2-(Phenylthio)ethanol supplier

Name
2-(Phenylthio)ethanol
EINECS 211-828-9
CAS No. 699-12-7
Article Data61
CAS DataBase
Density 1.14 g/cm³
Solubility
Melting Point
Formula C₈H₁₀OS
Boiling Point 278.4 °C at 760 mmHg
Molecular Weight 154.233
Flash Point 131.5 °C
Transport Information
Appearance clear colorless to yellow liquid
Safety 23-24/25
Risk Codes 36
Molecular Structure
Hazard Symbols Xi
Synonyms 2-(Phenylthio)ethanol;2-Hydroxyethyl phenyl sulfide;2-Phenylsulfanylethanol;NSC 57851;b-Phenylthioethyl alcohol;
PSA 45.53000
LogP 1.77100

Synthetic route

: 16654-71-0
O-trimethylsilyl-S-phenylethylene monothioglycol

: 699-12-7
2-(phenylthio)ethanol

Conditions

Conditions	Yield
With water; 1,1,1,3,3,3-hexamethyl-disilazane In dichloromethane at 20℃; for 0.616667h;	96%

: 123299-91-2, 22063-21-4
2-(phenylsulfinyl)ethanol

: 699-12-7
2-(phenylthio)ethanol

Conditions

Conditions	Yield
With 1,3,5-trichloro-2,4,6-triazine; potassium iodide In acetonitrile at 20℃; for 0.133333h; chemoselective reaction;	95%
With titanium(IV) iodide In acetonitrile at 0℃; for 0.166667h; Reduction;	87%
With sodium iodide at 20℃; for 4h; Green chemistry;	87%

: 591-50-4
iodobenzene

: 60-24-2
2-hydroxyethanethiol

: 699-12-7
2-(phenylthio)ethanol

Conditions

Conditions	Yield
With copper(l) iodide; potassium phosphate tribasic trihydrate at 110℃; for 12h;	95%
With potassium phosphate In neat (no solvent) at 70℃; for 9h;	70%
With potassium hydroxide In dimethyl sulfoxide at 110℃; for 8h; Inert atmosphere;	67%

: 66303-55-7
2-(phenylthio)acetaldehyde

: 699-12-7
2-(phenylthio)ethanol

Conditions

Conditions	Yield
With lithium aluminium tetrahydride In tetrahydrofuran at -78℃;	95%

: C14H13NO3S2

: 699-12-7
2-(phenylthio)ethanol

Conditions

Conditions	Yield
With triethylamine In dichloromethane for 14h; Irradiation;	93%

: C14H12N2O5S2

: 699-12-7
2-(phenylthio)ethanol

Conditions

Conditions	Yield
With triethylamine In dichloromethane for 5.5h; Irradiation;	93%

: 108-90-7
chlorobenzene

: 60-24-2
2-hydroxyethanethiol

: 699-12-7
2-(phenylthio)ethanol

Conditions

Conditions	Yield
With potassium phosphate In neat (no solvent) at 70℃; for 10h;	40%

: 5535-49-9
2-Chloroethyl phenyl sulfide

: 7732-18-5
water

: 699-12-7
2-(phenylthio)ethanol

Conditions

Conditions	Yield
With HKUST-1 metal organic framework In tetrachloromethane at 20℃; Kinetics;	38%

: 75-21-8
oxirane

: 108-98-5
thiophenol

: 699-12-7
2-(phenylthio)ethanol

Conditions

Conditions	Yield
With pyrographite
With sodium hydroxide

: 108-98-5
thiophenol

: 107-07-3
2-chloro-ethanol

: 699-12-7
2-(phenylthio)ethanol

Conditions

Conditions	Yield
With sodium ethanolate
With sodium hydroxide
With sodium hydroxide

: 371-62-0
2-fluoroethanol

: 108-98-5
thiophenol

: 699-12-7
2-(phenylthio)ethanol

Conditions

Conditions	Yield
With sodium hydroxide

: 930-69-8
sodium thiophenolate

: 107-07-3
2-chloro-ethanol

: 699-12-7
2-(phenylthio)ethanol

: 75-21-8
oxirane

: 18863-43-9
Tetrathiophosphoric acid diphenyl ester; compound with triethyl-amine

A: 699-12-7
2-(phenylthio)ethanol

B: 2-Phenylsulfanyl-[1,3,2]oxathiaphospholane 2-sulfide

Conditions

Conditions	Yield
With boron trifluoride diethyl etherate In chloroform at -30 - 20℃; for 12h;

...Expand

: 50-00-0
formaldehyd

: 100-68-5
methyl-phenyl-thioether

: 699-12-7
2-(phenylthio)ethanol

Conditions

Conditions	Yield
With n-butyllithium; N,N,N,N,-tetramethylethylenediamine Multistep reaction;

: 4837-01-8
1-bromo-2-phenylthioethane

: 699-12-7
2-(phenylthio)ethanol

Conditions

Conditions	Yield
With water Kinetics; Mechanism;

: 107-21-1
ethylene glycol

: 108-98-5
thiophenol

: 699-12-7
2-(phenylthio)ethanol

Conditions

Conditions	Yield
With potassium hydroxide In N,N-dimethyl acetamide

: Naphthalene-2-sulfonic acid 2-phenylsulfanyl-ethyl ester

A: 699-12-7
2-(phenylthio)ethanol

B: 72005-23-3
N-(2-hydroxyethyl)-naphthalene-2-sulfonamide

Conditions

Conditions	Yield
With potassium hydroxide In dimethyl sulfoxide at 25℃; Rate constant; var. solvents;

: 114396-25-7
2-(phenylthio)ethyl brosylate

: 74-89-5
methylamine

A: 699-12-7
2-(phenylthio)ethanol

B: 59724-43-5
4-bromo-N-(2-hydroxy-ethyl)-benzenesulfonamide

Conditions

Conditions	Yield
With potassium hydroxide In dimethyl sulfoxide at 25℃; Rate constant; var. solvents;

...Expand

: 699-12-7
2-(phenylthio)ethanol

: 20611-21-6
2-(phenylsulfonyl)ethanol

Conditions

Conditions	Yield
With dihydrogen peroxide; phosphotungstate-non-cross-linked amphiphilic polymer compl at 50℃; for 4h;	100%
With phosphotungstic acid; poly(acrylamide) based ammonium salt; dihydrogen peroxide at 50℃; for 4h;	100%
With dihydrogen peroxide; titanium(IV) oxide In acetonitrile at 20℃; for 1.5h; chemoselective reaction;	100%

: 699-12-7
2-(phenylthio)ethanol

: 123299-91-2, 22063-21-4
2-(phenylsulfinyl)ethanol

Conditions

Conditions	Yield
With iron(III) chloride; periodic acid In acetonitrile at 0 - 25℃; for 0.416667h;	100%
With aluminum(III) nitrate nonahydrate; sulfuric acid; silica gel; silica gel; sodium bromide In dichloromethane; water at 20℃; for 3.5h; chemoselective reaction;	99%
With water; ammonium bromide In dichloromethane at 20℃; for 8h; chemoselective reaction;	99%

: 699-12-7
2-(phenylthio)ethanol

: 66303-55-7
2-(phenylthio)acetaldehyde

Conditions

Conditions	Yield
With 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione In ethyl acetate for 8h; Heating;	100%
With 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione In dimethyl sulfoxide at 20℃; for 4h;	90%
With 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione In dimethyl sulfoxide at 10 - 30℃; for 8h;	42%

: 699-12-7
2-(phenylthio)ethanol

: 29681-57-0
tert-butyldimethylsilane

: 82112-28-5
1-(t-BuMe2Si)-2-(t-BuMe2Si-S)ethyl ether

Conditions

Conditions	Yield
With palladium dichloride In N,N-dimethyl acetamide at 24.85℃; for 3h;	100%

: 699-12-7
2-(phenylthio)ethanol

: 4837-01-8
1-bromo-2-phenylthioethane

Conditions

Conditions	Yield
With carbon tetrabromide; Cu(tmp)(BINAP)BF4; sodium bromide In N,N-dimethyl-formamide for 24h; Appel Halogenation; UV-irradiation; Inert atmosphere;	99%
With sulfurous dibromide; N,N-dimethyl-formamide In cyclohexane at 20℃; for 3h; Bromination;	98%
With phosphorus tribromide at 20℃; for 0.5h;	98%

: 75-91-2
tert.-butylhydroperoxide

: bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]}

: 699-12-7
2-(phenylthio)ethanol

: Rh2(α,α,α′,α′-tetramethyl-1,3-benzenedipropanoate)2-bis-2-(phenylsulfinyl)ethanol

Conditions

Conditions	Yield
In dichloromethane at 20℃; for 9h;	99%

...Expand

: 699-12-7
2-(phenylthio)ethanol

: 5535-49-9
2-Chloroethyl phenyl sulfide

Conditions

Conditions	Yield
With 1,3,5-trichloro-2,4,6-triazine; N,N-dimethyl-formamide In dichloromethane at 25℃; for 48h;	98%
With thionyl chloride	96%
With hydrogenchloride; tetrafluoroboric acid In hydrogenchloride	72.4%

: 699-12-7
2-(phenylthio)ethanol

: 144127-38-8
C34H37NO5Si

: 144127-41-3
C36H41NO5SSi

Conditions

Conditions	Yield
With sodium hydride In tetrahydrofuran at 0℃; for 0.0833333h;	98%

: 699-12-7
2-(phenylthio)ethanol

: 130031-64-0, 141783-00-8
C26H19NO3

: 142807-49-6, 144178-71-2
C28H23NO3S

Conditions

Conditions	Yield
With sodium hydride In tetrahydrofuran at 0℃; for 0.0833333h;	96%
With 18-crown-6 ether; caesium carbonate In acetonitrile at 25℃; for 12h;

: 699-12-7
2-(phenylthio)ethanol

A: 123299-91-2, 22063-21-4
2-(phenylsulfinyl)ethanol

B: 20611-21-6
2-(phenylsulfonyl)ethanol

Conditions

Conditions	Yield
With dihydrogen peroxide In water at 30℃; for 1h;	A 94% B 6%
With dihydrogen peroxide at 50℃; for 4h;	A 80% B 13%
With (Bu4N)2[{MoO(O2)2}2(μ-O)]; dihydrogen peroxide In acetonitrile for 2h; Time;	A 66% B 30%

: 109-83-1
(2-hydroxyethyl)(methyl)amine

: 32315-10-9
bis(trichloromethyl) carbonate

: 699-12-7
2-(phenylthio)ethanol

: C12H17NO3S

Conditions

Conditions	Yield
Stage #1: bis(trichloromethyl) carbonate; 2-(phenylthio)ethanol With pyridine In tetrahydrofuran at 20℃; for 0.75h; Cooling with ice; Stage #2: With pyridine; 1-hydroxy-pyrrolidine-2,5-dione In tetrahydrofuran at 20℃; for 0.5h; Stage #3: (2-hydroxyethyl)(methyl)amine In tetrahydrofuran at 20℃; for 2h; Cooling with ice;	93%

...Expand

: 699-12-7
2-(phenylthio)ethanol

: 144127-84-4
C45H39NO4Si

: 144127-85-5
C47H43NO4SSi

Conditions

Conditions	Yield
With sodium hydride In tetrahydrofuran at 25℃; for 0.166667h;	92%

: 699-12-7
2-(phenylthio)ethanol

: 2873-29-2
D-glucal triacetate

: 121237-63-6, 121252-52-6
Acetic acid (2R,3S)-2-acetoxymethyl-6-(2-phenylsulfanyl-ethoxy)-3,6-dihydro-2H-pyran-3-yl ester

Conditions

Conditions	Yield
With boron trifluoride diethyl etherate In benzene for 0.133333h; Ambient temperature;	92%

: 110-87-2
3,4-dihydro-2H-pyran

: 699-12-7
2-(phenylthio)ethanol

: 2-(2-phenylsulfanyl-ethoxy)-tetrahydro-pyran

Conditions

Conditions	Yield
With ruthenium(III) acetate at 20℃; for 24h;	92%

: 699-12-7
2-(phenylthio)ethanol

: 141328-78-1, 144178-75-6
C27H21NO4

: 144127-43-5
C29H25NO4S

Conditions

Conditions	Yield
With 18-crown-6 ether; caesium carbonate In acetonitrile at 25℃; for 45h;	91%

: 699-12-7
2-(phenylthio)ethanol

: 407-25-0
trifluoroacetic anhydride

: 52060-27-2
2-(phenylthio)ethyl trifluoroacetate

Conditions

Conditions	Yield
With pyridine In dichloromethane at 0℃; for 2h;	91%

: 136-95-8
2-amino-benzthiazole

: 699-12-7
2-(phenylthio)ethanol

: 1353280-20-2
N-(2-(phenylthio)ethyl)benzo[d]thiazol-2-amine

Conditions

Conditions	Yield
With bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]; sodium hydroxide at 150℃; for 12h; Inert atmosphere; regioselective reaction;	91%

: 699-12-7
2-(phenylthio)ethanol

: 135144-00-2, 141395-14-4
C27H21NO4

: 144127-39-9
C29H25NO4S

Conditions

Conditions	Yield
With sodium hydride In tetrahydrofuran at 0℃; for 0.0833333h;	90%
With 18-crown-6 ether; caesium carbonate In acetonitrile at 25℃; for 12h;

: 699-12-7
2-(phenylthio)ethanol

: 164267-52-1
5'-O-tert-butyldimethylsilyl-3'-O-(4,4'-dimethoxytriphenylmethyl)thymidine

: 903570-37-6
1-[4-[bis-(4-methoxy-phenyl)-phenyl-methoxy]-5-(tert-butyl-dimethyl-silanyloxymethyl)-tetrahydro-furan-2-yl]-5-methyl-3-(2-phenylsulfanyl-ethyl)-1H-pyrimidine-2,4-dione

Conditions

Conditions	Yield
With tributylphosphine; 1,1'-azodicarbonyl-dipiperidine In benzene at 20℃; for 18h; Mitsunobu reaction;	90%

: 75430-97-6
1-(4-nitrophenyl)-5-tetrazolone

: 699-12-7
2-(phenylthio)ethanol

: 1972-28-7
diethylazodicarboxylate

: 1-(4-Nitrophenyl)-4-(2-phenylsulfanylethyl)-1,4-dihydrotetrazol-5-one

Conditions

Conditions	Yield
With triphenylphosphine In tetrahydrofuran	90%

...Expand

: 75430-97-6
1-(4-nitrophenyl)-5-tetrazolone

: 699-12-7
2-(phenylthio)ethanol

: 1-(4-Nitrophenyl)-4-(2-phenylsulfanylethyl)-1,4-dihydrotetrazol-5-one

Conditions

Conditions	Yield
With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran for 12h;	90%

: 699-12-7
2-(phenylthio)ethanol

: 80-62-6
methacrylic acid methyl ester

: 95175-52-3
2-phenylthioethyl methacrylate

Conditions

Conditions	Yield
With titanium(IV) isopropylate; 2,4-dimethyl-6-tert-butylphenol; pyrographite In cyclohexane at 90 - 92℃;	90%

: 699-12-7
2-(phenylthio)ethanol

: 999-97-3
1,1,1,3,3,3-hexamethyl-disilazane

: 16654-71-0
O-trimethylsilyl-S-phenylethylene monothioglycol

Conditions

Conditions	Yield
With asymmetric salen type di-Schiff base-based zinc complex supported on Fe3O4 nanoparticles at 20℃; for 0.416667h;	89%
With cross-linked poly((30percent)4-vinylpyridine/(70percent)styrene) copolymer-supported bismuth(III) triflate In dichloromethane at 20℃; for 0.166667h;	86%
With chloro-trimethyl-silane

: 699-12-7
2-(phenylthio)ethanol

: 108-98-5
thiophenol

: 622-20-8
1,2-bis(phenylthio)ethane

Conditions

Conditions	Yield
With toluene-4-sulfonic acid In toluene for 3h; Heating;	89%

2-(Phenylthio)ethanol Chemical Properties

IUPAC Name: 2-Phenylsulfanylethanol
Synonyms of Ethanol,2-(phenylthio)- (CAS NO.699-12-7): 2-Phenylmercaptoethanol ; AI3-17423 ; EINECS 211-828-9 ; NSC 57851 ; Phenylthioethanol ; 2-(Phenylthio)ethanol
CAS NO: 699-12-7
Molecular Formula of Ethanol,2-(phenylthio)- (CAS NO.699-12-7): C₈H₁₀OS
Molecular Weight: 154.2294
Molecular Structure:

ProductCategories: Alkohols
Polar Surface Area: 34.53 Å²
Index of Refraction: 1.592
Molar Refractivity: 45.55 cm³
Molar Volume: 134.5 cm³
Surface Tension: 47.5 dyne/cm
Density of Ethanol,2-(phenylthio)- (CAS NO.699-12-7): 1.14 g/cm³
Flash Point: 131.5 °C
Enthalpy of Vaporization: 54.61 kJ/mol
Boiling Point: 278.4 °C at 760 mmHg
Vapour Pressure: 0.00205 mmHg at 25°C

2-(Phenylthio)ethanol Safety Profile

Hazard Codes: Irritant Xi
Risk Statements: 36
R36: Irritating to eyes.
Safety Statements: 23-24/25
S23: Do not breathe vapour.
S24/25: Avoid contact with skin and eyes.
WGK Germany: 3
TSCA: T
HazardClass: STENCH
HS Code: 29309070

Product Name

2-(Phenylthio)ethanol

Synthetic route

2-(Phenylthio)ethanol Chemical Properties

2-(Phenylthio)ethanol Safety Profile

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