Product Name

  • Name

    Cobalt

  • EINECS 231-158-0
  • CAS No. 7440-48-4
  • Article Data818
  • CAS DataBase
  • Density 8.92
  • Solubility insoluble
  • Melting Point 1495 ºC
  • Formula Co
  • Boiling Point 2870 ºC
  • Molecular Weight 58.9932
  • Flash Point
  • Transport Information UN 1760/3089
  • Appearance grey or orange powder, or silver solid
  • Safety 53-23-26-36/37/39-45-61-24-22-5
  • Risk Codes R42/43;R53   
  • Molecular Structure Molecular Structure of 7440-48-4 (Cobalt)
  • Hazard Symbols
  • Synonyms ACO 4;C.I.77320;COE 03PB;Co 0138E;Cobalt element;Cobalt-59;N 354Di;R 401;R 401(metal);
  • PSA 0.00000
  • LogP 0.00000

Synthetic route

cobalt(II) chloride
7646-79-9

cobalt(II) chloride

A

chlorine
7782-50-5

chlorine

B

cobalt
7440-48-4

cobalt

Conditions
ConditionsYield
In acetonitrile Electrolysis; Ag-anode;;A n/a
B 100%
In acetonitrile Electrolysis; Ag-anode;;A n/a
B 100%
In neat (no solvent) Electrolysis; Cl2 is formed on anode, Co on cathode;;
In neat (no solvent) decompn. of CoCl2 at 600 ° C;
In neat (no solvent) Electrolysis; Cl2 is formed on anode, Co on cathode;;
{Co(NH3)6}(2+)*SO4(2-)={Co(NH3)6}SO4
65459-62-3

{Co(NH3)6}(2+)*SO4(2-)={Co(NH3)6}SO4

cobalt
7440-48-4

cobalt

Conditions
ConditionsYield
With hydrogen In ammonia pptn. of 100.0% metallic Co out of NH3-containing (Co(NH3)6)SO4-solution with H2 (50-75 atm) at 200°C after 2 h;;100%
With H2 In ammonia aq. ammonia=NH3; pptn. of 100.0% metallic Co out of NH3-containing (Co(NH3)6)SO4-solution with H2 (50-75 atm) at 200°C after 2 h;;100%
With hydrogen In ammonia pptn. of 95.5% metallic Co out of NH3-containing (Co(NH3)6)SO4-solution with H2 (50-75 atm) at 190°C after 2 h;;95.5%
(η6-toluene)bis(η1-pentafluorophenyl)cobalt(II)
60528-58-7

(η6-toluene)bis(η1-pentafluorophenyl)cobalt(II)

A

decafluorobiphenyl
434-90-2

decafluorobiphenyl

B

cobalt
7440-48-4

cobalt

C

toluene
108-88-3

toluene

Conditions
ConditionsYield
In neat (no solvent, solid phase) pyrolysis at 150°C;A 93%
B n/a
C 100%
cobalt(II) sulfate

cobalt(II) sulfate

cobalt
7440-48-4

cobalt

Conditions
ConditionsYield
With NH4-sulfate In ammonia Electrolysis; electrolysis at pH=8-12 with 5-10 mg metal in the electrolyt;;99%
With ammonium sulfate; triethanolamine In not given Electrolysis; electrolyte contains 5-10mg metal, triethanolamin and (NH4)2SO4;;99%
With ammonium sulfate In not given Electrolysis; electolyte: 8% educt, 2.5% (NH4)2SO4, 3.7-4.5V, 2.5A/dm(2), pH=5.0;;85%
dichloromethane
75-09-2

dichloromethane

water
7732-18-5

water

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

cobalt(II) chloride
7646-79-9

cobalt(II) chloride

A

ZnCl4(2-)*2(C6H5)(CH3)3P(1+)=[(C6H5)(CH3)3P]2[ZnCl4]

ZnCl4(2-)*2(C6H5)(CH3)3P(1+)=[(C6H5)(CH3)3P]2[ZnCl4]

B

cobalt
7440-48-4

cobalt

C

zinc(II) chloride
7646-85-7

zinc(II) chloride

D

zinc(II) hydroxide

zinc(II) hydroxide

Conditions
ConditionsYield
In dichloromethaneA n/a
B 99%
C n/a
D n/a
dichloromethane
75-09-2

dichloromethane

tributylphosphine
998-40-3

tributylphosphine

water
7732-18-5

water

cobalt(II) chloride
7646-79-9

cobalt(II) chloride

A

ZnCl4(2-)*2(C4H9)3(CH3)P(1+)=[(C4H9)3(CH3)P]2[ZnCl4]

ZnCl4(2-)*2(C4H9)3(CH3)P(1+)=[(C4H9)3(CH3)P]2[ZnCl4]

B

cobalt
7440-48-4

cobalt

C

zinc(II) chloride
7646-85-7

zinc(II) chloride

D

zinc(II) hydroxide

zinc(II) hydroxide

Conditions
ConditionsYield
In dichloromethaneA n/a
B 99%
C n/a
D n/a
bis(salicylidene)cobalt(II)
14220-65-6, 922735-20-4, 41139-17-7

bis(salicylidene)cobalt(II)

cobalt
7440-48-4

cobalt

Conditions
ConditionsYield
With oleylamine; Ph3P In neat (no solvent) (Ar); Co complex was reacted with oleylamine; heated to 100°C for90 min; soln. was injected to Ph3P at 220°C; aged at 210° C for 45 min; cooled to room temp.; EtOH added; centrifuged;70%
[((Co(CO)3)2)2(HCCC6H4C)2]
252329-39-8

[((Co(CO)3)2)2(HCCC6H4C)2]

graphite

graphite

B

carbon dioxide
124-38-9

carbon dioxide

C

carbon monoxide
201230-82-2

carbon monoxide

D

hydrogen
1333-74-0

hydrogen

E

cobalt
7440-48-4

cobalt

Conditions
ConditionsYield
In solid byproducts: CH4; below 200°C, then graphitization (800°C, 6 h);A 60%
B n/a
C n/a
D n/a
E n/a
[(CC6H4CC((Co(CO)3)2)CCC6H4C(Co(CO)3))2]
252329-37-6

[(CC6H4CC((Co(CO)3)2)CCC6H4C(Co(CO)3))2]

graphite

graphite

B

carbon dioxide
124-38-9

carbon dioxide

C

carbon monoxide
201230-82-2

carbon monoxide

D

hydrogen
1333-74-0

hydrogen

E

cobalt
7440-48-4

cobalt

Conditions
ConditionsYield
In solid byproducts: CH4; below 200°C, then graphitization (800°C, 6 h);A 60%
B n/a
C n/a
D n/a
E n/a
(hydridotris(3-tert-butyl-5-methylpyrazolyl)borato)cobalt(II)(N2)

(hydridotris(3-tert-butyl-5-methylpyrazolyl)borato)cobalt(II)(N2)

hydrogen
1333-74-0

hydrogen

A

hydrido(hydridotris(3-tert-butyl-5-methylpyrazolyl)borato)cobalt(II)

hydrido(hydridotris(3-tert-butyl-5-methylpyrazolyl)borato)cobalt(II)

B

cobalt
7440-48-4

cobalt

Conditions
ConditionsYield
In toluene 60°C (overnight); filtering, evapn. (vac.), recrystn. (toluene); elem. anal.;A 59%
B n/a
(hydridotris(3-tert-butyl-5-methylpyrazolyl)borato)cobalt(II)(N2)

(hydridotris(3-tert-butyl-5-methylpyrazolyl)borato)cobalt(II)(N2)

deuterium
16873-17-9

deuterium

A

deuterido(hydridotris(3-tert-butyl-5-methylpyrazolyl)borato)cobalt(II)

deuterido(hydridotris(3-tert-butyl-5-methylpyrazolyl)borato)cobalt(II)

B

cobalt
7440-48-4

cobalt

Conditions
ConditionsYield
In (2)H8-toluene 60°C (overnight); filtering, evapn. (vac.), recrystn. (toluene);A 58%
B n/a
Conditions
ConditionsYield
In 1,2-dimethoxyethane Irradiation (UV/VIS); under Ar; mole ratios NaBPh4 : CoCl2 : CuBr2 = 4 : 1 : 1; irradn. (254 nm) for 10 h gave deposition of Co and Cu;A 47%
B 48%
cobaltocene
1277-43-6

cobaltocene

CoBr2*DME

CoBr2*DME

tetraphenylborate anion
4358-26-3

tetraphenylborate anion

1,5-dicyclooctadiene
5259-72-3, 10060-40-9, 111-78-4

1,5-dicyclooctadiene

A

cobalt(II) oxide
1307-96-6

cobalt(II) oxide

B

(η5-cyclopentadienyl)-η4-cycloocta-1,5-dienecobalt(I)
12184-35-9

(η5-cyclopentadienyl)-η4-cycloocta-1,5-dienecobalt(I)

C

[(cyclopentadienyl)2Co][tetraphenylborate]

[(cyclopentadienyl)2Co][tetraphenylborate]

D

cobalt(II)

cobalt(II)

E

cobalt
7440-48-4

cobalt

Conditions
ConditionsYield
With C5H5Na In tetrahydrofuran; water; pentane under N2, CoBr2*DME, NaCp, CoCp2 and COD mixed in THF in molar ratio of2/2.06/0.5/1.16 (CoCp2 added at -80°C prior to NaCp), warmed to room temp. during 3 h, evapd., pentane ext. passed through Al2O3/4% H2O and CuCl powder; concd., cooled to -80°C, CpCoCOD filtered off; CuCl washed with water, CoCp2(1+) pptd. with BPh4(1-) from aq. soln., filtered off; pentane-insol. residue treated with water, Co and CoO mixt. filtered, Co(2+) determined complexometrically;A n/a
B 45.3%
C n/a
D n/a
E n/a
With C5H5Na In tetrahydrofuran; water; pentane under N2, CoBr2*DME, NaCp, CoCp2 and COD mixed in THF in molar ratio of2/2.06/0.5/1.16 (CoCp2 added at -80°C after NaCp), warmed to room temp. during 3 h, evapd., pentane ext. passed through Al2O3/4% H2O andCuCl powder; concd., cooled to -80°C, CpCoCOD filtered off; CuCl washed with water, CoCp2(1+) pptd. with BPh4(1-) from aq. soln., filtered off; pentane-insol. residue treated with water, Co and CoO mixt. filtered, Co(2+) determined complexometrically;A n/a
B 43%
C n/a
D n/a
E n/a
With C5H5Na In tetrahydrofuran; water; pentane under N2, CoBr2*DME, NaCp, CoCp2 and COD mixed in THF in molar ratio of2/2.06/0.5/1.16 (CoCp2 added at 0°C prior to NaCp at -80°C), warmed to room temp. during 3 h, evapd., pentane ext. passed throughAl2O3/4% H2O and CuCl powder; concd., cooled to -80°C, CpCoCOD filtered off; CuCl washed with water, CoCp2(1+) pptd. with BPh4(1-) from aq. soln., filtered off; pentane-insol. residue treated with water, Co and CoO mixt. filtered, Co(2+) determined complexometrically;A n/a
B 37.5%
C n/a
D n/a
E n/a
With C5H5Na In tetrahydrofuran; water; pentane under N2, CoBr2*DME, NaCp, CoCp2 and COD mixed in THF in molar ratio of2/3/0.5/1.16, warmed to room temp. during 3 h, evapd., pentane ext. passed through Al2O3/4% H2O and CuCl powder; concd., cooled to -80°C, CpCoCOD filtered off; CuCl washed with water, CoCp2(1+) pptd. with BPh4(1-) from aq. soln., filtered off; pentane-insol. residue treated with water, Co and CoO mixt. filtered, Co(2+) determined complexometrically;A n/a
B 11.5%
C n/a
D n/a
E n/a
With C5H5Na In hexane; water; pentane under N2, CoBr2*DME, NaCp, CoCp2 and COD mixed in molar ratio of 2/3/0.5/1.16 in hexane at -80°C, warmed to room temp. during 3 h, evapd., pentane ext. passed through Al2O3/4% H2O and CuCl powder; concd., cooled to -80°C, CpCoCOD filtered off; CuCl washed with water, CoCp2(1+) pptd. with BPh4(1-) from aq. soln., filtered off; pentane-insol. residue treated with water, Co and CoO mixt. filtered, Co(2+) determined complexometrically;A n/a
B 8.6%
C n/a
D n/a
E n/a
Co4(CO)10C6F4

Co4(CO)10C6F4

A

1,2,3,4,5,6,7,8-Octafluoro-9-fluorenone
19925-96-3

1,2,3,4,5,6,7,8-Octafluoro-9-fluorenone

B

cobalt
7440-48-4

cobalt

Conditions
ConditionsYield
In neat (no solvent) byproducts: CO; in vac., thermic decompn.;A 45%
B n/a
In neat (no solvent) byproducts: CO; in vac., thermic decompn.;A 45%
B n/a
(η6-toluene)bis(η1-pentafluorophenyl)cobalt(II)
60528-58-7

(η6-toluene)bis(η1-pentafluorophenyl)cobalt(II)

A

Pentafluorobenzene
363-72-4

Pentafluorobenzene

B

decafluorobiphenyl
434-90-2

decafluorobiphenyl

C

cobalt
7440-48-4

cobalt

Conditions
ConditionsYield
In toluene refluxing under N2 for 3 d;A 135 %
B 30%
C n/a
cobaltocene
1277-43-6

cobaltocene

CoBr2*DME

CoBr2*DME

tetraphenylborate anion
4358-26-3

tetraphenylborate anion

cyclopentadienyllithium
16733-97-4

cyclopentadienyllithium

1,5-dicyclooctadiene
5259-72-3, 10060-40-9, 111-78-4

1,5-dicyclooctadiene

A

cobalt(II) oxide
1307-96-6

cobalt(II) oxide

B

(η5-cyclopentadienyl)-η4-cycloocta-1,5-dienecobalt(I)
12184-35-9

(η5-cyclopentadienyl)-η4-cycloocta-1,5-dienecobalt(I)

C

[(cyclopentadienyl)2Co][tetraphenylborate]

[(cyclopentadienyl)2Co][tetraphenylborate]

D

cobalt(II)

cobalt(II)

E

cobalt
7440-48-4

cobalt

Conditions
ConditionsYield
In tetrahydrofuran; water; pentane under N2, CoBr2*DME, LiCp, CoCp2 and COD mixed in THF in molar ratio of2/2.06/0.5/1.16, warmed to room temp. during 3 h, evapd., pentane ext. passed through Al2O3/4% H2O and CuCl powder; concd., cooled to -80°C, CpCoCOD filtered off; CuCl washed with water, CoCp2(1+) pptd. with BPh4(1-) from aq. soln., filtered off; pentane-insol. residue treated with water, Co and CoO mixt. filtered, Co(2+) determined complexometrically;A n/a
B 18%
C n/a
D n/a
E n/a
Trioxalatcobaltat-(III)

Trioxalatcobaltat-(III)

tin(II)

tin(II)

cobalt
7440-48-4

cobalt

Conditions
ConditionsYield
presence of V(5+);2%
cobalt(II) chloride
7646-79-9

cobalt(II) chloride

cobalt
7440-48-4

cobalt

Conditions
ConditionsYield
for 0.0833333h;
In not given Electrolysis; deposition potential given; influence of electrolyte concn. and acidifying addtives (12% H3BO3, 0.003 n-HCl) investigated);;
chloride In N,N-dimethyl-formamide Electrochem. Process; electrodeposition;
Reaxys ID: 15738947

Reaxys ID: 15738947

cobalt
7440-48-4

cobalt

Conditions
ConditionsYield
In water at 60℃; for 0.5h;
water
7732-18-5

water

cobalt
7440-48-4

cobalt

5-(4-chlorophenylazo)-3-cyano-4,6-dimethyl-pyridine-2-(1H)-thione

5-(4-chlorophenylazo)-3-cyano-4,6-dimethyl-pyridine-2-(1H)-thione

Co(ClC6H4NNC5N(CH3)2(CN)(S))2(H2O)2

Co(ClC6H4NNC5N(CH3)2(CN)(S))2(H2O)2

Conditions
ConditionsYield
In acetone byproducts: H2; Electrolysis; Pt-cathode, Co-anode, 40 mA, 35 min, Et4NClO4, two drops of water; ppt. was filtered, washed with Et2O, elem. anal.;100%
cobalt
7440-48-4

cobalt

5-(4-methylphenylazo)-3-cyano-4,6-dimethyl-pyridine-2-(1H)-thione
147675-09-0

5-(4-methylphenylazo)-3-cyano-4,6-dimethyl-pyridine-2-(1H)-thione

Co(CH3C6H4NNC5N(CH3)2(CN)(S))2

Co(CH3C6H4NNC5N(CH3)2(CN)(S))2

Conditions
ConditionsYield
In acetone byproducts: H2; Electrolysis; Pt-cathode, Co-anode, 40 mA, 30 min, Et4NClO4, two drops of water; ppt. was filtered, washed with Et2O;100%
lanthanum(III) oxide

lanthanum(III) oxide

tungsten(VI) oxide

tungsten(VI) oxide

cobalt
7440-48-4

cobalt

sulfur
7704-34-9

sulfur

tungsten
7440-33-7

tungsten

La3CoS3(6+)*WO6(6-)=La3CoWS3O6

La3CoS3(6+)*WO6(6-)=La3CoWS3O6

Conditions
ConditionsYield
In melt stoich. amts. of La2O3, S, W, WO3, Co mixed with KCl flux; sealed in carbon coated SiO2 ampoule under vac.; heated from 200 to 400°C in 24 h; held for 48 h; heated to 950°C in 12 h; held for 120 h; cooled to room temp. within 24 h; soaked in H2O overnight; washed with H2O; detn. by EDX, XRD;100%
Conditions
ConditionsYield
In acetone Electrolysis; 2 h, initial voltage 32 V; washed with acetonitrile and dried in vacuo for 3-4 h at room temp.;elem.anal;98%
water
7732-18-5

water

cobalt
7440-48-4

cobalt

5-(4-chlorophenylazo)-3-cyano-4-methyl-6-phenylpyridine-2-(1H)-thione
147675-15-8

5-(4-chlorophenylazo)-3-cyano-4-methyl-6-phenylpyridine-2-(1H)-thione

Co(ClC6H4NNC5N(CH3)(C6H5)(CN)(S))2(H2O)2*H2O

Co(ClC6H4NNC5N(CH3)(C6H5)(CN)(S))2(H2O)2*H2O

Conditions
ConditionsYield
In acetone byproducts: H2; Electrolysis; Pt-cathode, Co-anode, 40 mA, 30 min, Et4NClO4, two drops of water; ppt. was filtered, washed with Et2O, elem. anal.;98%
water
7732-18-5

water

hydrogen bromide
10035-10-6, 12258-64-9

hydrogen bromide

cobalt
7440-48-4

cobalt

tetrazol-1-yl-tris(hydroxymethyl)methane
103518-51-0

tetrazol-1-yl-tris(hydroxymethyl)methane

Co(tetrazol-1-yl-tris(hydroxymethyl)methane)2Br2*2H2O
1363414-20-3

Co(tetrazol-1-yl-tris(hydroxymethyl)methane)2Br2*2H2O

Conditions
ConditionsYield
In methanol metal, tetrazol compd., 35% HBr added to MeOH. heated in air to 50-60°C for 2-3 h, cooled to 18-20°C, stored in air for a week (slow evapn.); filtered, dried (air); elem. anal., metal content by colorimetry or complexonometric titration, halide content by Volhard's method;98%
1-phenyl-3-methyl-4-[4-methyl-2-(4-methylphenylazophenyl)hydrazono]-5H-pyrazol-5-one
1609350-31-3

1-phenyl-3-methyl-4-[4-methyl-2-(4-methylphenylazophenyl)hydrazono]-5H-pyrazol-5-one

cobalt
7440-48-4

cobalt

C48H42CoN12O2

C48H42CoN12O2

Conditions
ConditionsYield
With tetraethylammonium perchlorate In methanol for 1h; Electrochemical reaction;97%
1,2-dimethoxyethane
110-71-4

1,2-dimethoxyethane

bromine
7726-95-6

bromine

cobalt
7440-48-4

cobalt

cobalt dibromide*1,2-dimethoxyethane

cobalt dibromide*1,2-dimethoxyethane

Conditions
ConditionsYield
at 0 - 20℃; for 24h; Inert atmosphere;96%
cobalt
7440-48-4

cobalt

cyclohexanol
108-93-0

cyclohexanol

2(C6H11O)(1-)*Co(2+)=Co(C6H11O)2

2(C6H11O)(1-)*Co(2+)=Co(C6H11O)2

Conditions
ConditionsYield
With tetraethylammonium chloride In acetonitrile Electrolysis; cyclohexanol soln. is electrolyzed in presence of Et4NCl at -2.5 V withstirring in a electrolyzer without diaphragma with Co as electrodes; ppt. is filtered off, washed with hot CH3CN and dried at 1-2 mm, elem. anal.;95.7%
cobalt
7440-48-4

cobalt

acetylacetone
123-54-6

acetylacetone

cobalt(III) acetylacetonate

cobalt(III) acetylacetonate

Conditions
ConditionsYield
With tert-butylammonium hexafluorophosphate(V) In acetylacetone Electrochem. Process; tetra-n-butylammonium hexafluorophosphate added to dry acetylacetone, Coelectrode; evapd. under vac., oily residue dissolved in CHCl3, evapd.;95.1%
cobalt
7440-48-4

cobalt

isopropyl alcohol
67-63-0

isopropyl alcohol

cobalt(II) isopropoxide

cobalt(II) isopropoxide

Conditions
ConditionsYield
With carbon monoxide; tetrabutylammomium bromide In isopropyl alcohol Electrochem. Process; CO 10 bar, electrolysis (Co-anode, Bu4NBr, 293 K, 30 mA, 7.5 V, 44 h);95%
1,10-Phenanthroline
66-71-7

1,10-Phenanthroline

cobalt
7440-48-4

cobalt

4-Phenyl-3-thiosemicarbazide
5351-69-9

4-Phenyl-3-thiosemicarbazide

Cu(PTS)*phen

Cu(PTS)*phen

Conditions
ConditionsYield
In acetone Electrolysis; electrolysis of Cu into a soln. of thiosemicarbazide, 1,10-phenanthroline and Et2NClO4 in acetone, 30V, 40 mA, 1h; crystn.; filtration; washing (acetone, ether); elem. anal.;95%
potassium sulfide

potassium sulfide

cobalt
7440-48-4

cobalt

sulfur
7704-34-9

sulfur

10K(1+)*Co4Sn4S17(10-)=K10Co4Sn4S17

10K(1+)*Co4Sn4S17(10-)=K10Co4Sn4S17

Conditions
ConditionsYield
In neat (no solvent) heating (50°C/h.) of a mixt. of Sn, Co, K2S, S (stoich. mol. ratio 5:4:4:12) in a quartz tube sealed under vac. to 650°C, heating at this temp. for 60 h; cooling to room temp. at 5°C/h.;95%
In neat (no solvent, solid phase) all manipulations under N2 atm.; calcd. amts. of elements and K2S sealedunder vac. in silica tube and heated to 650°C (50°C/h) fo r 60 h, cooled to room temp. (5°C/h); excess flux (K2S) removed with MeOH; elem. anal.;90%
In melt byproducts: CoS2; heating (50°C/h.) of a mixt. of Sn, Co, K2S, S (mol. ratio 1:1:3:12) in a quartz tube sealed under vac. to 650°C for 60 h; cooling to room temp. at 5°C/h.;0%
2,6-bis(1-[2-(tosylamino)phenylimino]ethyl)pyridine
660394-39-8

2,6-bis(1-[2-(tosylamino)phenylimino]ethyl)pyridine

cobalt
7440-48-4

cobalt

Co(2+)*C5H3N(C(CH3)NC6H4NSO2C6H4CH3)2(2-)*H2O=[Co(C5H3N(C(CH3)NC6H4NSO2C6H4CH3)2)](H2O)
660394-36-5

Co(2+)*C5H3N(C(CH3)NC6H4NSO2C6H4CH3)2(2-)*H2O=[Co(C5H3N(C(CH3)NC6H4NSO2C6H4CH3)2)](H2O)

Conditions
ConditionsYield
With (CH3)4NClO4; Pt In acetone Electrolysis; suspn. of ligand in warm acetone (contained Me4NClO4 as supporting electrolyte) electrolysed for 2.5 h (10 mA) using metal plate as anode and Ptwire as cathode; solid washed with Et2O, dried in vac., elem. anal.;95%
pyridine-2-formaldehyde N4-methyl thiosemicarbazone
6839-88-9

pyridine-2-formaldehyde N4-methyl thiosemicarbazone

water
7732-18-5

water

cobalt
7440-48-4

cobalt

Co(4-N-methylthiosemicarbazone-2-pyridinecarboxaldehyde(-H))2(H2O)3.3

Co(4-N-methylthiosemicarbazone-2-pyridinecarboxaldehyde(-H))2(H2O)3.3

Conditions
ConditionsYield
With tetraethylammonium perchlorate In acetonitrile Electrochem. Process; soln. of thiosemicarbazone in CH3CN contg. Et4NClO4 electrolysed for 1.3h using Pt cathode and Co platelet anode and a current of 10 mA; solid filtered off; washed with diethyl ether; dried under vac.; elem. anal.;95%
cobalt
7440-48-4

cobalt

(2-hydrazinyl-2-oxoethyl)benzamide
2443-68-7

(2-hydrazinyl-2-oxoethyl)benzamide

acetone
67-64-1

acetone

Co(C9H10N3O2)2*(CH3)2CO = Co(C9H10N3O2)2(CH3)2CO

Co(C9H10N3O2)2*(CH3)2CO = Co(C9H10N3O2)2(CH3)2CO

Conditions
ConditionsYield
With Et4NClO4 In acetone byproducts: H2; Electrolysis; electrolysis (20 V, 3 h); elem. anal.;95%

Cobalt History

1.Cobalt has been detected in Egyptian sculpture and Persian jewelry from the third millennium BC.
2.Swedish chemist Georg Brandt (1694–1768) is credited with isolating cobalt circa 1735.
3.During the 19th century, cobalt blue was produced at the Norwegian Blaafarveværket (70–80% of world production), led by the Prussian industrialist Benjamin Wegner.
4.In 1938, John Livingood and Glenn Seaborg discovered cobalt-60. This isotope was famously used at Columbia University in the 1950s to establish parity violation in beta decay.

Cobalt Consensus Reports

 Cobalt is reported in EPA TSCA Inventory. Cobalt and its compounds are on the Community Right-To-Know List.

Cobalt Standards and Recommendations

OSHA PEL: TWA 0.05 mg/m3
ACGIH TLV: (metal, dust, and fume) TWA 0.02 mg(Co)/m3; Animal Carcinogen
DFG MAK: DFG TRK: Animal Carcinogen, Suspected Human Carcinogen
NIOSH REL: (Cobalt) Insufficient evidence for recommending limit

Cobalt Analytical Methods

For occupational chemical analysis use OSHA: #ID-125 G or NIOSH: Cobalt, 7027; Elements, 7300.

Cobalt Specification

The Cobalt, with the cas registry number 7440-48-4, is a kind of steel grey chemical. This chemical is insoluble in water, and it is stable chemically but incompatible with acetylene, hydrazinium nitrate, oxidizing agents, acids. Its product categories are various, including Metals; Inorganics; Catalysis and Inorganic Chemistry; Chemical Synthesis; CobaltMetal and Ceramic Science; Cobalt; Metal and Ceramic Science; C-D, Puriss p.a.Chemical Synthesis; Analytical Reagents for General Use; Puriss p.a.

The physical properties of this chemical are below: (1)#H bond acceptors: 0; (2)#H bond donors: 0; (3)#Freely Rotating Bonds: 0; (4)Polar Surface Area: 0; (5)Exact Mass: 58.9332; (6)MonoIsotopic Mass: 58.9332; (7)Heavy Atom Count: 1; (8)Covalently-Bonded Unit Count: 1.

As to its usage, it is widely applied in many ways. This chemical is usually used in the preparation of magnetic, wear-resistant, and high-strength alloys; It is also used in paints, varnishes, and inks as drying agents through the oxidation of certain compounds.

When you are using this chemical, you should be very cautious. For one thing, it is harmful which may cause damage to health. This is irritating to eyes and respiratory system and skin and may cause sensitization by inhalation and skin contact. For another thing, it is toxic which may at low levels cause damage to health. If by inhalation, in contact with skin and if swallowed, it will be very dangerous to our body. Besides, it may cause cancer and has limited evidence of a carcinogenic effect. Besides all these, it is highly flammable which may catch fire in contact with air, only needing brief contact with an ignition source, and it has a very low flash point or evolve highly flammable gases in contact with water. What's more, it may cause long-term adverse effects in the aquatic environment.

Due to so many dangers, you could take the different measures to deal with different cases. Wear suitable protective clothing, gloves and eye/face protection. If in case of contact with eyes, rinse immediately with plenty of water and seek medical advice, and if in case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) Then do not not breathe vapour and dust and remember to avoid exposure - obtain special instructions before use. Besides, avoid release to the environment and you could also refer to special instructions / safety data sheets. When store this chemical, keep contents under ... (there follows the name of a liquid). 

Additionally, you could convert the following datas into the molecular structure:
(1)Canonical SMILES: [Co]
(2)InChI: InChI=1S/Co
(3)InChIKey: GUTLYIVDDKVIGB-UHFFFAOYSA-N  

Below are the toxicity information of this chemical:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LDLo intraperitoneal 100mg/kg (100mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
 
rabbit LDLo intravenous 100mg/kg (100mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
 
rabbit LDLo oral 750mg/kg (750mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) Archives Internationales de Pharmacodynamie et de Therapie. Vol. 62, Pg. 347, 1939.
rat LD50 intraperitoneal 100mg/kg (100mg/kg) VASCULAR: REGIONAL OR GENERAL ARTERIOLAR OR VENOUS DILATION

LIVER: OTHER CHANGES

BLOOD: OTHER CHANGES
Industrial Medicine. Vol. 15, Pg. 482, 1946.
rat LD50 oral 6171mg/kg (6171mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: ATAXIA

GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA"
Acute Toxicity Data. Journal of the American College of Toxicology, Part B. Vol. 1, Pg. 686, 1992.
rat LDLo intratracheal 25mg/kg (25mg/kg)   National Technical Information Service. Vol. AEC-TR-6710,
rat LDLo intravenous 100mg/kg (100mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
 

 

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