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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis according to the contract research and development services for t

High purity 4-Formylphenylboronic acid 98% TOP1 supplier in China

Cas:87199-17-5

Min.Order:1 Kilogram

FOB Price: $3.0

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China Synchem Technology Co.,Ltd

4-Formylphenylboronic acid CAS No. 87199-17-5 Appearance: Off-white powder Purity (GC) : >98% Customization service Company Profile: Synchem is dedicated to custom synthesis and manufacturing services for small molecules. We serv

4-Formylphenylboronic acid manufacturer

Cas:87199-17-5

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Jinan Finer Chemical Co., Ltd

Product Description Product website: http://www.finerchem.com/pro01en/id/70.html Product Name 4-Formylphenylboronic acid CAS No. 87199-17-5

4-Formylphenylboronic acid

Cas:87199-17-5

Min.Order:1 Gram

FOB Price: $54.0

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 4-Formylphenyl Boronic Acid

Cas:87199-17-5

Min.Order:1 Kilogram

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Wuhan Fortuna Chemical Co.,Ltd

High quality 4-Formylphenylboronic acid CAS 87199-17-5 with factory price Company profile Wuhan Fortuna Chemical Co.,Ltd established in 2006, is a big integrative chemical enterprise being engaged in Pharmaceutical & its intermediates, Food/

High quality 4-Formylphenylboronic acid CAS 87199-17-5 with factory price

Cas:87199-17-5

Min.Order:10 Gram

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off white powder Storage:Sealed, dry, microtherm , avoid light and smell Package:According to the demand of customer Application:Pharmaceutical intermediates Transportation:by air or by sea Port:shanghai

4-Formylphenylboronic acid

Cas:87199-17-5

Min.Order:1 Kilogram

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 4-Formylphenyl Boronic Acid

Cas:87199-17-5

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 87199-17-5 4-Formylphenylboronic acid Manufacturer

Cas:87199-17-5

Min.Order:1 Gram

FOB Price: $0.1

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

4-Formylbenzeneboronic acid

Cas:87199-17-5

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 6 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

87199-17-5 4-Formylphenylboronic acid

Cas:87199-17-5

Min.Order:1 Kilogram

FOB Price: $1000.0

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Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

4-Formylphenylboronic acid

Cas:87199-17-5

Min.Order:1 Gram

FOB Price: $1000.0 / 1300.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

BP Standard CAS 87199-17-5 with best quality

Cas:87199-17-5

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

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Hubei Langyou International Trading Co., Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:liquid Storage:Store in sealed containers at cool & dry plac

4-Formylphenylboronic acid(CAS:87199-17-5)

Cas:87199-17-5

Min.Order:100 Gram

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

4-Formylphenylboronic acid 87199-17-5

Cas:87199-17-5

Min.Order:1 Kilogram

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

4-Formylphenylboronic acid with CAS:87199-17-5

Cas:87199-17-5

Min.Order:1 Kilogram

FOB Price: $6.0 / 8.0

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Qingdao Beluga Import and Export Co., LTD

4-Formylphenylboronic acid CAS:87199-17-5 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organi

4-Formylphenylboronic acid CAS:87199-17-5

Cas:87199-17-5

Min.Order:1 Gram

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

4-Formylphenylboronic acid

Cas:87199-17-5

Min.Order:1 Kilogram

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Changchun Artel lmport and Export trade company

Superiority We can customize and synthesize products that other suppliers may not be able to provide. Advantage cof, mof ligand manufacturer Product Detail bes

99% :4-Formylphenylboronic Acid CAS:87199-17-5

Cas:87199-17-5

Min.Order:100 Kilogram

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Type:Trading Company

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:87199-17-5

Cas:87199-17-5

Min.Order:0

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

4-Formylphenylboronic acid

Cas:87199-17-5

Min.Order:0 Metric Ton

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

4-Formylphenylboronic acid CAS87199-17-5

Cas:87199-17-5

Min.Order:10 Kilogram

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Type:Trading Company

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

4-Formylphenyl Boronic Acid

Cas:87199-17-5

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Triumph International Development Limilted

Appearance:white or light yellow crystalline powder Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for research and industrial manufacture. Transportation:As

4-Formylphenylboronic acid 87199-17-5

Cas:87199-17-5

Min.Order:0 Metric Ton

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Kunshan Push Trading Co.,LTD

4-Formylbenzeneboronic acid 87199-17-5 ADVANTAGE 1.Professional: More than 10 years chemical exporting experience. We have produced chemical more than fifteen years, 95% products are for export . More than 10 years chemical exporting experience. Go

4-Formylbenzeneboronic acid 87199-17-5

Cas:87199-17-5

Min.Order:1 Kilogram

FOB Price: $1.0

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Hebei Miheng Trading Co., Ltd.

4-Formylphenylboronic acid CAS 87199-17-5 Our advantage 1.Top quality: Using high quality material and establishing a strict quality control system,assigning specific persons in charge of each part of production,from raw material purchase

4-Formylphenylboronic acid CAS 87199-17-5

Cas:87199-17-5

Min.Order:1 Kilogram

FOB Price: $10.0 / 50.0

Type:Trading Company

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Taizhou Crene Biotechnology co.ltd

Our company provides one-stop services of research - development - production for a variety of special prouducts. Not only do we make effective use of our strong technological strength, but also establish of cooperative relations with several well-

4-Formylphenylboronic acid 87199-17-5

Cas:87199-17-5

Min.Order:50 Gram

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Hefei Zhaobo Technology Co., Ltd.

4-Formylphenylboronic acid CAS 87199-17-5 Description Purity: 99% Min Application: Intermediates Appearance: Powder Package: Bag Delivery: 3-5days Our Advantage & Service 1.Top quality: Using high quality material and establishing

4-Formylphenylboronic acid CAS 87199-17-5

Cas:87199-17-5

Min.Order:1 Kilogram

FOB Price: $10.0 / 50.0

Type:Trading Company

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

4-formylphenylboronic acid

Cas:87199-17-5

Min.Order:0

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Afine Chemicals Limited

Our Services 1. New Molecules R&D 2. Own test center HPLC NMR GC LC-MS 3. API and Intermediates from China reputed manufacturers 4. Documents support COA MOA MSDS DMF open part Our advantages 1. Government awarded company. Top 100 enter

4-FORMYLPHENYLBORONIC ACID

Cas:87199-17-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

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SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

4-Formylphenylboronic acid

Cas:87199-17-5

Min.Order:4 Kilogram

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Synthetic route

potassium 4-formylphenyltrifluoroborate

potassium 4-formylphenyltrifluoroborate

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

Conditions
ConditionsYield
With iron(III) chloride; water In tetrahydrofuran at 20℃; for 1h;97%
With aluminum oxide; water at 70℃; for 0.25h; Microwave irradiation;92%
With water; silica gel at 20℃; for 24h; Inert atmosphere;88%
p-hydroxymethylphenylboronic acid
59016-93-2

p-hydroxymethylphenylboronic acid

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

Conditions
ConditionsYield
With 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione In dimethyl sulfoxide at 20℃; for 5h; Inert atmosphere;90%
With o-iodoxybenzoic acid In dimethylsulfoxide reaction at room temp.; one phase-switch purification used;90%
4-allylphenylboronic acid
186497-79-0

4-allylphenylboronic acid

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

Conditions
ConditionsYield
With Triethoxysilane; iron(III) chloride In methanol for 12h; Reflux;88%
2-(4-bromophenyl)-1,3-dioxane
61568-51-2

2-(4-bromophenyl)-1,3-dioxane

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

Conditions
ConditionsYield
Stage #1: 2-(4-bromophenyl)-1,3-dioxane With tert.-butyl lithium In tetrahydrofuran; pentane at -78℃; for 1h;
Stage #2: With Trimethyl borate In tetrahydrofuran; pentane at -78 - 20℃; for 3h;
Stage #3: With hydrogenchloride In tetrahydrofuran; water; pentane
81%
Stage #1: 2-(4-bromophenyl)-1,3-dioxane With magnesium; ethylene dibromide In tetrahydrofuran for 0.5h; Metallation; Heating;
Stage #2: With Trimethyl borate In tetrahydrofuran at -78 - -45℃; for 7.5h; Grignard reaction;
Stage #3: With hydrogenchloride; water for 0.25h; Hydrolysis; Heating;
67%
Stage #1: 2-(4-bromophenyl)-1,3-dioxane With magnesium; ethylene dibromide In tetrahydrofuran for 1.66667h;
Stage #2: With Trimethyl borate In tetrahydrofuran for 0.666667h;
Stage #3: With hydrogenchloride In water for 1h; Reflux;
48%
p-bromobenzaldehyde 1,3-dioxolane
10602-01-4

p-bromobenzaldehyde 1,3-dioxolane

Triisopropyl borate
5419-55-6

Triisopropyl borate

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

Conditions
ConditionsYield
Stage #1: p-bromobenzaldehyde 1,3-dioxolane With n-butyllithium In tetrahydrofuran at -78℃; for 1h; Inert atmosphere; Schlenk technique;
Stage #2: Triisopropyl borate In tetrahydrofuran at -78 - 20℃; for 12h; Inert atmosphere; Schlenk technique;
Stage #3: With hydrogenchloride In tetrahydrofuran; water at 20℃; for 3h; Inert atmosphere; Schlenk technique;
78%
With n-butyllithium In tetrahydrofuran; hexane at 20℃; for 2h; Inert atmosphere;71%
Stage #1: p-bromobenzaldehyde 1,3-dioxolane With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.75h;
Stage #2: Triisopropyl borate In tetrahydrofuran; hexane at 20℃;
Stage #3: With hydrogenchloride In tetrahydrofuran; hexane at 20℃; for 2h;
64%
With hydrogenchloride; n-butyllithium In tetrahydrofuran; hexane n-C4H9Li/hexanes added dropwise to a soln. of 2-(4-bromophenyl)-1,3-dioxolane in THF at -78°C, stirred at -78°C for 45 min, B compd. added dropwise, warmed slowly to room temp. and stirred overnight, quenched with HCl at room temp. for 2 h; extd. (EtOAc), the combined org. layers washed (brine), dried (MgSO4), flash-chromd. (silica gel, EtOAc/petroleum ether, then MeOH); elem. anal.;64%
boric acid tributyl ester
688-74-4

boric acid tributyl ester

4-bromobenzaldehyde diethyl acetal
34421-94-8

4-bromobenzaldehyde diethyl acetal

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

Conditions
ConditionsYield
With Mg; aq. H2SO4; KOH In tetrahydrofuran; diethyl ether byproducts: BuOH, Mg(OH)2, MgBr2; dropwise addn. of the grignard compd. of the acetal in THF to mixt. of B(OC4H9)3 in THF (under N2, -68°C, under stirring), stirred after thawing (1 h), evapn. of volatiles (20°C, 1 Torr), addn. of 1 M H2SO4 to soln. of the residue in ether; extn. with ether, evapn. of ether (vac.), addn. of KOH to aq. phase, after addn. of water azeotropic distn. of H2O/ BuOH in vac., residue acidified with 1 M H2SO4, refluxed (30 min), filtered, cooling of the filtrate, recrystn. from hot H2O; elem. anal.;78%
potassium 4-formylphenyltrifluoroborate

potassium 4-formylphenyltrifluoroborate

water
7732-18-5

water

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

Conditions
ConditionsYield
With montmorillonite K10 at 25℃; for 24h;75%
C41H63BO6

C41H63BO6

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

Conditions
ConditionsYield
In water; dimethyl sulfoxide at 219.85℃; for 120h;72%
(HO)2BC6H4CH(C6H2(OH)2(CH2)10CH3)2

(HO)2BC6H4CH(C6H2(OH)2(CH2)10CH3)2

water
7732-18-5

water

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

Conditions
ConditionsYield
In dimethyl sulfoxide thermolysis of mixt. of boron compound, DMSO and water at 493 K, 5 d, cooling; filtration, evapn. in vac., washing with ethyl acetate, drying;72%
p-bromobenzaldehyde 1,3-dioxolane
10602-01-4

p-bromobenzaldehyde 1,3-dioxolane

Trimethyl borate
121-43-7

Trimethyl borate

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

Conditions
ConditionsYield
Stage #1: p-bromobenzaldehyde 1,3-dioxolane With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 2h; Inert atmosphere;
Stage #2: Trimethyl borate In tetrahydrofuran; hexane at 20℃; for 1h; Inert atmosphere;
63%
p-bromobenzaldehyde 1,3-dioxolane
10602-01-4

p-bromobenzaldehyde 1,3-dioxolane

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

Conditions
ConditionsYield
Stage #1: p-bromobenzaldehyde 1,3-dioxolane With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.5h;
Stage #2: With boric acid tributyl ester In tetrahydrofuran; hexane at -78℃; for 1h;
54%
Stage #1: p-bromobenzaldehyde 1,3-dioxolane With n-butyllithium In tetrahydrofuran at -78℃; for 0.166667h; Inert atmosphere;
Stage #2: With Triisopropyl borate In tetrahydrofuran at -78 - 20℃; for 1h; Inert atmosphere;
Stage #3: With hydrogenchloride; water; sodium chloride In tetrahydrofuran for 0.5h;
4-bromomethylphenylboronic acid
68162-47-0

4-bromomethylphenylboronic acid

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

Conditions
ConditionsYield
With hexamethylenetetramine
<4-dibromomethyl-phenyl>-dihydroxy-borane

<4-dibromomethyl-phenyl>-dihydroxy-borane

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

Conditions
ConditionsYield
With sulphurous acid
C11H17BO4

C11H17BO4

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

Conditions
ConditionsYield
With hydrogenchloride; water at 20℃; for 7h;
4-bromo-benzaldehyde
1122-91-4

4-bromo-benzaldehyde

LiPh2InH2

LiPh2InH2

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: 89 percent / p-TsOH / toluene / 20 h / Heating
2.1: n-BuLi / tetrahydrofuran; hexane / 0.75 h / -78 °C
2.2: tetrahydrofuran; hexane / 20 °C
2.3: 64 percent / aq. HCl / hexane; tetrahydrofuran / 2 h / 20 °C
View Scheme
4-bromobenzaldehyde diethyl acetal
34421-94-8

4-bromobenzaldehyde diethyl acetal

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: nBuLi; B(O-iPr)3 / tetrahydrofuran; hexane / 20 °C
2: HCl; water / 7 h / 20 °C
View Scheme
4-bromo-benzaldehyde
1122-91-4

4-bromo-benzaldehyde

4-acetylbenzoyl-Rink resin

4-acetylbenzoyl-Rink resin

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 89 percent / p-TsOH*H2O / ethanol / 20 °C
2: nBuLi; B(O-iPr)3 / tetrahydrofuran; hexane / 20 °C
3: HCl; water / 7 h / 20 °C
View Scheme
4-bromo-benzaldehyde
1122-91-4

4-bromo-benzaldehyde

decyl magnesium halide

decyl magnesium halide

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: 96 percent / BF3*OEt2 / toluene / 4.5 h / Heating
2.1: Mg; 1,2-dibromoethane / tetrahydrofuran / 0.5 h / Heating
2.2: B(OCH3)3 / tetrahydrofuran / 7.5 h / -78 - -45 °C
2.3: 67 percent / HCl; H2O / 0.25 h / Heating
View Scheme
Trimethyl borate
121-43-7

Trimethyl borate

4-bromo-benzaldehyde
1122-91-4

4-bromo-benzaldehyde

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran N2; BuLi dropping into org. compd. soln. at -78°C, mixt. keeping 3 h, B-compd. soln. addn. dropwise at -78°C, mixt. allowing to warm to room temp. overnight , stirring 1 h with 10% HCl, extn. (Et2O); org. extracts washing (water), drying, solvent vac. removal;
tris(4-dibromomethyl phenyl)boroxine
111561-46-7

tris(4-dibromomethyl phenyl)boroxine

water
7732-18-5

water

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

Conditions
ConditionsYield
In water hydrolysis on boiling in SO2-satd. H2O (10min);;
In water hydrolysis on boiling in SO2-satd. H2O (10min);;
m-tolylboronic acid
17933-03-8

m-tolylboronic acid

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: benzoyl peroxide / tetrachloromethane
2: benzoyl peroxide / tetrachloromethane
3: water
View Scheme
tris(4-bromomethyl phenyl)boroxine
51239-44-2

tris(4-bromomethyl phenyl)boroxine

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: benzoyl peroxide / tetrachloromethane
2: water
View Scheme
4-chlorobenzaldehyde
104-88-1

4-chlorobenzaldehyde

A

p-hydroxymethylphenylboronic acid
59016-93-2

p-hydroxymethylphenylboronic acid

B

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

Conditions
ConditionsYield
With tetrahydroxydiboron; (chloro(2-dicyclohexylphosphino-2′,4′,6′-triisopropyl-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II)); potassium acetate; XPhos In ethanol at 80℃; for 20h; Inert atmosphere;
4-bromo-benzaldehyde
1122-91-4

4-bromo-benzaldehyde

A

p-hydroxymethylphenylboronic acid
59016-93-2

p-hydroxymethylphenylboronic acid

B

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

Conditions
ConditionsYield
With tetrahydroxydiboron; (chloro(2-dicyclohexylphosphino-2′,4′,6′-triisopropyl-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II)); potassium acetate; XPhos In methanol at 80℃; for 4h; Inert atmosphere;
4-bromo-benzaldehyde
1122-91-4

4-bromo-benzaldehyde

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: toluene-4-sulfonic acid / toluene / 20 h / Reflux; Dean-Stark
2.1: n-butyllithium / hexane; tetrahydrofuran / 0.5 h / -78 °C
2.2: 1 h / -78 °C
View Scheme
With tetrahydroxydiboron; 1,3-bis[(diphenylphosphino)propane]dichloronickel(II); N-ethyl-N,N-diisopropylamine; triphenylphosphine In ethanol at 20℃; for 6h; Miyaura Borylation Reaction; Inert atmosphere; Sealed tube;
Multi-step reaction with 2 steps
1: toluene-4-sulfonic acid / toluene / 24 h / Dean-Stark; Reflux
2: n-butyllithium / tetrahydrofuran; hexane / 2 h / 20 °C / Inert atmosphere
View Scheme
4-Vinylphenylboronic acid
2156-04-9

4-Vinylphenylboronic acid

A

4-(1,2-dihydroxyethyl)phenylboronic acid

4-(1,2-dihydroxyethyl)phenylboronic acid

B

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

C

4-Vinylphenol
2628-17-3

4-Vinylphenol

Conditions
ConditionsYield
With [(hydrotris(3,5-diphenyl-pyrazol-1-yl)borate)FeII(benzilate)]; oxygen In benzene at 20℃; for 0.333333h;
Trimethyl borate
121-43-7

Trimethyl borate

4-bromobenzaldehyde diethyl acetal
34421-94-8

4-bromobenzaldehyde diethyl acetal

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

Conditions
ConditionsYield
Stage #1: 4-bromobenzaldehyde diethyl acetal With n-butyllithium In tetrahydrofuran; hexane at -30℃; Inert atmosphere; Flow reactor;
Stage #2: Trimethyl borate In tetrahydrofuran; hexane at -30℃; Inert atmosphere; Flow reactor;
2,4,6-tris(4-bromophenyl)boroxin
7519-94-0

2,4,6-tris(4-bromophenyl)boroxin

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

Conditions
ConditionsYield
Stage #1: 2,4,6-tris(4-bromophenyl)boroxin; N,N-dimethyl-formamide With n-butyllithium In tetrahydrofuran; hexane at -60 - 20℃; Inert atmosphere;
Stage #2: With hydrogenchloride In tetrahydrofuran; hexane; water at 20℃; pH=2 - 3;
112.4 g
2,3-dimethyl-2,3-butane diol
76-09-5

2,3-dimethyl-2,3-butane diol

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde
128376-64-7

4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde

Conditions
ConditionsYield
In tetrahydrofuran; toluene100%
In diethyl ether at 20℃; cyclocondensation;100%
Inert atmosphere;100%
4-bromobenzenecarbonitrile
623-00-7

4-bromobenzenecarbonitrile

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

4-(4-cyanophenyl)-benzaldehyde
50670-55-8

4-(4-cyanophenyl)-benzaldehyde

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; sodium carbonate In tetrahydrofuran; water at 80℃; Schlenk technique; Inert atmosphere;100%
With bis-triphenylphosphine-palladium(II) chloride; sodium carbonate In tetrahydrofuran; water at 80℃; Schlenk technique; Inert atmosphere;100%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water Suzuki Coupling; Reflux; Inert atmosphere;100%
4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

4-bromopyridine hydrochloride
19524-06-2

4-bromopyridine hydrochloride

4-(pyridin-4-yl)benzaldehyde
99163-12-9

4-(pyridin-4-yl)benzaldehyde

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In 1,4-dioxane; water for 4h; Suzuki Coupling; Reflux; Inert atmosphere;100%
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In water; isopropyl alcohol; toluene for 7h; Inert atmosphere; Reflux;94%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In water; isopropyl alcohol; toluene for 7h; Inert atmosphere; Reflux;84%
2-bromo-pyridine
109-04-6

2-bromo-pyridine

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

2-(4-formylphenyl)pyridine
127406-56-8

2-(4-formylphenyl)pyridine

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In 1,4-dioxane; water for 8h; Suzuki coupling; Reflux;100%
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; water; toluene for 18h; Inert atmosphere; Reflux;100%
Stage #1: 2-bromo-pyridine; 4-formylphenylboronic acid, With potassium carbonate In 1,4-dioxane; water for 0.5h; Inert atmosphere;
Stage #2: With tetrakis(triphenylphosphine) palladium(0) In 1,4-dioxane; water Inert atmosphere; Reflux;
100%
N-(2-bromophenyl)-N'-methylpiperazine

N-(2-bromophenyl)-N'-methylpiperazine

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

2'-(4-Methyl-piperazine-1-yl)-biphenyl-4-carboxaldehyde
735333-36-5

2'-(4-Methyl-piperazine-1-yl)-biphenyl-4-carboxaldehyde

Conditions
ConditionsYield
With sodium carbonate; tetrakis(triphenylphosphine)palladium (0) In ethanol; water at 90℃; for 18h;100%
2-({4-[(4-fluorophenyl)amino]-1-piperidinyl}carbonyl)-3-pyridinyl trifluoromethanesulfonate
920511-33-7

2-({4-[(4-fluorophenyl)amino]-1-piperidinyl}carbonyl)-3-pyridinyl trifluoromethanesulfonate

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

4-[2-({4-[(4-fluorophenyl)amino]-1-piperidinyl}carbonyl)-3-pyridinyl]benzaldehyde
920511-34-8

4-[2-({4-[(4-fluorophenyl)amino]-1-piperidinyl}carbonyl)-3-pyridinyl]benzaldehyde

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In 1,2-dimethoxyethane; water at 50℃; Suzuki-Miyaura coupling;100%
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In 1,2-dimethoxyethane; water at 60℃; for 4h;
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In 1,2-dimethoxyethane; water at 20 - 60℃;
4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

trimethyleneglycol
504-63-2

trimethyleneglycol

4-(1,3,2-dioxaborinan-2-yl)-benzaldehyde

4-(1,3,2-dioxaborinan-2-yl)-benzaldehyde

Conditions
ConditionsYield
In toluene at 135℃; for 5h; Inert atmosphere; Dean-Stark;100%
In toluene for 12h; Reflux;
4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

ethylene glycol
107-21-1

ethylene glycol

4-(OCH2CH2O-B)C6H4C(H)=O
328063-34-9

4-(OCH2CH2O-B)C6H4C(H)=O

Conditions
ConditionsYield
In toluene for 2.5h; Reflux;100%
In toluene for 8h; Reflux;43%
In toluene 1:1 molar ratio, mixt. refluxed for 8 h; cooled, evapd., elem. anal.;43%
2,6-dichloro-4-iodopyridine
98027-84-0

2,6-dichloro-4-iodopyridine

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

4-(2,6-dichloropyridin-4-yl)benzaldehyde
1628606-70-1

4-(2,6-dichloropyridin-4-yl)benzaldehyde

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In 1,4-dioxane; water for 4h; Suzuki Coupling; Reflux; Inert atmosphere;100%
5-ethyl-3-iodo-2,5-dihydrofuran-2-one
1206522-04-4

5-ethyl-3-iodo-2,5-dihydrofuran-2-one

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

5-ethyl-3-(4-formylphenyl)furan-2(5H)-one

5-ethyl-3-(4-formylphenyl)furan-2(5H)-one

Conditions
ConditionsYield
With 1,1',1'',1'''-benzene-1,2,4,5-tetrayltetrakis(methylene)tetrakis-(piperidin-4-ol); palladium diacetate; potassium carbonate In ethanol; water at 20℃; for 0.25h; Suzuki-Miyaura Coupling;100%
4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

2,2-Dimethyl-1,3-propanediol
126-30-7

2,2-Dimethyl-1,3-propanediol

5,5-dimethyl-2-(4-formylphenyl)-1,3,2-dioxaborinane
128376-65-8

5,5-dimethyl-2-(4-formylphenyl)-1,3,2-dioxaborinane

Conditions
ConditionsYield
In benzene 4-formylphenylboronic acid and 2,2-dimethylpropane-1,3-diol were refluxed in benzene for 2 h 30 min; soln. was evapd. to dryness;99%
In tetrahydrofuran at 20℃; for 0.166667h; Esterification;98%
In tetrahydrofuran97%
4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

para-nitrophenyl bromide
586-78-7

para-nitrophenyl bromide

4-(4'-nitrophenyl)benzaldehyde
98648-23-8

4-(4'-nitrophenyl)benzaldehyde

Conditions
ConditionsYield
With bis(1,1'-ethylene-3,3'-divinylimidazole-2,2'-diylidene)nickel(II) dibromide dihydrate; potassium carbonate In water; N,N-dimethyl-formamide at 100℃; for 8h; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique;99%
With potassium carbonate In ethanol; water at 50℃; for 19h; Reagent/catalyst; Suzuki-Miyaura Coupling;98%
With potassium carbonate In ethanol; water at 80℃; for 0.166667h; Reagent/catalyst; Suzuki Coupling;95%
4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

2.3-butanediol
513-85-9

2.3-butanediol

2-(4-formylphenyl)-4,5-dimethyl-1,3,2-dioxaborolane
215876-82-7

2-(4-formylphenyl)-4,5-dimethyl-1,3,2-dioxaborolane

Conditions
ConditionsYield
With magnesium sulfate In ethyl acetate at 20℃;99%
iodobenzene
591-50-4

iodobenzene

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

4-Phenylbenzaldehyde
3218-36-8

4-Phenylbenzaldehyde

Conditions
ConditionsYield
With bis(1,1'-ethylene-3,3'-divinylimidazole-2,2'-diylidene)nickel(II) dibromide dihydrate; potassium carbonate In water; N,N-dimethyl-formamide at 100℃; for 8h; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique;99%
With potassium carbonate In water; N,N-dimethyl-formamide at 30℃; for 4h; Suzuki-Miyaura Coupling; Irradiation; Inert atmosphere;98%
With potassium phosphate In ethanol; water at 80℃; for 3h; Suzuki-Miyaura Coupling;98%
4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

4-bromo-benzaldehyde
1122-91-4

4-bromo-benzaldehyde

4,4'-diformylbiphenyl
66-98-8

4,4'-diformylbiphenyl

Conditions
ConditionsYield
With potassium carbonate In ethanol; water at 50℃; for 19h; Reagent/catalyst; Suzuki-Miyaura Coupling;99%
With potassium carbonate In ethanol; water at 50℃; for 19h; Suzuki Coupling;99%
With potassium carbonate In ethanol; water at 60℃; for 24h; Catalytic behavior; Reagent/catalyst; Solvent; Temperature; Suzuki-Miyaura Coupling;99%
p-nitrobenzene iodide
636-98-6

p-nitrobenzene iodide

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

4-(4'-nitrophenyl)benzaldehyde
98648-23-8

4-(4'-nitrophenyl)benzaldehyde

Conditions
ConditionsYield
With palladium diacetate; 4-Ph2P-C6H4-2-N-glucosamine; sodium carbonate In tetrahydrofuran; ethanol; water at 60℃; for 1h;99%
With polyhydroxylated phosphine; sodium carbonate; palladium diacetate In ethanol; water; toluene at 60℃; for 1h;99%
With triethylamine In ethanol; water at 80℃; for 0.5h; Suzuki-Miyaura Coupling; Microwave irradiation;97%
bromobenzene
108-86-1

bromobenzene

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

4-Phenylbenzaldehyde
3218-36-8

4-Phenylbenzaldehyde

Conditions
ConditionsYield
With potassium carbonate In ethanol; water at 80℃; for 2h; Suzuki-Miyaura Coupling;99%
With palladium diacetate In water; isopropyl alcohol at 27℃; for 1h; Suzuki-Miyaura Coupling;96%
With C12H12Cl2N4O2Pd; caesium carbonate In water at 60℃; for 5h; Suzuki-Miyaura Coupling;90%
4-tolyl iodide
624-31-7

4-tolyl iodide

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

4-(4-methylphenyl)benzaldehyde
36393-42-7

4-(4-methylphenyl)benzaldehyde

Conditions
ConditionsYield
With potassium carbonate In ethanol; water at 80℃; for 0.166667h; Reagent/catalyst; Suzuki Coupling;99%
With potassium carbonate In ethanol; water at 50℃; for 19h; Reagent/catalyst; Suzuki-Miyaura Coupling;92%
With potassium carbonate In ethanol; water at 50℃; for 19h; Catalytic behavior; Suzuki Coupling;92%
With sodium carbonate; 1,2-bis(2'-pyrazineethynyl)benzene palladium dichloride In water; acetonitrile at 70℃; for 6h; Suzuki coupling;89%
4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

1,7-dibromo-N,N'-bis(2,6-diisopropylphenyl)perylene-3,4:9,10-tetracarboxylic acid diimide
331861-94-0

1,7-dibromo-N,N'-bis(2,6-diisopropylphenyl)perylene-3,4:9,10-tetracarboxylic acid diimide

N,N'-bis(2,6-diisopropylphenyl)-1,7-di(4-formylphenyl)perylene-3,4,9,10-tetracarboxydiimide

N,N'-bis(2,6-diisopropylphenyl)-1,7-di(4-formylphenyl)perylene-3,4,9,10-tetracarboxydiimide

Conditions
ConditionsYield
With potassium carbonate; tetrakis(triphenylphosphine) palladium(0) In ethanol; water; toluene at 70℃; for 15h; Inert atmosphere;99%
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In ethanol; water; benzene at 80℃; for 96h; Suzuki coupling;72%
5-bromopyrimidine
4595-59-9

5-bromopyrimidine

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

4-(pyrimidin-5-yl)benzaldehyde
198084-12-7

4-(pyrimidin-5-yl)benzaldehyde

Conditions
ConditionsYield
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In 1,2-dimethoxyethane; water at 90℃; for 18h; Suzuki Coupling;99%
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate monohydrate In 1,2-dimethoxyethane; water at 90℃; Suzuki Coupling; Inert atmosphere;
tetrakis(μ-caprolactamato)dirhodium(Rh-Rh)

tetrakis(μ-caprolactamato)dirhodium(Rh-Rh)

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

bis-(σ-(4-formylphenyl))-tetrakis-μ-(caprolactamato)dirhodium(III)
1039763-74-0, 1158952-16-9

bis-(σ-(4-formylphenyl))-tetrakis-μ-(caprolactamato)dirhodium(III)

Conditions
ConditionsYield
With sodium methylate; copper(I) trifluoromethanesulfonate benzene In methanol; dichloromethane room temp., 10 equiv. of 4-HOCC6H4B(OH)2, 15 mol% (CuOTf)2*C6H6, 10 equiv. of NaOMe, 12 h, in 4:1 CH2Cl2-MeOH; column chromy. on silica gel or recrystn. from react. soln. by titrn. with MeOH;99%
With sodium methylate; copper(ll) sulfate pentahydrate In methanol; dichloromethane room temp., 10 equiv. of 4-HOCC6H4B(OH)2, 10 mol% CuSO4*5H2O, 10 equiv. of NaOMe, 12 h, in 4:1 CH2Cl2-MeOH; column chromy. on silica gel;95%
1-Bromonaphthalene
90-11-9

1-Bromonaphthalene

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

4-(naphthalene-1-yl)benzaldehyde
56432-18-9

4-(naphthalene-1-yl)benzaldehyde

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene for 24h; Inert atmosphere; Reflux;99%
With potassium phosphate; sodium tetrachloropalladate(II); sodium dodecyl-sulfate In water at 100℃; for 0.0833333h; Suzuki coupling;90%
With palladium diacetate; potassium carbonate In water; N,N-dimethyl-formamide at 100℃; for 8h; Suzuki-Miyaura cross-coupling;56 %Chromat.
benzoimidazole
51-17-2

benzoimidazole

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

4-(1H-benzo[d]imidazol-1-yl)benzaldehyde
90514-72-0

4-(1H-benzo[d]imidazol-1-yl)benzaldehyde

Conditions
ConditionsYield
With N,N,N,N,-tetramethylethylenediamine; oxygen; copper(II) nitrate In methanol at 20℃; under 760.051 Torr; for 24h;99%
With copper diacetate; tetrasodium meso-tetra(p-sulfonatophenyl)porphyrin In water at 50℃; for 4h; Chan-Lam Coupling; chemoselective reaction;81%
pinanediol
18680-27-8

pinanediol

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

4-(2,9,9-trimethyl-3,5-dioxa-4-boratricyclo[6.1.1.0(2,6)]dec-4-yl)-benzaldehyde

4-(2,9,9-trimethyl-3,5-dioxa-4-boratricyclo[6.1.1.0(2,6)]dec-4-yl)-benzaldehyde

Conditions
ConditionsYield
In diethyl ether at 20℃; for 24h; Inert atmosphere;99%
In diethyl ether (Ar); mixt. of boronic acid and pinandiol was stirred in Et2O at room temp. for 24 h; dried over MgSO4, concd., elem. anal.;99%
(R)-1-(2-bromo-benzenesulfonyl)-2-methyl-pyrrolidine
1202647-41-3

(R)-1-(2-bromo-benzenesulfonyl)-2-methyl-pyrrolidine

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

2'-((R)-2-Methyl-pyrrolidine-1-sulfonyl)-biphenyl-4-carbaldehyde
1202647-44-6

2'-((R)-2-Methyl-pyrrolidine-1-sulfonyl)-biphenyl-4-carbaldehyde

Conditions
ConditionsYield
With sodium carbonate; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride In 2-Methyl-1,2-propanediol; ISOPROPYLAMIDE at 100℃; Suzuki Coupling;99%
4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

4-hydroxy-benzaldehyde
123-08-0

4-hydroxy-benzaldehyde

Conditions
ConditionsYield
With copper(II) ferrite; water; sodium hydroxide at 40℃; for 24h; Green chemistry;99%
With N-ethyl-N,N-diisopropylamine In water; acetonitrile at 20℃; for 48h; Reagent/catalyst; Irradiation; Green chemistry;99%
With N-ethyl-N,N-diisopropylamine In water; acetonitrile for 48h; Irradiation;99%
4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

4-fluoroaniline
371-40-4

4-fluoroaniline

(E)-(4-(((4-fluorophenyl)imino)methyl)phenyl)boronic acid

(E)-(4-(((4-fluorophenyl)imino)methyl)phenyl)boronic acid

Conditions
ConditionsYield
In toluene for 24h; Reflux;99%
4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

sodium 4-iodo-benzoate
1005-30-7

sodium 4-iodo-benzoate

4′-formyl-(1,1′-biphenyl)-4-carboxylic Acid
70916-98-2

4′-formyl-(1,1′-biphenyl)-4-carboxylic Acid

Conditions
ConditionsYield
With palladium diacetate; potassium carbonate In water at 70℃; for 2h;99%
3-Chloropyridine
626-60-8

3-Chloropyridine

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

4-(pyridin-3-yl)benzaldehyde
127406-55-7

4-(pyridin-3-yl)benzaldehyde

Conditions
ConditionsYield
Stage #1: 3-Chloropyridine; 4-formylphenylboronic acid, With palladium diacetate; (R)-6-dicyclohexylphoshino-6'-diphenylphosphino-3,3'-dimethoxy-2,2',4,4'-tetramethyl-1,1'-biphenyl In dodecane; butan-1-ol at 25℃; for 0.0833333h; Suzuki-Miyaura Coupling; Glovebox; Inert atmosphere;
Stage #2: With cesiumhydroxide monohydrate In dodecane; water; butan-1-ol at 80℃; for 4h; Suzuki-Miyaura Coupling; Glovebox; Inert atmosphere;
99%
With Pd(Cy*Phine)2Cl2 ; potassium hydroxide In butan-1-ol at 100℃; for 1h; Suzuki-Miyaura Coupling; Glovebox; Inert atmosphere; Schlenk technique;91%
N-(phenylmethyl)-di(p-toluenesulfonyl)amine
61079-82-1

N-(phenylmethyl)-di(p-toluenesulfonyl)amine

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

4-benzylbenzaldehyde
67468-65-9

4-benzylbenzaldehyde

Conditions
ConditionsYield
With tetrakis(acetonitrile)palladium(II) tetrafluoroborate; potassium carbonate; bis[2-(diphenylphosphino)phenyl] ether In N,N-dimethyl-formamide at 60℃; for 1.5h; Inert atmosphere;99%

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