Iododimethylarsine supplier

Name
DIMETHYLARSENIC IODIDE
EINECS 211-630-2
CAS No. 676-75-5
Article Data32
CAS DataBase
Density
Solubility
Melting Point
Formula C2H6 As I
Boiling Point 133.4 °C at 760 mmHg
Molecular Weight 231.896
Flash Point 45.1 °C
Transport Information
Appearance
Safety
Risk Codes
Molecular Structure
Hazard Symbols
Synonyms Arsine,iododimethyl- (6CI,7CI,8CI); Dimethylarsine iodide; Dimethylarsinous iodide;Dimethyliodoarsine; Iododimethylarsine
PSA 0.00000
LogP 1.67250

Synthetic route

: 75-60-5
Dimethylarsinic acid

: 676-75-5
dimethyliodoarsine

Conditions

Conditions	Yield
With sulfuric acid; sulfur dioxide; potassium iodide In water for 3h;	76%
With sulfuric acid; sulfur dioxide; potassium iodide
With hydrogenchloride; sulfur dioxide; potassium iodide
Multistep reaction;
With sulfuric acid; sulfur dioxide; potassium iodide In water

: 124-65-2
sodium cacodylate

: 676-75-5
dimethyliodoarsine

Conditions

Conditions	Yield
With hydrogenchloride; sulfur dioxide; potassium iodide In water for 2h;	54%

: 101-02-0
triphenyl phosphite

: dimethylarsinosulfenyl iodide

A: 676-75-5
dimethyliodoarsine

B: 597-82-0
O,O,O-triphenyl phosphorothioate

Conditions

Conditions	Yield
In chloroform-d1 for 6h;	A 22% B n/a

...Expand

: 593-57-7
dimethylarsine

: 507-02-8
acetyl iodide

A: 676-75-5
dimethyliodoarsine

B: 75-07-0
acetaldehyde

...Expand

: 557-89-1
Dimethylchloroarsine

: 676-75-5
dimethyliodoarsine

Conditions

Conditions	Yield
With ethanol; potassium iodide unter Luftausschluss;
With acetone; sodium iodide unter Luftausschluss;

: 503-80-0
bis-{dimethylarsenic}-oxide

: 676-75-5
dimethyliodoarsine

Conditions

Conditions	Yield
With hydrogen iodide bei der Destillation;

: 5814-21-1
tetramethyl-arsonium; triiodide

A: 676-75-5
dimethyliodoarsine

B: 74-88-4
methyl iodide

Conditions

Conditions	Yield
Zersetzt sich beim Erhitzen;

: 471-35-2
tetramethyldiarsine

: 74-88-4
methyl iodide

: 676-75-5
dimethyliodoarsine

: 471-35-2
tetramethyldiarsine

: 74-88-4
methyl iodide

A: 676-75-5
dimethyliodoarsine

B: 5814-20-0
tetramethylarsonium iodide

Conditions

Conditions	Yield
analog reagiert Aethyljodid;

...Expand

: 74-88-4
methyl iodide

: 7207-97-8
methyldiiodoarsine

: 676-75-5
dimethyliodoarsine

Conditions

Conditions	Yield
With sodium hydroxide; ethanol und reduziert das Reaktionsprodukt in salzsaurer Loesung mit Schwefeldioxyd;
With sodium hydroxide anschliessend mit wss.HCl und SO2;

: 74-88-4
methyl iodide

: 676-75-5
dimethyliodoarsine

Conditions

Conditions	Yield
With arsenic

: 696-26-4
dimethylphenylarsine

: 676-75-5
dimethyliodoarsine

Conditions

Conditions	Yield
With hydrogen iodide In dichloromethane

: 6618-05-9
Tri-methylsilyl-(dimethyl)-arsan

: 676-75-5
dimethyliodoarsine

Conditions

Conditions	Yield
With Iodine monochloride

: 74-88-4
methyl iodide

: 7207-97-8
methyldiiodoarsine

aqueous-alcoholic NaOH-solution: aqueous-alcoholic NaOH-solution

: 676-75-5
dimethyliodoarsine

...Expand

(CH3)4AsI+I2: (CH3)4AsI+I2

: 676-75-5
dimethyliodoarsine

Conditions

Conditions	Yield
bei der Destillation;

: 7647-01-0
hydrogenchloride

: 75-60-5
Dimethylarsinic acid

sulfur dioxide: sulfur dioxide

potassium iodide: potassium iodide

: 676-75-5
dimethyliodoarsine

...Expand

: 75-60-5
Dimethylarsinic acid

: 7664-93-9
sulfuric acid

sulfur dioxide: sulfur dioxide

potassium iodide: potassium iodide

: 676-75-5
dimethyliodoarsine

...Expand

: 75-60-5
Dimethylarsinic acid

: 10034-85-2
hydrogen iodide

A: 676-75-5
dimethyliodoarsine

B: 7732-18-5
water

C: 7553-56-2
iodine

...Expand

: 7732-18-5
water

: iodo-dimethyl-arsine; hydriodide

A: 676-75-5
dimethyliodoarsine

B: 10034-85-2
hydrogen iodide

...Expand

: arsenic

: 74-88-4
methyl iodide

A: 676-75-5
dimethyliodoarsine

B: 7784-45-4
arsenic triiodide

C: 5814-20-0
tetramethylarsonium iodide

D: 7207-97-8
methyldiiodoarsine

Conditions

Conditions	Yield
In not given reaction of CH3I with amorphous As at room temperature;;

...Expand

: 591-10-6
cacodyl sulfide

: 17933-09-4
dimethyl iodoborane

A: 676-75-5
dimethyliodoarsine

B: 31732-46-4
(CH3)2AsSB(CH3)2

...Expand

: dimethylarsinosulfenyl iodide

: 603-35-0
triphenylphosphine

A: 676-75-5
dimethyliodoarsine

B: 59840-68-5
dimethylarsino dimethyldithioarsinate

C: 3878-45-3
triphenylphosphine sulfide

Conditions

Conditions	Yield
In chloroform-d1 for 1h;

...Expand

: 18535-43-8, 15444-72-1
(ClMn(CO)4)2

: 676-75-5
dimethyliodoarsine

: 480431-38-7
Mn(CO)4Cl(As(CH3)2I)

Conditions

Conditions	Yield
In melt Mn2(CO)8Cl2 in ampoule cooled to -196 °C, (CH3)2AsI added, held at 60 °C 4 h, cooled to room temp.; sublimated in vac., elem. anal.;	100%

: 14100-30-2
pentacarbonylchloromanganese(I)

: 676-75-5
dimethyliodoarsine

: 480431-38-7
Mn(CO)4Cl(As(CH3)2I)

Conditions

Conditions	Yield
In melt byproducts: CO; Mn(CO)5Cl in ampoule cooled to -196 °C, (CH3)2AsI added, held at 60 °C 4 h, cooled to room temp.; sublimated in vac., elem. anal.;	100%

: 14879-42-6
iodo(pentacarbonyl)manganese(I)

: 676-75-5
dimethyliodoarsine

: 70675-98-8
Mn(CO)4I(As(CH3)2I)

Conditions

Conditions	Yield
In melt byproducts: CO; Mn(CO)5I in ampoule cooled to -196 °C, (CH3)2AsI added, held at 80 °C 4 h, cooled to room temp.; sublimated in vac., elem. anal.;	100%

: 14516-54-2
bromopentacarbonylmanganese(I)

: 676-75-5
dimethyliodoarsine

: 480431-39-8
Mn(CO)4Br(As(CH3)2I)

Conditions

Conditions	Yield
In melt byproducts: CO; Mn(CO)5Br in ampoule cooled to -196 °C, (CH3)2AsI added, held at 70 °C 4 h, cooled to room temp.; sublimated in vac., elem. anal.;	100%

: 15680-90-7
Mn2(CO)8I2

: 676-75-5
dimethyliodoarsine

: 70675-98-8
Mn(CO)4I(As(CH3)2I)

Conditions

Conditions	Yield
In melt Mn2(CO)8I2 in ampoule cooled to -196 °C, (CH3)2AsI added, held at80 °C 4 h, cooled to room temp.; sublimated in vac., elem. anal.;	100%

: 18535-44-9
[Mn2Br2(CO)8]

: 676-75-5
dimethyliodoarsine

: 480431-39-8
Mn(CO)4Br(As(CH3)2I)

Conditions

Conditions	Yield
In melt Mn2(CO)8Br2 in ampoule cooled to -196 °C, (CH3)2AsI added, held at 70 °C 4 h, cooled to room temp.; sublimated in vac., elem. anal.;	100%

: 676-75-5
dimethyliodoarsine

AsF5: AsF5

: 126949-78-8
Diiodo(dimethyl)arsen(V)-hexafluoroarsenat

Conditions

Conditions	Yield
With iodine monofluoride In trichlorofluoromethane 1.) -78 deg C, 15 min, 2.) RT, 30 min;	95%

: 676-75-5
dimethyliodoarsine

: 75744-91-1
3,4,6-tri-O-benzoyl-2-deoxy-1-thio-β-D-arabino-hexopyranose

: 75744-95-5
3,4,6-tri-O-benzoyl-2-deoxy-1-S-dimethylarsino-1-thio-β-D-arabino-hexopyranose

Conditions

Conditions	Yield
With pyridine In dichloromethane Heating;	90%

: 676-75-5
dimethyliodoarsine

: C22H16(2-)*2C6H16N2*2Li(1+)

: 121334-94-9
2,2'-bis(dimethylarsinomethyl)-1,1'-binaphthyl

Conditions

Conditions	Yield
In tetrahydrofuran Ambient temperature;	90%

: (η(5)-cyclopentadienyl)W(CO)2(C(CH3))

: 676-75-5
dimethyliodoarsine

: carbonyliodo(η5cyclopentadienyl)(η3-dimethylarsino-methylketen)tungsten

Conditions

Conditions	Yield
In dichloromethane (Ar); addn. of org. compd. to W-complex in CH2Cl2, stirring (-78°C); pptn. on addn. of ether/pentane, recryst. (CH2Cl2/ether/pentane), drying (high vac., room temp.); elem. anal.;	86%

: carbonyl(η5-cyclopentadienyl)(η2-4-methylphenylketenyl)trimethylphosphinetungsten

: 676-75-5
dimethyliodoarsine

: 86508-28-3
Carbonyl(η5-cyclopentadienyl)[(dimethylarsino)(4-methylphenyl)keten]iodo(trimethylphosphan)wolfram

Conditions

Conditions	Yield
In dichloromethane under Ar, dropping of AsI(CH3)2 to the solution of η2-ketenyl complex in dichloromethane at room temp., stirred for 1 h; evapn. in vac., extn. with ether/pentane, recrystn. evapn. in vac., elem. anal.;	85%

: (C5H5)W(CO)(P(CH3)3)(CH3CCO)

: 676-75-5
dimethyliodoarsine

: 89672-92-4
Carbonyl(η5-cyclopentadienyl)[(dimethylarsino)methylketen]iodo(trimethylphosphan)wolfram

Conditions

Conditions	Yield
In dichloromethane under Ar, dropping of AsI(CH3)2 to the solution of η2-ketenyl complex in dichloromethane at room temp., stirred for 1 h; evapn. in vac., extn. with ether/pentane, recrystn. evapn. in vac., elem. anal.;	82%

: 107087-45-6, 86013-21-0
(tris(2-diphenylphosphinoethyl)amin)Pd

: 676-75-5
dimethyliodoarsine

: 143-66-8
sodium tetraphenyl borate

: 132108-07-7
{(N(CH2CH2P(C6H5)2)3)PdAs(CH3)2}(1+)*B(C6H5)4(1-)={(N(CH2CH2P(C6H5)2)3)PdAs(CH3)2}B(C6H5)4

Conditions

Conditions	Yield
In ethanol; benzene byproducts: NaI; Room temp. reaction of (np3)Pd with equimolar quantities of Me2AsI in benzene-ethanol soln. under a nitrogen atmosphere.;	80%

...Expand

: 123224-08-8
(tris(2-diphenylphosphinoethyl)amin)Pt(PPh3)

: 676-75-5
dimethyliodoarsine

: 143-66-8
sodium tetraphenyl borate

: 132108-28-2
{(N(CH2CH2P(C6H5)2)3)PtAs(CH3)2}(1+)*B(C6H5)4(1-)={(N(CH2CH2P(C6H5)2)3)PtAs(CH3)2}B(C6H5)4

Conditions

Conditions	Yield
In ethanol; benzene byproducts: NaI; Room temp. reaction of (np3)Pt(PPh3) with equimolar quantities of Me2AsI in benzene-ethanol soln. under a nitrogen atmosphere.;	80%

...Expand

: 697302-50-4, 697302-51-5, 12082-08-5, 697302-53-7
(benzene)tricarbonylchromium

: 676-75-5
dimethyliodoarsine

: 186464-78-8
(η6-phenyl)tricarbonylchromium dimethylarsine

Conditions

Conditions	Yield
With n-C4H9Li In tetrahydrofuran (Ar); addn. of n-BuLi in hexane to cold soln. of Cr-complex in THF at .-78°C; stirred for 60 min; addn. of Me2AsI in THF; stirred for 60 min at -78°C; slowly warmed to room temp.;; filtration (through SiO2); solvent removed (reduced pressure); crystn. (hexane/CH2Cl2); elem. anal.;	70%
With BuLi In tetrahydrofuran; hexane Ar-atmosphere; addn. of 1 equiv. BuLi (in hexane) to Cr-complex (in THF)at -78°C, stirring (-78°C), addn. of arsine, stirring (-7 8°C, then room temp.); evapn., dissoln. in CH2Cl2, filtration, evapn.; elem. anal.;	70%

: 103-83-3
N,N'-dimethylbenzylamine

: 676-75-5
dimethyliodoarsine

: (2-dimethylarsanyl-benzyl)-dimethyl-amine

Conditions

Conditions	Yield
Stage #1: N,N'-dimethylbenzylamine With n-butyllithium In diethyl ether; hexane for 24h; Stage #2: dimethyliodoarsine In diethyl ether for 5h;	67%
Stage #1: N,N'-dimethylbenzylamine With n-butyllithium Stage #2: dimethyliodoarsine

: hexaaquanickel(II) perchlorate

: 676-75-5
dimethyliodoarsine

: 7440-23-5
sodium

: 167384-01-2
(+/-)-1-Chloro-2-(methylphenylphosphino)benzene

: [Ni((+/-)-1-(dimethylarsino)-2-(methylphenylphosphino)benzene)2][ClO4]2

Conditions

Conditions	Yield
In acetone byproducts: tetramethyldiarsane, methyldiphenylphosphine, methylphenylphosphine; Ar-atmosphere; addn. of Na-foil to Me2AsI (in THF), filtration, addn. to chlorophosphine (-78°C), stirring for 48 h (-20°C), evapn., treatment with CH2Cl2/H2O, evapn. of org. layer, fractional distn., treatment with Ni(ClO4)2 (pptn.); collection, washing (Et2O), drying (vac.); second crop on evapn. of filtrate, extn. into Et2O and addn. of Ni(ClO4)2 (in acetone soln.); elem. anal.;	67%

Yield

In acetone byproducts: tetramethyldiarsane, methyldiphenylphosphine, methylphenylphosphine; Ar-atmosphere; addn. of Na-foil to Me2AsI (in THF), filtration, addn. to chlorophosphine (-78°C), stirring for 48 h (-20°C), evapn., treatment with CH2Cl2/H2O, evapn. of org. layer, fractional distn., treatment with Ni(ClO4)2 (pptn.); collection, washing (Et2O), drying (vac.); second crop on evapn. of filtrate, extn. into Et2O and addn. of Ni(ClO4)2 (in acetone soln.); elem. anal.;

67%

...Expand

: 36989-07-8
1-diphenylphosphinomethyl-1,2-dicarba-closo-dodecaborane

: 676-75-5
dimethyliodoarsine

: 93370-16-2
1-dimethylarsino-2-diphenylphosphinomethyl-o-carborane

Conditions

Conditions	Yield
With hydrogenchloride; n-butyllithium In benzene inert atmosphere; dropwise addn. of BuLi soln. to B-compd., mixt. stirring (1h), Me2AsCl addn., mixt. heating until reaction complete, cooling,treatment with dild. HCl; extn. (ether), extract drying (Na2SO4), evapn., residue chromy. (silicagel); elem. anal.;	66%

: 676-75-5
dimethyliodoarsine

: 821-48-7
bis-(2-chloroethyl)amine hydrochloride

: 117013-44-2
bis<-2(dimethylarsinoethyl)>amine

Conditions

Conditions	Yield
In tetrahydrofuran for 3h;	65%

: 676-75-5
dimethyliodoarsine

: 75745-01-6
1,3,4-tri-O-acetyl-2-deoxy-6-thio-β-D-arabino-hexopyranose

: 75745-02-7
1,3,4-tri-O-acetyl-2-deoxy-6-S-dimethylarsino-6-thio-β-D-arabino-hexopyranose

Conditions

Conditions	Yield
With pyridine In toluene for 1h; Heating;	65%

: Fe3(CO)9(SC(CH3)3)(1-)*(CH3)3CNH3(1+)=(Fe3(CO)9(SC(CH3)3))((CH3)3CNH3)

: 676-75-5
dimethyliodoarsine

A: Fe2(CO)6(SC(CH3)3)(As(CH3)2)

B: 87511-05-5
Fe3(CO)9(μ3-S-t-C4H9)(μ2-As(CH3)2)

Conditions

Conditions	Yield
In diethyl ether; toluene byproducts: [H3N(t-C4H9)]I; under N2, Fe complex dissolved at 20°C in Et2O, treated with toluene, Me2AsI added, stirred for 1 h at room temp.; SiO2 added, dried in high vac., chromd. (SiO2, -20°C, n-pentane/toluene), evapd., recrystd. from toluene at -30°C; elem. anal.;	A n/a B 64%

...Expand

: 77308-89-5
1-{(dimethylarsino)methyl}-o-carbaborane

: 676-75-5
dimethyliodoarsine

: 93640-20-1
1-(dimethylarsino)-2-[(dimethylarsino)methyl]-o-carbaborane

Conditions

Conditions	Yield
With hydrogenchloride; n-butyllithium In benzene inert atmosphere; dropwise addn. of BuLi soln. to B-compd., mixt. stirring (1h), Ph2PCl addn., mixt. heating until reaction complete, cooling, treatment with dild. HCl; extn. (ether), extract drying (Na2SO4), evapn., residue chromy. (silicagel); elem. anal.;	62%

: 676-75-5
dimethyliodoarsine

: 79807-06-0
C8H20Li4N4P4

: 79807-01-5
2,4,6,8-Tetrakis-dimethylarsanylmethyl-2,4,6,8-tetramethyl-2λ5,4λ5,6λ5,8λ5-[1,3,5,7,2,4,6,8]tetrazatetraphosphocine

Conditions

Conditions	Yield
With potassium fluoride In diethyl ether at -78℃; for 0.166667h;	55%

: 151-56-4
ethyleneimine

: 676-75-5
dimethyliodoarsine

: (2-aminoethyl)-dimethylarsine

Conditions

Conditions	Yield
With sodium In tetrahydrofuran at 35℃; for 60h;	51%

: 676-75-5
dimethyliodoarsine

: 175877-63-1
(R)-2,3-dibenzyloxypropyl 5-bromo-5-deoxy-2,3-O-isopropylidene-β-D-riboside

: 370860-10-9
(R)-2,3-dibenzyloxypropyl 5-deoxy-5-dimethylarsino-2,3-O-isopropylidene-β-D-riboside

Conditions

Conditions	Yield
Stage #1: dimethyliodoarsine With sodium In tetrahydrofuran at 20℃; for 1.5h; Stage #2: (R)-2,3-dibenzyloxypropyl 5-bromo-5-deoxy-2,3-O-isopropylidene-β-D-riboside In tetrahydrofuran for 1h;	41%

: 676-75-5
dimethyliodoarsine

: 370860-11-0
(R)-2,3-dibenzyloxypropyl 5-chloro-5-deoxy-2,3-O-isopropylidene-β-D-riboside

: 370860-10-9
(R)-2,3-dibenzyloxypropyl 5-deoxy-5-dimethylarsino-2,3-O-isopropylidene-β-D-riboside

Conditions

Conditions	Yield
Stage #1: dimethyliodoarsine With sodium In tetrahydrofuran at 20℃; for 1.5h; Stage #2: (R)-2,3-dibenzyloxypropyl 5-chloro-5-deoxy-2,3-O-isopropylidene-β-D-riboside In tetrahydrofuran for 3h;	41%

: 31886-58-5
(R)-N,N-dimethyl-1-ferrocenylethylamine

: 676-75-5
dimethyliodoarsine

: Fe(C5H5)(C5H3)CHCH3N(CH3)2As(CH3)2

Conditions

Conditions	Yield
With n-butyllithium In diethyl ether the amine was stirred with n-BuLi in diethyl ether for 1.5 h, then the halide was added and stirred for 3 h; aq. slurry of NaHCO3 was added and stirred for 1 h before filtration. the ppt. was washed with ether, the filtrate and washings were washed with water, the organic layer was dried over K2CO3 and evapd., then chromd.; elem. anal.;	40%

: (3,3,3-trifluoro propinyl) magnesiumiodide

: 676-75-5
dimethyliodoarsine

: 6618-08-2
Dimethyl-trifluoroprop-1-ynyl-arsane

Conditions

Conditions	Yield
In diethyl ether reaction at 20°C, 2 hours;;	35%
In diethyl ether reaction at 20°C, 2 hours;;	35%

Iododimethylarsine Chemical Properties

IUPAC Name: Iodo(dimethyl)arsane
Synonyms of Iododimethylarsine (CAS NO.676-75-5) : Arsinous iodide, As,As-dimethyl- ; Dimethylarsinous iodide ; Arsine, iododimethyl- ; Dimethylarsenic iodide ; Iododimethylarsine
CAS NO:676-75-5
Molecular Formula:C₂H₆AsI
Molecular Weight :231.8951
Molecular Structure :
EINECS: 211-630-2
Flash Point: 45.1 °C
Enthalpy of Vaporization: 35.56 kJ/mol
Boiling Point: 133.4 °C at 760 mmHg
Vapour Pressure: 10.4 mmHg at 25°C

Iododimethylarsine Consensus Reports

Arsenic and its compounds are on the Community Right-To-Know List.

Iododimethylarsine Safety Profile

Iododimethylarsine (CAS NO.676-75-5) is incompatible with air. Residue from distillation explodes at 72°C. When Iododimethylarsine (CAS NO.676-75-5) is heated to decomposition, it emits toxic fumes of As and I⁻. See also ARSENIC COMPOUNDS, IODIDES, and ACETYLENE COMPOUNDS and ALKYNES.

Product Name

DIMETHYLARSENIC IODIDE

Synthetic route

Iododimethylarsine Chemical Properties

Iododimethylarsine Consensus Reports

Iododimethylarsine Safety Profile

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