Conditions | Yield |
---|---|
With phosphoric acid; hydrogen; nitric acid; palladium on activated charcoal; germanium dioxide at 40℃; Product distribution / selectivity; |
Conditions | Yield |
---|---|
Irradiation; |
ammonia
sodium hydroxide
A
ammonium hydroxide
B
diamminesilver(I) hydroxide
Conditions | Yield |
---|---|
In water |
Conditions | Yield |
---|---|
With air; Zn0.12Mo0.12Cd0.9S1.14/graphitic carbon nitride (g-C3N4)(20 mass percent) In ethanol at 30℃; under 760.051 Torr; Reagent/catalyst; Irradiation; | |
With hydrogenated Bi5O7I (H-Bi5O7I) at 15℃; Catalytic behavior; Reagent/catalyst; UV-irradiation; | |
With Bi5O7Br In neat (no solvent) Catalytic behavior; Mechanism; Reagent/catalyst; UV-irradiation; | |
With potassium sulfate Catalytic behavior; Reagent/catalyst; Electrochemical reaction; | |
With methanol Catalytic behavior; Irradiation; |
Conditions | Yield |
---|---|
With sulfuric acid In water at 20℃; for 20h; Kinetics; Catalytic behavior; Electrochemical reaction; |
Conditions | Yield |
---|---|
With ruthenium oxychloride In water at 25℃; Kinetics; Inert atmosphere; Electrolysis; |
Conditions | Yield |
---|---|
With ruthenium oxychloride In water at 25℃; Kinetics; Inert atmosphere; Electrolysis; |
Conditions | Yield |
---|---|
With ruthenium oxychloride In water at 25℃; Kinetics; Inert atmosphere; Electrolysis; |
Conditions | Yield |
---|---|
With ruthenium oxychloride In water at 25℃; Kinetics; Mechanism; Reagent/catalyst; Concentration; Electrolysis; Inert atmosphere; |
Conditions | Yield |
---|---|
With ruthenium oxychloride In water at 25℃; Kinetics; Inert atmosphere; Electrolysis; |
water
oxygen
4-methyl-1,2-diaminobenzene
A
ammonium hydroxide
B
carbon dioxide
Conditions | Yield |
---|---|
With Sr0.3Pb0.7TiO3/CoFe2O4 core-shell magnetic nanocomposite In aq. phosphate buffer at 20℃; for 0.00694444h; pH=7.1; Catalytic behavior; Concentration; pH-value; Electrochemical reaction; Green chemistry; chemoselective reaction; |
Conditions | Yield |
---|---|
With potassium sulfate; FeReS3 for 192h; Mechanism; Kinetics; Time; Electrolysis; |
ammonium hydroxide
benzoyl chloride
arabinosyl adenine
N6-benzoyl-9-β-D-arabinofuranosyladenine
Conditions | Yield |
---|---|
With chloro-trimethyl-silane In pyridine; N-methyl-acetamide; methanol; water | 100% |
With chloro-trimethyl-silane In pyridine; N-methyl-acetamide; methanol; water | 100% |
With chloro-trimethyl-silane In pyridine; N-methyl-acetamide; methanol; water | 100% |
ammonium hydroxide
chloro-trimethyl-silane
benzoyl chloride
arabinosyl adenine
N6-benzoyl-9-β-D-arabinofuranosyladenine
Conditions | Yield |
---|---|
In pyridine; N-methyl-acetamide; methanol; water | 100% |
In pyridine; N-methyl-acetamide; methanol; water | 100% |
In pyridine; N-methyl-acetamide; methanol; water | 100% |
Conditions | Yield |
---|---|
With 4-methyl-morpholine In 1,2-dimethoxyethane; water | 100% |
ammonium hydroxide
ethyl (4-methoxyphenyl)carbamodithioate
1-(4-methoxyphenyl)thiourea
Conditions | Yield |
---|---|
at 60℃; Neat (no solvent); | 100% |
Conditions | Yield |
---|---|
In dichloromethane at 20℃; for 2h; Inert atmosphere; | 100% |
ammonium hydroxide
PdCl(N,N-dimethylformamide)(μ-azobenzene)PdCl(N,N-dimethylformamide)
Conditions | Yield |
---|---|
In neat (no solvent) at 20℃; for 0.0833333h; Kinetics; | 100% |
Conditions | Yield |
---|---|
In water Heating; | 100% |
ammonium hydroxide
[platinum(II)(chloride)(η1-C2H4OMe)(1,10-phenanthroline)]
Conditions | Yield |
---|---|
In water at 20℃; for 4.8h; | 99.9% |
ammonium hydroxide
Trichlorbutylstannan
sodium carbonate
n-butylstannoic acid
Conditions | Yield |
---|---|
In water at 60℃; for 2.5h; Temperature; | 99.4% |
Conditions | Yield |
---|---|
In hydrogenchloride | 99% |
Conditions | Yield |
---|---|
99% |
Conditions | Yield |
---|---|
Stage #1: ammonium hydroxide; C4H19B12O2(1-)*2C16H36N(1+) In acetonitrile at 50℃; for 11h; Stage #2: tetra(n-butyl)ammonium hydroxide In methanol | 99% |
Conditions | Yield |
---|---|
pH=9; | 98.3% |
Conditions | Yield |
---|---|
Stage #1: C14H13BrF4N2O With copper(l) iodide; sodium carbonate; N,N`-dimethylethylenediamine In dimethyl sulfoxide at 110℃; for 6h; Stage #2: ammonium hydroxide In water | 98% |
Conditions | Yield |
---|---|
In ethanol; dichloromethane | 98% |
Conditions | Yield |
---|---|
pH=9; | 97.2% |
Conditions | Yield |
---|---|
Stage #1: ammonium hydroxide; copper(II) oxide at 20℃; for 0.833333h; Stage #2: glycine at 95℃; for 2h; Concentration; Temperature; | 96.8% |
ammonium hydroxide
Conditions | Yield |
---|---|
With potassium carbonate In water | 96% |
ammonium hydroxide
Conditions | Yield |
---|---|
With potassium carbonate In water | 96% |
Conditions | Yield |
---|---|
Stage #1: p-nitroacetanilide-15N With hydrogenchloride In water for 24h; Reflux; Stage #2: ammonium hydroxide In water at 0℃; | 96% |
ammonium hydroxide
benzoyl chloride
2'-Deoxycytidine
N4-benzoyl-2'-deoxycytidine
Conditions | Yield |
---|---|
Stage #1: 2'-Deoxycytidine With pyridine; chloro-trimethyl-silane Stage #2: benzoyl chloride With pyridine Stage #3: ammonium hydroxide | 96% |
Conditions | Yield |
---|---|
In water at 20℃; for 24h; pH=11; | 96% |
ammonium hydroxide
2-bromonaphthalene
trimethyltin(IV)chloride
tert.-butyl lithium
A
1-(trimethylstannyl)naphthalene
B
β-naphthyltrimethylstannane
Conditions | Yield |
---|---|
In 1,4-dioxane; diethyl ether; pentane | A 95.6% B n/a |
Conditions | Yield |
---|---|
Stage #1: ammonium hydroxide; palladium dichloride at 50℃; Inert atmosphere; Stage #2: water With barium(II) hydroxide for 24h; Cooling with ice; Stage #3: acetic acid With acetamide at 20℃; for 48h; Inert atmosphere; | 95.46% |
ammonium hydroxide
potassium tetrachloroplatinate(II)
potassium iodide
cis-diamminediiodoplatinum (II)
Conditions | Yield |
---|---|
Stage #1: potassium tetrachloroplatinate(II); potassium iodide In water at 40 - 60℃; Darkness; Stage #2: ammonium hydroxide In water Darkness; | 95.1% |
Stage #1: potassium tetrachloroplatinate(II); potassium iodide In water at 50℃; for 0.0833333h; Stage #2: ammonium hydroxide In water for 3h; | 89% |
In water at 50 - 60℃; Inert atmosphere; | 80% |
(3S,4S)-4-[(S)-3-(4-fluorobenzyl)-piperidin-1-ylmethyl]-1,1-dioxo-tetrahydro-thiophen-3-ylamine
ammonium hydroxide
3-acetylphenyl isocyanate
Conditions | Yield |
---|---|
With triethylamine; trifluoroacetic acid In methanol; water; N,N-dimethyl-formamide; acetonitrile | 95% |
ammonium hydroxide
2,4-difluorobenzene-1-sulfonyl chloride
2,4-difluoro-1-benzenesulfonamide
Conditions | Yield |
---|---|
In dichloromethane; ethyl acetate | 95% |
Ammonium hydroxide with the CAS registry number 1336-21-6, is also named as Spirit of hartshorn. The product's categories are Industrial / Fine Chemicals; Inorganics, and the other registry numbers are 125888-87-1; 132103-60-7; 16393-49-0; 178115-93-0. Besides, it is colorless aqueous solution, which should be stored in tightly sealed containers in a cool, dry place. And you should ensure that the workplaces have good ventilation or exhaust devices. It is stable, but incompatible with copper, copper alloys, acids, galvanised iron, zinc, aluminium, bronze, dimethyl sulphate, mercury, alkali metals. In addition, its molecular formula is H5NO and molecular weight is 35.04.
Properties about Ammonium hydroxide are: (1)H-Bond Donor: 2; (2)H-Bond Acceptor: 1; (3)Rotatable Bond Count: 0; (4)Exact Mass: 35.037114; (5)MonoIsotopic Mass: 35.037114; (6)Topological Polar Surface Area: 2; (7)Heavy Atom Count: 2; (8)Density: 0.91 g/mL at 20 °C; (9)Melting point: -77 °C; (10)Enthalpy of Vaporization: 23.33 kJ/mol; (11)Boiling Point: 165 °C at 760 mmHg; (12)Vapour Pressure: 5990 mmHg at 25 °C.
Preparation of Ammonium hydroxide: This chemical can be prepared by liquid ammonia. You can use it to dissolve in pure water. Then cool it by cold water. And you will obtain this chemcial.
Uses of Ammonium hydroxide: This chemical in water is an ingredient of cleaning agents. It is also used as a precursor to some alkyl amines in industry. Moreover, it was traditionally used to darken or stain wood containing tannic acid in furniture-making. And it cna be used in the meat packing industry. Furthermore, it is used as a complexant and base in traditional qualitative inorganic analysis in laboratory.
When you are using this chemical, please be cautious about it as the following: it may cause burns. It is also very toxic to aquatic organisms. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. And you should wear suitable protective clothing, gloves and eye/face protection. Please avoid release to the environment. Refer to special instructions / safety data sheets. Moreover, in case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
You can still convert the following datas into molecular structure:
(1)SMILES: [OH-].[NH4+]
(2)InChI: InChI=1/H3N.H2O/h1H3;1H2
(3)InChIKey: VHUUQVKOLVNVRT-UHFFFAOYAI
The toxicity data is as follows:
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
cat | LDLo | oral | 750mg/kg (750mg/kg) | "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." Vol. 4, Pg. 1289, 1935. | |
frog | LDLo | parenteral | 2500mg/kg (2500mg/kg) | "Structure et Activite Pharmacodyanmique des Medicaments du Systeme Nerveux Vegetatif," Bovet, D., and F. Bovet-Nitti, New York, S. Karger, 1948Vol. -, Pg. 688, 1948. | |
human | LCLo | inhalation | 5000ppm (5000ppm) | "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969Vol. -, Pg. 95, 1969. | |
human | LDLo | oral | 43mg/kg (43mg/kg) | "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969Vol. -, Pg. 95, 1969. | |
human | TCLo | inhalation | 408ppm (408ppm) | LUNGS, THORAX, OR RESPIRATION: "FIBROSIS, FOCAL (PNEUMOCONIOSIS)" LUNGS, THORAX, OR RESPIRATION: ACUTE PULMONARY EDEMA | Journal of the Iowa State Medical Society. Vol. 61, Pg. 271, 1971. |
mouse | LD50 | intravenous | 91mg/kg (91mg/kg) | BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD BEHAVIORAL: COMA LUNGS, THORAX, OR RESPIRATION: RESPIRATORY STIMULATION | Journal of Clinical Investigation. Vol. 37, Pg. 497, 1958. |
mouse | LDLo | subcutaneous | 160mg/kg (160mg/kg) | "Structure et Activite Pharmacodyanmique des Medicaments du Systeme Nerveux Vegetatif," Bovet, D., and F. Bovet-Nitti, New York, S. Karger, 1948Vol. -, Pg. 688, 1948. | |
rabbit | LDLo | intravenous | 10mg/kg (10mg/kg) | "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." Vol. 4, Pg. 1289, 1935. | |
rabbit | LDLo | subcutaneous | 200mg/kg (200mg/kg) | "Structure et Activite Pharmacodyanmique des Medicaments du Systeme Nerveux Vegetatif," Bovet, D., and F. Bovet-Nitti, New York, S. Karger, 1948Vol. -, Pg. 688, 1948. | |
rat | LD50 | oral | 350mg/kg (350mg/kg) | GASTROINTESTINAL: OTHER CHANGES LIVER: OTHER CHANGES KIDNEY, URETER, AND BLADDER: OTHER CHANGES | Journal of Industrial Hygiene and Toxicology. Vol. 23, Pg. 259, 1941. |
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