Benzaldehyde dimethyl acetal supplier

Name
Benzaldehyde dimethyl acetal
EINECS 214-413-0
CAS No. 1125-88-8
Article Data264
CAS DataBase
Density 1 g/cm³
Solubility decomposes in water
Melting Point 87-89 °C (18 mmHg)
Formula C₉H₁₂O₂
Boiling Point 199.711 °C at 760 mmHg
Molecular Weight 152.193
Flash Point 69.444 °C
Transport Information UN 3271
Appearance Clear colorless liquid
Safety 23-24/25-37/39-36-26
Risk Codes 22-36/37/38
Molecular Structure
Hazard Symbols Xn
Synonyms Benzaldehyde,dimethyl acetal (6CI,7CI,8CI);(Dimethoxymethyl)benzene;Dimethoxyphenylmethane;NSC 286137;Phenyldimethoxymethane;a,a-Dimethoxytoluene;a-Methoxybenzyl methyl ether;
PSA 18.46000
LogP 1.97800

Synthetic route

: 100-52-7
benzaldehyde

: 149-73-5
trimethyl orthoformate

: 1125-88-8
benzaldehyde dimethyl acetal

Conditions

Conditions	Yield
With [Sc2(C4O4)3]n In tetrachloromethane at 60℃; for 1h;	100%
With lithium tetrafluoroborate In methanol for 0.5h; Heating;	100%
indium(III) triflate In dichloromethane at 20℃; for 0.0833333h;	99%

: 67-56-1
methanol

: 100-52-7
benzaldehyde

: 1125-88-8
benzaldehyde dimethyl acetal

Conditions

Conditions	Yield
With trimethyl orthoformate at 20℃; for 0.5h;	99%
With cobalt(II) 2-propyliminomethyl-phenolate functionalized mesoporous silica for 2h; Reflux;	99%
With Zr6(µ3-O)4(µ3-OH)4(2,2-bis(trifluoromethyl)-4,4’-biphenyldicarboxylate)4[Cu(2,2'-bipyridine-5,5’-dicarboxylate)(MeCN)I](C6H3(NH-CO-C6H4-SO3H)(PhCOO)2) at 20℃; for 2h; Catalytic behavior; Reagent/catalyst;	99%

: 67-56-1
methanol

: 23246-12-0
3,3,5-triphenyl-1,2,4-trioxolane

A: 93-58-3
benzoic acid methyl ester

B: 119-61-9
benzophenone

C: 1125-88-8
benzaldehyde dimethyl acetal

Conditions

Conditions	Yield
With chlorosulfonic acid for 80h;	A 75% B 95% C 25%

...Expand

: 23246-12-0
3,3,5-triphenyl-1,2,4-trioxolane

A: 93-58-3
benzoic acid methyl ester

B: 119-61-9
benzophenone

C: 1125-88-8
benzaldehyde dimethyl acetal

Conditions

Conditions	Yield
With chlorosulfonic acid In methanol for 80h;	A 75% B 95% C 25%

...Expand

: 67-56-1
methanol

: 108-88-3
toluene

A: 93-58-3
benzoic acid methyl ester

B: 1125-88-8
benzaldehyde dimethyl acetal

C: 100-52-7
benzaldehyde

Conditions

Conditions	Yield
With sodium perchlorate; Tris(2,4-dibromophenyl)amine In dichloromethane indirect electrochemical oxidation; Yields of byproduct given;	A 95% B n/a C n/a
With lithium perchlorate direct electrochemical oxidation; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

...Expand

: 67-56-1
methanol

: 4460-46-2
3-chloro-3-phenyl-3H-diazirine

A: 98-87-3
benzylidene dichloride

B: 1125-88-8
benzaldehyde dimethyl acetal

C: 100-52-7
benzaldehyde

Conditions

Conditions	Yield
at 80℃; for 6h; Mechanism; other 3-chloro-3-aryldiazirines;	A n/a B 95% C 1%
at 80℃; for 6h;	A n/a B 95% C 1%

...Expand

: 1825-61-2
Methoxytrimethylsilane

: 100-52-7
benzaldehyde

: 1125-88-8
benzaldehyde dimethyl acetal

Conditions

Conditions	Yield
trimethylsilyl trifluoromethanesulfonate In dichloromethane at -78℃; for 3h; Product distribution;	94%
trimethylsilyl trifluoromethanesulfonate In dichloromethane at -78℃; for 3h;	94%
trimethylsilyl trifluoromethanesulfonate In dichloromethane at -78℃; for 3h;	94%
In dichloromethane at -78℃; for 0.0833333h;

: 292638-84-7
styrene

: 67-56-1
methanol

: 1125-88-8
benzaldehyde dimethyl acetal

Conditions

Conditions	Yield
With 2-Picolinic acid; ferrous(II) sulfate heptahydrate; dihydrogen peroxide at 20 - 60℃; for 12h; Schlenk technique; Molecular sieve;	93%
With potassium trifluoroacetate at 55 - 60℃; electrochemical oxidation;	42 % Spectr.
With tert.-butylhydroperoxide; C30H29ClN4ORu(2+)*2F6P(1-) at 50℃; Catalytic behavior; Kinetics; Reagent/catalyst; Schlenk technique; Molecular sieve;	87 %Chromat.
With zinc indium sulfide; phenylmethanethiol for 15h; Irradiation;	81 %Chromat.

: 67-56-1
methanol

: 873-66-5
1-propenylbenzene

: 1125-88-8
benzaldehyde dimethyl acetal

Conditions

Conditions	Yield
With 2-Picolinic acid; ferrous(II) sulfate heptahydrate; dihydrogen peroxide at 20 - 60℃; for 12h; Schlenk technique; Molecular sieve;	93%

: 67-56-1
methanol

: 5721-88-0
2-phenyl-1,3-oxathiolane

: 1125-88-8
benzaldehyde dimethyl acetal

Conditions

Conditions	Yield
With N-Bromosuccinimide at 20℃; for 0.166667h;	92%

: 67-56-1
methanol

: 100-52-7
benzaldehyde

A: 93-58-3
benzoic acid methyl ester

B: 1125-88-8
benzaldehyde dimethyl acetal

Conditions

Conditions	Yield
With oxygen; Pd5-Bi2-Pb1-Fe1/(100)SiO2-MgO	A 90.3% B n/a
With oxygen; Pd5-Bi2-Fe1/(100)SiO2-MgO	A 88.8% B n/a
With oxygen; Pd5-Bi2-Pb1-Co1/(100)SiO2	A 88.6% B n/a

...Expand

: 67-56-1
methanol

: 138173-30-5
3-α-bromobenzyloxy-3-fluorodiazirine

: 1125-88-8
benzaldehyde dimethyl acetal

Conditions

Conditions	Yield
In acetonitrile at 25℃; Rate constant; Mechanism; also in the presence of HCl or bases, use of CD3OD/CD3CN, also with ethylene glycol or piperidine;	90%

: 67-56-1
methanol

: 3240-34-4
[bis(acetoxy)iodo]benzene

: 28867-76-7
benzaldehyde benzylidenehydrazone

A: 591-50-4
iodobenzene

B: 1125-88-8
benzaldehyde dimethyl acetal

Conditions

Conditions	Yield
With sodium methylate at 0 - 25℃; for 48h; Product distribution; Var. aldazines and alcohols;	A n/a B 88%

...Expand

: 67-56-1
methanol

: 28867-76-7
benzaldehyde benzylidenehydrazone

: 1125-88-8
benzaldehyde dimethyl acetal

Conditions

Conditions	Yield
With [bis(acetoxy)iodo]benzene; sodium methylate at 0 - 25℃; for 48h;	88%

: 681-84-5
tetramethylorthosilicate

: 100-52-7
benzaldehyde

: 1125-88-8
benzaldehyde dimethyl acetal

Conditions

Conditions	Yield
trimethylsilyl iodide In dichloromethane 1.) -78 deg C, 3 h, 2.) RT, 4h;	87%
With hydrogenchloride

: 67-56-1
methanol

: 622-29-7
N-Benzylidenemethylamine

: 1125-88-8
benzaldehyde dimethyl acetal

Conditions

Conditions	Yield
With bromine for 1h; Heating;	87%

: 67-56-1
methanol

: 5616-55-7
2-phenyl-1,3-dithiane

: 1125-88-8
benzaldehyde dimethyl acetal

Conditions

Conditions	Yield
With N-Bromosuccinimide at 20℃; for 0.0833333h;	86%

: 431-47-0
trifluoroacetic acid-methyl ester

: 124-41-4
sodium methylate

: 100-52-7
benzaldehyde

: 1125-88-8
benzaldehyde dimethyl acetal

Conditions

Conditions	Yield
In methanol at 20℃; Inert atmosphere;	85%

...Expand

: 67-56-1
methanol

: 5411-12-1
chalcone epoxide

A: 93-58-3
benzoic acid methyl ester

B: 1125-88-8
benzaldehyde dimethyl acetal

C: 412017-63-1
2-hydroxy-3-methoxy-1,3-diphenylpropan-1-one

Conditions

Conditions	Yield
With tetraethylammonium bromide at 25℃; Product distribution; reaction in CH3OD and nitromethane (1:50); in acetic acid; retention/inversion products;	A 2% B 13% C 84%

...Expand

: 100-52-7
benzaldehyde

: 77-76-9
2,2-dimethoxy-propane

: 1125-88-8
benzaldehyde dimethyl acetal

Conditions

Conditions	Yield
With toluene-4-sulfonic acid at 70℃; Addition;	84%
With toluene-4-sulfonic acid	67%

: 67-56-1
methanol

: 32345-80-5, 4013-37-0
1,2-dimethoxyethylbenzene

A: 1125-88-8
benzaldehyde dimethyl acetal

B: 143191-51-9
1-phenyl-1,1,2-trimethoxyethane

Conditions

Conditions	Yield
With potassium fluoride; 100 mA cm-2 at 60℃; Product distribution; various supporting electrolytes and anode materials;	A 82% B 10%
With potassium fluoride at 60℃; 100 mA cm-2, Pt anode;	A 82% B 10%

...Expand

: 292638-84-7
styrene

: 67-56-1
methanol

A: 1125-88-8
benzaldehyde dimethyl acetal

B: 32345-80-5, 4013-37-0
1,2-dimethoxyethylbenzene

C: 32673-77-1
1,4-dimethoxy-1,4-diphenylbutane

D: 54845-42-0
1-phenyl-1,2,2-trimethoxy ethane

Conditions

Conditions	Yield
With potassium fluoride at 60℃; 100 mA cm-2, Pt anode; Further byproducts given;	A 1% B 80% C 3% D 5%
With TPC at 60℃; 100 mA cm-2, C anode;	A 16% B 45% C 13% D 2%

...Expand

: 292638-84-7
styrene

: 67-56-1
methanol

A: 1125-88-8
benzaldehyde dimethyl acetal

B: 32345-80-5, 4013-37-0
1,2-dimethoxyethylbenzene

C: 32673-77-1
1,4-dimethoxy-1,4-diphenylbutane

D: 54845-42-0
1-phenyl-1,2,2-trimethoxy ethane

E: 80621-69-8
meso-1,4-dimethoxy-2,3-diphenylbutane

F: 80634-49-7
1,4-dimethoxy-1,3-diphenylbutane

Conditions

Conditions	Yield
With potassium fluoride; 100 mA cm-2 at 60℃; Product distribution; various supporting electrolytes and anode materials;	A 1% B 80% C 3% D 5% E 2% F 2%

...Expand

: 67-56-1
methanol

: 100-52-7
benzaldehyde

: 98-86-2
acetophenone

A: 4316-35-2
acetophenone dimethyl acetal

B: 1125-88-8
benzaldehyde dimethyl acetal

Conditions

Conditions	Yield
With CoCl2 for 2h; Heating;	A n/a B 77%

...Expand

: 98-87-3
benzylidene dichloride

: 149-73-5
trimethyl orthoformate

: 1125-88-8
benzaldehyde dimethyl acetal

Conditions

Conditions	Yield
at 225℃; for 39h;	76%
With zinc(II) chloride at 20 - 25℃; for 1h;

: 67-56-1
methanol

: 100-52-7
benzaldehyde

A: 93-58-3
benzoic acid methyl ester

B: 1125-88-8
benzaldehyde dimethyl acetal

C: 65-85-0
benzoic acid

Conditions

Conditions	Yield
With Eco1a; dihydrogen peroxide In water at 20℃; for 17h; Reflux;	A 76% B 10% C 11%
With dihydrogen peroxide; zinc(II) chloride In water at 20℃;
With oxygen at 179.84℃; under 7500.75 Torr; for 2h; Inert atmosphere;

...Expand

: 292638-84-7
styrene

: 67-56-1
methanol

A: 1125-88-8
benzaldehyde dimethyl acetal

B: 100-52-7
benzaldehyde

Conditions

Conditions	Yield
With tert.-butylhydroperoxide; C29H25Cl2N4Ru(1+)*F6P(1-) at 50℃; for 6h; Reagent/catalyst; Schlenk technique; Molecular sieve;	A 73% B 7%
With ozone; thiourea 1) -10-(-15) deg C, 65 min, CH3OH; 2) 0 deg C, 55 min; Yield given. Multistep reaction;

...Expand

: 35364-99-9
α-chlorobenzyl methyl ether

: 149-73-5
trimethyl orthoformate

: 1125-88-8
benzaldehyde dimethyl acetal

Conditions

Conditions	Yield
at 20℃; for 24h;	72%

: 35364-99-9
α-chlorobenzyl methyl ether

: 149-73-5
trimethyl orthoformate

A: 107-31-3
Methyl formate

B: 1125-88-8
benzaldehyde dimethyl acetal

Conditions

Conditions	Yield
	A n/a B 72%

...Expand

: 67-56-1
methanol

: 544-25-2
Cyclohepta-1,3,5-triene

A: 1714-38-1
7-methoxy-1,3,5-cycloheptatriene

B: 1125-88-8
benzaldehyde dimethyl acetal

Conditions

Conditions	Yield
With sodium methylate; tetraethylammonium tosylate at -10 - 0℃; anodic oxidation;	A 71% B 15%

...Expand

: 1125-88-8
benzaldehyde dimethyl acetal

: 762-72-1
allyl-trimethyl-silane

: 22039-97-0
4-methoxy-4-phenyl-1-butene

Conditions

Conditions	Yield
With trimethylaluminum; aluminum tri-bromide; copper(I) bromide In dichloromethane; toluene at 20℃; for 3h;	100%
With 2,4-dinitrobenzenesulfonic acid In acetonitrile at 20℃; for 1h; Hosomi-Sakurai reaction;	99%
With 30% bis[triphenyl(3-sulfopropyl)phosphonium]HPW12O40/SiO2 In acetonitrile at 20℃; for 0.5h; Catalytic behavior; Reagent/catalyst; Solvent; Hosomi-Sakurai Reaction; Inert atmosphere; Green chemistry; chemoselective reaction;	99%

: 69556-70-3
4-methoxy-5H-furan-2-one

: 1125-88-8
benzaldehyde dimethyl acetal

: 82204-21-5
methyl 5-(1-methoxybenzyl)tetronate

Conditions

Conditions	Yield
zinc dibromide	100%
With n-butyllithium; boron trifluoride diethyl etherate 1.) ether, hexane, -78 deg C, 2.) ether, -78 deg C.; Yield given. Multistep reaction;

: 13735-81-4
1-styrenyloxytrimethylsilane

: 1125-88-8
benzaldehyde dimethyl acetal

: 89524-37-8
3-methoxy-1,3-diphenylpropan-1-one

Conditions

Conditions	Yield
polymeric dicyanoketene acetal In acetonitrile for 6.5h; Substitution; Heating;	100%
With polymer-supported DCKA In acetonitrile for 6.5h; Heating;	100%
With Celite; polystyrene-bound super Broensted acid In toluene at 20℃; flow system;	99%

: 13735-81-4
1-styrenyloxytrimethylsilane

: 1125-88-8
benzaldehyde dimethyl acetal

: 614-47-1
1,3-diphenyl-propen-3-one

Conditions

Conditions	Yield
With chloromethyl methyl ether; tin(ll) chloride In dichloromethane for 2h; Ambient temperature;	100%

: 6651-36-1
1-(Trimethylsilyloxy)cyclohexene

: 1125-88-8
benzaldehyde dimethyl acetal

: 5682-83-7, 31021-02-0, 1467-15-8
(E)-2-benzylidenecyclohexanone

Conditions

Conditions	Yield
With acetyl chloride; tin(ll) chloride In dichloromethane for 2h; Product distribution; Ambient temperature; effect of catalyst-activator system;	100%
With acetyl chloride; tin(ll) chloride In dichloromethane for 2h; Ambient temperature;	100%

: 1125-88-8
benzaldehyde dimethyl acetal

: 17314-33-9
tributyltin phenyl sulfide

: 13865-07-1
(methoxy(phenylthio))methylbenzene

Conditions

Conditions	Yield
With boron trifluoride diethyl etherate In hexane; toluene addn. of BF3*OEt2 in toluene to the acetal in toluene at -78°C and stirring for 1 h; GLC analysis;	100%
With boron trifluoride diethyl etherate In hexane; toluene at -78℃; for 1h;	100 % Chromat.

: 119072-55-8, 7188-38-7
tert-butylisonitrile

: 1125-88-8
benzaldehyde dimethyl acetal

: 13031-13-5
2-methoxy-2-phenylacetonitrile

Conditions

Conditions	Yield
With titanium tetrachloride at -78 - -30℃;	100%
With titanium tetrachloride In dichloromethane at -70 - 20℃; for 3h;	96%

: 1125-88-8
benzaldehyde dimethyl acetal

: 100-52-7
benzaldehyde

Conditions

Conditions	Yield
sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate In water at 30℃; for 0.0833333h;	100%
With water at 80℃; for 2h;	100%
With water at 90℃; Inert atmosphere;	100%

: 1125-88-8
benzaldehyde dimethyl acetal

: 2936-70-1, 5624-48-6, 13992-15-9, 16758-34-2, 28244-97-5, 77481-62-0, 77481-63-1, 105088-17-3, 149495-84-1
(2R,3S,4S,5R,6S)-2-Hydroxymethyl-6-phenylsulfanyl-tetrahydro-pyran-3,4,5-triol

: 71676-30-7, 87508-18-7, 138922-03-9, 87508-17-6
(2R,4aR,6S,7R,8R,8aS)-2-Phenyl-6-phenylsulfanyl-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol

Conditions

Conditions	Yield
With toluene-4-sulfonic acid In N,N-dimethyl-formamide at 60℃; pH=2 - 3; Inert atmosphere;	100%
With 1,3,5-trichloro-2,4,6-triazine In acetonitrile at 60℃; for 0.166667h; Sonication; Inert atmosphere; regioselective reaction;	95%
With iron(III) chloride In acetonitrile at 20℃; for 2.5h; regioselective reaction;	92%

: 1125-88-8
benzaldehyde dimethyl acetal

: 126-30-7
2,2-Dimethyl-1,3-propanediol

: 776-88-5
5,5-dimethyl-2-phenyl-[1,3]dioxane

Conditions

Conditions	Yield
With camphor-10-sulfonic acid In dichloromethane Inert atmosphere;	100%
With 4 A molecular sieve; camphor-10-sulfonic acid In dichloromethane for 0.5h;	99%
With camphor-10-sulfonic acid In dichloromethane Ambient temperature;	97%

: 1125-88-8
benzaldehyde dimethyl acetal

: 163380-63-0
(2R,4R,5R)-5-Methyl-hept-6-ene-2,4-diol

: (4R,6R)-4-Methyl-6-((R)-1-methyl-allyl)-2-phenyl-[1,3]dioxane

Conditions

Conditions	Yield
With camphor-10-sulfonic acid In dichloromethane at 25℃; for 1.5h;	100%

: 1125-88-8
benzaldehyde dimethyl acetal

: 155581-30-9
(2R,4S,5S)-5-Methyl-hept-6-ene-2,4-diol

: (4R,6S)-4-Methyl-6-((S)-1-methyl-allyl)-2-phenyl-[1,3]dioxane

Conditions

Conditions	Yield
With camphor-10-sulfonic acid In dichloromethane at 25℃; for 1.5h;	100%

: 1125-88-8
benzaldehyde dimethyl acetal

: (Z)-(1R,4S,7R,8R)-3-Allyl-4,8-bis-benzyloxy-7-methoxymethoxy-2,2-dimethyl-cyclooct-5-ene-1,3-diol

: (Z)-(1S,2S,5R,6S,7R,9S)-1-Allyl-2,6-bis-benzyloxy-5-methoxymethoxy-11,11-dimethyl-9-phenyl-8,10-dioxa-bicyclo[5.3.1]undec-3-ene

Conditions

Conditions	Yield
With camphor-10-sulfonic acid In benzene	100%

: 1125-88-8
benzaldehyde dimethyl acetal

: 709-50-2
methyl beta-D-glucopyranoside

: 71117-37-8
(2R,4aR,6R,7R,8R,8aS)-6-Methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol

Conditions

Conditions	Yield
With toluene-4-sulfonic acid In N,N-dimethyl-formamide at 50℃; under 37.5038 Torr; for 2h;	100%
With (1S)-10-camphorsulfonic acid In acetonitrile at 20℃; for 4h;	93%
With iodine In acetonitrile at 20℃; for 1h;	92%

: 1125-88-8
benzaldehyde dimethyl acetal

: 3396-99-4
methyl α-D-galactopyranoside

: 64552-06-3
methyl 4,6-O-benzylidene-α-D-galactopyranoside

Conditions

Conditions	Yield
With camphor-10-sulfonic acid In chloroform at 65℃;	100%
With tetrafluoroboric acid In diethyl ether; N,N-dimethyl-formamide at 20℃; for 16h;	96%
With toluene-4-sulfonic acid; 1-butyl-3-methylimidazolium Tetrafluoroborate at 80℃; for 2h;	92%

: 1125-88-8
benzaldehyde dimethyl acetal

: 182865-98-1
((2R,3R,4R,5S,6R)-2-Ethoxy-4,5-dihydroxy-6-hydroxymethyl-tetrahydro-pyran-3-yl)-carbamic acid allyl ester

: 182865-71-0
((2R,4aR,6R,7R,8R,8aS)-6-Ethoxy-8-hydroxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl)-carbamic acid allyl ester

Conditions

Conditions	Yield
With toluene-4-sulfonic acid In acetonitrile	100%

: 67-56-1
methanol

: 1125-88-8
benzaldehyde dimethyl acetal

: 93-58-3
benzoic acid methyl ester

Conditions

Conditions	Yield
With carbon tetrabromide; oxygen for 5h; Irradiation;	100%
With hydrogenchloride; dihydrogen peroxide	95%
With dihydrogen peroxide In water at 30℃; for 3h; Green chemistry;	65%
With oxygen at 90℃; under 3800.26 Torr; for 2h;

: 1125-88-8
benzaldehyde dimethyl acetal

: 7393-43-3
tetraallyl tin

: 80735-94-0
1-Phenyl-3-buten-1-ol

Conditions

Conditions	Yield
With trifluoroacetic acid In ethanol at 30℃; for 20h;	100%

: 1125-88-8
benzaldehyde dimethyl acetal

: 193829-28-6
(Z)-1-Trimethylsilanyl-5-trimethylsilanyloxy-pent-2-ene

: (2R,3R)-2-Phenyl-3-vinyl-tetrahydro-furan

Conditions

Conditions	Yield
With trimethylsilyl trifluoromethanesulfonate In acetonitrile at -20℃; for 0.333333h;	100%

: 54400-75-8, 64650-83-5, 88903-97-3, 116347-86-5, 140849-88-3, 144300-01-6, 54400-77-0
allyl 2-acetamido-2-deoxy-β-D-glucopyranoside

: 1125-88-8
benzaldehyde dimethyl acetal

: 63064-49-3, 65947-37-7, 74984-84-2, 88903-98-4, 92841-84-4, 116347-88-7, 136845-44-8, 138456-61-8, 74984-83-1
allyl 2-acetamido-(R)-4,6-O-benzylidene-2-deoxy-β-D-glucopyranoside

Conditions

Conditions	Yield
With camphor-10-sulfonic acid In acetonitrile at 20℃; for 12h;	100%
With camphor-10-sulfonic acid In acetonitrile at 20℃; regioselective reaction;	93%
With toluene-4-sulfonic acid In acetonitrile for 2h; Ambient temperature; Yield given;
With camphor-10-sulfonic acid In acetonitrile at 20℃;

: 1125-88-8
benzaldehyde dimethyl acetal

: 199850-99-2
(2R,3S,4R)-3-Benzyloxy-5-[4-(tert-butyl-dimethyl-silanyloxy)-3,5-dimethoxy-phenyl]-1,1-bis-ethylsulfanyl-pentane-2,4-diol

: {4-[(2R,4R,5S,6R)-5-Benzyloxy-6-(bis-ethylsulfanyl-methyl)-2-phenyl-[1,3]dioxan-4-ylmethyl]-2,6-dimethoxy-phenoxy}-tert-butyl-dimethyl-silane

Conditions

Conditions	Yield
With camphor-10-sulfonic acid In benzene for 0.333333h; Ambient temperature;	100%

: 1125-88-8
benzaldehyde dimethyl acetal

: 197164-63-9
(2R,3R,4S,5S,6R)-2-Dicyclohexylmethylsulfanyl-6-hydroxymethyl-tetrahydro-pyran-3,4,5-triol

: 197164-99-1
(2R,4aR,6R,7R,8R,8aS)-6-Dicyclohexylmethylsulfanyl-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol

Conditions

Conditions	Yield
With camphor-10-sulfonic acid In N,N-dimethyl-formamide at 57℃; under 20 Torr; for 3h;	100%

: 1125-88-8
benzaldehyde dimethyl acetal

: 58107-40-7, 69291-83-4
N-(2-hydroxycyclohexyl)-4-methylbenzenesulfonamide

: (3aR,7aS)-2-Phenyl-3-(toluene-4-sulfonyl)-octahydro-benzooxazole

Conditions

Conditions	Yield
With 4 A molecular sieve; pyridinium p-toluenesulfonate In toluene for 48h; Heating;	100%

: 1125-88-8
benzaldehyde dimethyl acetal

: 55915-78-1, 65760-72-7, 109735-34-4, 131164-09-5
trans-2-(tert-butylamino)cyclohexan-1-ol

: (3a,7a-trans)-octahydro-3-(t-butyl)-2-phenylbenzoxazole

Conditions

Conditions	Yield
With 4 Angstroem molecular sives; pyridinium p-toluenesulfonate In toluene for 100h; Heating;	100%

: 1125-88-8
benzaldehyde dimethyl acetal

: 1464-44-4
phenyl-β-D-glucopyranoside

: 22887-10-1, 42821-94-3, 54502-82-8, 57783-84-3, 61169-05-9, 61169-06-0, 61221-61-2, 75829-66-2, 111137-95-2, 117677-62-0
phenyl 4,6-O-benzylidene-β-D-glucopyranoside

Conditions

Conditions	Yield
With toluene-4-sulfonic acid In N,N-dimethyl-formamide at 50℃; for 12h;	100%
With sodium hydrogen sulfate; silica gel In acetonitrile at 20℃; for 4h;	95%
With toluene-4-sulfonic acid In N,N-dimethyl-formamide at 0℃; for 48h;	95%

: 1125-88-8
benzaldehyde dimethyl acetal

: 98-86-2
acetophenone

: tributyl-(1-ethoxy-vinyloxy)-silane

: 762-72-1
allyl-trimethyl-silane

A: 22039-97-0
4-methoxy-4-phenyl-1-butene

B: 3-phenyl-3-tributylsilanyloxy-butyric acid ethyl ester

Conditions

Conditions	Yield
With trimethylsilyl trifluoromethanesulfonate In dichloromethane at -78℃; for 9h; parallel recognition;	A 100% B 95%

...Expand

: 1125-88-8
benzaldehyde dimethyl acetal

: 220384-85-0
ethyl (2R,3R,4S)-4-(t-butyldimethylsilyloxy)-2,3-dihydroxy-4-phenylbutanoate

: 220384-86-1
ethyl (2R,3R,4S)-2,3-benzylidenedioxy-4-(t-butyldimethylsilyloxy)-4-phenylbutanoate

Conditions

Conditions	Yield
With camphor-10-sulfonic acid In benzene for 1h; Heating;	100%
With camphor-10-sulfonic acid In benzene for 1h; Cyclization; Heating;	95%

: 1125-88-8
benzaldehyde dimethyl acetal

: 316804-46-3
6-O-(3-deoxy-3-tosylamido-α-D-glucopyranosyl)-2,5-dideoxy-5-epi-5-fluoro-1,3-di-N-tosylstreptamine

: 316804-47-4
6-O-(4,6-O-benzylidene-3-deoxy-3-tosylamido-α-D-glucopyranosyl)-2,5-dideoxy-5-epi-5-fluoro-1,3-di-N-tosylstreptamine

Conditions

Conditions	Yield
With toluene-4-sulfonic acid In N,N-dimethyl-formamide at 60℃; under 35 Torr; for 1h;	100%

: 1125-88-8
benzaldehyde dimethyl acetal

: 212136-31-7
ethyl (2S,3R)-3-hydroxy-2-methyl-2-(methylthio)-3-phenylpropanoate

: (2S,4R,5R)-5-Methyl-5-methylsulfanyl-2,4-diphenyl-[1,3]dioxane

Conditions

Conditions	Yield
Stage #1: ethyl (2S,3R)-3-hydroxy-2-methyl-2-(methylthio)-3-phenylpropanoate With lithium borohydride In dichloromethane at 20℃; Stage #2: benzaldehyde dimethyl acetal With camphor-10-sulfonic acid In dichloromethane at 20℃;	100%

Benzaldehyde dimethyl acetal Chemical Properties

Molecular Formula: C₉H₁₂O₂
Molar mass: 152.1904 g/mol
EINECS: 221-192-4
Density: 0.999 g/cm³
Flash Point: 69.4 °C
Index of Refraction: 1.488
Melting point: 87-89°C
Water solubility: Decomposes
Sensitive: Moisture Sensitive
Appearance: Clear colorless liquid
Boiling Point: 199.7 °C at 760 mmHg
Vapour Pressure: 0.476 mmHg at 25°C
Product categories: Biochemistry;Aromatic Ethers
Structure of Benzaldehyde dimethyl acetal (1125-88-8):

XLogP3-AA: 1.6
H-Bond Donor: 0
H-Bond Acceptor: 2
IUPAC Name: Dimethoxymethylbenzene
Canonical SMILES: COC(C1=CC=CC=C1)OC
InChI: InChI=1S/C9H12O2/c1-10-9(11-2)8-6-4-3-5-7-8/h3-7,9H,1-2H3
InChIKey: HEVMDQBCAHEHDY-UHFFFAOYSA-N

Benzaldehyde dimethyl acetal Uses

Benzaldehyde dimethyl acetal (1125-88-8) is used as reagent for oligosaccharide synthesis.

Benzaldehyde dimethyl acetal Toxicity Data With Reference

1.		skn-rbt 500 mg/24H MLD		FCTXAV Food and Cosmetics Toxicology. 17 (1979),711.
2.		orl-rat LD50:1220 mg/kg		FCTXAV Food and Cosmetics Toxicology. 17 (1979),711.

Carcinogenicity of Benzaldehyde dimethyl acetal (1125-88-8) hasn't been listed as a carcinogen by NTP, IARC,ACGIH, or CA Prop 65. And its toxicological properties have not been fully investigated.You can see actual entry in RTECS for complete information.

Benzaldehyde dimethyl acetal Consensus Reports

Reported in EPA TSCA Inventory.

Benzaldehyde dimethyl acetal Safety Profile

Moderately toxic by ingestion. A skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes.
Hazard Codes: Xn
Risk Statements:
22: Harmful if swallowed
36: Irritating to the eyes
37: Irritating to the respiratory system
38: Irritating to the skin
Safety Statements:
23: Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer)
24: Avoid contact with skin
25: Avoid contact with eyes
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36: Wear suitable protective clothing
37: Wear suitable gloves
39: Wear eye/face protection

Benzaldehyde dimethyl acetal Specification

Benzaldehyde dimethyl acetal (1125-88-8) also can be called Alpha,alpha-dimethoxytoluene ; .Alpha.,.alpha.-Dimethoxytoluene ; (dimethoxymethyl)benzene ; Toluene, .alpha.,.alpha.-dimethoxy- ; benzene, (dimethoxymethyl)- .Its first aid measures and others should be known.Such as: When on the skin: should flush skin with plenty of water immediatelyfor at least 15 minutes while removing contaminated clothing. Or in the eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. While ,it's Inhaled: Remove from exposure and move to fresh air immediately.Then you have the ingesting of the product : Wash mouth out with water.
In addition, Benzaldehyde dimethyl acetal (1125-88-8) can be stable under normal temperature and pressure conditions.It is not compatible with strong oxidizing agents,moisture, and you must not take it with incompatible materials.And also prevent it to broken down into hazardous decomposition products: irritating and toxic fumes and gases,carbon dioxide,carbon monoxide.

Product Name

Benzaldehyde dimethyl acetal

Synthetic route

Benzaldehyde dimethyl acetal Chemical Properties

Benzaldehyde dimethyl acetal Uses

Benzaldehyde dimethyl acetal Toxicity Data With Reference

Benzaldehyde dimethyl acetal Consensus Reports

Benzaldehyde dimethyl acetal Safety Profile

Benzaldehyde dimethyl acetal Specification

Related Products

Hot Products