Benzyl Methacrylate supplier

Name
Benzyl methacrylate
EINECS 219-674-4
CAS No. 2495-37-6
Article Data41
CAS DataBase
Density 1.036 g/cm³
Solubility Insoluble in water.
Melting Point <25 °C
Formula C₁₁H₁₂O₂
Boiling Point 247.033 °C at 760 mmHg
Molecular Weight 176.215
Flash Point 124.13 °C
Transport Information
Appearance colourless liquid
Safety 26
Risk Codes 36/37/38
Molecular Structure
Hazard Symbols Xi
Synonyms Methacrylicacid, benzyl ester (6CI,7CI,8CI);Acryester BZ;Benzyl 2-methyl-2-propenoate;Benzyl 2-methylacrylate;Benzyl methacrylate;BzMA;Fancryl FA-BZM;Light EsterBZ;NSC 20970;Phenylmethyl 2-methyl-2-propenoate;
PSA 26.30000
LogP 2.30590

Synthetic route

: 79-41-4
poly(methacrylic acid)

: 100-51-6
benzyl alcohol

: 2495-37-6
benzyl methacrylate

Conditions

Conditions	Yield
tetrachlorobis(tetrahydrofuran)hafnium(IV) In benzene for 40h; Heating;	99%
With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 20℃; for 4h;	90%
toluene-4-sulfonic acid In benzene for 15h; Heating;	85%

: 80-62-6
methacrylic acid methyl ester

: 100-51-6
benzyl alcohol

: 2495-37-6
benzyl methacrylate

Conditions

Conditions	Yield
With C2H3O3(1-)*C37H78N(1+) In hexane at 90℃; for 2h; Reagent/catalyst; Molecular sieve;	97%
With lanthanum (III) nitrate * water; 1,1,1-trioctyl-1-methylphosphonium methylcarbonate In hexane for 10h; Molecular sieve; Reflux;	80%

: 920-46-7
Methacryloyl chloride

: 100-51-6
benzyl alcohol

: 2495-37-6
benzyl methacrylate

Conditions

Conditions	Yield
With triethylamine at 0℃; Inert atmosphere; Microwave irradiation;	96%
With triethylamine In dichloromethane at 0℃;	62%
With triethylamine In dichloromethane at 0℃; Inert atmosphere;	50%

: 81171-49-5
(1-Benzyloxy-2-chloro-2-methyl-cyclopropoxy)-trimethyl-silane

: 2495-37-6
benzyl methacrylate

Conditions

Conditions	Yield
With triethylamine In methanol for 6h; Heating;	91%
With triethylamine In methanol for 12h; Heating; Yield given;

: 1426060-15-2
benzyl 3-(dimethylamino)-2-methylpropanoate

: 2495-37-6
benzyl methacrylate

Conditions

Conditions	Yield
With 2-chloro-4,6-dimethoxy-1 ,3,5-triazine; triethylamine In isopropyl alcohol at 20℃; for 0.25h; Eschenmoser Methylenation;	90%

: 65-85-0
benzoic acid

: 75107-16-3
2-bromoisobutyric acid,benzyl ester

A: C18H18O4

B: 2495-37-6
benzyl methacrylate

Conditions

Conditions	Yield
With silver(l) oxide In water; acetonitrile at 100℃; for 24h;	A 89% B n/a

...Expand

: 100-44-7
benzyl chloride

: 920-46-7
Methacryloyl chloride

: 2495-37-6
benzyl methacrylate

Conditions

Conditions	Yield
With dmap; caesium carbonate at 50℃; for 24h; Concentration;	89%

: 4245-37-8
vinyl methacrylate

: 100-51-6
benzyl alcohol

: 2495-37-6
benzyl methacrylate

Conditions

Conditions	Yield
With TBA7[γ-HGeW10O36] In acetonitrile at 39.84℃; for 0.0166667h;	83%

: 63613-50-3
benzyl 2-(tripheny l-λ5phosphanylidene)propanoate

: 2495-37-6
benzyl methacrylate

Conditions

Conditions	Yield
With carbon dioxide; potassium tert-butylate In N,N-dimethyl-formamide at 100℃; under 760.051 Torr; for 12h;	83%

: 463-49-0
1,2-propanediene

: 201230-82-2
carbon monoxide

: 100-51-6
benzyl alcohol

: 2495-37-6
benzyl methacrylate

Conditions

Conditions	Yield
dodecacarbonyl-triangulo-triruthenium at 80℃; under 22800 Torr; for 5h;	73%

...Expand

: 94751-48-1
benzyl 2-methyl-3-(methylthio)propanoate

: 333-27-7
methyl trifluoromethanesulfonate

: 2495-37-6
benzyl methacrylate

Conditions

Conditions	Yield
In dichloromethane	65%

: α-ethoxycarbonyloxy-isobutyric acid benzyl ester

: 2495-37-6
benzyl methacrylate

Conditions

Conditions	Yield
Destillation;

: 19444-23-6
benzyl 2-hydroxy-2-methylpropanoate

: 2495-37-6
benzyl methacrylate

Conditions

Conditions	Yield
With phosphorus pentachloride In toluene at 80℃;

: 79-41-4
poly(methacrylic acid)

: 100-44-7
benzyl chloride

: 2495-37-6
benzyl methacrylate

Conditions

Conditions	Yield
With triethylamine In toluene at 75℃; Kinetics; Thermodynamic data; other reagents, solvents; influence of the nature of the solvent on the kinetics of the formation of benzyl methacrylate;

: 100-44-7
benzyl chloride

sodium-compound of acetoacetanilide: sodium-compound of acetoacetanilide

: 2495-37-6
benzyl methacrylate

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: dimethylformamide / 160 °C 2: PCl5 / toluene / 80 °C View Scheme

: 81171-44-0
1-benzyloxy-1-(trimethylsilyloxy)ethylene

: 2495-37-6
benzyl methacrylate

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: n-butyllithium / diethyl ether / -35 °C 2: triethylamine / methanol / 12 h / Heating View Scheme
Multi-step reaction with 2 steps 1: butyllithium / hexane; diethyl ether / -40 - -30 °C 2: 91 percent / triethylamine / methanol / 6 h / Heating View Scheme

: 5437-45-6
Benzyl bromoacetate

: 2495-37-6
benzyl methacrylate

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: 60 percent / Zn 2: n-butyllithium / diethyl ether / -35 °C 3: triethylamine / methanol / 12 h / Heating View Scheme

: 140-11-4
Benzyl acetate

: 2495-37-6
benzyl methacrylate

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: 1.) diisopropylamine, n-butyllithium / 1.) THF, hexane, -78 deg C, 30 min; 2.) -78 deg C, 15 min; room temp., 1 h 2: butyllithium / hexane; diethyl ether / -40 - -30 °C 3: 91 percent / triethylamine / methanol / 6 h / Heating View Scheme

: benzyl 3-[(ethoxycarbonyl)oxy]-2-methyl-2-[(propionyloxy)methyl]propanoate

A: 2495-37-6
benzyl methacrylate

B: 802294-64-0
propionic acid

Conditions

Conditions	Yield
at 626.84℃; Kinetics; Further Variations:; Temperatures;

: 108-88-3
toluene

: 2495-37-6
benzyl methacrylate

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: hydrogen bromide; dihydrogen peroxide / water / 6 h / 5 - 10 °C 2: 4-methoxy-phenol / water / 8 h / 95 °C View Scheme

: 5536-61-8
sodium methacrylate

: 100-39-0
benzyl bromide

: 2495-37-6
benzyl methacrylate

Conditions

Conditions	Yield
With 4-methoxy-phenol In water at 95℃; for 8h;

: 124-38-9
carbon dioxide

: 63613-50-3
benzyl 2-(tripheny l-λ5phosphanylidene)propanoate

: 2495-37-6
benzyl methacrylate

Conditions

Conditions	Yield
With sodium t-butanolate In N,N-dimethyl-formamide at 100℃; under 760.051 Torr; for 12h; Schlenk technique; Sealed tube;	59 mg

: 2495-37-6
benzyl methacrylate

: 37067-52-0
α,α-dichloromethyl p-tolyl sulfoxide

: 2-chloro-1-methyl-2-(toluene-4-sulfinyl)cyclopropanecarboxylic acid benzyl ester

Conditions

Conditions	Yield
With sodium hexamethyldisilazane In tetrahydrofuran at -78 - 0℃; for 2h;	99%

: 2495-37-6
benzyl methacrylate

: 37067-52-0
α,α-dichloromethyl p-tolyl sulfoxide

: C19H19ClO3S

Conditions

Conditions	Yield
With sodium hexamethyldisilazane In tetrahydrofuran at -78 - 0℃; for 2h;	99%

: 75-91-2
tert.-butylhydroperoxide

: 2495-37-6
benzyl methacrylate

: 630-19-3
pivalaldehyde

: 1415690-07-1
C19H30O4

Conditions

Conditions	Yield
With iron(II) chloride In decane; acetonitrile at 85℃; for 1h; Inert atmosphere;	99%

...Expand

: 2495-37-6
benzyl methacrylate

: 766-08-5
methylphenylsilane

: C18H22O2Si

Conditions

Conditions	Yield
With (tris(4,4-dimethyl-2-oxazolinyl)phenylborate)MgHB(C6F5)3 In benzene at 20℃; for 4h;	99%

: 2495-37-6
benzyl methacrylate

: 4-methylbenzo[d]oxadiazole

: C19H19NO3

Conditions

Conditions	Yield
With di-μ-acetato-bis(η4-1,5-cyclooctadiene)dirhodium(I); 4,4'-di-tert-butylbiphenyl; C46H50N2O4P2; cesium acetate In acetonitrile at 100℃; for 48h; Glovebox; Sealed tube; Inert atmosphere; enantioselective reaction;	98%
With di-μ-acetato-bis(η4-1,5-cyclooctadiene)dirhodium(I); C46H50N2O4P2; C14H17NO3; cesium acetate In acetonitrile at 100℃; for 48h; Glovebox; Sealed tube; Inert atmosphere; enantioselective reaction;	95%

: 2495-37-6
benzyl methacrylate

: 815-17-8
trimethylpyruvic acid

: 114222-35-4
benzyl 2,4,4-trimethylpentanoate

Conditions

Conditions	Yield
With 1,4-diaza-bicyclo[2.2.2]octane; [4,4′-bis(1,1-dimethylethyl)-2,2′-bipyridine-N1,N1′]bis{3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κN]phenyl-κC}iridium(III) hexafluorophosphate In acetone at 25℃; for 3h; Inert atmosphere; Irradiation;	97%

: 2495-37-6
benzyl methacrylate

: 623-33-6
glycine ethyl ester hydrochloride

: 5-benzyl 3-ethyl 5-methyl-4,5-dihydroisoxazole-3,5-dicarboxylate

Conditions

Conditions	Yield
With tert.-butylnitrite; dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; sodium hydrogencarbonate; zinc dibromide In tert-butyl methyl ether at 20℃; for 24h; Schlenk technique; Inert atmosphere; Sealed tube;	97%

: 2495-37-6
benzyl methacrylate

: 18854-19-8
benzyl pyruvate

Conditions

Conditions	Yield
Stage #1: benzyl methacrylate With ozone In dichloromethane at -78℃; Stage #2: With Merrifield resin-bound piperidine In dichloromethane at 20℃; for 8h;	96%

: 2495-37-6
benzyl methacrylate

: 103-28-6
benzyl 2-methylpropanoate

Conditions

Conditions	Yield
With 1,4-dioxane; bis(1,5-cyclooctadiene)diiridium(I) dichloride; 1,2-bis-(dicyclohexylphosphino)ethane at 130℃; for 10h; Inert atmosphere; Sealed tube; chemoselective reaction;	96%
With hydrogen In methanol at 20℃; for 5h; chemoselective reaction;	92%
With palladium on activated charcoal; hydrogen In methanol at 20℃; for 24h; chemoselective reaction;	86%

: 75-25-2
Bromoform

: 2495-37-6
benzyl methacrylate

: benzyl 2,2-dibromo-1-methylcyclopropylcarboxylate

Conditions

Conditions	Yield
With benzyltriethylammonium bromide; sodium hydroxide at 20℃; for 4h;	93.6%

: 2495-37-6
benzyl methacrylate

: C16H28N2OSi

: C24H32N2O3

Conditions

Conditions	Yield
With tris(2,2'-bipyridyl)ruthenium dichloride In N,N-dimethyl-formamide at 25℃; for 12h; Schlenk technique; Sealed tube; Glovebox; Inert atmosphere; Irradiation;	93%

: 2495-37-6
benzyl methacrylate

: 19444-23-6
benzyl 2-hydroxy-2-methylpropanoate

Conditions

Conditions	Yield
With phenylsilane; oxygen; bis(dipivaloylmethanato)manganese(II) In isopropyl alcohol at 0℃; under 760 Torr; for 1.5h;	92%
Multi-step reaction with 3 steps 1: triphenylphosphine; Stryker's reagent / toluene / 1 h / 20 °C / Inert atmosphere 2: tributylphosphine / toluene / 144 h / 20 °C / Inert atmosphere 3: N,N-dimethylaniline N-oxide / dichloromethane / 0 - 20 °C / Inert atmosphere View Scheme

: 626-62-0
1-iodocyclohexane

: 2495-37-6
benzyl methacrylate

: benzyl 3-cyclohexyl-2-methylpropanoate

Conditions

Conditions	Yield
With dimanganese decacarbonyl; diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate In dimethyl sulfoxide at 20℃; for 24h; Inert atmosphere; Sealed tube; Irradiation;	92%

: 75-91-2
tert.-butylhydroperoxide

: 2495-37-6
benzyl methacrylate

: 100-52-7
benzaldehyde

: 1415689-92-7
benzyl 2-(tert-butylperoxy)-2-methyl-4-oxo-4-phenylbutanoate

Conditions

Conditions	Yield
With iron(II) chloride In decane; acetonitrile at 85℃; for 1h; Concentration; Reagent/catalyst; Inert atmosphere;	91%

...Expand

: 2495-37-6
benzyl methacrylate

: 16883-69-5
N-phenacylpyridinium bromide

: benzyl 2-methyl-5-oxo-5-phenyl-2-(pyridin-2-yl)pentanoate

Conditions

Conditions	Yield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In toluene at 20℃; for 72h; Sealed tube; Irradiation; Inert atmosphere; regioselective reaction;	90%

: 67-66-3
chloroform

: 2495-37-6
benzyl methacrylate

: benzyl 2,2-dichloro-1-methylcyclopropylcarboxylate

Conditions

Conditions	Yield
With benzyltriethylammonium bromide; sodium hydroxide at 20℃; for 4h;	89.5%

: 2495-37-6
benzyl methacrylate

: 1,3-dioxoisoindolin-2-yl (tert-butoxycarbonyl)valinate

: benzyl 4-((tert-butoxycarbonyl)amino)-2,5-dimethylhexanoate

Conditions

Conditions	Yield
With eosin; N-ethyl-N,N-diisopropylamine In dichloromethane at 20℃; for 18h; Irradiation; Green chemistry;	89%

: 12120-15-9
ethylenebis(triphenylphosphine)platinum(0)

: 2495-37-6
benzyl methacrylate

: 186495-05-6
Pt(P(C6H5)3)2(CH2C(CH3)COOCH2C6H5)

Conditions

Conditions	Yield
In toluene byproducts: C2H4; N2-atmosphere; stirring equimolar amts. for 2 h; cooling to 0°C, pptn. on addn. of petroleum ether, collection (filtration), washing (petroleum ether), drying (vac.);	88%

: 2495-37-6
benzyl methacrylate

: 446065-11-8
cyclohexyltrifluoro-λ4-borane potassium salt

: benzyl 3-cyclohexyl-2-methylpropanoate

Conditions

Conditions	Yield
With methanol; 9-(2-mesityl)-10-methylacridinium perchlorate In acetone at 20℃; for 24h; Irradiation;	88%

: 2495-37-6
benzyl methacrylate

: benzyl 2,3-dihydroxy-2-methylpropanoate

Conditions

Conditions	Yield
With osmium(VIII) oxide; 4-methylmorpholine N-oxide In acetone; tert-butyl alcohol for 48h;	87%
With AD-mix-α In water; tert-butyl alcohol at 20℃; for 18h; Sharpless asymmetric dihydroxylation;	85%
With potassium permanganate; N-benzyl-N,N,N-triethylammonium chloride In acetone at -2 - 2℃; for 0.5h;	84%
Stage #1: benzyl methacrylate With C28H55N2(1+)*Cl(1-) In acetone at 20℃; for 0.166667h; Stage #2: With potassium permanganate In acetone at 0 - 5℃; for 2.17h;	83%

: 2495-37-6
benzyl methacrylate

: 125764-09-2
tetraethylammonium bis<α,α-bis(trifluoromethyl)benzenemethanolato(2-)-C2,O>cyclohexylsilicate

: benzyl 3-cyclohexyl-2-methylpropanoate

Conditions

Conditions	Yield
With 3,6‐di‐tert‐butyl‐9‐mesityl‐10‐phenylacridin‐10‐ium tetrafluoroborate In methanol; acetone at 23℃; for 3h; Irradiation;	87%

: 2495-37-6
benzyl methacrylate

: 3-methylbutyl tert-butylsulfamate

: benzyl 6-((N-(tert-butyl)sulfamoyl)oxy)-2,4,4-trimethylhexanoate

Conditions

Conditions	Yield
With potassium phosphate tribasic trihydrate In N,N-dimethyl-formamide at 25℃; for 48h; Inert atmosphere; Irradiation;	86%

: 2495-37-6
benzyl methacrylate

: 103-67-3
benzyl-methyl-amine

: 1148109-08-3
benzyl 2-methyl-3-[(phenylmethyl)amino]propionate

Conditions

Conditions	Yield
In glycerol at 100℃; for 5h; aza-Michael reaction;	85%

Benzyl Methacrylate Chemical Properties

Molecular Formula: C₁₁H₁₂O₂
Formula Weight: 176.21
bp: 95-98 ^°C 4 mm Hg(lit.)
density: 1.04 g/mL at 25 ^°C(lit.)
refractive index: n20/D 1.512(lit.)
Fp: 225^°F
Sensitive: Light Sensitive
PHYSICAL STATE: clear liquid
SOLUBILITY IN WATER: Insoluble
STABILITY Of Benzyl Methacrylate: Polymerization will occur under light and HEAT

Benzyl Methacrylate Uses

Benzyl Methacrylate can be used as funtional monomer for polymers, coatings, Adhesives. Textile treatment agent, LUBRICATING OIL .

Benzyl Methacrylate Toxicity Data With Reference

Oral rat LD₅₀: 3600 mg/kg

Benzyl Methacrylate Safety Profile

Hazard Codes : Xi
Risk Statements : 36/37/38
Safety Statements : 26
WGK Germany : 1

Benzyl Methacrylate Standards and Recommendations

PURITY (G.C): 98.0% min
COLOR, APHA: 30 max
SPECIFIC GRAVITY: 1.035 - 1.045
WATER: 0.1% max
FREE ACID:0.05% max (Methacrlic acid)
INHIBITOR: 200ppm max (Monomethyl Ether Hydroquinone)

Benzyl Methacrylate Specification

PACKING OF Benzyl Methacrylate: 200kgs in drum

Product Name

Benzyl methacrylate

Synthetic route

Benzyl Methacrylate Chemical Properties

Benzyl Methacrylate Uses

Benzyl Methacrylate Toxicity Data With Reference

Benzyl Methacrylate Safety Profile

Benzyl Methacrylate Standards and Recommendations

Benzyl Methacrylate Specification

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