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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

9-Bromophenanthrene Manufacturer/High quality/Best price/In stock

Cas:573-17-1

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 9-Bromophenanthrene supplier in China

Cas:573-17-1

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:yello crystalline powder Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:OLED Intermediate Transportation:by air or by sea Port:shanghai

9-Bromophenanthrene

Cas:573-17-1

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 9-Bromophenanthrene

Cas:573-17-1

Min.Order:1

Negotiable

Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 573-17-1 Phenanthrene, 9-bromo- Manufacturer

Cas:573-17-1

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

9-Bromophenanthrene

Cas:573-17-1

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Jinan Finer Chemical Co., Ltd

Product Description Product website: http://www.finerchem.com/pro01en/id/752.html Product Name 9-Bromophenanthrene CAS No. 573-17-1

9-Bromophenanthrene

Cas:573-17-1

Min.Order:1 Gram

FOB Price: $66.0

Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

9-Bromophenanthrene Basic information Product Name: 9-Bromophenanthrene Synonyms: 9-bromo-phenanthren;9-Phenanthryl bromide;9-Phenathryl bromide;9-phenathrylbromide;9-BROMOPHENANTHRENE;9

9-Bromophenanthrene 573-17-1

Cas:573-17-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

9-Bromophenanthrene CAS 573-17-1

Cas:573-17-1

Min.Order:1 Gram

FOB Price: $6.0 / 9.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 573-17-1 with best quality

Cas:573-17-1

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

9-Bromophenanthrene Basic information Product Name: 9-Bromophenanthrene Synonyms: 9-bromo-phenanthren;9-Phenanthryl bromide;9-Phenathryl bromide;9-phenathrylbromide

9-Bromophenanthrene

Cas:573-17-1

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

9-Bromophenanthrene 573-17-1

Cas:573-17-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Qingdao Beluga Import and Export Co., LTD

9-Bromophenanthrene CAS:573-17-1 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic interme

9-Bromophenanthrene CAS:573-17-1

Cas:573-17-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists

9-bromophenanthrene 573-17-1

Cas:573-17-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

9-Bromo Phenanthrene

Cas:573-17-1

Min.Order:0

Negotiable

Type:Manufacturers

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Zhengzhou Yuanli Biological Technology Co., Ltd.

Product Name: 9-Bromophenanthrene CAS No.:573-17-1 Molecular Formula:C14H9Br Molecular Weight:257.13 Assay: 99% Place of Origin: CN EINECS NO : 209-351-6 We could give you: 1.Fast response to customer within 6 hours 2.Lower Price with highe

Top grade 99% light yellow powder;573-17-1

Cas:573-17-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

9-Bromophenanthrene

Cas:573-17-1

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

9-Bromophenanthrene

Cas:573-17-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products 9-Bromophenanthrene

Cas:573-17-1

Min.Order:100 Gram

Negotiable

Type:Other

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 9-Bromophenanthrene

Cas:573-17-1

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

1)quick response within 12 hours; 2)quality guarantee: all products are strictly tested by our qc, confirmed by qa and approved by third party lab in china, usa, canada, germany, uk, italy, france etc. 3) oem/odm available; 4) rea

9-BromophenanthreneCAS NO.:573-17-1

Cas:573-17-1

Min.Order:1 Gram

FOB Price: $4.0

Type:Lab/Research institutions

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Suzhou Sinosun Imp.&Exp. Corporation

We supply high quality 9-bromophenanthrene CAS#573-17-1 at competitive price. Our 9-bromophenanthrene CAS#573-17-1 has been exported to many countries and regions. If you are looking for 9-bromophenanthrene CAS#573-17-1 suppliers in China, Sinos

9-Bromophenanthrene

Cas:573-17-1

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

9-Bromophenanthrene

Cas:573-17-1

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

Shanghai Minstar Chemical Co., Ltd

Product Name: 9-Bromophenanthrene Synonyms: 9-BROMOPHENANTHRENE;9-Bromophenathrene;9-Bromophenanthrene,95%;9-Bromophenanthrene,97%;Phenanthrene, 9-bromo-;9-Bromoanth raceme 96%;9-Bromophenanthrene,96%;9-BroMophenanthrene, 96% 10GR CAS: 573-1

9-Bromophenanthrene

Cas:573-17-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

9-Bromophenanthrene

Cas:573-17-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

SAGECHEM LIMITED

SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in custom synthe

SAGECHEM/9-Bromo Phenanthrene

Cas:573-17-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

9-bromophenanthrene

Cas:573-17-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:white crystalline powder Storage:stored in a cool, dry and ventilated place to provent sun and rain Package:25kg/drum, or as per your request. Application:Used as Pharmaceutical

9-Bromophenanthrene

Cas:573-17-1

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

9-Bromophenanthrene cas no. 573-17-1 98%

Cas:573-17-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

9-Bromophenanthrene

Cas:573-17-1

Min.Order:0

Negotiable

Type:Other

inquiry

Synthetic route

phenanthrene
85-01-8

phenanthrene

9-bromophenanthrene
573-17-1

9-bromophenanthrene

Conditions
ConditionsYield
With aluminum oxide; copper(ll) bromide In chlorobenzene at 80℃; for 2h;97%
With aluminum oxide; copper(ll) bromide In tetrachloromethane at 80℃; for 2h;95%
With bromine In chloroform for 17h; Reflux; Inert atmosphere;93%
phenanthrene
85-01-8

phenanthrene

A

9-bromophenanthrene
573-17-1

9-bromophenanthrene

9,10-dibromo-9,10-dihydrophenanthrene

9,10-dibromo-9,10-dihydrophenanthrene

Conditions
ConditionsYield
With bromine In Hexadecane for 480h; Cooling;A 32%
B 42%
With tri(decyl)(methyl)phosphonium tribromide; bromine In Hexadecane; tetradecafluorohexane for 480h;A 36%
B 7%
9-iodo-phenanthrene
17024-12-3

9-iodo-phenanthrene

9-bromophenanthrene
573-17-1

9-bromophenanthrene

Conditions
ConditionsYield
In tetrahydrofuran at 25℃; for 60h;18%
tetrachloromethane
56-23-5

tetrachloromethane

N-Bromosuccinimide
128-08-5

N-Bromosuccinimide

phenanthrene
85-01-8

phenanthrene

9-bromophenanthrene
573-17-1

9-bromophenanthrene

9,10-dibromo-9,10-dihydro-phenanthrene
17533-18-5

9,10-dibromo-9,10-dihydro-phenanthrene

silver(I) acetate
563-63-3

silver(I) acetate

acetic acid
64-19-7

acetic acid

9-bromophenanthrene
573-17-1

9-bromophenanthrene

Phenanthrene-9-carbonyl bromide

Phenanthrene-9-carbonyl bromide

9-bromophenanthrene
573-17-1

9-bromophenanthrene

Conditions
ConditionsYield
With RhCl(PPh3)3 at 300℃;
phenanthrene dibromide

phenanthrene dibromide

9-bromophenanthrene
573-17-1

9-bromophenanthrene

α-tetrahydrophenanthrene

α-tetrahydrophenanthrene

A

9-bromophenanthrene
573-17-1

9-bromophenanthrene

B

2,7-dibromophenanthrene
62325-30-8

2,7-dibromophenanthrene

Conditions
ConditionsYield
With chloroform; bromine
tetrachloromethane
56-23-5

tetrachloromethane

phenanthrene
85-01-8

phenanthrene

bromine (2 or 3 atoms)

bromine (2 or 3 atoms)

9-bromophenanthrene
573-17-1

9-bromophenanthrene

Conditions
ConditionsYield
at 0 - 76℃;
chloroform
67-66-3

chloroform

phenanthrene
85-01-8

phenanthrene

bromine (2 or 3 atoms)

bromine (2 or 3 atoms)

9-bromophenanthrene
573-17-1

9-bromophenanthrene

Conditions
ConditionsYield
at 0 - 76℃;
phenanthrene
85-01-8

phenanthrene

bromine
7726-95-6

bromine

A

9-bromophenanthrene
573-17-1

9-bromophenanthrene

B

9,10-dibromo-9,10-dihydro-phenanthrene
17533-18-5

9,10-dibromo-9,10-dihydro-phenanthrene

C

1.9-,2.7-,2(?).10-,3.9-or 4.10-dibromo-phenanthrene

1.9-,2.7-,2(?).10-,3.9-or 4.10-dibromo-phenanthrene

9,10-dibromo-9,10-dihydro-phenanthrene
17533-18-5

9,10-dibromo-9,10-dihydro-phenanthrene

A

9-bromophenanthrene
573-17-1

9-bromophenanthrene

B

hydrogen bromide
10035-10-6, 12258-64-9

hydrogen bromide

Conditions
ConditionsYield
beim Erhitzen fuer sich;
9,10-dibromo-9,10-dihydro-phenanthrene
17533-18-5

9,10-dibromo-9,10-dihydro-phenanthrene

water
7732-18-5

water

A

9-bromophenanthrene
573-17-1

9-bromophenanthrene

B

hydrogen bromide
10035-10-6, 12258-64-9

hydrogen bromide

Conditions
ConditionsYield
im geschlossenen Rohr;
9,10-dihydrophenanthrene
776-35-2

9,10-dihydrophenanthrene

A

9-bromophenanthrene
573-17-1

9-bromophenanthrene

B

phenanthrene
85-01-8

phenanthrene

Conditions
ConditionsYield
With N-Bromosuccinimide; biphenyl In benzene at 20℃; for 2h; Product distribution; Further Variations:; time dependence; Irradiation;A 5.5 % Chromat.
B 94.5 % Chromat.
phenanthrene
85-01-8

phenanthrene

A

9-bromophenanthrene
573-17-1

9-bromophenanthrene

B

9-chlorophenanthrene
947-72-8

9-chlorophenanthrene

Conditions
ConditionsYield
With bromine at 100℃; for 4h; Reflux; Ionic liquid;
naphthalene
91-20-3

naphthalene

9-bromophenanthrene
573-17-1

9-bromophenanthrene

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: N-Bromosuccinimide; gold(III) chloride / 1,2-dichloro-ethane / 15 h / 80 °C / Inert atmosphere
2: sodium amide; potassium tert-butylate / tetrahydrofuran / 15 h / 50 °C / Inert atmosphere
3: perrhenic acid anhydride; triphenyl phosphite / toluene / 80 °C / Inert atmosphere
4: N-Bromosuccinimide; gold(III) chloride / 1,2-dichloro-ethane / 15 h / 80 °C / Inert atmosphere
View Scheme
1-Bromonaphthalene
90-11-9

1-Bromonaphthalene

9-bromophenanthrene
573-17-1

9-bromophenanthrene

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: sodium amide; potassium tert-butylate / tetrahydrofuran / 15 h / 50 °C / Inert atmosphere
2: perrhenic acid anhydride; triphenyl phosphite / toluene / 80 °C / Inert atmosphere
3: N-Bromosuccinimide; gold(III) chloride / 1,2-dichloro-ethane / 15 h / 80 °C / Inert atmosphere
View Scheme
1,4-dihydro-1,4-epoxyphenanthrene
83164-98-1

1,4-dihydro-1,4-epoxyphenanthrene

9-bromophenanthrene
573-17-1

9-bromophenanthrene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: perrhenic acid anhydride; triphenyl phosphite / toluene / 80 °C / Inert atmosphere
2: N-Bromosuccinimide; gold(III) chloride / 1,2-dichloro-ethane / 15 h / 80 °C / Inert atmosphere
View Scheme
benzene
71-43-2

benzene

9-bromophenanthrene
573-17-1

9-bromophenanthrene

Conditions
ConditionsYield
Multi-step reaction with 7 steps
1: N-Bromosuccinimide; gold(III) chloride / 1,2-dichloro-ethane / 24 h / 80 °C / Inert atmosphere
2: sodium amide; potassium tert-butylate / tetrahydrofuran / 15 h / 50 °C / Inert atmosphere
3: ammonium perrhenate; triphenyl phosphite / toluene / 18 h / 80 °C / Inert atmosphere
4: N-Bromosuccinimide; gold(III) chloride / 1,2-dichloro-ethane / 15 h / 80 °C / Inert atmosphere
5: sodium amide; potassium tert-butylate / tetrahydrofuran / 15 h / 50 °C / Inert atmosphere
6: perrhenic acid anhydride; triphenyl phosphite / toluene / 80 °C / Inert atmosphere
7: N-Bromosuccinimide; gold(III) chloride / 1,2-dichloro-ethane / 15 h / 80 °C / Inert atmosphere
View Scheme
bromobenzene
108-86-1

bromobenzene

9-bromophenanthrene
573-17-1

9-bromophenanthrene

Conditions
ConditionsYield
Multi-step reaction with 6 steps
1: sodium amide; potassium tert-butylate / tetrahydrofuran / 15 h / 50 °C / Inert atmosphere
2: ammonium perrhenate; triphenyl phosphite / toluene / 18 h / 80 °C / Inert atmosphere
3: N-Bromosuccinimide; gold(III) chloride / 1,2-dichloro-ethane / 15 h / 80 °C / Inert atmosphere
4: sodium amide; potassium tert-butylate / tetrahydrofuran / 15 h / 50 °C / Inert atmosphere
5: perrhenic acid anhydride; triphenyl phosphite / toluene / 80 °C / Inert atmosphere
6: N-Bromosuccinimide; gold(III) chloride / 1,2-dichloro-ethane / 15 h / 80 °C / Inert atmosphere
View Scheme
1,4-dihydronaphthalene-1,4-epoxide
573-57-9

1,4-dihydronaphthalene-1,4-epoxide

9-bromophenanthrene
573-17-1

9-bromophenanthrene

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: ammonium perrhenate; triphenyl phosphite / toluene / 18 h / 80 °C / Inert atmosphere
2: N-Bromosuccinimide; gold(III) chloride / 1,2-dichloro-ethane / 15 h / 80 °C / Inert atmosphere
3: sodium amide; potassium tert-butylate / tetrahydrofuran / 15 h / 50 °C / Inert atmosphere
4: perrhenic acid anhydride; triphenyl phosphite / toluene / 80 °C / Inert atmosphere
5: N-Bromosuccinimide; gold(III) chloride / 1,2-dichloro-ethane / 15 h / 80 °C / Inert atmosphere
View Scheme
9,10-dihydrodibenzazepine
494-19-9

9,10-dihydrodibenzazepine

9-bromophenanthrene
573-17-1

9-bromophenanthrene

N-(9-phenanthryl)iminodibenzyl

N-(9-phenanthryl)iminodibenzyl

Conditions
ConditionsYield
With C30H43O2P*C13H12N(1-)*CH3O3S(1-)*Pd(2+); lithium hexamethyldisilazane In 1,4-dioxane at 100℃; for 16h; Inert atmosphere;100%
9-bromophenanthrene
573-17-1

9-bromophenanthrene

2,6-dimethylbenzene boronic acid
100379-00-8

2,6-dimethylbenzene boronic acid

9-(2,6-dimethyl-phenyl)-phenanthrene

9-(2,6-dimethyl-phenyl)-phenanthrene

Conditions
ConditionsYield
With potassium phosphate; N,N-diisopropyl 2-dicyclohexylphosphino-4-phenylbenzamide; tris(dibenzylideneacetone)dipalladium (0) In N,N-dimethyl-formamide at 110℃; for 9h; Suzuki cross-coupling;99.5%
9-bromophenanthrene
573-17-1

9-bromophenanthrene

phenanthrene
85-01-8

phenanthrene

Conditions
ConditionsYield
With potassium fluoride In tetrahydrofuran; water at 80℃; for 4h; Catalytic behavior; Reagent/catalyst; Solvent; Temperature; Schlenk technique; Sealed tube; Inert atmosphere;99%
With 4-methyl-morpholine; tetrahydroxydiboron; 5%-palladium/activated carbon In 1,2-dichloro-ethane at 50℃; for 1.5h; Reagent/catalyst; Solvent; Temperature;99%
With 2-H-1,3-di-tert-butyl-1,3,2-diazaphosphorinane; 2,2'-azobis(isobutyronitrile) In toluene at 90℃; for 5h;99%
9-bromophenanthrene
573-17-1

9-bromophenanthrene

9-deuteriophenanthrene
4819-99-2

9-deuteriophenanthrene

Conditions
ConditionsYield
With 4-methyl-morpholine; tetrahydroxydiborane(4); 5%-palladium/activated carbon; DMAP-d6 In 1,2-dichloro-ethane at 50℃; for 3.5h; Solvent; Reagent/catalyst;99%
With potassium phosphate; d(4)-methanol; palladium diacetate; catacxium A In toluene at 80℃; for 16h;94%
With 2,2'-azobis(isobutyronitrile); C11H24(2)HN2P In (2)H8-toluene at 90℃; for 5h; Mechanism;90%
With n-butyllithium; water-d2 1.) ehter, hexane, 2.) ether, hexane, from 0 to 5 deg C, 1 h; Yield given. Multistep reaction;
With deuteromethanol; tetraethylammonium perchlorate; triethylamine In dimethyl sulfoxide at 20℃; for 32h; Reagent/catalyst; Electrolysis; Green chemistry;96 %Spectr.
9-bromophenanthrene
573-17-1

9-bromophenanthrene

dimethyl sulfate
77-78-1

dimethyl sulfate

9-methylphenanthrene
883-20-5

9-methylphenanthrene

Conditions
ConditionsYield
Stage #1: 9-bromophenanthrene With n-butyllithium In diethyl ether at 20℃; for 1h;
Stage #2: dimethyl sulfate In diethyl ether for 5h; Heating; Further stages.;
99%
Stage #1: 9-bromophenanthrene With n-butyllithium In diethyl ether; hexane at 20℃; Inert atmosphere; Cooling with ice;
Stage #2: dimethyl sulfate In diethyl ether; hexane at 0℃; Inert atmosphere; Reflux;
99%
Stage #1: 9-bromophenanthrene With n-butyllithium In diethyl ether; hexane at 0 - 23℃; for 0.333333h; Inert atmosphere;
Stage #2: dimethyl sulfate In diethyl ether; hexane at 0℃; for 5.5h; Reflux; Inert atmosphere;
72%
With n-butyllithium 1)room temp., 2h,ether, hexane 2)reflux, 8h; Yield given. Multistep reaction;
9-bromophenanthrene
573-17-1

9-bromophenanthrene

phenylboronic acid
98-80-6

phenylboronic acid

9-phenylphenanthrene
844-20-2

9-phenylphenanthrene

Conditions
ConditionsYield
With potassium fluoride; o-(dicyclohexylphosphino)diisopropylbenzamide; tris(dibenzylideneacetone)dipalladium (0) In N,N-dimethyl-formamide at 60℃; for 4h; Suzuki cross-coupling;99%
With 1,2,4,5-[3-(2,6-(iPr)2C6H3)imidazol-1-yl-CH2]4-Ph(4+)*4Br(-); potassium carbonate; palladium diacetate In ethanol at 20℃; for 22h; Suzuki cross-coupling;97%
Stage #1: 9-bromophenanthrene With [Pd(2-phenylpyridine)(Bmim)(saccharinate)] In toluene at 80℃; for 0.0833333h; Inert atmosphere; Schlenk technique;
Stage #2: phenylboronic acid With sodium carbonate In water at 80℃; for 12h; Catalytic behavior; Temperature; Reagent/catalyst; Concentration; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique;
96%
9-bromophenanthrene
573-17-1

9-bromophenanthrene

ortho-nitrobenzoic acid
552-16-9

ortho-nitrobenzoic acid

1-(9-phenanthryl)-2-nitrobenzene
911217-05-5

1-(9-phenanthryl)-2-nitrobenzene

Conditions
ConditionsYield
Stage #1: ortho-nitrobenzoic acid With potassium carbonate In various solvent(s) at 120℃; for 0.5h;
Stage #2: 9-bromophenanthrene With 1,10-Phenanthroline; copper(l) iodide In various solvent(s) at 160℃; for 24h; Further stages.;
99%
With potassium fluoride; copper(II) carbonate; bis(acetylacetonato)palladium(II); isopropyldiphenylphosphine In 1-methyl-pyrrolidin-2-one at 120℃; for 24h; Product distribution / selectivity; Molecular sieve;86 %Chromat.
copper(l) iodide; Phenanthroline; bis(acetylacetonato)palladium(II) In 1-methyl-pyrrolidin-2-one at 160℃; for 24h; Product distribution / selectivity; Molecular sieve;99 %Chromat.
9-bromophenanthrene
573-17-1

9-bromophenanthrene

1-Naphthylboronic acid
13922-41-3

1-Naphthylboronic acid

9-(naphthalen-1-yl) phenanthrene
119925-45-0

9-(naphthalen-1-yl) phenanthrene

Conditions
ConditionsYield
With potassium phosphate; 2C32H41O4P*Pd(2+)*2Cl(1-) In toluene at 110℃; for 16h; Suzuki-Miyaura Coupling; Inert atmosphere;99%
With [Pd{C6H2(CH2CH2NH2)-(OMe)2,3,4} (μ-Br)]2; potassium carbonate In N,N-dimethyl-formamide at 130℃; for 0.333333h; Suzuki-Miyaura coupling; Microwave irradiation;80%
With dichloro[1,1'-bis(di-t-butylphosphino)ferrocene]palladium(II); triethylamine In water at 20℃; for 24h; Suzuki-Miyaura reaction; Inert atmosphere; Micellar solution;78%
lithium trimethoxy(1,2,2-trifluorovinyl)borate

lithium trimethoxy(1,2,2-trifluorovinyl)borate

9-bromophenanthrene
573-17-1

9-bromophenanthrene

9-(1,2,2-trifluorovinyl)phenanthrene

9-(1,2,2-trifluorovinyl)phenanthrene

Conditions
ConditionsYield
With potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0); XPhos In tetrahydrofuran at 20 - 60℃; for 15.25h; Suzuki coupling; Inert atmosphere;99%
9-bromophenanthrene
573-17-1

9-bromophenanthrene

4-methoxy-2,6-dimethylphenylboronic acid
361543-99-9

4-methoxy-2,6-dimethylphenylboronic acid

C23H20O
1392512-39-8

C23H20O

Conditions
ConditionsYield
With Pd-PEPPSI-IPrAn; potassium tert-butylate In 1,4-dioxane at 80℃; for 24h; Suzuki coupling; Inert atmosphere;99%
9-bromophenanthrene
573-17-1

9-bromophenanthrene

S-phenyl tert-butylcarbamothioate
56741-04-9

S-phenyl tert-butylcarbamothioate

A

N-(tert-butyl)phenanthrene-9-carboxamide
1579273-93-0

N-(tert-butyl)phenanthrene-9-carboxamide

B

diphenyldisulfane
882-33-7

diphenyldisulfane

Conditions
ConditionsYield
Stage #1: 9-bromophenanthrene With iodine; magnesium In 2-methyltetrahydrofuran at 60℃; for 1h; Schlenk technique; Inert atmosphere;
Stage #2: S-phenyl tert-butylcarbamothioate In 2-methyltetrahydrofuran at 0 - 20℃; for 2h; Inert atmosphere; Schlenk technique;
Stage #3: With ammonium hydroxide; oxygen In 2-methyltetrahydrofuran; water under 760.051 Torr; for 18h;
A 76%
B 99%
9-bromophenanthrene
573-17-1

9-bromophenanthrene

C28H37AgF2N2S

C28H37AgF2N2S

(difluoromethyl)(phenanthren-9-yl)thioether

(difluoromethyl)(phenanthren-9-yl)thioether

Conditions
ConditionsYield
With dicyclohexyl-(2′,4′,6′-triisopropyl-3,6-dimethoxy-[1,1′-biphenyl]-2-yl)phosphine; [(2-di-cyclohexylphosphino-3,6-dimethoxy-2’,4’,6’-triisopropyl-1,1‘-biphenyl)-2-(2‘-amino-1,1’-biphenyl)]palladium(II) methanesulfonate In tetrahydrofuran at 50℃; for 2h; Inert atmosphere; Schlenk technique;99%
2-methylfuran
534-22-5

2-methylfuran

9-bromophenanthrene
573-17-1

9-bromophenanthrene

2-methyl-5-(phenanthren-9-yl)furan

2-methyl-5-(phenanthren-9-yl)furan

Conditions
ConditionsYield
With [Pd(IPr*IMe)An(3-Cl-pyridinyl)Cl2]; potassium carbonate; acetic acid In N,N-dimethyl acetamide at 130℃; for 12h; regioselective reaction;99%
2-pentylfuran
3777-69-3

2-pentylfuran

9-bromophenanthrene
573-17-1

9-bromophenanthrene

2-pentyl-5-(phenanthren-9-yl)furan

2-pentyl-5-(phenanthren-9-yl)furan

Conditions
ConditionsYield
With [Pd(IPr*IMe)An(3-Cl-pyridinyl)Cl2]; potassium carbonate; Trimethylacetic acid In N,N-dimethyl acetamide at 130℃; for 12h; regioselective reaction;99%
9-bromophenanthrene
573-17-1

9-bromophenanthrene

(5-chloro-2-methylphenyl)boronic acid
148839-33-2

(5-chloro-2-methylphenyl)boronic acid

C21H15Cl

C21H15Cl

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene at 90℃; for 4.5h; Inert atmosphere;98.6%
methanol
67-56-1

methanol

9-bromophenanthrene
573-17-1

9-bromophenanthrene

9-methoxyphenanthrene
5085-74-5

9-methoxyphenanthrene

Conditions
ConditionsYield
Stage #1: methanol With pyridine; copper(l) iodide; sodium at 80℃; Inert atmosphere;
Stage #2: 9-bromophenanthrene With pyridine for 42.1667h; Reflux; Inert atmosphere;
98%
Stage #1: methanol With sodium
Stage #2: 9-bromophenanthrene With pyridine; copper(l) iodide at 80℃; for 48h;
89%
With pyridine; copper(l) iodide; sodium for 18h; Heating;86%
1-ethenylcyclohexene
931-49-7

1-ethenylcyclohexene

9-bromophenanthrene
573-17-1

9-bromophenanthrene

9-(cyclohex-1-enylethynyl)phenanthrene
1052216-08-6

9-(cyclohex-1-enylethynyl)phenanthrene

Conditions
ConditionsYield
With dichloro bis(acetonitrile) palladium(II); triethylamine; XPhos In water at 20℃; Sonogashira coupling; Inert atmosphere; Micellar solution;98%
3,7-dihydro-1,3,7-trimethyl-1H-purine-2,6-dione
58-08-2

3,7-dihydro-1,3,7-trimethyl-1H-purine-2,6-dione

9-bromophenanthrene
573-17-1

9-bromophenanthrene

3,7-Dihydro-1,3,7-trimethyl-8-(9-phenanthryl)-1H-purin-2,6-dion
99765-06-7

3,7-Dihydro-1,3,7-trimethyl-8-(9-phenanthryl)-1H-purin-2,6-dion

Conditions
ConditionsYield
With potassium phosphate; palladium diacetate; Trimethylacetic acid In N,N-dimethyl-formamide at 20 - 120℃; for 7.16667h; Inert atmosphere;98%
With potassium phosphate; copper(l) iodide; 1,10-Phenanthroline In 5,5-dimethyl-1,3-cyclohexadiene; N,N-dimethyl-formamide at 20 - 140℃; for 36.1667h; Inert atmosphere; regioselective reaction;95%
9-bromophenanthrene
573-17-1

9-bromophenanthrene

3,5-dimethylphenyl boronic acid
172975-69-8

3,5-dimethylphenyl boronic acid

9-(3,5-dimethylphenyl)phenanthrene

9-(3,5-dimethylphenyl)phenanthrene

Conditions
ConditionsYield
Stage #1: 9-bromophenanthrene With [Pd(2-phenylpyridine)(Bmim)(saccharinate)] In toluene at 80℃; for 0.0833333h; Inert atmosphere; Schlenk technique;
Stage #2: 3,5-dimethylphenyl boronic acid With sodium carbonate In water at 80℃; for 12h; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique;
98%
9-bromophenanthrene
573-17-1

9-bromophenanthrene

C68H72B4N4O8Zn

C68H72B4N4O8Zn

C100H60N4Zn

C100H60N4Zn

Conditions
ConditionsYield
With pyridine; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; sodium t-butanolate In toluene at 130℃; under 2250.23 Torr; for 1h; Suzuki-Miyaura Coupling; Microwave irradiation; Inert atmosphere; Sealed tube;98%
dibenzoazepine
256-96-2

dibenzoazepine

9-bromophenanthrene
573-17-1

9-bromophenanthrene

N-(9-phenanthryl)iminostilbene

N-(9-phenanthryl)iminostilbene

Conditions
ConditionsYield
With C30H43O2P*C13H12N(1-)*CH3O3S(1-)*Pd(2+); lithium hexamethyldisilazane In 1,4-dioxane at 100℃; for 16h; Inert atmosphere;98%

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