CADMIUM CHLORIDE supplier | CasNO.10108-64-2

Name
Cadmium chloride
EINECS 233-296-7
CAS No. 10108-64-2
Article Data205
CAS DataBase
Density 4.047 g/cm³
Solubility 1400 g/L (20 °C) in water
Melting Point 568 °C
Formula CdCl₂
Boiling Point 967 °C
Molecular Weight 183.316
Flash Point 960°C
Transport Information UN 3082 9/PG 3
Appearance white crystalline solid
Safety 53-45-61-60-36/37-28
Risk Codes 45-46-60-61-25-26-48/23/25-51/53-50/53-48/20/22-23-22
Molecular Structure
Hazard Symbols T, N, T+
Synonyms Cadmiumchloride;Cadmium dichloride;Dichlorocadmium;NSC 51148;Cadmium chloride(CdCl2);
PSA 0.00000
LogP 1.37650

Synthetic route

: 7791-25-5
sulfuryl dichloride

: cadmium(II) sulphide

: 10108-64-2
cadmium(II) chloride

Conditions

Conditions	Yield
In neat (no solvent) 250°C (4 h/CO2 stream);;	96%
In neat (no solvent) 250°C (4 h/CO2 stream);;	96%
In neat (no solvent) 250°C (16 h/sealed tube);;	94%

: 7791-25-5
sulfuryl dichloride

: cadmium(II) sulphide

A: 7446-09-5
sulfur dioxide

B: 7704-34-9
sulfur

C: 10108-64-2
cadmium(II) chloride

Conditions

Conditions	Yield
3-4 h at 350°C in a sealed bombe tube;	A n/a B n/a C 95%
3-4 h at 350°C in a sealed bombe tube;	A n/a B n/a C 95%
16 h at 250°C in a sealed bombe tube;	A n/a B n/a C 94%

...Expand

: (C2F5)2Cd*2(CH2)4SO2

: 10025-91-9
antimony(III) chloride

A: 34837-31-5
Sb(C2F5)3

B: 10108-64-2
cadmium(II) chloride

Conditions

Conditions	Yield
In sulfolane N2 atm.; stirring (4-5 d, 60°C); distn. (vac., 50°C); elem. anal.;	A 94% B n/a

...Expand

: Cd(n-C4F9)2

: 10025-91-9
antimony(III) chloride

A: 194549-83-2
Sb(C4F9)3

B: 10108-64-2
cadmium(II) chloride

Conditions

Conditions	Yield
In sulfolane N2 atm.; stirring (4-5 d, 60°C); distn. (vac., 80°C); elem. anal.;	A 76% B n/a

...Expand

: cadmium(II) selenide

: 7791-25-5
sulfuryl dichloride

A: 10026-03-6
selenium tetrachloride

B: 10025-68-0
diselenium dichloride

C: 10108-64-2
cadmium(II) chloride

Conditions

Conditions	Yield
SO2Cl2 vapor diluted with CO2, 2.5h at 280-290°C;	A n/a B n/a C 71%
SO2Cl2 vapor diluted with CO2, 2.5h at 280-290°C;	A n/a B n/a C 71%
SO2Cl2 vapor diluted with CO2, 5h in room temp., then short heating at 180-190°C;	A n/a B n/a C 60%
SO2Cl2 vapor diluted with CO2, 5h in room temp., then short heating at 180-190°C;	A n/a B n/a C 60%

...Expand

: 10049-04-4, 25052-55-5
chlorine dioxide

: 7440-43-9
cadmium

A: cadmium chlorite

B: cadmium chlorate

C: cadmium(II) oxide

D: 10108-64-2
cadmium(II) chloride

Conditions

Conditions	Yield
In water The formed CdCl2 behaves as catalyst in the reaction.;	A 66% B 7% C 19% D 8%
In water The formed CdCl2 behaves as catalyst in the reaction.;	A 66% B 7% C 19% D 8%

...Expand

: 12107-04-9
dicarbonyl(cyclopentadienyl)iron(II) chloride

: 7440-43-9
cadmium

A: 38117-54-3
cyclopentadienyl iron(II) dicarbonyl dimer

B: (dicarbonylcyclopentadienyliron)cadmium chloride

C: 10108-64-2
cadmium(II) chloride

Conditions

Conditions	Yield
In tetrahydrofuran (Ar); at 20°C; sepd., evapd., treated with Et2O, sepd., concd. (vac.), pentane added at-5°C, washed (cold pentane), dried (vac.); elem. anal.;	A 14% B 53.6% C 20.6%

...Expand

: 10025-91-9
antimony(III) chloride

: 104698-09-1
Cd(C6F13)2

A: Sb(C6F13)3

B: 10108-64-2
cadmium(II) chloride

Conditions

Conditions	Yield
In acetonitrile N2 atm.; stirring (4-5 d, 60°C), pptn.; filtn., washing (CH3CN), extraction (pentane), distn.; elem. anal.;	A 52% B n/a

...Expand

: 15989-98-7
bis(pentafluorophenyl)cadmium

: 10025-82-8
indium(III) chloride

A: In(3+)*3C6F5(1-)*CH3CN=In(C6F5)3*CH3CN

B: 10108-64-2
cadmium(II) chloride

Conditions

Conditions	Yield
In acetonitrile byproducts: C6F5H; N2 atm.; heating (-30 to 0°C), stirring (24 h, room temp.), refluxing; evapn., extraction (n-pentane), evapn.; elem. anal.;	A 42.7% B n/a

...Expand

: 15989-98-7
bis(pentafluorophenyl)cadmium

: 10025-82-8
indium(III) chloride

A: In(3+)*3C6F5(1-)*CH3OCH2CH2OCH3=In(C6F5)3*CH3OCH2CH2OCH3

B: 10108-64-2
cadmium(II) chloride

Conditions

Conditions	Yield
In further solvent(s) byproducts: C6F5H; N2 atm.; glyme, heating (-30 to 0°C), stirring (24 h, room temp.), refluxing; evapn., extraction (n-pentane), evapn.;	A 34.7% B n/a

...Expand

: (Cd(μ-L)Cl(H2O)2*H2O)n

A: cadmium(II) oxide

B: 10108-64-2
cadmium(II) chloride

Conditions

Conditions	Yield
In neat (no solvent, solid phase) dehydrn. between 60-180 °C, pyrolysis in the range of 220-800 °C;	A 18.53% B n/a

: Cd(2+)*2C2H5C5H4N*2Cl(1-)=Cd(C2H5C5H4N)2Cl2

: 10108-64-2
cadmium(II) chloride

Conditions

Conditions	Yield
In neat (no solvent) thermal decomposition;

: cadmium(II) chloride dihydrate

: 10108-64-2
cadmium(II) chloride

Conditions

Conditions	Yield
With triethyl orthoformate refluxing for several hours in triethyl orthoformate;
In neat (no solvent) dehydratation (433K, vac.);
In neat (no solvent) at 200°C for 12 h;

: cadmium subchloride

: 7732-18-5
water

A: 10108-64-2
cadmium(II) chloride

B: 7440-43-9
cadmium

Conditions

Conditions	Yield
decomposition in presence of water;;
decomposition in presence of water;;

...Expand

: 2696-92-6
nitrosylchloride

: 7440-43-9
cadmium

: 10108-64-2
cadmium(II) chloride

Conditions

Conditions	Yield
In not given heating for several days;;

: ammonium carbonate

: 7647-01-0
hydrogenchloride

: cadmium(II) sulphide

: 10108-64-2
cadmium(II) chloride

Conditions

Conditions	Yield
dissolving CdS in hot concd. HCl; filtration; precipitation with (NH4)2CO3; glowing the precipitate; dissolving the residue in HCl;;
dissolving CdS in hot concd. HCl; filtration; precipitation with (NH4)2CO3; glowing the precipitate; dissolving the residue in HCl;;

...Expand

: 14700-96-0, 14835-24-6, 15723-23-6, 16547-50-5, 16885-04-4, 16887-00-6, 16904-11-3, 16904-12-4, 16999-02-3, 20337-89-7, 20499-73-4, 22537-15-1, 22537-27-5, 22541-73-7, 22541-74-8, 24203-47-2, 33944-49-9, 34937-26-3, 37352-90-2
clorine

: cadmium(II) sulphide

A: 7704-34-9
sulfur

B: 10108-64-2
cadmium(II) chloride

C: 7440-43-9
cadmium

Conditions

Conditions	Yield
slow heating of CdS containing Cl; 1/2 h at 800°C or 1000°C;
slow heating of CdS containing Cl; 1/2 h at 800°C or 1000°C;

...Expand

: 7719-09-7
thionyl chloride

: cadmium(II) sulphide

A: 10025-67-9
disulfur dichloride

B: 7446-09-5
sulfur dioxide

C: 10108-64-2
cadmium(II) chloride

Conditions

Conditions	Yield
In neat (no solvent) reaction of CdS with SOCl2 in a sealed tube at 200 °C;;
In neat (no solvent) reaction of CdS with SOCl2 in a sealed tube at 200 °C;;

...Expand

: cadmium(II) sulphide

: 10025-68-0
diselenium dichloride

A: 7782-49-2
selenium

B: 7704-34-9
sulfur

C: 10108-64-2
cadmium(II) chloride

...Expand

: 75-44-5
phosgene

: cadmium(II) sulphide

A: 463-58-1
carbon oxide sulfide

B: 10108-64-2
cadmium(II) chloride

Conditions

Conditions	Yield
reaction of CdS with COCl2 at 400 °C;;
400°C;
reaction of CdS with COCl2 at 400 °C;;

...Expand

: 75-44-5
phosgene

: cadmium(II) sulphide

: 10108-64-2
cadmium(II) chloride

Conditions

Conditions	Yield
In neat (no solvent) byproducts: COS; passing stream of COCl2 over CdS at 400 °C;;

: 10025-67-9
disulfur dichloride

: cadmium(II) sulphide

A: 557774-20-6
thiozone

B: 10108-64-2
cadmium(II) chloride

Conditions

Conditions	Yield
In benzene addition of dry CdS to a solution of S2Cl2 in benzene; decantation from green-black lumps; heating solution at 70 °C;; heterogenous product mixture obtained;;
In toluene addition of dry CdS to a solution of S2Cl2 in toluene; decantation from green-black lumps; heating solution at 70 °C;; heterogenous product mixture obtained;;
In carbon disulfide addition of dry CdS to a solution of S2Cl2 in CS2; decantation from green-black lumps; heating solution at 70 °C;; heterogenous product mixture obtained;;

...Expand

: 10025-67-9
disulfur dichloride

: cadmium(II) sulphide

: sulfur

B: 10108-64-2
cadmium(II) chloride

Conditions

Conditions	Yield
In toluene shaking;;
In toluene shaking;;

...Expand

: 56-23-5
tetrachloromethane

: cadmium(II) sulphide

A: 75-15-0
carbon disulfide

B: 10108-64-2
cadmium(II) chloride

Conditions

Conditions	Yield
In neat (no solvent) Kinetics; reaction at 200-500°C;; enthalpy of reaction;;

...Expand

: 7647-01-0
hydrogenchloride

: cadmium(II) sulphide

A: 7664-93-9
sulfuric acid

B: 7790-99-0
Iodine monochloride

C: 10108-64-2
cadmium(II) chloride

Conditions

Conditions	Yield
With potassium iodate In not given byproducts: S, KCl, H2O; oxidation with KIO3 in presence of HCl;;
With KIO3 In not given byproducts: S, KCl, H2O; oxidation with KIO3 in presence of HCl;;

...Expand

: 7647-01-0
hydrogenchloride

: cadmium(II) sulphide

: 10108-64-2
cadmium(II) chloride

Conditions

Conditions	Yield
In neat (no solvent) passing gaseous HCl over CdS;;
In neat (no solvent) passing gaseous HCl over CdS;;

: 7647-01-0
hydrogenchloride

: cadmium(II) sulphide

A: 7783-06-4
hydrogen sulfide

B: 10108-64-2
cadmium(II) chloride

Conditions

Conditions	Yield
In water equil. reaction at 20 and 80°C; amt. of H2S depends on the temp. and the presence of NaCl;
In neat (no solvent) 232-352°C; heterogenous equil.;
In neat (no solvent) 232-352°C; heterogenous equil.;

...Expand

: cadmium telluride

: 7791-25-5
sulfuryl dichloride

A: 10025-71-5
tellurium dichloride

B: 10108-64-2
cadmium(II) chloride

Conditions

Conditions	Yield
at room temp.; SO2Cl2 vapor dild. with CO2;

...Expand

: cadmium telluride

: 7791-25-5
sulfuryl dichloride

A: 10025-71-5
tellurium dichloride

B: 10026-07-0
tellurium tetrachloride

C: 10108-64-2
cadmium(II) chloride

Conditions

Conditions	Yield
420-450°C; SO2Cl2 vapor dild. with CO2;

...Expand

: 108-99-6
3-Methylpyridine

: 10108-64-2
cadmium(II) chloride

: 14321-54-1
Cd(β-picoline)2I2

Conditions

Conditions	Yield
In water ratio Cd/picoline 1:5; elem. anal.;	100%
In neat (no solvent) excess of picoline; elem. anal.;	92.5%
In ethanol; water treatment of aq. soln. CdCl2 with picoline in EtOH (ratio Cd/picoline 1:5); elem. anal.;	67%
In water; acetone treatment of aq. soln. CdCl2 with picoline in acetone (ratio Cd/picoline 1:5); elem. anal.;	58.9%

: cadmium(II) hydroxide

: 10108-64-2
cadmium(II) chloride

cadmium hydroxide chloride: cadmium hydroxide chloride

Conditions

Conditions	Yield
In not given 2 d;	100%

: 15307-79-6
diclofenac sodium

: 10108-64-2
cadmium(II) chloride

: 149753-43-5
{Cd(C6H3Cl2NHC6H4CH2COO)2(H2O)}

Conditions

Conditions	Yield
With H2O; KOH In water byproducts: NaCl; mixing aq. soln. of the components, adjusting to pH 5.5-7.5 with KOH and stirring at room temp. for 4-6 h; filtn., washing with water, drying over silica gel (vac.) and over P4O10 at 90°C (vac.);	100%

: 1,2-dimethoxyethanebis(pentadeuterocyclopentadienyl)ytterbium(II)

: 10108-64-2
cadmium(II) chloride

A: chlorobis(cyclopentadienyl)ytterbium(III)-tetrahydrofuran(2:1)

B: 7440-43-9
cadmium

Conditions

Conditions	Yield
In tetrahydrofuran N2-atmosphere; stirring Yb-complex with 0.5 equiv. of halide (room temp., 16 h); filtration, washing (THF), evapn. (vac.), drying (vac.);	A 80% B 100%

...Expand

: 6389-79-3
methyl methylphenylphosphinate

: 10108-64-2
cadmium(II) chloride

: poly(cadmium methylphenylphosphinate)

Conditions

Conditions	Yield
In further solvent(s) byproducts: MeCl; slow heating in neat Ph(Me)P(O)OMe until complete pptn.; particle size and polymerization degree depending on heating rate;	100%

: 5,20-diphenyl-10,15-bis(p-tolyl)-21-vacataporphyrin

: 10108-64-2
cadmium(II) chloride

: Cd(5,20-diphenyl-10,15-bis(p-tolyl)-21-vacataporphyrin(1-))Cl

Conditions

Conditions	Yield
With triethylamine In chloroform; acetonitrile CdCl2 in MeCN was refluxed for 15 min, soln. vacataporphyrin in CHCl3 and Et3N were added and refluxed for 20 min; solvent was evapd., residue was mixed with CH2Cl2 and filtered, solvent was evapd.;	100%

: 7446-07-3
tellurium(IV) oxide

: cadmium(II) oxide

: 10108-64-2
cadmium(II) chloride

: Cd7Cl8(Te7O17)

Conditions

Conditions	Yield
In neat (no solvent, solid phase) at 720°C for 6 d;	99%
With Er2O3 In neat (no solvent, solid phase) ground, pressed, sealed, heated at 720°C for 6 d; cooled to 300°C at 4°C/h;

...Expand

: 7446-07-3
tellurium(IV) oxide

: cadmium(II) oxide

: 10108-64-2
cadmium(II) chloride

: [Cd2(Te6O13)][Cd2Cl6]

Conditions

Conditions	Yield
In neat (no solvent, solid phase) at 670°C for 6 d;	99%

...Expand

: imino-bis(diisopropylphosphine selenide)

: 10108-64-2
cadmium(II) chloride

: 234766-51-9
cadmium(II) tetraisopropyldiselenoimidodiphosphinate

Conditions

Conditions	Yield
With sodium methoxide In methanol byproducts: NaCl; sodium methoxide added to a soln. of P compd., stirred for 10 min at room temp., metal salt added, stirred for 2-3 h; ppt. filtered, dried (vac.), recrystd. (CH2Cl2/methanol); elem. anal.;	99%
With sodium methylate In methanol for 3h; Inert atmosphere; Schlenk technique; Heating;	77%

: 91006-19-8
N,N'-ethylenebis(pyrrolidine-2-thione)

: 10108-64-2
cadmium(II) chloride

: CdCl2(N,N'-ethylenebis(pyrrolidine-2-thione))

Conditions

Conditions	Yield
In ethanol pptn. on mixing equimolar amts.; elem. anal.;	99%

: 6,11,16,21-tetraphenyl-m-benziporphyrin

: 10108-64-2
cadmium(II) chloride

: chlorocadmium(II) 6,11,16,21-tetraphenyl-m-benziporphyrin

Conditions

Conditions	Yield
In chloroform; acetonitrile a mixt. of the ligand and anhyd. CdCl2 was refluxed in 1:1 CH2Cl2-MeCN for ca. 2 h, the reaction was monitored by UV-vis spectroscopy; filtd. and evapd. to dryness;	99%

: 5,20-diphenyl-10,15-di-p-tolyl-2-oxa-3-(2'-pyrrolyl)-21-carbaporphyrin

: 10108-64-2
cadmium(II) chloride

: 5,20-diphenyl-10,15-di-p-tolyl-2-oxa-3-(2'-pyrrolyl)-21-carbaporphyrinato chlorocadmium(II)

Conditions

Conditions	Yield
With triethylamine In chloroform dissolving ligand in CHCl3 with NEt3, addn. of metal salt, reflux for 30min; evapn., dissolving in CH2Cl2, washing with water, drying org. layer withNa2SO4, filtration, evapn., recrystn. (CHCl3/hexane);	99%

: 61081-36-5
8-quinolinesulfinic acid sodium salt

: 10108-64-2
cadmium(II) chloride

: C18H12CdN2O4S2*2H2O

Conditions

Conditions	Yield
In water stirring (pH=4-6), pptn., digestion (water bath, 30 min), cooling; filtration, washing (water, ether), drying (vac.); elem. anal.;	99%

: 6,11,16,21-tetraphenyl-22-acetoxy-m-benziporphyrin

: 10108-64-2
cadmium(II) chloride

: chlorocadmium(II) 6,11,16,21-tetraphenyl-22-acetoxy-m-benziporphyrin

Conditions

Conditions	Yield
In chloroform; acetonitrile a mixt. in CHCl3 and CH3CN was refluxed under N2 for 30 min; evapd. to dryness, dissolved in min CH2Cl2, filtered, the solvent was removed;	99%

: 6,6,21,21-tetraphenyl-11,16-bis(4-nitrophenyl)-meta-benziporphodimethene

: 10108-64-2
cadmium(II) chloride

: 689262-16-6
chlorocadmium(II) 11,16-bis(4-nitrophenyl)-6,6,21,21-tetraphenyl-meta-benziporphodimethene

Conditions

Conditions	Yield
In chloroform; acetonitrile a mixt. of the ligand and anhyd. CdCl2 was refluxed in 1:1 CH2Cl2-MeCN for ca. 2 h, the reaction was monitored by UV-vis spectroscopy; filtd. and evapd. to dryness;	99%

: 5,10,15,20-tetraphenyl-2-thia-21-carbaporphyrin

: 10108-64-2
cadmium(II) chloride

: 5,10,15,20-tetraphenyl-2-thia-21-carbaporphyrinato chlorocadmium(II)

Conditions

Conditions	Yield
In chloroform; acetonitrile under N2 atm. soln. CdCl2 and ligand in CHCl3-MeCN was refluxed for 1 h; solvents were removed in vacuo, residue was dissolved in dry CH2Cl2, filtered and evapd.;	99%

: 902138-01-6
2-[bis(2-phenylethyl)thiophosphorylhydroxymethyl]-1-ethylimidazole

: 10108-64-2
cadmium(II) chloride

: (2-[bis(2-phenylethyl)thiophosphorylhydroxymethyl]-1-ethylimidazole)dichlorocadmium

Conditions

Conditions	Yield
In acetone org. ligand and CdCl2 mixed in anhyd. acetone (20-25°C); kept (8 h); pptd. with ether; filtered; washed with acetone-ether mixt. (1:1); dried (vac.); elem. anal.;	99%

: 1636184-62-7
1,4-bis((1H-pyrrol-2-yl)methylene)thiosemicarbazide

: 10108-64-2
cadmium(II) chloride

: 1636184-58-1
Cd(1,4-bis((1H-pyrrol-2-yl)methylene)thiosemicarbazide)Cl2

Conditions

Conditions	Yield
In methanol Reflux;	98.29%

: 1636184-62-7
1,4-bis((1H-pyrrol-2-yl)methylene)thiosemicarbazide

: 10108-64-2
cadmium(II) chloride

: Cd(1,4-bis((1H-pyrrol-2-yl)methylene)thiosemicarbazide)2Cl2

Conditions

Conditions	Yield
In methanol Reflux;	98.27%

: 63901-49-5
3-(vinylthio)-1,2,4-triazole

: 10108-64-2
cadmium(II) chloride

: Cd(2+)*2Cl(1-)*C4H5N3S=CdCl2(C4H5N3S)

Conditions

Conditions	Yield
In not given mixing calcd. amts. of ligand and metal salt dissolved in solvent (alc.or alc. and ether); ppt. formed was filtered off, washed, dried (room temp., vac.); elem. anal.;	98%

: 534-13-4
N,N-dimethylthiourea

: 10108-64-2
cadmium(II) chloride

: 17048-50-9
cadmium(II) Cl2 bis(N,N'-dimetylthiourea)

Conditions

Conditions	Yield
In ethanol mixed in hot ethanol, stirred and refluxed for 2 h; filtered hot, crystd. at room temp. for 24 h, filtered, washed twice (ethanol), dried (vac.), dried (vac.), elem. anal.;	98%

: 902138-02-7
2-[bis(2-phenylethyl)thiophosphorylhydroxymethyl]-1-vinylimidazole

: 10108-64-2
cadmium(II) chloride

: (2-[bis(2-phenylethyl)thiophosphorylhydroxymethyl]-1-vinylimidazole)dichlorocadmium

Conditions

Conditions	Yield
In acetone org. ligand and CdCl2 mixed in anhyd. acetone (20-25°C); kept (8 h); pptd. with ether; filtered; washed with acetone-ether mixt. (1:1); dried (vac.); elem. anal.;	98%

: 820247-53-8
1-(1-silatranylmethyl)-3,5-dimethyl-1H-pyrazole

: 10108-64-2
cadmium(II) chloride

: 1262109-89-6
(1-(1-silatranylmethyl)-3,5-dimethyl-1H-pyrazole)*CdCl2

Conditions

Conditions	Yield
In not given to soln. of CdCl2 in C6H6, CHCl3 or MeCN was added soln. of silatrane inC6H6, CHCl3 or MeCN, stirred at 70-80°C for 6-10 h; filtered, washed with MeCN, elem. anal.;	98%

: 1074-52-8
ammonium phenyldithiocarbamate

: 19779-48-7
ammonium N-ethyl-N-phenyldithiocarbamate

: 10108-64-2
cadmium(II) chloride

: Cd(2+)*C7H6NS2(1-)*C9H10NS2(1-)

Conditions

Conditions	Yield
In water at 20℃; for 1h;	98%

...Expand

: 290312-25-3, 676593-94-5
pyridine-2-carboxamide thiosemicarbazide

: 7732-18-5
water

: 10108-64-2
cadmium(II) chloride

: [(2-pydidineformamide thiosemicarbazone)Cl2]*0.25H2O

Conditions

Conditions	Yield
In ethanol soln. of Cd salt mixed with soln. of ligand, stirred under reflux for 2 h; filtered, washed with anhydrous ether to apparent dryness, placed on warm plate at 35°C, elem. anal.;	97.4%

...Expand

: 2764-84-3
1-vinylbenzotriazole

: 10108-64-2
cadmium(II) chloride

: Cd(1-vinylbenzotriazole)Cl2

Conditions

Conditions	Yield
In not given org. solvent (alcohol, acetone, ether or dioxane), stirring (room temp., 0.25 - 24 h); washing, drying (vacuum); elem. anal.;	97%

: 64317-97-1
cyclenphosphorane

: 10108-64-2
cadmium(II) chloride

: 124461-97-8
cyclenphosphorane*CdCl2

Conditions

Conditions	Yield
In tetrahydrofuran under N2, mixt. of the phosphorane and CdCl2 in THF stirred for 12 h; filtration, washed (THF), pumped dry; elem. anal.;	97%

: 148-18-5
sodium N,N-diethyldithiocarbamate

: 10108-64-2
cadmium(II) chloride

: 14239-68-0
cadmium(II) diethyldithiocarbamate

Conditions

Conditions	Yield
In neat (no solvent, solid phase) byproducts: NaCl; placing of CdCl2 and NaS2CNEt2 in 1:2 ratio to the reactor; sealing, vibrating for 60 min; sublimating in vac. at 180-230°C; crystn.; elem. anal.;	96.6%
In water byproducts: NaCl; pptn. of complex from soln. at room temp., filtration while hot, drying (80°C, vac.); recrystn. (benzene); (1)H- and (13)C-NMR;
In water byproducts: NaCl; ZnCl2, the thiocarbamate in water, immediately pptn.; filtered hot to remove NaCl and any excess of unreacted thiocarbamate, dried (vac. at 80°C), recrystn. (boiling benzene);
In water solution of CdCl2 added to stirred solution of the ligand; filtered, dried, recrystd. from chloroform;

: potassium dihydrobis(pyrazol-1-yl)borate

: 10108-64-2
cadmium(II) chloride

: bis{dihydrobis(1-pyrazolyl)borato}cadmium(II)

Conditions

Conditions	Yield
In tetrahydrofuran; water byproducts: KCl; React. of 2 equiv of K-compd. in THF with CdCl2 in H2O; the 2 solns. are combined, along with addnl. H2O, and the mixt. is shaken.; Extn. with CH2Cl2, sepn. of CH2Cl2 layer from mixt., removal of solvent, mass spectroscopy, elem. anal.;	96%

CADMIUM CHLORIDE Chemical Properties

Molecular Structure of CADMIUM CHLORIDE(10108-64-2):

IUPAC Name: dichlorocadmium
Molecular Formula:CdCl₂
Molecular Weight:183.317000 g/mol
Appearance:milky White free flowing crystalline powder
Melting Point:568 °C(lit.)
Boiling Point:960 °C
Density:4.047 g/cm³
Solubility:soluble in acetone, alcohol, insoluble in ether
Water Solubility:100 g/100 mL (0 °C), 135 g/100 mL (20 °C), 147 g/100 mL (100 °C)
Sensitive:Hygroscopic
Vapor Density:6.3 (vs air)
Vapor Pressure:10 mm Hg (656 °C)
EINECS:233-296-7
Synonyms of CADMIUM CHLORIDE(10108-64-2):
Caddy;Cadmium chloride (CdCl2);Cadmium turf fungicide;cadmiumchloride(cdcl2);cadmiumchloride,anhydrous;CdCl2;Dichlorocadmium;Kadmiumchlorid
Categories of CADMIUM CHLORIDE(10108-64-2):
Inorganics;Analytical Reagents for General Use;C-D, Puriss p.a. ACS;Puriss p.a. ACS;Cadmium Salts;CadmiumMetal and Ceramic Science;Catalysis and Inorganic Chemistry;Chemical Synthesis;Crystal Grade Inorganics;Salts;Metal and Ceramic Science

CADMIUM CHLORIDE Uses

CADMIUM CHLORIDE(10108-64-2) is used for the preparation of cadmium sulfide. It is also used for photocopying, dyeing and electroplating.

CADMIUM CHLORIDE Production

CADMIUM CHLORIDE(10108-64-2) can be made by the action of anhydrous chlorine or hydrogen chloride gas on heated cadmium metal.
Cd(s) + 2 HCl(g) → CdCl₂(s) + H₂(g)

CADMIUM CHLORIDE Toxicity Data With Reference

1.	dni-hmn:hla 250 µmol/L	MUREAV Mutation Research. 92 (1982),427.
2.	cyt-ofs-mul 630 µg/L/4 W-C	BECTA6 Bulletin of Environmental Contamination and Toxicology. 36 (1986),199.
3.	orl-wmn LDLo:3 g/kg:BPR,GIT	BMJOAE British Medical Journal. 292 (1986),1559.
4.	orl-rat LD50:88 mg/kg	AFDOAQ Association of Food and Drug Officials of the United States, Quarterly Bulletin. 15 (1951),122.
5.	ipr-rat LD50:1800 µg/kg	EVHPAZ EHP, Environmental Health Perspectives. Subseries of DHEW Publications. 28 (1979),89.
6.	orl-mus LD50:60 mg/kg	APTOA6 Acta Pharmacologica et Toxicologica. 48 (1981),108.
7.	ihl-mus LC50:2300 mg/m3	NTIS** National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) PB158-508 .
8.	ipr-mus LD50:9300 µg/kg	NEZAAQ Nippon Eiseigaku Zasshi. Japanese Journal of Hygiene. 32 (1977),472.
9.	scu-mus LD50:3200 µg/kg	APTOA6 Acta Pharmacologica et Toxicologica. 48 (1981),108.
10.	ivn-mus LD50:3500 µg/kg

CADMIUM CHLORIDE Consensus Reports

NTP 10th Report on Carcinogens. IARC Cancer Review: Group 1 IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 58 , 1993,p. 119.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Sufficient Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 2 , 1973,p. 74.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Sufficient Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 11 , 1976,p. 39.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Human Sufficient Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 58 , 1993,p. 119.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; IARC Cancer Review: Animal Sufficient Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 58 , 1993,p. 119.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; EPA Genetic Toxicology Program. Cadmium and its compounds are on the Community Right-To-Know List. Reported in EPA TSCA Inventory.

CADMIUM CHLORIDE Safety Profile

The safety information of CADMIUM CHLORIDE(10108-64-2) is as follows:
Hazard Codes:T,T+ ,N
Risk Statements:45-46-60-61-25-26-48/23/25-51/53-50/53-48/20/22-23-22
45:May cause cancer
46:May cause heritable genetic damage
61:May cause harm to the unborn child
25:Toxic if swallowed
26:Very toxic by inhalation
48/23/25:Toxic : danger of serious damage to health by prolonged exposure through inhalation and if swallowed
51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
48/20/22:Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed
22:Harmful if swallowed
23:Toxic by inhalation
Safety Statements:53-45-61-60-36/37-28
53:Avoid exposure - obtain special instructions before use
45:In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible)
60:This material and its container must be disposed of as hazardous waste
61:Avoid release to the environment. Refer to special instructions/safety data sheets
36/37:Wear suitable protective clothing and gloves
28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer)
RIDADR:UN 3082 9/PG 3
WGK Germany:3
RTECS:EV0175000
F:3-9-23
HazardClass:6.1
PackingGroup:III
Confirmed human carcinogen with experimental carcinogenic and tumorigenic data. Poison by ingestion, inhalation, skin contact, intraperitoneal, subcutaneous, intravenous, and possibly other routes. Human systemic effects by ingestion: blood pressure, acute pulmonary edema, hypermotility, diarrhea. Experimental teratogenic and reproductive effects. Human mutation data reported. Reacts violently with BrF₃ and K. When heated to decomposition it emits very toxic fumes of Cd and Cl⁻. See also CADMIUM COMPOUNDS and CHLORIDES.

CADMIUM CHLORIDE Standards and Recommendations

OSHA PEL: TWA 5 μg(Cd)/m³
ACGIH TLV: TWA 0.002 mg(Cd)/m³ (respirable dust), Suspected Human Carcinogen); BEI: 5 μg/g creatinine in urine; 5 μg/L in blood
DFG MAK: Animal Carcinogen, Suspected Human Carcinogen
NIOSH REL: (Cadmium) Reduce to lowest feasible level

CADMIUM CHLORIDE Specification

First aid measures of CADMIUM CHLORIDE(10108-64-2):
Eyes:Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin Get medical aid immediately. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:Get medical aid immediately. Wash mouth out with water.
Inhalation:Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.

Storage Information of CADMIUM CHLORIDE(10108-64-2):
Keep away from sources of ignition. Store in a cool, dry place. Do not store in direct sunlight. Store in a tightly closed container. Keep under a nitrogen blanket.

Product Name

Cadmium chloride

Synthetic route

CADMIUM CHLORIDE Chemical Properties

CADMIUM CHLORIDE Uses

CADMIUM CHLORIDE Production

CADMIUM CHLORIDE Toxicity Data With Reference

CADMIUM CHLORIDE Consensus Reports

CADMIUM CHLORIDE Safety Profile

CADMIUM CHLORIDE Standards and Recommendations

CADMIUM CHLORIDE Specification

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