zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed produc
Cas:445-27-2
Min.Order:1 Kilogram
FOB Price: $3.0
Type:Lab/Research institutions
inquiryIn stock Contract customization Low Temperature Reactions Fluorine Chemistry Hydrogenation Nitration Chlorination Appearance:colorless to light yellow or light green liquid Storage:cool and dry warehouse Package:200KG/DRUM Application:Pharmace
DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe
Cas:445-27-2
Min.Order:1 Kilogram
FOB Price: $3.0
Type:Lab/Research institutions
inquiryWelcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our
Cas:445-27-2
Min.Order:1 Metric Ton
Negotiable
Type:Manufacturers
inquiryThe company has a professional R & D team, mature technology, very competitive prices and stable high quality products for customers to order high quality and low price product efforts! Appearance:White or off-white Solid Storage:Sealed, dry, m
The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
Company Profile: Synchem is dedicated to custom synthesis and manufacturing services for small molecules. We serve the needs of customers in the pharmaceutical, agrochemical, and electrical industries with top quality products and service. Vision:
Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new api, intermedi
Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block
Cas:445-27-2
Min.Order:5 Kiloliter
FOB Price: $1.2 / 5.0
Type:Manufacturers
inquiryOur advantage:Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scient
Cas:445-27-2
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryOur advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva
Cas:445-27-2
Min.Order:1 Kilogram
FOB Price: $9.0 / 99.0
Type:Trading Company
inquiryWITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
Cas:445-27-2
Min.Order:1 Kilogram
FOB Price: $139.0 / 210.0
Type:Trading Company
inquiryName: 2'-Fluoroacetophenone Synonyms:2'-Fluoro;uoroacetophenone;2-Fluoracetophenon;TAK438 Impurity 97;Fluoroacetophenone1;O-FLUOROACETOPHENONE;2-FLUOROACETOPHENONE;2'-FLUOROACETOPHENONE;2-Acetylfluorobenzene;2'-Flouoroacetophenone M
Cas:445-27-2
Min.Order:1 Kilogram
FOB Price: $1.0
Type:Other
inquiry1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized
Cas:445-27-2
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiry2'-Fluoroacetophenone CAS:445-27-2 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic
Cas:445-27-2
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryOur Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We
Product quality: Our company have high quality product , and also the product we have good manufacture . First of all, this product is of fine quality. Every finish should be checked by quality inspection system.And every one should be also tried
Cas:445-27-2
Min.Order:1 Kilogram
FOB Price: $20.0 / 30.0
Type:Trading Company
inquiry1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures s
Cas:445-27-2
Min.Order:1 Kilogram
FOB Price: $30.0 / 50.0
Type:Lab/Research institutions
inquiryHenan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
Cas:445-27-2
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryBest quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia
1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie
Cas:445-27-2
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryHangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det
Cas:445-27-2
Min.Order:0 Metric Ton
Negotiable
Type:Lab/Research institutions
inquiryJ&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
1. Product advantages: exquisite appearance and unique functions. 2. Product Advantages: Our products are the best,fast speed ,in large stock 3. High-quality products and thoughtful service are your greatest satisfaction. 4. The product
Cas:445-27-2
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryMassive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and
Cas:445-27-2
Min.Order:1 Gram
FOB Price: $1.0
Type:Lab/Research institutions
inquiryZibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:445-27-2
Min.Order:10 Gram
Negotiable
Type:Lab/Research institutions
inquiryWe are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov
Cas:445-27-2
Min.Order:100 Gram
FOB Price: $100.0 / 2000.0
Type:Lab/Research institutions
inquirySuperior quality, moderate price & quick delivery. Appearance:clear colorless to light yellow or light green Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:as per your request Application:Used as Pharmace
hebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developmen
Cas:445-27-2
Min.Order:1 Kilogram
FOB Price: $35.0
Type:Trading Company
inquiryProduct name: O-Fluoroacetophenone CAS No.: 445-27-2 Molecule Formula:C8H7FO Molecule Weight:138.14 Purity: 99.0% Package: 200kg/drum Description:Colorless transparent liquid Manufacture Standards:Enterprise Standard TESTING ITEM
Cas:445-27-2
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryConditions | Yield |
---|---|
With [(2-(benzoimidazol-2-yl)-6-(3,5-dimethylpyrazol-1-yl)pyridine)RuCl2(PPh3)]; potassium tert-butylate; acetone In methanol at 56℃; under 750.075 Torr; for 0.5h; Catalytic behavior; Oppenauer Oxidation; Inert atmosphere; | 97% |
With Langlois reagent In acetonitrile at 25℃; for 12h; Irradiation; Sealed tube; | 89% |
With calcomenite; potassium hydroxide In toluene for 28h; Reflux; | 87% |
Conditions | Yield |
---|---|
With iron(III) trifluoromethanesulfonate; C65H77N5O4S2; oxygen In 1,2-dichloro-ethane at 75℃; under 760.051 Torr; for 24h; Green chemistry; chemoselective reaction; | 97% |
Conditions | Yield |
---|---|
With C22H20AuN3O2P(1+)*CF3O3S(1-); water; silver trifluoromethanesulfonate; acetic acid at 100℃; for 10h; | 93% |
With silver trifluoromethanesulfonate In water; acetic acid at 110℃; for 6h; Schlenk technique; | 87% |
With p-toluenesulfonic acid monohydrate; acetic acid In dichloromethane at 80℃; for 8h; Sealed tube; | 80% |
Conditions | Yield |
---|---|
Stage #1: methyllithium With copper(l) cyanide In diethyl ether at 0℃; for 0.0833333h; Inert atmosphere; Stage #2: o-fluoro-benzoic acid In diethyl ether at 0 - 20℃; for 15h; Inert atmosphere; | 90% |
Conditions | Yield |
---|---|
With 1,10-Phenanthroline; nickel(II) bromide 2-methoxyethyl ether complex; sodium hydrogencarbonate In water at 100℃; for 5h; Autoclave; | 89% |
Conditions | Yield |
---|---|
Stage #1: diethyl malonate With ethanol; magnesium In tetrachloromethane; tert-butyl methyl ether for 3h; Reflux; Large scale; Stage #2: 2-Fluorobenzoyl chloride In tert-butyl methyl ether for 0.25h; Reflux; Large scale; Stage #3: With sulfuric acid; water; acetic acid In tert-butyl methyl ether for 4h; Reagent/catalyst; Reflux; Large scale; | 83% |
Conditions | Yield |
---|---|
With palladium diacetate; silver nitrate; N-fluorobis(benzenesulfon)imide; methyl carbamate In dichloromethane at 95℃; for 12h; Catalytic behavior; Solvent; Sealed tube; | 82% |
Multi-step reaction with 3 steps 1: sodium acetate / ethanol; water / 2 h / Reflux 2: tris(dibenzylideneacetone)dipalladium(0) chloroform complex; N-fluorobis(benzenesulfon)imide; potassium nitrate / nitromethane / 24 h / 25 °C 3: hydrogenchloride; water / diethyl ether / 30 h / 20 °C View Scheme |
Conditions | Yield |
---|---|
With 1,3-bis-(diphenylphosphino)propane; diisopropylamine; 1-butyl-3-methylimidazolium Tetrafluoroborate; palladium diacetate In dimethyl sulfoxide at 115℃; for 36h; Heck arylation; | 81% |
Conditions | Yield |
---|---|
With 1,10-Phenanthroline; water; palladium diacetate at 100℃; under 760.051 Torr; for 6h; | 81% |
1-(2,2-dibromovinyl)-2-fluorobenzene
2'-Fluoroacetophenone
Conditions | Yield |
---|---|
With water; zinc at 275℃; for 4h; | 79% |
Conditions | Yield |
---|---|
With tris(dibenzylideneacetone)dipalladium (0); N-ethyl-N,N-diisopropylamine; lithium chloride In N,N-dimethyl-formamide at 100℃; for 8.5h; | 74% |
Conditions | Yield |
---|---|
With trifluorormethanesulfonic acid; water; palladium diacetate; 2-(3,5-dimethyl-1H-pyrazol-1-yl)pyridine at 60℃; for 5h; regioselective reaction; | 72% |
Conditions | Yield |
---|---|
With tert.-butylhydroperoxide; C21H19N5Pd(2+)*2BF4(1-) In decane; acetonitrile at 45℃; for 30h; Wacker Oxidation; | 70% |
With manganese(II) bromide; water; lithium perchlorate; copper dichloride In acetonitrile at 60℃; for 8h; Wacker-Tsuji Olefin Oxidation; Sealed tube; Inert atmosphere; Electrochemical reaction; regioselective reaction; | 46% |
With oxygen; potassium carbonate; isopropyl alcohol at 150℃; under 3000.3 Torr; for 6h; regioselective reaction; | 82.3 %Chromat. |
Conditions | Yield |
---|---|
Stage #1: 2'-fluoroacetophenone oxime With hexachlorodisilane; silica gel In toluene at 110℃; for 8h; Stage #2: With water In toluene for 0.5h; | 67% |
With ruthenium trichloride; toluene-4-sulfonic acid In N,N-dimethyl acetamide; water at 120℃; under 760.051 Torr; for 8h; Inert atmosphere; Green chemistry; | 61% |
2-(2-fluorophenyl)propane-1,2-diol
2'-Fluoroacetophenone
Conditions | Yield |
---|---|
With oxygen; sodium carbonate In water at 20℃; for 5h; Irradiation; Green chemistry; | 51% |
Conditions | Yield |
---|---|
With oxygen at 150℃; under 760.051 Torr; for 24h; Autoclave; | 36% |
Conditions | Yield |
---|---|
With dimethylcadmium; benzene |
1-(2-Fluoro-4-trimethylsilanyl-phenyl)-ethanone
2'-Fluoroacetophenone
Conditions | Yield |
---|---|
With potassium fluoride In N,N-dimethyl-formamide at -40℃; for 3h; Yield given; |
Conditions | Yield |
---|---|
With copper 1) THF, 25 deg C, 10 min, 2a) 25 deg C, 30 min; Yield given. Multistep reaction; | |
With CuI*P(Et)3; naphthalen-1-yl-lithium 1.) DME, 25 deg C, 10 min, 2.) 25 deg C, 30 min; Yield given. Multistep reaction; |
acetophenone
A
2'-Fluoroacetophenone
B
1-(4-fluorophenyl)ethanone
C
1-(3-fluorophenyl)ethanone
Conditions | Yield |
---|---|
With cobalt (III) fluoride In chloroform for 18h; Product distribution; Heating; |
2-Fluoro-1,4-bis-trimethylsilanyl-benzene
acetyl chloride
2'-Fluoroacetophenone
Conditions | Yield |
---|---|
With aluminium trichloride; water; fluoride Multistep reaction; |
fluorosulphonic acid
acetophenone
A
2'-Fluoroacetophenone
B
2,3-difluoroacetophenone
Conditions | Yield |
---|---|
at 110℃; |
Conditions | Yield |
---|---|
Erhitzen des von Aether befreiten Reaktionsgemisches auf dem Dampfbad und anschliessendes Behandeln mit wss. Essigsaeure; |
acetophenone
A
2'-Fluoroacetophenone
B
1-(3,3,6,6-tetrafluoro-1,4-cyclohexyldienyl)-1-ethanone
C
2',5'-difluoroacetophenone
D
1-(3-fluorophenyl)ethanone
Conditions | Yield |
---|---|
With hydrogen fluoride In diethyl ether; acetone at 5℃; for 18h; Electrochemical reaction; |
1-(1-butoxy-vinyl)-2-fluoro-benzene
2'-Fluoroacetophenone
Conditions | Yield |
---|---|
With hydrogenchloride for 0.5h; | |
With hydrogenchloride; water In isopropyl alcohol for 0.5h; | |
With hydrogenchloride; water In ethylene glycol Inert atmosphere; | |
With hydrogenchloride; water In diethyl ether at 20℃; for 1h; Inert atmosphere; | |
With hydrogenchloride In acetone at 20℃; for 1h; |
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 1,3-bis(diphenylphosphino)propane; Pd(OAc)2; Et3N / 1-butyl-3-methylimidazolium tetrafluoroborate / 36 h / 115 °C 2: aq. HCl / 0.5 h View Scheme |
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: diethyl ether 2: pyridinium chlorochromate / CH2Cl2 View Scheme |
2-Fluoro-1,4-bis-trimethylsilanyl-benzene
2'-Fluoroacetophenone
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: AlCl3 2: KF / dimethylformamide / 3 h / -40 °C View Scheme |
Conditions | Yield |
---|---|
Stage #1: methylmagnesium bromide; 2-Fluorobenzaldehyde In tetrahydrofuran Stage #2: With pyridinium chlorochromate In dichloromethane |
Conditions | Yield |
---|---|
Stage #1: 2'-Fluoroacetophenone With C107H90Cl2N10P4Ru2(2+)*2Cl(1-) In isopropyl alcohol at 82℃; for 0.166667h; Inert atmosphere; Stage #2: With potassium isopropoxide In isopropyl alcohol for 2h; Catalytic behavior; Inert atmosphere; | 100% |
With C40H37ClN2PRuS(1+)*C24H20B(1-); isopropyl alcohol; potassium hydroxide at 82℃; for 2h; Catalytic behavior; | 100% |
With [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; sodium formate; ephedrine hydrochloride at 20℃; | 99% |
2'-Fluoroacetophenone
A
(1S)-1-(2-fluorophenyl)ethanol
B
(R)-1-(2-fluorophenyl)ethanol
Conditions | Yield |
---|---|
With RuBr2[(S,S)-2,4-bis(diphenylphosphino)pentane](2-picolylamine); potassium tert-butylate; hydrogen In ethanol at 40℃; under 7600.51 Torr; for 19h; Inert atmosphere; Autoclave; | A 100% B n/a |
With dimethylsulfide borane complex; (S)-tetrahydro-1-butyl-3,3-diphenyl-1H,3H-pyrrolo{2,1-c}{1,3,2}oxazaborole In tetrahydrofuran for 0.166667h; Yield given. Yields of byproduct given. Title compound not separated from byproducts; | |
With Cp*RhCl<(R,R)-Tscydn>; potassium tert-butylate In isopropyl alcohol at 30℃; for 12h; Yield given; Yields of byproduct given. Title compound not separated from byproducts; |
2'-Fluoroacetophenone
(1S)-1-(2-fluorophenyl)ethanol
Conditions | Yield |
---|---|
With [((R,R)-diphenylethylenediamine)((R)-Binap)dichlororuthenium(II)]; potassium tert-butylate; hydrogen In isopropyl alcohol at 26 - 30℃; under 3040 Torr; for 3h; | 100% |
With tris(bis(trimethylsilyl)amido)lanthanum(III); 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane; ((2S,2'S)-((2-hydroxy-5-methyl-1,3-phenylene)bis(methylene))bis(pyrrolidine-1,2-diyl))bis(diphenylmethanol) In tetrahydrofuran at 0℃; for 8h; enantioselective reaction; | 99% |
In phosphate buffer for 48h; Microbiological reaction; | 98% |
2'-Fluoroacetophenone
(R)-1-(2-fluorophenyl)ethanol
Conditions | Yield |
---|---|
With (S,S)-RuCl2(2,2'-bis(di-3,5-xylylphosphino)-1,1'-binaphthyl)(1,1-dianisyl-2-isopropyl-1,2-ethylenediamine); potassium tert-butylate; hydrogen In isopropyl alcohol at 26 - 30℃; under 6080 Torr; for 13h; | 100% |
With water; sodium formate; sodium dodecyl-sulfate at 39.84℃; for 96h; Inert atmosphere; optical yield given as %ee; enantioselective reaction; | 95% |
With bromopentacarbonylmanganese(I); hydrogen; C45H43FeNP2; potassium hydroxide In methanol; toluene at 20℃; for 36h; enantioselective reaction; | 93% |
2'-Fluoroacetophenone
(S)-1-phenyl-ethylamine
[1-(3-Fluoro-phenyl)-eth-(E)-ylidene]-((S)-1-phenyl-ethyl)-amine
Conditions | Yield |
---|---|
zinc(II) chloride In toluene for 15h; Heating; | 100% |
Conditions | Yield |
---|---|
With hydroxylamine hydrochloride; sodium acetate In ethanol; water at 95℃; | 100% |
With hydroxylamine hydrochloride; sodium hydroxide In ethanol; water at 25℃; for 4h; | 94.7% |
With hydroxylamine hydrochloride; sodium acetate In ethanol; water Heating; |
Conditions | Yield |
---|---|
With acetic acid In ethanol for 12h; Reflux; Inert atmosphere; | 100% |
Conditions | Yield |
---|---|
In toluene at -43 - 20℃; for 6.5h; Inert atmosphere; | 100% |
Conditions | Yield |
---|---|
With potassium hydroxide In ethanol for 1h; Ambient temperature; | 99% |
Conditions | Yield |
---|---|
N,N,N',N'-tetramethylguanidine at 25℃; for 15h; | 99% |
With C42H50Mg2N4 In benzene-d6 at 25℃; for 0.8h; Glovebox; Inert atmosphere; | 99% |
Fe(Cp)2PF6 at 20℃; for 0.166667h; | 94% |
2'-Fluoroacetophenone
2-propanethiol
1-(2-(isopropylthio)phenyl)ethan-1-one
Conditions | Yield |
---|---|
With potassium carbonate In N,N-dimethyl-formamide at 50℃; | 99% |
piperonal
2'-Fluoroacetophenone
(E)-3-(benzo[d][1,3]dioxol-5-yl)-1-(2-fluorophenyl)prop-2-en-1-one
Conditions | Yield |
---|---|
With sodium hydroxide In ethanol; water at 20℃; | 99% |
Conditions | Yield |
---|---|
Stage #1: 2'-Fluoroacetophenone With C38H26LiO5P In hexane; water; toluene at -78℃; for 0.166667h; Inert atmosphere; Stage #2: trimethylsilyl cyanide In hexane; water; toluene at -78℃; for 4h; Inert atmosphere; enantioselective reaction; | 99% |
2'-Fluoroacetophenone
Conditions | Yield |
---|---|
With 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; C51H41F4NO6P2; mesitylcopper(I) at 30℃; for 40h; diastereoselective reaction; | 99% |
2'-Fluoroacetophenone
4-methoxy-benzaldehyde
3-(4-methoxyphenyl)-1-(2-fluorophenyl)-2-propen-1-one
Conditions | Yield |
---|---|
With methanol; sodium In methanol at 20℃; Aldol Condensation; | 98.4% |
trimethyl (3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)prop-1-yn-1-yl)silane
2'-Fluoroacetophenone
(R)-2-(2-fluorophenyl)-5-(trimethylsilyl)pent-4-yn-2-ol
Conditions | Yield |
---|---|
With copper (II) isobutyrate; (R)-2,2'-bis(diphenylphosphanyl)-1,1'-binaphthyl; lithium tert-butoxide In tetrahydrofuran at -62℃; for 16h; Inert atmosphere; optical yield given as %ee; enantioselective reaction; | 98% |
Conditions | Yield |
---|---|
With bromine; acetic acid at 20℃; for 2h; | 97% |
With bromine In acetic acid at 20℃; for 2h; | 97% |
With copper(I) bromide In ethyl acetate at 80℃; | 95% |
2'-Fluoroacetophenone
1-(2-fluoro-5-nitrophenyl)ethanone
Conditions | Yield |
---|---|
With sulfuric acid; nitric acid at -42℃; for 0.5h; | 97% |
Stage #1: 2'-Fluoroacetophenone With sulfuric acid; nitric acid at -40℃; for 1.08333h; Stage #2: With water Cooling with ice; | 97% |
With sulfuric acid; nitric acid In water at -10 - 5℃; for 0.5h; | 93.7% |
Conditions | Yield |
---|---|
With iodine at 100℃; | 97% |
With iodine at 100℃; for 8h; | 66% |
With iodine; dimethyl sulfoxide at 80℃; for 12h; Schlenk technique; | 52% |
2'-Fluoroacetophenone
Conditions | Yield |
---|---|
Stage #1: 2'-Fluoroacetophenone; N-carbethoxy-4-tropinone With Nonafluorobutanesulfonyl fluoride; tert-butylimino-tri(pyrrolidino)phosphorane; lithium chloride In N,N-dimethyl-formamide at 10 - 25℃; Stage #2: With copper(l) iodide; diisopropylamine; triphenylphosphine; palladium diacetate In N,N-dimethyl-formamide at 60℃; for 5.5h; Sonogashira coupling; | 97% |
2'-Fluoroacetophenone
ammonium carbonate
(RS)-5-(2-fluoro-phenyl)-5-methyl-imidazolidine-2,4-dione
Conditions | Yield |
---|---|
With ammonium hydroxide In ethanol; water at 60℃; for 5.5h; | 97% |
With ammonium hydroxide In ethanol; water at 60℃; for 5.5h; | 97% |
In ethanol at 50℃; for 24h; Bucherer-Bergs Reaction; |
2'-Fluoroacetophenone
Benzimidazol-2-thiol
Conditions | Yield |
---|---|
With sulfuric acid; acetic acid for 0.5h; Reflux; | 97% |
Conditions | Yield |
---|---|
With C7H13N2O3S(1+)*C10H15O4S(1-) at 25℃; for 0.25h; Mannich Aminomethylation; | 97% |
2'-Fluoroacetophenone
ethyl 2-sulfanylacetate
ethyl 3-methyl-1-benzothiophene-2-carboxylate
Conditions | Yield |
---|---|
With potassium carbonate In N,N-dimethyl-formamide at 75℃; for 16h; Inert atmosphere; | 97% |
2'-Fluoroacetophenone
2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
2-(2-fluorophenyl)pent-4-en-2-ol
Conditions | Yield |
---|---|
With ethanol; diethylzinc In tetrahydrofuran at 20℃; for 2h; Inert atmosphere; | 96% |
With indium In water at 30℃; for 24h; Inert atmosphere; | 91% |
2-Aminobenzyl alcohol
2'-Fluoroacetophenone
2-(2-fluorophenyl)quinoline
Conditions | Yield |
---|---|
With C22H24ClN3ORu; potassium hydroxide In toluene at 80℃; for 5h; Catalytic behavior; Green chemistry; | 96% |
With copper(l) iodide; 1,10-Phenanthroline; potassium carbonate In tetrahydrofuran at 20℃; for 12h; | 96% |
With caesium carbonate In toluene at 120℃; for 10h; Schlenk technique; Inert atmosphere; | 71% |
Conditions | Yield |
---|---|
With C7H13N2O3S(1+)*C10H15O4S(1-) at 25℃; for 0.416667h; Mannich Aminomethylation; | 96% |
Conditions | Yield |
---|---|
With C7H13N2O3S(1+)*C10H15O4S(1-) at 25℃; for 0.416667h; Mannich Aminomethylation; | 96% |
About|Contact|Cas|Product Name|Molecular|Country|Encyclopedia
Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog
©2008 LookChem.com,License: ICP
NO.:Zhejiang16009103
complaints:service@lookchem.com Desktop View