Ferric acetylacetonate supplier

Name
Ferric acetylacetonate
EINECS 237-853-5
CAS No. 14024-18-1
Article Data33
CAS DataBase
Density 5.24 g/mL at 25 °C(lit.)
Solubility 2 g/L (20 °C) in water
Melting Point 180-182 °C (dec.)(lit.)
Formula C₁₅H₂₁FeO₆
Boiling Point 110 °C 2 mm
Molecular Weight 353.175
Flash Point 43.1ºC
Transport Information
Appearance dark red powder
Safety 26-37/39
Risk Codes 22-36
Molecular Structure
Hazard Symbols Xn
Synonyms Iron,tris(2,4-pentanedionato)- (6CI,7CI,8CI);Iron, tris(2,4-pentanedionato-O,O')-,(OC-6-11)-;Iron, tris(2,4-pentanedionato-kO,kO')-, (OC-6-11)- (9CI);(Acetylacetonato)iron(III);Acetope Fe(II);Ferric tris(acetoacetonate);Ferric tris(acetylacetonate);Iron acetylacetonate;Iron triacetylacetonate;Iron tris(2,4-pentanedionate);Iron tris(acetoacetonate);Iron tris(acetylacetonate);Iron(3+)acetylacetonate;Iron(III) acetylacetonate;NSC 43622;Nacem Iron;Tris(2,4-pentanedionato)iron;Tris(acetylacetonato)iron;Tris(acetylacetone)iron;Tris(acetylacetonyl)aluminum iron(III);
PSA 102.42000
LogP 1.66100

Synthetic route

: iron(III) chloride hexahydrate

: 19393-11-4
potassium acetylacetonate

: 14024-18-1
iron(III)-acetylacetonate

Conditions

Conditions	Yield
In ethanol at pH 5-6 by the method of Fackler, Progress in Inorganic Chemistry, 1966, 7, 403; subliming twice (t=180 °C, P=5E-2 torr); elem. anal.;	95%

: 7705-08-0
iron(III) chloride

: 123-54-6
acetylacetone

: 14024-18-1
iron(III)-acetylacetonate

Conditions

Conditions	Yield
With ammonia In water anhyd. FeCl3 dissolved in water, excess ammonia soln. added slowly withstirring and mixt heated on steam-bath for 15-20 min, Fe(OH)3 filtered off, washed with water and heated with acetylacetone on steam-bath for 35 min.; mixt. cooled, crystalsdried and recrystd. from ethanol; elem. anal.;	90%
In water Aq. FeCl3 soln. was added to acetylacetone under stirring, mixt. was heated on a water bath, slight excess of NH4OH was added during stirring in hot conditions; crystals were filtered, washed with water, dried and recrystd. from CHCl3;	37%
With sodium acetate In ethanol; water to aq. soln. of FeCl3 and sodium acetate alc. soln. of acetylacetonate was added;; recrystn. (ether or alc.);;

: 7705-08-0
iron(III) chloride

: 1118-67-8
sodium (Z)-4-oxopent-2-en-2-olate

: 14024-18-1
iron(III)-acetylacetonate

Conditions

Conditions	Yield
In solid byproducts: NaCl; mechanical treatment of the react. mixt. (FeCl3 (1.18 mmol) and an org.compd. (3.55 mmol)) in stainless steel reactors; the steel balls were used as an activating packing; in a dry box under N2; self-propagating synthesis; isolation by sublimation or extn.; elem. anal.; IR-spectroscopy; X-ray diffraction;	80%
In benzene byproducts: NaCl; a react. of FeCl3 and an org. compd. in the ratio 1:3; under N2; stirring for 2 d; elem. anal.; IR-spectroscopy; X-ray diffraction;	60%

: 7439-89-6
iron

: 123-54-6
acetylacetone

: 14024-18-1
iron(III)-acetylacetonate

Conditions

Conditions	Yield
With tert-butylammonium hexafluorophosphate(V) In acetylacetone Electrochem. Process; tetra-n-butylammonium hexafluorophosphate added to dry acetylacetone, Feelectrode, 300 V, 10-50 mA, ca. 10 h; evapd. under vac., solid washed twice with hexane and twice with petroleum ether;	75.7%

: Fe(2+)*3NO3(1-)*9H2O

: 123-54-6
acetylacetone

: 14024-18-1
iron(III)-acetylacetonate

Conditions

Conditions	Yield
In ethanol; dichloromethane for 0.5h;	73%

: iron(III) 2-ethylhexanoate

: 123-54-6
acetylacetone

: 14024-18-1
iron(III)-acetylacetonate

Conditions

Conditions	Yield
In toluene; Petroleum ether byproducts: 2-ethylhexanoic acid; a soln. of Fe-salt in petrol ether was added dropwise to a warm soln. (70-80°C) of dione in dry toluene under stirring, cooled; filtered, recrystd. from toluene, petrole ether or a mixt. of both solvents;	70%

: sodium nitroprusside

: 14024-18-1
iron(III)-acetylacetonate

Conditions

Conditions	Yield
With sodium hydroxide; acetylacetone In water Kinetics; byproducts: {Fe(CN)6}(4-), NO, HONC(COCH3)2; addn. of NaOH to a soln. of pentane-2,4-dione and Na2{Fe(CN)5(NO)} in water, standing in the dark for 3 h (mechanism discussed); filtration of crystals;	16%

: iron (III) hydroxide

: 123-54-6
acetylacetone

: 14024-18-1
iron(III)-acetylacetonate

Conditions

Conditions	Yield
With potassium hydroxide at 0 - 20℃; for 0.75h; Neat (no solvent);

: 13463-40-6
iron pentacarbonyl

: 123-54-6
acetylacetone

: 14024-18-1
iron(III)-acetylacetonate

Conditions

Conditions	Yield
In neat (no solvent)
Irradiation (UV/VIS);
Irradiation (UV/VIS);

: iron(III) chloride hexahydrate

: 123-54-6
acetylacetone

: 14024-18-1
iron(III)-acetylacetonate

Conditions

Conditions	Yield
In methanol iron(III)chloride hexahydrate, acetylacetone, sodium acetate trihydrate and methanol used, according to J. D. Woolines (Ed.) Metal Acetylacetonate Complexes by C. Gildewell, VCH, Weinheim. 1994, pp 116-121;
With CH3COONa In methanol; water soln. of acetylacetonate in methanol added to soln. of FeCl3*6H2O in water; soln. of CH3COONa added; heated at 50°C; cooled for 24 h at 4°C; filtered; washed (water); recrystd. (toluene);

: iron(III) ammonium sulfate dodecahydrate

: 123-54-6
acetylacetone

: 14024-18-1
iron(III)-acetylacetonate

Conditions

Conditions	Yield
With sodium hydrogencarbonate In water Room temp.;;

: 7705-08-0
iron(III) chloride

: thallium(I) 2,4-pentanedionate

: 14024-18-1
iron(III)-acetylacetonate

Conditions

Conditions	Yield
In diethyl ether metathesis; waterfree FeCl3; dry ether;;
In diethyl ether metathesis; waterfree FeCl3; dry ether;;

: ferric hydroxide

A: 14024-18-1
iron(III)-acetylacetonate

: FeO(C5H8O2)2(C5H7O2)

Conditions

Conditions	Yield
With acetylacetone In ethanol Fernelius methode (according to W. C. Fernelius, Inorganic Synthesis, Vol2, McGraw-Hill Publ. Co, New York 1946 (p. 10)); pptn. from soln.;

: ferric hydroxide

: 123-54-6
acetylacetone

: 14024-18-1
iron(III)-acetylacetonate

Conditions

Conditions	Yield
In water small excess of acetylacetone (24 hours); pptn.;; recrystn.: twice from benzene;;
In water small excess of acetylacetone (24 hours); pptn.;; recrystn.: twice from benzene;;
In neat (no solvent) Heating;

: 13463-40-6
iron pentacarbonyl

: 123-54-6
acetylacetone

A: 14024-18-1
iron(III)-acetylacetonate

B: iron(II) diacetylacetonate

Conditions

Conditions	Yield
Irradiation (UV/VIS); small amounts of Fe(II) compound;;
Irradiation (UV/VIS); small amounts of Fe(II) compound;;

...Expand

: 7439-89-6
iron(II)

: 123-54-6
acetylacetone

: 14024-18-1
iron(III)-acetylacetonate

Conditions

Conditions	Yield
without formation of hydrogen;;
without formation of hydrogen;;

: tris-(trifluoroacetylacetonato)iron(III)

: 123-54-6
acetylacetone

: 14024-18-1
iron(III)-acetylacetonate

Conditions

Conditions	Yield
In tetrachloromethane Kinetics; 298 K;

: Fe{Al(OCH(CH3)2)4}3

A: aluminium(III) acetylacetonate

B: 14024-18-1
iron(III)-acetylacetonate

Conditions

Conditions	Yield
With acetylacetone In benzene byproducts: isopropanol; anhydrous conditions; molar ratio=1:12; distn.;

: [Fe(NCtBu2)4]

: 123-54-6
acetylacetone

: 14024-18-1
iron(III)-acetylacetonate

Conditions

Conditions	Yield
In benzene-d6 for 0.166667h; Solvent; Inert atmosphere;

: iron(III) chloride

: 123-54-6
acetylacetone

: 14024-18-1
iron(III)-acetylacetonate

Conditions

Conditions	Yield
Stage #1: iron(III) chloride In ethanol at 110 - 130℃; for 4h; Stage #2: acetylacetone With sodium acetate for 24h; Reagent/catalyst;

: iron(III) chloride hexahydrate

: 123-54-6
acetylacetone

: 14024-18-1
iron(III)-acetylacetonate

Conditions

Conditions	Yield
Stage #1: iron(III) chloride hexahydrate With potassium hydroxide In water pH=8; Stage #2: acetylacetone In methanol; water at 70 - 75℃; for 0.333333h;

: 14024-18-1
iron(III)-acetylacetonate

: ferric hydroxide

Conditions

Conditions	Yield
With alkali In water immediate pptn.;;	100%
With alkali In water immediate pptn.;;	100%
In water on boiling;;
In water on boiling;;

: 14024-18-1
iron(III)-acetylacetonate

: 4201-86-9
tris(2-mercaptoethyl)amine

: 201230-82-2
carbon monoxide

: 220024-67-9
[Fe(Fe(CO)(N(CH2CH2S)3))2]

Conditions

Conditions	Yield
In acetonitrile (N2); using Schlenk techniques; stirring of soln. of (Fe(acac)3) (2 mmol) and N(CH2CH2SH)3 (3 mmol) in MeCN under CO atmosphere for 20 min (two thirds of mol of CO per mol of Fe);	100%
In dimethyl sulfoxide (N2); using Schlenk techniques; stirring of soln. of (Fe(acac)3) (2 mmol) and N(CH2CH2SH)3 (3 mmol) in dmso under CO atmosphere for 20 min (two thirds of mol of CO per mol of Fe); filtration under CO; pptn.; elem. anal.;	59%
In dimethyl sulfoxide (N2); using Schlenk techniques; mixing of soln. of (Fe(acac)3) (0.5 mmol) in MeCN and N(CH2CH2SH)3 (0.5 mmol) in MeCN; evacuation and filling with CO atmosphere for week (two thirds of mol of CO per mol of Fe); filtration under CO; crystn., filtration, washing with ether, drying in vac.;
In N,N-dimethyl-formamide (N2); using Schlenk techniques; mixing of soln. of (Fe(acac)3) and N(CH2CH2SH)3 in DMF under CO atmosphere (two thirds of mol of CO per mol of Fe);

...Expand

: 14024-18-1
iron(III)-acetylacetonate

: 866-54-6
diethyldithiophosphinic acid

: Fe(3+)*3PS2(C2H5)2(1-)=Fe(PS2(C2H5)2)3

Conditions

Conditions	Yield
In not given stoich. mixt. in solvent (benzene, toluene, acetone, ethanol, butanol orchloroform) refluxing for 3-4 h; solid sepn. by filtration, washing several times with EtOH, drying at 105°C to const. weight; elem. anal., TG, DTG, DTA;	99%
In neat (no solvent) stoich. mixt. heating a little over m.p. of the acid for 3-4 h; solid sepn. by filtration, washing several times with EtOH, drying at 105°C to const. weight; elem. anal.;	99%

: 14024-18-1
iron(III)-acetylacetonate

: 14278-72-9
diphenylthiophosphinic acid

: Fe(3+)*3POS(C6H5)2(1-)=Fe(POS(C6H5)2)3

Conditions

Conditions	Yield
In not given stoich. mixt. in solvent (benzene, toluene, acetone, ethanol, butanol orchloroform) refluxing for 3-4 h; solid sepn. by filtration, washing several times with EtOH, drying at 105°C to const. weight; elem. anal., TG, DTG, DTA;	99%
In neat (no solvent) stoich. mixt. heating a little over m.p. of the acid for 3-4 h; solid sepn. by filtration, washing several times with EtOH, drying at 105°C to const. weight; elem. anal.;	99%

: 14024-18-1
iron(III)-acetylacetonate

: 813-76-3
diethylphosphinic acid

: iron diethylphosphinate

Conditions

Conditions	Yield
In not given stoich. mixt. in solvent (benzene, toluene, acetone, ethanol, butanol orchloroform) refluxing for 3-4 h; solid sepn. by filtration, washing several times with EtOH, drying at 105°C to const. weight; elem. anal., TG, DTG, DTA;	99%
In neat (no solvent) stoich. mixt. heating a little over m.p. of the acid for 3-4 h; solid sepn. by filtration, washing several times with EtOH, drying at 105°C to const. weight; elem. anal.;	99%

: 14024-18-1
iron(III)-acetylacetonate

: 866-53-5
diethyl-phosphinothioic acid

: Fe(3+)*3POS(C2H5)2(1-)=Fe(POS(C2H5)2)3

Conditions

Conditions	Yield
In not given stoich. mixt. in solvent (benzene, toluene, acetone, ethanol, butanol orchloroform) refluxing for 3-4 h; solid sepn. by filtration, washing several times with EtOH, drying at 105°C to const. weight; elem. anal., TG, DTG, DTA;	99%
In neat (no solvent) stoich. mixt. heating a little over m.p. of the acid for 3-4 h; solid sepn. by filtration, washing several times with EtOH, drying at 105°C to const. weight; elem. anal.;	99%

: 14024-18-1
iron(III)-acetylacetonate

: 1015-38-9
diphenylphosphinodithioic acid

: Fe(3+)*3PS2(C6H5)2(1-)=Fe(PS2(C6H5)2)3

Conditions

Conditions	Yield
In neat (no solvent) stoich. mixt. heating a little over m.p. of the acid for 3-4 h; solid sepn. by filtration, washing several times with EtOH, drying at 105°C to const. weight; elem. anal.;	99%
In not given stoich. mixt. in solvent (benzene, toluene, acetone, ethanol, butanol orchloroform) refluxing for 3-4 h; solid sepn. by filtration, washing several times with EtOH, drying at 105°C to const. weight; elem. anal., TG, DTG, DTA;	99%

: 14024-18-1
iron(III)-acetylacetonate

: 866-32-0
dibutylphosphinic acid

: Fe(3+)*3PO2(C4H9)2(1-)=Fe(PO2(C4H9)2)3

Conditions

Conditions	Yield
In not given stoich. mixt. in solvent (benzene, toluene, acetone, ethanol, butanol orchloroform) refluxing for 3-4 h; solid sepn. by filtration, washing several times with EtOH, drying at 105°C to const. weight; elem. anal., TG, DTG, DTA;	99%
In neat (no solvent) stoich. mixt. heating a little over m.p. of the acid for 3-4 h; solid sepn. by filtration, washing several times with EtOH, drying at 105°C to const. weight; elem. anal.;	99%

: 14024-18-1
iron(III)-acetylacetonate

: 1707-03-5
diphenyl-phosphinic acid

: Fe(3+)*3PO2(C6H5)2(1-)=Fe(PO2(C6H5)2)3

Conditions

Conditions	Yield
In not given stoich. mixt. in solvent (benzene, toluene, acetone, ethanol, butanol orchloroform) refluxing for 3-4 h; solid sepn. by filtration, washing several times with EtOH, drying at 105°C to const. weight; elem. anal., TG, DTG, DTA;	99%
In neat (no solvent) stoich. mixt. heating a little over m.p. of the acid for 3-4 h; solid sepn. by filtration, washing several times with EtOH, drying at 105°C to const. weight; elem. anal.;	99%

: 14024-18-1
iron(III)-acetylacetonate

: 104556-07-2
Desferri-danoxamin

: danoxamine

Conditions

Conditions	Yield
In methanol at 40℃; for 2h; Inert atmosphere;	99%
In methanol at 40℃; for 2h; Inert atmosphere;	99%

: 14024-18-1
iron(III)-acetylacetonate

: 62132-82-5
2,9,16,23-tetra-tert-butylphthalocyanine

: [iron(III)(tetra-tert-butylphthalocyanine)(acetylacetonate)]

Conditions

Conditions	Yield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In 1,2-dichloro-benzene to a soln. of C32H14N8 in C6H4Cl2, DBU and Fe complex added; heated at 150°C for 1.5 h; pptd. by CH3OH; UV-vis and TLC control; detd. by MALDI-TOF mass-spectrometry;	98%

: 35984-93-1
2,9,16,23-tetra-t-butyl-29H,31H-phthalocyanine

: 14024-18-1
iron(III)-acetylacetonate

: C53H55FeN8O2

Conditions

Conditions	Yield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In 1,2-dichloro-benzene at 150℃; for 1.5h;	98%

: 14024-18-1
iron(III)-acetylacetonate

: trocCl

: C34H42FeN5O12

Conditions

Conditions	Yield
In methanol at 40℃; for 2h;	98%

: 14024-18-1
iron(III)-acetylacetonate

: 147-93-3
Thiosalicylic acid

: 3260-92-2
2-acetyl-3-hydroxybenzo[b]thiophene

Conditions

Conditions	Yield
Stage #1: iron(III)-acetylacetonate; Thiosalicylic acid In ethylene glycol at 120℃; for 4h; Inert atmosphere; Stage #2: With hydrogenchloride In water; ethylene glycol at 20℃; Inert atmosphere;	97%
Stage #1: iron(III)-acetylacetonate; Thiosalicylic acid In ethylene glycol at 120℃; Inert atmosphere; Stage #2: With hydrogenchloride In water; ethylene glycol for 0.5h;

: 14024-18-1
iron(III)-acetylacetonate

: 1394037-06-9
C26H47N5O11

: 1394037-07-0
C26H44FeN5O11

Conditions

Conditions	Yield
In methanol at 40℃; for 2h; Inert atmosphere;	97%

: 288-13-1
NH-pyrazole

: 14024-18-1
iron(III)-acetylacetonate

: iron(III) pyrazolate

Conditions

Conditions	Yield
In neat (no solvent) Fe(acac)3 and pyrazole were heated under N2 for 6 h at 180°C; mixt. was allowed to cool, washed with acetone and filtered; elem. anal.;	96.6%

: 14024-18-1
iron(III)-acetylacetonate

: 85324-36-3
(R,S)-2-(diphenylphosphinoyl)propanoic acid

: [Fe((C6H5)2P(O)CH(CH3)CO2)3]*H2O*CH2Cl2

Conditions

Conditions	Yield
In tetrahydrofuran stirring (3 d); addn. of Et2O, standing (4°C, overnight), filtration, washing (Et2O), drying in air, recrystn. (toluene/CH2Cl2, 4°C, several d), filtration, washing (toluene), drying in air; elem. anal.;	95%

: 14024-18-1
iron(III)-acetylacetonate

: 1394037-22-9
C30H55N5O11

: 1394037-23-0
C30H52FeN5O11

Conditions

Conditions	Yield
In methanol at 40℃; for 2h; Inert atmosphere;	95%

: 14024-18-1
iron(III)-acetylacetonate

: [(pentamethylcyclopentadienyl)(tropolonyl)ruthenium(II)]hexafluorophosphate

: tris[(pentamethylcyclopentadienyl)(tropolonyl)ruthenium(II)]iron(III)tris(hexafluorophosphate)

Conditions

Conditions	Yield
In dichloromethane	95%

: 14024-18-1
iron(III)-acetylacetonate

: 36653-82-4
1-Hexadecanol

A: 56072-26-5
4-hydroxy-5-methylpentan-2-one

B: 629-70-9
hexadecyl acetate

C: 506-13-8
16-hydroxyhexadecanoic acid

: iron(III) oxide

Conditions

Conditions	Yield
at 80 - 300℃; under 760.051 Torr; for 2h; Green chemistry;	A n/a B n/a C n/a D 95%

...Expand

: 366-18-7
[2,2]bipyridinyl

: 14024-18-1
iron(III)-acetylacetonate

: 6063-88-3
methoxydimethylaluminium

: (CH3)2Fe(2,2'-bipyridyl)2

Conditions

Conditions	Yield
In diethyl ether under Ar; a mixt. of Fe-contg. compd. (12.9 mmol) and a ligand (30.3 mmol) in Et2O was treated dropwise at ca. -20°C with a soln. of AlMe2(OMe); the mixt. was allowed to warm up to room temp. and stirred at this temp. for 12 h; the suspn. was dild. with Et2O and the solid was filtered off, washed with Et2O, C7H16 and dried in vac.; IR-, NMR spectra;	93%

...Expand

: 14024-18-1
iron(III)-acetylacetonate

: 20324-50-9
5-chloro-2-mercapto-benzoic acid

: 873381-10-3
1-(5-chloro-3-hydroxy-benzo[b]thiophen-2-yl)-ethanone

Conditions

Conditions	Yield
Stage #1: iron(III)-acetylacetonate; 5-chloro-2-mercapto-benzoic acid In ethylene glycol at 120℃; Inert atmosphere; Stage #2: With hydrogenchloride In water; ethylene glycol at 20℃; Inert atmosphere;	93%

: 14024-18-1
iron(III)-acetylacetonate

: Desferri-danoxamin-methylester

: danoxamine-methyl ester

Conditions

Conditions	Yield
In methanol at 40℃; for 2h; Inert atmosphere;	93%

: 14024-18-1
iron(III)-acetylacetonate

: 13115-24-7
N-methylacetohydroxamic acid

: [Fe(N-methylacetohydroxamate)3]

Conditions

Conditions	Yield
In methanol at 20℃; for 2h;	93%

: 14024-18-1
iron(III)-acetylacetonate

: 876033-97-5
N(CH2CH2NHCOC5H2NCH3OOH)2(CH2CH2NHCOC6H2(OH)2CONHCH2CH2OCH3)*HCl

: potassium hydroxide

: K(1+)*Fe(N(C2H4NHCOC6H5NO2)2(C2H4NHCOC6H2O2CONHC3H7O))(1-)*4H2O=K(Fe(N(C2H4NHCOC6H5NO2)2(C2H4NHCOC6H2O2CONHC3H7O)))*4H2O

Conditions

Conditions	Yield
In methanol under N2 atm. to soln. ligand in MeOH soln. KOH in MeOH was added, soln.Fe(acac)3 in MeOH was added and stirred for 1 h; soln. was concd. and added to ether, ppt. was centrifugated, solid was suspended in ether and filtered; elem. anal.;	92.4%

...Expand

: 14024-18-1
iron(III)-acetylacetonate

: desferriferrithiocin monohydrate

: potassium hydroxide

: K(1+)*Fe(OC5H3NC3H2NS(CH3)COO)2(1-)*2.5H2O=K[Fe(OC5H3NC3H2NS(CH3)COO)2]*2.5H2O

Conditions

Conditions	Yield
In water portionwise addn. of equimolar amts. of Fe(acac)3 and 0.1 M KOH to 2 equiv. of ligand, stirring (room temp., 20 h); filtration, solvent removal, chromy. (Sephadex LH-20, MeOH), solvent removal; elem. anal.;	92%

...Expand

: 14024-18-1
iron(III)-acetylacetonate

: C8H10F3O2(1-)*Na(1+)

: iron(II) chloride

: C63H81F18Fe3Na2O18

Conditions

Conditions	Yield
In neat (no solvent, solid phase) at 70℃; for 168h; Sealed tube;	92%
In hexane for 1h; Inert atmosphere;	90%

...Expand

: 14024-18-1
iron(III)-acetylacetonate

: 876108-42-8
N(CH2CH2NHCOC6H2(OH)2CONHCH2CH2OCH3)3

: potassium hydroxide

: 3K(1+)*Fe(N(C2H4NHCOC6H2O2CONHC3H7O)3)(3-)*6H2O=K3(Fe(N(C2H4NHCOC6H2O2CONHC3H7O)3))*6H2O

Conditions

Conditions	Yield
In methanol under N2 atm. to soln. ligand in MeOH soln. KOH in MeOH was added, soln.Fe(acac)3 in MeOH was added and stirred for 1 h; soln. was concd. and added to ether, ppt. was centrifugated, solid was suspended in ether and filtered; elem. anal.;	91.7%

...Expand

: 14024-18-1
iron(III)-acetylacetonate

: 3,6,13-tribromo-2,7,12,17-tetra-n-propylporphycene

: 7732-18-5
water

: 753011-11-9
μ-oxodi[iron(III)(3,6,13-tribromo-2,7,12,17-tetra-n-propylporphycenato)]

Conditions

Conditions	Yield
With NaOH In dichloromethane reflux in phenol for 20 min, phenol was evapd. in vac., residue was dissolved in CH2Cl2, stirred with aq. NaOH over 1 h; soln. was washed with H2O, org. layer was dried over Na2SO4, mixt. was filtered, filtrate was concd. and dried in vac., recrysn. from CHCl3/MeOH, elem. anal.;	91%

...Expand

Ferric acetylacetonate Consensus Reports

Reported in EPA TSCA Inventory.

Ferric acetylacetonate Specification

The CAS register number of Ferric acetylacetonate is 14024-18-1. The IPUAC name about this chemicals is Iron(3+) , 4-oxopent-2-en-2-olate .It is stable and incompatible with strong bases, strong oxidizing agents. Although onechemicals only has one CAS number, it can have other registry number. Like this chemicals, it has two other registry number 38335-93-2 and 75042-68-1. It belongs to the following product categories, such as Organometallics; Catalysts for Organic Synthesis, Classes of Metal Compounds; Environmentally-Friendly Oxidation; Fe (Iron) Compounds; Homogeneous Catalysts; Metal Complexes; Synthetic Organic Chemistry; Transition Metal Complexes (Environmentally-friendly Oxidation) and Transition Metal Compounds.

The Ferric acetylacetonate is dark red powder and it slightly soluble in water. It is sensitive to humidity. It can be used as catalyst, promoting agents. If you want to use it, you should be more careful, because it is harmful if swallowed and it is irritating to eyes. In the use process, you need to wear suitable gloves and eye/face protection. In case of contacting with eyes you should rinse immediately with plenty of water and seek medical advice. If you want to hand it, please wash thoroughly after handling, use with adequate ventilation and avoid contacting with skin and eyes. If you want to store it, please store in a tightly closed container and in a cool, dry, well-ventilated area away from incompatible substances.

This chemicals can be described computed from structure:
1) Canonical SMILES: CC(=CC(=O)C)[O-].CC(=CC(=O)C)[O-].CC(=CC(=O)C)[O-].[Fe+3]
2) InChI: InChI=1S/3C5H8O2.Fe/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3
3) InChIKey: AQBLLJNPHDIAPN-UHFFFAOYSA-K

The most important thing about Ferric acetylacetonate is the toxicity, following is the form:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
mouse	LD50	intraperitoneal	76mg/kg (76mg/kg)		Chemotherapy Vol. 16, Pg. 371, 1971.
mouse	LD50	intravenous	100mg/kg (100mg/kg)		U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#02372,

Product Name

Ferric acetylacetonate

Synthetic route

Ferric acetylacetonate Consensus Reports

Ferric acetylacetonate Specification

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