYield
In dimethyl sulfoxide pH=7.4; Quantum yield; Solvent; Irradiation;
2-methylthiazole
3581-87-1

2-methylthiazole

4-bromo-benzaldehyde
1122-91-4

4-bromo-benzaldehyde

4-(2-methyl-1,3-thiazol-5-yl)benzaldehyde

4-(2-methyl-1,3-thiazol-5-yl)benzaldehyde

Conditions
ConditionsYield
With C82H77Cl2N3O2Pd; potassium carbonate; Trimethylacetic acid In N,N-dimethyl acetamide at 130℃; for 4h;100%
2-methylthiazole
3581-87-1

2-methylthiazole

tributyltin chloride
1461-22-9

tributyltin chloride

C13H25NSSn

C13H25NSSn

Conditions
ConditionsYield
Stage #1: 2-methylthiazole With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h; Inert atmosphere;
Stage #2: tributyltin chloride In tetrahydrofuran; hexane at -78℃; for 1h;
99.2%
2-methylthiazole
3581-87-1

2-methylthiazole

1-Bromonaphthalene
90-11-9

1-Bromonaphthalene

2-methyl-5-(naphthalen-1-yl)thiazole
107559-03-5

2-methyl-5-(naphthalen-1-yl)thiazole

Conditions
ConditionsYield
With C68H65Cl2N3Pd; potassium carbonate; Trimethylacetic acid In N,N-dimethyl acetamide at 130℃; for 12h; regioselective reaction;98%
With C82H77Cl2N3O2Pd; potassium carbonate; Trimethylacetic acid In N,N-dimethyl acetamide at 130℃; for 4h;90%
With C34H48Cl2N2Pd; potassium carbonate; Trimethylacetic acid In N,N-dimethyl acetamide at 100℃; for 8h;62%
2-methylthiazole
3581-87-1

2-methylthiazole

4-bromoquinoline
3964-04-3

4-bromoquinoline

2-methyl-5-(quinolin-4-yl)thiazole

2-methyl-5-(quinolin-4-yl)thiazole

Conditions
ConditionsYield
With C68H64Cl3N3Pd; potassium carbonate; Trimethylacetic acid In N,N-dimethyl acetamide at 130℃; for 12h; Reagent/catalyst; regioselective reaction;94%
With C82H77Cl2N3O2Pd; potassium carbonate; Trimethylacetic acid In N,N-dimethyl acetamide at 130℃; for 4h;80%
2-methylthiazole
3581-87-1

2-methylthiazole

ethyl acrylate
140-88-5

ethyl acrylate

(E)-ethyl 3-(2-methylthiazol-5-yl)acrylate
1392148-94-5

(E)-ethyl 3-(2-methylthiazol-5-yl)acrylate

Conditions
ConditionsYield
Stage #1: 2-methylthiazole With C37H24F2N6O2Pd In dichloromethane at 20℃; for 0.333333h;
Stage #2: ethyl acrylate With 1,1,1,3',3',3'-hexafluoro-propanol; silver(I) acetate; palladium diacetate; N-acetylglycine In dichloromethane at 80℃; for 30h; Sealed tube;
92%
2-methylthiazole
3581-87-1

2-methylthiazole

benzoyl chloride
98-88-4

benzoyl chloride

benzoic acid 1-phenyl-2-thiazol-2-ylvinyl ester
1256960-61-8

benzoic acid 1-phenyl-2-thiazol-2-ylvinyl ester

Conditions
ConditionsYield
With triethylamine In acetonitrile for 7h; Inert atmosphere; Reflux;89%
With triethylamine In acetonitrile at 20℃; for 7h; Inert atmosphere; Reflux;88.8%
With triethylamine In acetonitrile at 20℃; Inert atmosphere; Reflux;76%
2-methylthiazole
3581-87-1

2-methylthiazole

4-methoxycarbonylphenyl bromide
619-42-1

4-methoxycarbonylphenyl bromide

methyl 4-(2-methyl-1,3-thiazol-5-yl)benzoate

methyl 4-(2-methyl-1,3-thiazol-5-yl)benzoate

Conditions
ConditionsYield
With C82H77Cl2N3O2Pd; potassium carbonate; Trimethylacetic acid In N,N-dimethyl acetamide at 130℃; for 4h;88%
With C34H48Cl2N2Pd; potassium carbonate; Trimethylacetic acid In N,N-dimethyl acetamide at 100℃; for 8h;70%
methyl cyclohex-1-ene-1-carboxylate
18448-47-0

methyl cyclohex-1-ene-1-carboxylate

2-methylthiazole
3581-87-1

2-methylthiazole

methyl 6-(2-methylthiazol-5-yl)cyclohex-1-enecarboxylate

methyl 6-(2-methylthiazol-5-yl)cyclohex-1-enecarboxylate

Conditions
ConditionsYield
Stage #1: 2-methylthiazole With C37H24F2N6O2Pd In dichloromethane at 20℃; for 0.333333h;
Stage #2: methyl cyclohex-1-ene-1-carboxylate With 1,1,1,3',3',3'-hexafluoro-propanol; silver(I) acetate; palladium diacetate; N-acetylglycine In dichloromethane at 80℃; for 30h; Sealed tube;
88%
2-methoxy-5-bromopyridine
13472-85-0

2-methoxy-5-bromopyridine

2-methylthiazole
3581-87-1

2-methylthiazole

5-(6-methoxypyridin-3-yl)-2-methylthiazole

5-(6-methoxypyridin-3-yl)-2-methylthiazole

Conditions
ConditionsYield
With C82H77Cl2N3O2Pd; potassium carbonate; Trimethylacetic acid In N,N-dimethyl acetamide at 130℃; for 4h;88%
2-methylthiazole
3581-87-1

2-methylthiazole

tributyltin chloride
1461-22-9

tributyltin chloride

2-methyl-5-(tributylstannyl)thiazole
223418-75-5

2-methyl-5-(tributylstannyl)thiazole

Conditions
ConditionsYield
Stage #1: 2-methylthiazole With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h;
Stage #2: tributyltin chloride In tetrahydrofuran; hexane at -78 - 20℃; for 2h;
85%
Stage #1: 2-methylthiazole With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h;
Stage #2: tributyltin chloride In tetrahydrofuran; hexane at -78 - 20℃; for 2h;
85%
Stage #1: 2-methylthiazole With n-butyllithium In tetrahydrofuran at -78℃; for 1h;
Stage #2: tributyltin chloride In tetrahydrofuran at -78 - 20℃;
Stage #3: With sodium hydrogencarbonate In tetrahydrofuran; water at 20℃;
72%
3-bromoquinoline
5332-24-1

3-bromoquinoline

2-methylthiazole
3581-87-1

2-methylthiazole

2-methyl-5-(quinolin-3-yl)thiazole

2-methyl-5-(quinolin-3-yl)thiazole

Conditions
ConditionsYield
With C82H77Cl2N3O2Pd; potassium carbonate; Trimethylacetic acid In N,N-dimethyl acetamide at 130℃; for 4h;83%
2-methylthiazole
3581-87-1

2-methylthiazole

mesitylenesulfonylhydroxylamine
36016-40-7

mesitylenesulfonylhydroxylamine

3-amino-2-methyl-thiazolium; 2,4,6-trimethyl-benzenesulfonate
52197-75-8

3-amino-2-methyl-thiazolium; 2,4,6-trimethyl-benzenesulfonate

Conditions
ConditionsYield
In ethyl acetate; toluene for 2h; Cooling with ice;81%
In dichloromethane for 0.166667h; Ambient temperature;62%
2-methylthiazole
3581-87-1

2-methylthiazole

acrylic acid n-butyl ester
141-32-2

acrylic acid n-butyl ester

(E)-butyl 3-(2-methylthiazol-5-yl)acrylate
1236376-59-2

(E)-butyl 3-(2-methylthiazol-5-yl)acrylate

Conditions
ConditionsYield
With silver(I) acetate; palladium diacetate; propionic acid at 120℃; for 8h; Inert atmosphere;80%
With 5-Nitro-1,10-phenanthroline; copper diacetate; palladium diacetate; caesium carbonate; dimethyl sulfoxide In tert-Amyl alcohol at 100℃; for 12h; Inert atmosphere; regioselective reaction;46%
2-methylthiazole
3581-87-1

2-methylthiazole

methyl 2-(4-bromo-2-chlorophenyl)acetate
849934-94-7

methyl 2-(4-bromo-2-chlorophenyl)acetate

methyl 2-(2-chloro-4-(2-methylthiazol-5-yl)phenyl)acetate
1428761-21-0

methyl 2-(2-chloro-4-(2-methylthiazol-5-yl)phenyl)acetate

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium acetate at 100℃; for 15h; Inert atmosphere;80%
With tetrakis(triphenylphosphine) palladium(0); potassium acetate In 1,2-dimethoxyethane at 100℃; for 15h; Inert atmosphere;80%
2-methylthiazole
3581-87-1

2-methylthiazole

2-Dibromomethylthiazole
134271-22-0

2-Dibromomethylthiazole

Conditions
ConditionsYield
With N-Bromosuccinimide In tetrachloromethane for 1.75h; Heating; Irradiation;79%
With N-Bromosuccinimide; dibenzoyl peroxide In tetrachloromethane at 80℃; for 16h;
bromochlorobenzene
106-39-8

bromochlorobenzene

2-methylthiazole
3581-87-1

2-methylthiazole

5-(4-chlorophenyl)-2-methylthiazole
25594-97-2

5-(4-chlorophenyl)-2-methylthiazole

Conditions
ConditionsYield
With C82H77Cl2N3O2Pd; potassium carbonate; Trimethylacetic acid In N,N-dimethyl acetamide at 130℃; for 4h;79%
2-methylthiazole
3581-87-1

2-methylthiazole

p-trifluoromethylphenyl bromide
402-43-7

p-trifluoromethylphenyl bromide

2-methyl-5-(4-(trifluoromethyl)phenyl)thiazole
945860-92-4

2-methyl-5-(4-(trifluoromethyl)phenyl)thiazole

Conditions
ConditionsYield
With C82H77Cl2N3O2Pd; potassium carbonate; Trimethylacetic acid In N,N-dimethyl acetamide at 130℃; for 4h;78%
With C34H48Cl2N2Pd; potassium carbonate; Trimethylacetic acid In N,N-dimethyl acetamide at 100℃; for 8h;69%
2-methylthiazole
3581-87-1

2-methylthiazole

benzaldehyde
100-52-7

benzaldehyde

1-Phenyl-2-thiazol-2-yl-ethanol

1-Phenyl-2-thiazol-2-yl-ethanol

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine; B-(trifluoromethanesulfonyloxy)-9-borabicyclo[3.3.1]nonane In dichloromethane for 17h; Ambient temperature;77%
With diisopropylamine; 9-BBN triflate 1.) -78 deg C, 2.) RT, 17 h; Yield given. Multistep reaction;
diethyl sulfate
64-67-5

diethyl sulfate

2-methylthiazole
3581-87-1

2-methylthiazole

3-ethyl-2-methylthiazolium ethosulfate

3-ethyl-2-methylthiazolium ethosulfate

Conditions
ConditionsYield
In xylene at 90℃; for 0.5h;76%
2-methylthiazole
3581-87-1

2-methylthiazole

1,4-dibromo-2,5-difluorobenzene
327-51-5

1,4-dibromo-2,5-difluorobenzene

1,4-bis(2-methylthiazol-5-yl)-2,5-difluorobenzene

1,4-bis(2-methylthiazol-5-yl)-2,5-difluorobenzene

Conditions
ConditionsYield
With palladium diacetate; potassium carbonate; tricyclohexylphosphine; Trimethylacetic acid In N,N-dimethyl acetamide; toluene at 100℃; for 24h; Inert atmosphere;75%
5-bromo-2-fluoropyridine
766-11-0

5-bromo-2-fluoropyridine

2-methylthiazole
3581-87-1

2-methylthiazole

5-(6-fluoropyridin-3-yl)-2-methylthiazole

5-(6-fluoropyridin-3-yl)-2-methylthiazole

Conditions
ConditionsYield
With C82H77Cl2N3O2Pd; potassium carbonate; Trimethylacetic acid In N,N-dimethyl acetamide at 130℃; for 4h;75%
bromobenzene
108-86-1

bromobenzene

2-methylthiazole
3581-87-1

2-methylthiazole

2-methyl-5-phenylthiazole
19968-60-6

2-methyl-5-phenylthiazole

Conditions
ConditionsYield
With C82H77Cl2N3O2Pd; potassium carbonate; Trimethylacetic acid In N,N-dimethyl acetamide at 130℃; for 4h;74%
2-methylthiazole
3581-87-1

2-methylthiazole

3,6-bis(trifluoromethyl)bromobenzene
328-70-1

3,6-bis(trifluoromethyl)bromobenzene

C12H7F6NS

C12H7F6NS

Conditions
ConditionsYield
With C34H48Cl2N2Pd; potassium carbonate; Trimethylacetic acid In N,N-dimethyl acetamide at 100℃; for 8h;73%
triethylsilane
617-86-7

triethylsilane

2-methylthiazole
3581-87-1

2-methylthiazole

2-[(triethylsilyl)methyl]thiazole

2-[(triethylsilyl)methyl]thiazole

Conditions
ConditionsYield
With 3,5-Lutidine; chlorohydrido(2,6-bis(di-tert-butylphosphinito)phen-1-yl)iridium(III); sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate; cyclopentene at 130℃; for 20h; Schlenk technique; Inert atmosphere; regioselective reaction;73%
With 3,5-Lutidine; norborn-2-ene; dodecacarbonyltetrairidium In neat (no solvent) at 160℃; for 40h; Schlenk technique; Inert atmosphere; regioselective reaction;53%
5-bromo-2-methylpyridine
3430-13-5

5-bromo-2-methylpyridine

2-methylthiazole
3581-87-1

2-methylthiazole

2-methyl-5-(6-methylpyridin-3-yl)thiazole

2-methyl-5-(6-methylpyridin-3-yl)thiazole

Conditions
ConditionsYield
With C82H77Cl2N3O2Pd; potassium carbonate; Trimethylacetic acid In N,N-dimethyl acetamide at 130℃; for 4h;73%
2-methylthiazole
3581-87-1

2-methylthiazole

1,3-Diiodopropane
627-31-6

1,3-Diiodopropane

3-(3-iodopropyl)-2-methylthiazol-3-ium

3-(3-iodopropyl)-2-methylthiazol-3-ium

Conditions
ConditionsYield
In acetonitrile for 5h; Reflux;71%
2-methylthiazole
3581-87-1

2-methylthiazole

ethyl bromoacetate
105-36-2

ethyl bromoacetate

3-(2-ethoxy-2-oxoethyl)-2-methylthiazol-3-ium bromide

3-(2-ethoxy-2-oxoethyl)-2-methylthiazol-3-ium bromide

Conditions
ConditionsYield
for 16h; Reflux;70%

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