Conditions | Yield |
---|---|
In acetonitrile Electrolysis; Ag-anode;; | A n/a B 100% |
In acetonitrile Electrolysis; Ag-anode;; | A n/a B 100% |
In neat (no solvent) Electrolysis; Cl2 is formed on anode, Co on cathode;; | |
In neat (no solvent) decompn. of CoCl2 at 600 ° C; | |
In neat (no solvent) Electrolysis; Cl2 is formed on anode, Co on cathode;; |
{Co(NH3)6}(2+)*SO4(2-)={Co(NH3)6}SO4
cobalt
Conditions | Yield |
---|---|
With hydrogen In ammonia pptn. of 100.0% metallic Co out of NH3-containing (Co(NH3)6)SO4-solution with H2 (50-75 atm) at 200°C after 2 h;; | 100% |
With H2 In ammonia aq. ammonia=NH3; pptn. of 100.0% metallic Co out of NH3-containing (Co(NH3)6)SO4-solution with H2 (50-75 atm) at 200°C after 2 h;; | 100% |
With hydrogen In ammonia pptn. of 95.5% metallic Co out of NH3-containing (Co(NH3)6)SO4-solution with H2 (50-75 atm) at 190°C after 2 h;; | 95.5% |
(η6-toluene)bis(η1-pentafluorophenyl)cobalt(II)
A
decafluorobiphenyl
B
cobalt
C
toluene
Conditions | Yield |
---|---|
In neat (no solvent, solid phase) pyrolysis at 150°C; | A 93% B n/a C 100% |
cobalt
Conditions | Yield |
---|---|
With NH4-sulfate In ammonia Electrolysis; electrolysis at pH=8-12 with 5-10 mg metal in the electrolyt;; | 99% |
With ammonium sulfate; triethanolamine In not given Electrolysis; electrolyte contains 5-10mg metal, triethanolamin and (NH4)2SO4;; | 99% |
With ammonium sulfate In not given Electrolysis; electolyte: 8% educt, 2.5% (NH4)2SO4, 3.7-4.5V, 2.5A/dm(2), pH=5.0;; | 85% |
dichloromethane
water
Dimethyl(phenyl)phosphine
cobalt(II) chloride
zinc
B
cobalt
C
zinc(II) chloride
Conditions | Yield |
---|---|
In dichloromethane | A n/a B 99% C n/a D n/a |
dichloromethane
tributylphosphine
water
cobalt(II) chloride
zinc
B
cobalt
C
zinc(II) chloride
Conditions | Yield |
---|---|
In dichloromethane | A n/a B 99% C n/a D n/a |
bis(salicylidene)cobalt(II)
cobalt
Conditions | Yield |
---|---|
With oleylamine; Ph3P In neat (no solvent) (Ar); Co complex was reacted with oleylamine; heated to 100°C for90 min; soln. was injected to Ph3P at 220°C; aged at 210° C for 45 min; cooled to room temp.; EtOH added; centrifuged; | 70% |
[((Co(CO)3)2)2(HCCC6H4C)2]
B
carbon dioxide
C
carbon monoxide
D
hydrogen
E
cobalt
Conditions | Yield |
---|---|
In solid byproducts: CH4; below 200°C, then graphitization (800°C, 6 h); | A 60% B n/a C n/a D n/a E n/a |
[(CC6H4CC((Co(CO)3)2)CCC6H4C(Co(CO)3))2]
B
carbon dioxide
C
carbon monoxide
D
hydrogen
E
cobalt
Conditions | Yield |
---|---|
In solid byproducts: CH4; below 200°C, then graphitization (800°C, 6 h); | A 60% B n/a C n/a D n/a E n/a |
Conditions | Yield |
---|---|
In toluene 60°C (overnight); filtering, evapn. (vac.), recrystn. (toluene); elem. anal.; | A 59% B n/a |
deuterium
B
cobalt
Conditions | Yield |
---|---|
In (2)H8-toluene 60°C (overnight); filtering, evapn. (vac.), recrystn. (toluene); | A 58% B n/a |
sodium tetraphenyl borate
cobalt(II) chloride
copper(ll) bromide
A
cobalt
B
copper
Conditions | Yield |
---|---|
In 1,2-dimethoxyethane Irradiation (UV/VIS); under Ar; mole ratios NaBPh4 : CoCl2 : CuBr2 = 4 : 1 : 1; irradn. (254 nm) for 10 h gave deposition of Co and Cu; | A 47% B 48% |
cobaltocene
tetraphenylborate anion
1,5-dicyclooctadiene
A
cobalt(II) oxide
B
(η5-cyclopentadienyl)-η4-cycloocta-1,5-dienecobalt(I)
E
cobalt
Conditions | Yield |
---|---|
With C5H5Na In tetrahydrofuran; water; pentane under N2, CoBr2*DME, NaCp, CoCp2 and COD mixed in THF in molar ratio of2/2.06/0.5/1.16 (CoCp2 added at -80°C prior to NaCp), warmed to room temp. during 3 h, evapd., pentane ext. passed through Al2O3/4% H2O and CuCl powder; concd., cooled to -80°C, CpCoCOD filtered off; CuCl washed with water, CoCp2(1+) pptd. with BPh4(1-) from aq. soln., filtered off; pentane-insol. residue treated with water, Co and CoO mixt. filtered, Co(2+) determined complexometrically; | A n/a B 45.3% C n/a D n/a E n/a |
With C5H5Na In tetrahydrofuran; water; pentane under N2, CoBr2*DME, NaCp, CoCp2 and COD mixed in THF in molar ratio of2/2.06/0.5/1.16 (CoCp2 added at -80°C after NaCp), warmed to room temp. during 3 h, evapd., pentane ext. passed through Al2O3/4% H2O andCuCl powder; concd., cooled to -80°C, CpCoCOD filtered off; CuCl washed with water, CoCp2(1+) pptd. with BPh4(1-) from aq. soln., filtered off; pentane-insol. residue treated with water, Co and CoO mixt. filtered, Co(2+) determined complexometrically; | A n/a B 43% C n/a D n/a E n/a |
With C5H5Na In tetrahydrofuran; water; pentane under N2, CoBr2*DME, NaCp, CoCp2 and COD mixed in THF in molar ratio of2/2.06/0.5/1.16 (CoCp2 added at 0°C prior to NaCp at -80°C), warmed to room temp. during 3 h, evapd., pentane ext. passed throughAl2O3/4% H2O and CuCl powder; concd., cooled to -80°C, CpCoCOD filtered off; CuCl washed with water, CoCp2(1+) pptd. with BPh4(1-) from aq. soln., filtered off; pentane-insol. residue treated with water, Co and CoO mixt. filtered, Co(2+) determined complexometrically; | A n/a B 37.5% C n/a D n/a E n/a |
With C5H5Na In tetrahydrofuran; water; pentane under N2, CoBr2*DME, NaCp, CoCp2 and COD mixed in THF in molar ratio of2/3/0.5/1.16, warmed to room temp. during 3 h, evapd., pentane ext. passed through Al2O3/4% H2O and CuCl powder; concd., cooled to -80°C, CpCoCOD filtered off; CuCl washed with water, CoCp2(1+) pptd. with BPh4(1-) from aq. soln., filtered off; pentane-insol. residue treated with water, Co and CoO mixt. filtered, Co(2+) determined complexometrically; | A n/a B 11.5% C n/a D n/a E n/a |
With C5H5Na In hexane; water; pentane under N2, CoBr2*DME, NaCp, CoCp2 and COD mixed in molar ratio of 2/3/0.5/1.16 in hexane at -80°C, warmed to room temp. during 3 h, evapd., pentane ext. passed through Al2O3/4% H2O and CuCl powder; concd., cooled to -80°C, CpCoCOD filtered off; CuCl washed with water, CoCp2(1+) pptd. with BPh4(1-) from aq. soln., filtered off; pentane-insol. residue treated with water, Co and CoO mixt. filtered, Co(2+) determined complexometrically; | A n/a B 8.6% C n/a D n/a E n/a |
Conditions | Yield |
---|---|
In neat (no solvent) byproducts: CO; in vac., thermic decompn.; | A 45% B n/a |
In neat (no solvent) byproducts: CO; in vac., thermic decompn.; | A 45% B n/a |
(η6-toluene)bis(η1-pentafluorophenyl)cobalt(II)
A
Pentafluorobenzene
B
decafluorobiphenyl
C
cobalt
Conditions | Yield |
---|---|
In toluene refluxing under N2 for 3 d; | A 135 % B 30% C n/a |
cobaltocene
tetraphenylborate anion
cyclopentadienyllithium
1,5-dicyclooctadiene
A
cobalt(II) oxide
B
(η5-cyclopentadienyl)-η4-cycloocta-1,5-dienecobalt(I)
E
cobalt
Conditions | Yield |
---|---|
In tetrahydrofuran; water; pentane under N2, CoBr2*DME, LiCp, CoCp2 and COD mixed in THF in molar ratio of2/2.06/0.5/1.16, warmed to room temp. during 3 h, evapd., pentane ext. passed through Al2O3/4% H2O and CuCl powder; concd., cooled to -80°C, CpCoCOD filtered off; CuCl washed with water, CoCp2(1+) pptd. with BPh4(1-) from aq. soln., filtered off; pentane-insol. residue treated with water, Co and CoO mixt. filtered, Co(2+) determined complexometrically; | A n/a B 18% C n/a D n/a E n/a |
Conditions | Yield |
---|---|
presence of V(5+); | 2% |
Conditions | Yield |
---|---|
for 0.0833333h; | |
In not given Electrolysis; deposition potential given; influence of electrolyte concn. and acidifying addtives (12% H3BO3, 0.003 n-HCl) investigated);; | |
chloride In N,N-dimethyl-formamide Electrochem. Process; electrodeposition; |
cobalt
Conditions | Yield |
---|---|
In water at 60℃; for 0.5h; |
Conditions | Yield |
---|---|
In acetone byproducts: H2; Electrolysis; Pt-cathode, Co-anode, 40 mA, 35 min, Et4NClO4, two drops of water; ppt. was filtered, washed with Et2O, elem. anal.; | 100% |
cobalt
5-(4-methylphenylazo)-3-cyano-4,6-dimethyl-pyridine-2-(1H)-thione
Conditions | Yield |
---|---|
In acetone byproducts: H2; Electrolysis; Pt-cathode, Co-anode, 40 mA, 30 min, Et4NClO4, two drops of water; ppt. was filtered, washed with Et2O; | 100% |
Conditions | Yield |
---|---|
In melt stoich. amts. of La2O3, S, W, WO3, Co mixed with KCl flux; sealed in carbon coated SiO2 ampoule under vac.; heated from 200 to 400°C in 24 h; held for 48 h; heated to 950°C in 12 h; held for 120 h; cooled to room temp. within 24 h; soaked in H2O overnight; washed with H2O; detn. by EDX, XRD; | 100% |
Octanoic acid
cobalt
cobalt octanoate
Conditions | Yield |
---|---|
In acetone Electrolysis; 2 h, initial voltage 32 V; washed with acetonitrile and dried in vacuo for 3-4 h at room temp.;elem.anal; | 98% |
water
cobalt
5-(4-chlorophenylazo)-3-cyano-4-methyl-6-phenylpyridine-2-(1H)-thione
Conditions | Yield |
---|---|
In acetone byproducts: H2; Electrolysis; Pt-cathode, Co-anode, 40 mA, 30 min, Et4NClO4, two drops of water; ppt. was filtered, washed with Et2O, elem. anal.; | 98% |
water
hydrogen bromide
cobalt
tetrazol-1-yl-tris(hydroxymethyl)methane
Co(tetrazol-1-yl-tris(hydroxymethyl)methane)2Br2*2H2O
Conditions | Yield |
---|---|
In methanol metal, tetrazol compd., 35% HBr added to MeOH. heated in air to 50-60°C for 2-3 h, cooled to 18-20°C, stored in air for a week (slow evapn.); filtered, dried (air); elem. anal., metal content by colorimetry or complexonometric titration, halide content by Volhard's method; | 98% |
1-phenyl-3-methyl-4-[4-methyl-2-(4-methylphenylazophenyl)hydrazono]-5H-pyrazol-5-one
cobalt
Conditions | Yield |
---|---|
With tetraethylammonium perchlorate In methanol for 1h; Electrochemical reaction; | 97% |
Conditions | Yield |
---|---|
at 0 - 20℃; for 24h; Inert atmosphere; | 96% |
Conditions | Yield |
---|---|
With tetraethylammonium chloride In acetonitrile Electrolysis; cyclohexanol soln. is electrolyzed in presence of Et4NCl at -2.5 V withstirring in a electrolyzer without diaphragma with Co as electrodes; ppt. is filtered off, washed with hot CH3CN and dried at 1-2 mm, elem. anal.; | 95.7% |
Conditions | Yield |
---|---|
With tert-butylammonium hexafluorophosphate(V) In acetylacetone Electrochem. Process; tetra-n-butylammonium hexafluorophosphate added to dry acetylacetone, Coelectrode; evapd. under vac., oily residue dissolved in CHCl3, evapd.; | 95.1% |
Conditions | Yield |
---|---|
With carbon monoxide; tetrabutylammomium bromide In isopropyl alcohol Electrochem. Process; CO 10 bar, electrolysis (Co-anode, Bu4NBr, 293 K, 30 mA, 7.5 V, 44 h); | 95% |
Conditions | Yield |
---|---|
In acetone Electrolysis; electrolysis of Cu into a soln. of thiosemicarbazide, 1,10-phenanthroline and Et2NClO4 in acetone, 30V, 40 mA, 1h; crystn.; filtration; washing (acetone, ether); elem. anal.; | 95% |
Conditions | Yield |
---|---|
In neat (no solvent) heating (50°C/h.) of a mixt. of Sn, Co, K2S, S (stoich. mol. ratio 5:4:4:12) in a quartz tube sealed under vac. to 650°C, heating at this temp. for 60 h; cooling to room temp. at 5°C/h.; | 95% |
In neat (no solvent, solid phase) all manipulations under N2 atm.; calcd. amts. of elements and K2S sealedunder vac. in silica tube and heated to 650°C (50°C/h) fo r 60 h, cooled to room temp. (5°C/h); excess flux (K2S) removed with MeOH; elem. anal.; | 90% |
In melt byproducts: CoS2; heating (50°C/h.) of a mixt. of Sn, Co, K2S, S (mol. ratio 1:1:3:12) in a quartz tube sealed under vac. to 650°C for 60 h; cooling to room temp. at 5°C/h.; | 0% |
2,6-bis(1-[2-(tosylamino)phenylimino]ethyl)pyridine
cobalt
Co(2+)*C5H3N(C(CH3)NC6H4NSO2C6H4CH3)2(2-)*H2O=[Co(C5H3N(C(CH3)NC6H4NSO2C6H4CH3)2)](H2O)
Conditions | Yield |
---|---|
With (CH3)4NClO4; Pt In acetone Electrolysis; suspn. of ligand in warm acetone (contained Me4NClO4 as supporting electrolyte) electrolysed for 2.5 h (10 mA) using metal plate as anode and Ptwire as cathode; solid washed with Et2O, dried in vac., elem. anal.; | 95% |
Conditions | Yield |
---|---|
With tetraethylammonium perchlorate In acetonitrile Electrochem. Process; soln. of thiosemicarbazone in CH3CN contg. Et4NClO4 electrolysed for 1.3h using Pt cathode and Co platelet anode and a current of 10 mA; solid filtered off; washed with diethyl ether; dried under vac.; elem. anal.; | 95% |
Conditions | Yield |
---|---|
With Et4NClO4 In acetone byproducts: H2; Electrolysis; electrolysis (20 V, 3 h); elem. anal.; | 95% |
1.Cobalt has been detected in Egyptian sculpture and Persian jewelry from the third millennium BC.
2.Swedish chemist Georg Brandt (1694–1768) is credited with isolating cobalt circa 1735.
3.During the 19th century, cobalt blue was produced at the Norwegian Blaafarveværket (70–80% of world production), led by the Prussian industrialist Benjamin Wegner.
4.In 1938, John Livingood and Glenn Seaborg discovered cobalt-60. This isotope was famously used at Columbia University in the 1950s to establish parity violation in beta decay.
Cobalt is reported in EPA TSCA Inventory. Cobalt and its compounds are on the Community Right-To-Know List.
OSHA PEL: TWA 0.05 mg/m3
ACGIH TLV: (metal, dust, and fume) TWA 0.02 mg(Co)/m3; Animal Carcinogen
DFG MAK: DFG TRK: Animal Carcinogen, Suspected Human Carcinogen
NIOSH REL: (Cobalt) Insufficient evidence for recommending limit
For occupational chemical analysis use OSHA: #ID-125 G or NIOSH: Cobalt, 7027; Elements, 7300.
The Cobalt, with the cas registry number 7440-48-4, is a kind of steel grey chemical. This chemical is insoluble in water, and it is stable chemically but incompatible with acetylene, hydrazinium nitrate, oxidizing agents, acids. Its product categories are various, including Metals; Inorganics; Catalysis and Inorganic Chemistry; Chemical Synthesis; CobaltMetal and Ceramic Science; Cobalt; Metal and Ceramic Science; C-D, Puriss p.a.Chemical Synthesis; Analytical Reagents for General Use; Puriss p.a.
The physical properties of this chemical are below: (1)#H bond acceptors: 0; (2)#H bond donors: 0; (3)#Freely Rotating Bonds: 0; (4)Polar Surface Area: 0; (5)Exact Mass: 58.9332; (6)MonoIsotopic Mass: 58.9332; (7)Heavy Atom Count: 1; (8)Covalently-Bonded Unit Count: 1.
As to its usage, it is widely applied in many ways. This chemical is usually used in the preparation of magnetic, wear-resistant, and high-strength alloys; It is also used in paints, varnishes, and inks as drying agents through the oxidation of certain compounds.
When you are using this chemical, you should be very cautious. For one thing, it is harmful which may cause damage to health. This is irritating to eyes and respiratory system and skin and may cause sensitization by inhalation and skin contact. For another thing, it is toxic which may at low levels cause damage to health. If by inhalation, in contact with skin and if swallowed, it will be very dangerous to our body. Besides, it may cause cancer and has limited evidence of a carcinogenic effect. Besides all these, it is highly flammable which may catch fire in contact with air, only needing brief contact with an ignition source, and it has a very low flash point or evolve highly flammable gases in contact with water. What's more, it may cause long-term adverse effects in the aquatic environment.
Due to so many dangers, you could take the different measures to deal with different cases. Wear suitable protective clothing, gloves and eye/face protection. If in case of contact with eyes, rinse immediately with plenty of water and seek medical advice, and if in case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) Then do not not breathe vapour and dust and remember to avoid exposure - obtain special instructions before use. Besides, avoid release to the environment and you could also refer to special instructions / safety data sheets. When store this chemical, keep contents under ... (there follows the name of a liquid).
Additionally, you could convert the following datas into the molecular structure:
(1)Canonical SMILES: [Co]
(2)InChI: InChI=1S/Co
(3)InChIKey: GUTLYIVDDKVIGB-UHFFFAOYSA-N
Below are the toxicity information of this chemical:
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
mouse | LDLo | intraperitoneal | 100mg/kg (100mg/kg) | Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975. | |
rabbit | LDLo | intravenous | 100mg/kg (100mg/kg) | Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975. | |
rabbit | LDLo | oral | 750mg/kg (750mg/kg) | BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) | Archives Internationales de Pharmacodynamie et de Therapie. Vol. 62, Pg. 347, 1939. |
rat | LD50 | intraperitoneal | 100mg/kg (100mg/kg) | VASCULAR: REGIONAL OR GENERAL ARTERIOLAR OR VENOUS DILATION LIVER: OTHER CHANGES BLOOD: OTHER CHANGES | Industrial Medicine. Vol. 15, Pg. 482, 1946. |
rat | LD50 | oral | 6171mg/kg (6171mg/kg) | BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) BEHAVIORAL: ATAXIA GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA" | Acute Toxicity Data. Journal of the American College of Toxicology, Part B. Vol. 1, Pg. 686, 1992. |
rat | LDLo | intratracheal | 25mg/kg (25mg/kg) | National Technical Information Service. Vol. AEC-TR-6710, | |
rat | LDLo | intravenous | 100mg/kg (100mg/kg) | Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975. |
About|Contact|Cas|Product Name|Molecular|Country|Encyclopedia
Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog
©2008 LookChem.com,License: ICP
NO.:Zhejiang16009103
complaints:service@lookchem.com Desktop View