Butyl Nitrate supplier | CasNO.928-45-0

Name
N-BUTYL NITRATE
EINECS
CAS No. 928-45-0
Article Data38
CAS DataBase
Density 1.047g/cm³
Solubility 774.3mg/L(25 oC)
Melting Point -111.59°C (estimate)
Formula C4H9 N O3
Boiling Point 135.3°Cat760mmHg
Molecular Weight 119.12
Flash Point 49.9°C
Transport Information
Appearance Colourless Oil
Safety An explosive. Reacts explosively with Lewis acids (e.g., boron trifluoride; aluminum chloride; etc.). When heated to decomposition it emits toxic fumes of NO_x. See also NITRATES.
Risk Codes R61; R20/22; R33; R50/53; R62
Molecular Structure
Hazard Symbols T,N
Synonyms Butylnitrate (6CI,7CI); n-Butyl nitrate
PSA 55.05000
LogP 1.51800

Synthetic route

: 71-36-3
butan-1-ol

: 928-45-0
butyl nitrate

Conditions

Conditions	Yield
With N-nitro-2,4,6-trimethylpyridinium tetrafluoroborate In acetonitrile at 0℃; for 2h;	100%
With carbon dioxide; dinitrogen pentoxide at 0℃; under 45004.5 - 60006 Torr; for 0.5h; Autoclave;	94%
With nitric acid; urea; europium(III) trifluoromethanesulfonate In cyclohexane at 80℃; for 10h; Schlenk technique;	90%

: 73377-40-9
N-Butyl-2,4,6-triphenylpyridinium nitrate

: 928-45-0
butyl nitrate

Conditions

Conditions	Yield
at 250℃; under 760 Torr; for 3h;	50%

: 109-65-9
1-bromo-butane

: 928-45-0
butyl nitrate

Conditions

Conditions	Yield
With silver nitrate; acetonitrile
With silver nitrate In acetonitrile

: 542-69-8
1-iodo-butane

: 928-45-0
butyl nitrate

Conditions

Conditions	Yield
With silver nitrate; acetonitrile
With nitric acid at -10℃;

: 74-85-1
ethene

: 928-45-0
butyl nitrate

Conditions

Conditions	Yield
With nitric acid Electrolysis.an Platinanoden;

: 2372-45-4
sodium butanolate

: 928-45-0
butyl nitrate

Conditions

Conditions	Yield
With dichloromethane; dinitrogen tetraoxide; butan-1-ol at -80℃;

: 1-picryl-pyridinium; nitrate

: 71-36-3
butan-1-ol

: 928-45-0
butyl nitrate

: 69153-16-8
butyl-nitro-amine; ammonium salt

: 928-45-0
butyl nitrate

Conditions

Conditions	Yield
With nitrylfluoride In acetonitrile

: 2568-90-3
di-n-butyloxymethane

A: 928-45-0
butyl nitrate

B: 127510-61-6
n-butoxymethyl-nitrate

Conditions

Conditions	Yield
With dinitrogen pentoxide In dichloromethane at 0 - 10℃;

: 106-97-8
n-butane

A: 544-16-1
n-Butyl nitrite

B: 928-45-0
butyl nitrate

C: 924-43-6
sec-butyl nitrite

D: 600-24-8, 116783-22-3
2-nitrobutane

E: 924-52-7
2-butyl nitrate

F: 627-05-4
1-nitrobutane

Conditions

Conditions	Yield
With dihydrogen peroxide; Nitrogen dioxide at 24.9℃; under 300.02 Torr; Rate constant; Product distribution; Mechanism; boric-acid-coated surface; various pressure and carrier-gas composition;	A 6 % Chromat. B 0.3 % Chromat. C 31 % Chromat. D 51 % Chromat. E 3 % Chromat. F 7 % Chromat.

...Expand

: 106-97-8
n-butane

A: 928-45-0
butyl nitrate

B: 924-52-7
2-butyl nitrate

Conditions

Conditions	Yield
With methyl nitrite; ultra-zero air; nitrogen(II) oxide at 25.9℃; for 0.333333h; Product distribution; Rate constant; Irradiation; other alkyl peroxy radical generator (Cl2);

: 106-97-8
n-butane

A: 928-45-0
butyl nitrate

B: 924-43-6
sec-butyl nitrite

C: 600-24-8, 116783-22-3
2-nitrobutane

D: 924-52-7
2-butyl nitrate

E: 123-72-8
butyraldehyde

F: 78-93-3
butanone

Conditions

Conditions	Yield
With dihydrogen peroxide; oxygen; Nitrogen dioxide at 24.9℃; under 300.02 Torr; Rate constant; Product distribution; Mechanism; boric-acid-coated surface; various O2 concn.;

...Expand

: 110-62-3
pentanal

A: 928-45-0
butyl nitrate

B: 2278-22-0
peroxyacetyl nitrate

C: peroxy-n-butyryl nitrate

D: 154292-37-2
n-pentanoyl peroxynitrate

Conditions

Conditions	Yield
With air; nitrogen(II) oxide Nitration; sunlight; Further byproducts given. Title compound not separated from byproducts;

...Expand

: 28384-48-7
peroxypentanoic acid

A: 598-58-3
methyl nitrate

B: 928-45-0
butyl nitrate

C: 2278-22-0
peroxyacetyl nitrate

D: 154292-37-2
n-pentanoyl peroxynitrate

Conditions

Conditions	Yield
With nitric acid In dodecane Nitration; Title compound not separated from byproducts;

...Expand

: 64-19-7
acetic acid

: 109-73-9
N-butylamine

sodium nitrite: sodium nitrite

A: 928-45-0
butyl nitrate

B: 105-46-4
sec-Butyl acetate

C: 123-86-4
acetic acid butyl ester

Conditions

Conditions	Yield
Mechanism;

...Expand

: 106-97-8
n-butane

A: 625-58-1
ethyl nitrate

B: 928-45-0
butyl nitrate

C: 924-52-7
2-butyl nitrate

D: 2278-22-0
peroxyacetyl nitrate

E: peroxy-n-butyryl nitrate

F: 78-93-3
butanone

G C2H5C(O)OONO2: C2H5C(O)OONO2

Conditions

Conditions	Yield
With air; Nitrogen dioxide at 25℃; for 6h; Product distribution; Mechanism; Kinetics; Irradiation; also addition of NO;	A 1.3 % Chromat. B 1.3 % Chromat. C 16 % Chromat. D 23 % Chromat. E 1.3 % Chromat. F 37 % Chromat. G n/a

...Expand

: 109-52-4
valeric acid

NaNO3: NaNO3

natrium carbonate: natrium carbonate

A: 544-16-1
n-Butyl nitrite

B: 928-45-0
butyl nitrate

C: 591-68-4
butyl valerate

D racbutanediol-(2.3)-dinitrate(?): racbutanediol-(2.3)-dinitrate(?)

Conditions

Conditions	Yield
Reaktion des Natriumsalzes; Produkt 5: Octan; Produkt 6: Octandioldinitrat.Electrolysis;

...Expand

: 137-40-6
sodium proprionate

CaCO3: CaCO3

: 928-45-0
butyl nitrate

Conditions

Conditions	Yield
With sodium nitrate; water Electrolysis;

: 70458-10-5, 119247-49-3
(-)-1-deuterio-butylamine

: 64-19-7
acetic acid

sodium nitrite: sodium nitrite

A: 928-45-0
butyl nitrate

B (+)-1-acetoxy-1-deuterio-butane: (+)-1-acetoxy-1-deuterio-butane

C (+-)2-acetoxy-1-deuterio-butane: (+-)2-acetoxy-1-deuterio-butane

...Expand

: 74-85-1
ethene

: 7697-37-2
nitric acid

platinum: platinum

A: 625-58-1
ethyl nitrate

B: 928-45-0
butyl nitrate

C: 628-96-6
1,2-ethyl dinitrate

D: 693-21-0
diethylene glycol dinitrate

Conditions

Conditions	Yield
Electrolysis;

...Expand

: 74-85-1
ethene

: 7697-37-2
nitric acid

: 64-19-7
acetic acid

platinum: platinum

A: 625-58-1
ethyl nitrate

B: 928-45-0
butyl nitrate

C: 628-96-6
1,2-ethyl dinitrate

D: 693-21-0
diethylene glycol dinitrate

Conditions

Conditions	Yield
Electrolysis;

...Expand

: 74-85-1
ethene

: 67-64-1
acetone

Ca(NO3)2: Ca(NO3)2

platinum: platinum

A: 625-58-1
ethyl nitrate

B: 928-45-0
butyl nitrate

C: 628-96-6
1,2-ethyl dinitrate

D: 693-21-0
diethylene glycol dinitrate

Conditions

Conditions	Yield
Electrolysis;

...Expand

: 74-85-1
ethene

: 64-19-7
acetic acid

NaNO3: NaNO3

platinum: platinum

A: 625-58-1
ethyl nitrate

B: 928-45-0
butyl nitrate

C: 628-96-6
1,2-ethyl dinitrate

D: 693-21-0
diethylene glycol dinitrate

Conditions

Conditions	Yield
Electrolysis;

...Expand

: 74-85-1
ethene

: 7732-18-5
water

: 67-64-1
acetone

NaNO3: NaNO3

platinum: platinum

A: 625-58-1
ethyl nitrate

B: 928-45-0
butyl nitrate

C: 628-96-6
1,2-ethyl dinitrate

D: 693-21-0
diethylene glycol dinitrate

Conditions

Conditions	Yield
Electrolysis;

...Expand

: 137-40-6
sodium proprionate

: sodium perchlorate

CaCO3: CaCO3

A: 625-58-1
ethyl nitrate

B: 928-45-0
butyl nitrate

C: 628-96-6
1,2-ethyl dinitrate

D: 3457-91-8
1,4-butanediol dinitrate

Conditions

Conditions	Yield
Elektrolyse an Platinanode.Electrolysis;

...Expand

: 137-40-6
sodium proprionate

NaNO3: NaNO3

CaCO3: CaCO3

A: 625-58-1
ethyl nitrate

B: 928-45-0
butyl nitrate

C: 628-96-6
1,2-ethyl dinitrate

D: 3457-91-8
1,4-butanediol dinitrate

Conditions

Conditions	Yield
Produkt5:Aethylpropionat ;Elektrolyse an Platinanode.Electrolysis;

...Expand

: 137-40-6
sodium proprionate

sodium sulfate: sodium sulfate

CaCO3: CaCO3

A: 625-58-1
ethyl nitrate

B: 928-45-0
butyl nitrate

C: 628-96-6
1,2-ethyl dinitrate

D: 3457-91-8
1,4-butanediol dinitrate

Conditions

Conditions	Yield
Elektrolyse an Platinanode.Electrolysis;

...Expand

: 616-47-7
1-methyl-1H-imidazole

: 928-45-0
butyl nitrate

: 179075-88-8
1-butyl-3-methylimidazolium nitrate

Conditions

Conditions	Yield
at 120℃; for 0.5h; Microwave irradiation;	96%
In ethyl acetate for 24h; Reflux;	89%

: 110-89-4
piperidine

: 928-45-0
butyl nitrate

: 4945-48-6
1-butyl-piperidine

Conditions

Conditions	Yield
Mehrtaegiges Stehenlassen.;

: 928-45-0
butyl nitrate

: 123-72-8
butyraldehyde

Conditions

Conditions	Yield
zersetzt sich beim Erhitzen explosionsartig;

: 928-45-0
butyl nitrate

: 106-49-0
p-toluidine

A: 10387-24-3
N-butyl-4-methylaniline

B: 32954-54-4
para-methyl anilinium nitrate

Conditions

Conditions	Yield
at 100℃;

...Expand

: 928-45-0
butyl nitrate

: 122-39-4
diphenylamine

: 382165-80-2
N-nitrosodiphenylamine

Conditions

Conditions	Yield
at 100℃;

: 928-45-0
butyl nitrate

: 62-53-3
aniline

A: 1126-78-9
N-(n-butyl)aniline

B: 542-15-4
anilinium nitrate

Conditions

Conditions	Yield
at 100℃;

...Expand

: 928-45-0
butyl nitrate

: 108-88-3
toluene

A: 99-99-0
1-methyl-4-nitrobenzene

B: 88-72-2
1-methyl-2-nitrobenzene

Conditions

Conditions	Yield
With sulfuric acid at 40 - 60℃;

...Expand

: 928-45-0
butyl nitrate

: 95-53-4
o-toluidine

: 32954-52-2
o-toluidine nitrate

Conditions

Conditions	Yield
at 100℃;

: 928-45-0
butyl nitrate

: 76-05-1
trifluoroacetic acid

: 367-64-6
n-butyl trifluoroacetate

: 502-49-8
cycloactanone

: 928-45-0
butyl nitrate

A: 13154-28-4
2-nitrocyclooctanone

B: 82781-91-7
butyl 8-nitrooctanoate

...Expand

: 928-45-0
butyl nitrate

: 71-36-3
butan-1-ol

Conditions

Conditions	Yield
With dihexylamine at 60℃; Rate constant;

: 928-45-0
butyl nitrate

: 7664-93-9
sulfuric acid

: 108-88-3
toluene

: 99-99-0
1-methyl-4-nitrobenzene

...Expand

Butyl Nitrate Chemical Properties

Chemistry informtion about Butyl Nitrate(CAS NO.928-45-0) is:
IUPAC Name: butyl nitrate
Synonyms: N-Butyl Nitrate ; 1-Butylnitrate ; Butylnitrate ; N-C₄H₉ONO₂ ; Nitric Acid, Butyl Ester ; Nitricacid,Butylester ; Nitricacidbutylester ; 1-Nitrooxybutane
Molecular Weight: 119.11916 [g/mol]
Molecular Formula: C₄H₉NO₃
XLogP3: 2.1
H-Bond Donor: 0
H-Bond Acceptor: 3
EINECS: 213-172-9
Canonical SMILES: CCCCO[N+](=O)[O-]
InChI: InChI=1S/C4H9NO3/c1-2-3-4-8-5(6)7/h2-4H2,1H3
InChIKey: QQHZPQUHCAKSOL-UHFFFAOYSA-N
Density: 1.047 g/cm³
Flash Point: 49.9 °C
Enthalpy of Vaporization: 35.74 kJ/mol
Boiling Point: 135.3 °C at 760 mmHg
Vapour Pressure: 9.6 mmHg at 25°C
Product Categories: Alkylnitrate ; Intermediate ; Miscellaneous Reagents
Following is the molecular structure of Butyl Nitrate(CAS NO.928-45-0) is:

Butyl Nitrate Uses

Despite its health risks, Butyl Nitrate(CAS NO.928-45-0) is used as an inhalant.

Butyl Nitrate Safety Profile

An explosive. Reacts explosively with Lewis acids (e.g., boron trifluoride; aluminum chloride; etc.). When heated to decomposition it emits toxic fumes of NO_x. See also NITRATES.
RIDADR: 1992
HazardClass: 3.2
PackingGroup: III

Butyl Nitrate Specification

Butyl Nitrate(CAS NO.928-45-0) is colourless oil with a flammable chemical compound.

Product Name

N-BUTYL NITRATE

Synthetic route

Butyl Nitrate Chemical Properties

Butyl Nitrate Uses

Butyl Nitrate Safety Profile

Butyl Nitrate Specification

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