Product Name

  • Name

    Magnesium nitrate hexahydrate

  • EINECS 231-104-6
  • CAS No. 13446-18-9
  • Article Data62
  • CAS DataBase
  • Density 1.63 g/cm3
  • Solubility 420 g/L (20 °C ) in water
  • Melting Point 89 °C
  • Formula H12MgN2O12
  • Boiling Point 83 °C at 760 mmHg
  • Molecular Weight 148.315
  • Flash Point -26 °F
  • Transport Information UN 2056 3/PG 2
  • Appearance White colourless crystal
  • Safety 43-7/8-37/39-36-17-26-45-36/37/39-23
  • Risk Codes 34-8-36/37/38
  • Molecular Structure Molecular Structure of 13446-18-9 (Magnesium nitrate hexahydrate)
  • Hazard Symbols CorrosiveC,IrritantXi,OxidizingO
  • Synonyms Nitric acid, magnesiumsalt, hydrate (2:1:6);Dusicnan horecnaty;
  • PSA 193.14000
  • LogP 0.18240

Synthetic route

nitric acid
7697-37-2

nitric acid

magnesium oxide

magnesium oxide

magnesium(II) nitrate
13446-18-9

magnesium(II) nitrate

Conditions
ConditionsYield
In nitric acid mgO dissolved in HNO3;
In water drying the mixing soln. of MgO and HNO3;
In nitric acid prepn. by dissolving MgO in threefold excess of HNO3;
Heating;
In water
ammonium nitrate

ammonium nitrate

magnesium oxide

magnesium oxide

magnesium(II) nitrate
13446-18-9

magnesium(II) nitrate

Conditions
ConditionsYield
In neat (no solvent) byproducts: NH3, H2O; MgO reacted with molten NH4NO3 with formation of Mg(NO3)2, NH3 and H2O;;
byproducts: NH3; H2O;
In neat (no solvent) byproducts: NH3, H2O; MgO reacted with molten NH4NO3 with formation of Mg(NO3)2, NH3 and H2O;;
nitric acid
7697-37-2

nitric acid

magnesium(II) nitrate
13446-18-9

magnesium(II) nitrate

Conditions
ConditionsYield
With magnesium chloride evapn. with excess of HNO3 soln.;>99
With magnesium chloride no reaction at low temp.;0%
With MgCl2 no reaction at low temp.;0%
With MgCl2 evapn. with excess of HNO3 soln.;>99
ammonium nitrate

ammonium nitrate

magnesium
7439-95-4

magnesium

A

magnesium(II) nitrate
13446-18-9

magnesium(II) nitrate

B

ammonia
7664-41-7

ammonia

C

water
7732-18-5

water

Conditions
ConditionsYield
byproducts: N2; 10-20°C above the melting-point;
Nitrogen dioxide
10102-44-0

Nitrogen dioxide

magnesium
7439-95-4

magnesium

magnesium(II) nitrate
13446-18-9

magnesium(II) nitrate

Conditions
ConditionsYield
byproducts: MgO; Mg in form of filings, at dark red heat;
byproducts: MgO; Mg in form of filings, at dark red heat;
magnesium hyponitrate tetrahydrate

magnesium hyponitrate tetrahydrate

A

magnesium hydroxide

magnesium hydroxide

B

magnesium(II) nitrate
13446-18-9

magnesium(II) nitrate

Conditions
ConditionsYield
In neat (no solvent) byproducts: nitrogen oxides; decompn. on thermal dehydration at 130°C with and without vacuum;;
nitric acid
7697-37-2

nitric acid

magnesium carbonate

magnesium carbonate

magnesium(II) nitrate
13446-18-9

magnesium(II) nitrate

Conditions
ConditionsYield
In water
In water
silver nitrate

silver nitrate

magnesium chloride
7786-30-3

magnesium chloride

magnesium(II) nitrate
13446-18-9

magnesium(II) nitrate

Conditions
ConditionsYield
In methanol at 70℃; Inert atmosphere;
methanol
67-56-1

methanol

magnesium(II) nitrate
13446-18-9

magnesium(II) nitrate

[Cu(pyrimidine-2-olate-N1,N3)2]n*nH2O

[Cu(pyrimidine-2-olate-N1,N3)2]n*nH2O

[Cu(pyrimidine-2-olate-N1,N3)2]*0.5Mg(nitrate)2*0.5methanol*0.5water

[Cu(pyrimidine-2-olate-N1,N3)2]*0.5Mg(nitrate)2*0.5methanol*0.5water

Conditions
ConditionsYield
In methanol; water stirring suspn. of copper compd. in 0.05 M soln. of magnesium nitrate in4:1 mixt. of methanol and water for 1 wk at room temp.; elem. anal.;99%
magnesium(II) nitrate
13446-18-9

magnesium(II) nitrate

sodium tetrakis(imidazolyl)borate

sodium tetrakis(imidazolyl)borate

magnesium tetrakis(imidazolyl)borate dihydrate

magnesium tetrakis(imidazolyl)borate dihydrate

Conditions
ConditionsYield
In ethanol; water soln. Na(B(Im)4) in aq. EtOH was layered with aq. soln. Mg(NO3)2, diffusion for 1 week at 60°C; ppt. was filtered; elem. anal.;92%
magnesium(II) nitrate
13446-18-9

magnesium(II) nitrate

monoaqua 3-methoxysalicylaldehyde-ethyldiamine copper(II)
157143-69-6, 41754-70-5

monoaqua 3-methoxysalicylaldehyde-ethyldiamine copper(II)

[Cu(N,N'-ethylenedi(3-methoxysalicylideneimine))]Mg(NO3)2(H2O)

[Cu(N,N'-ethylenedi(3-methoxysalicylideneimine))]Mg(NO3)2(H2O)

Conditions
ConditionsYield
In methanol Cu-compd. and 1 equiv. of alkaline earth-compd. were stirred in MeOH for3 h; ppt. was filtered off, dried, elem. anal.;90%
potassium pyrophosphate

potassium pyrophosphate

magnesium(II) nitrate
13446-18-9

magnesium(II) nitrate

dipotassium magnesium diphosphate tetrahydrate

dipotassium magnesium diphosphate tetrahydrate

Conditions
ConditionsYield
In water molar ratio P2O7(4-) : Mg(2+) = 3 : 1; addn. of soln. of Mg-salt to soln. of diphosphate (stirring, pptn.); standing (24 h), pptn. on use of glass rod (2 h), standing (23 d, pH = 9.45), filtration, washing (ice H2O), drying (room temp.); elem. anal.;87%
In water molar ratio P2O7(4-):Mg(2+) = 4, 0.5 M solns.; pptn. on mixing at 20°C; elem. anal.;
magnesium(II) nitrate
13446-18-9

magnesium(II) nitrate

mono-K,Li-heptadecatungstodiphosphate*18H2O 18H2O*K9LiO61P2W17, α1

mono-K,Li-heptadecatungstodiphosphate*18H2O 18H2O*K9LiO61P2W17, α1

mono-K,Mg-heptadecatungstodiphosphate*17H2O 17H2O*K8MgO61P2W17, α1

mono-K,Mg-heptadecatungstodiphosphate*17H2O 17H2O*K8MgO61P2W17, α1

Conditions
ConditionsYield
In water soln. of metal salt added to Li salt by stirring; filtered, soln. pptd. with KCl, filtered, washed with EtOH and Et2O, air-dried, elem. anal.;80%
magnesium(II) nitrate
13446-18-9

magnesium(II) nitrate

C48H28O16

C48H28O16

water
7732-18-5

water

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

C48H20O16(8-)*4Mg(2+)*4.5C3H7NO*4H2O

C48H20O16(8-)*4Mg(2+)*4.5C3H7NO*4H2O

Conditions
ConditionsYield
at 85℃; for 48h; Sealed tube;70%
magnesium(II) nitrate
13446-18-9

magnesium(II) nitrate

hydrogen fluoride
7664-39-3

hydrogen fluoride

magnesium fluoride (catalyst B)

magnesium fluoride (catalyst B)

Conditions
ConditionsYield
In water at 20 - 400℃;
ammonium metavanadate

ammonium metavanadate

ammonium molibdate

ammonium molibdate

magnesium(II) nitrate
13446-18-9

magnesium(II) nitrate

caesium nitrate

caesium nitrate

zinc(II) nitrate
10196-18-6

zinc(II) nitrate

phosphoric acid
86119-84-8, 7664-38-2

phosphoric acid

copper(II) nitrate

copper(II) nitrate

ferric nitrate
7782-61-8

ferric nitrate

telluric acid
13520-55-3

telluric acid

catalyst 1

catalyst 1

Conditions
ConditionsYield
In water at 95 - 100℃; for 0.25h;
magnesium(II) nitrate
13446-18-9

magnesium(II) nitrate

alumina hydrate

alumina hydrate

Modified catalyst support EXAMPLE S1

Modified catalyst support EXAMPLE S1

Conditions
ConditionsYield
Stage #1: magnesium(II) nitrate; alumina hydrate In water at 100℃; for 16h;
Stage #2: at 725℃; for 4h;
aluminum oxide
1333-84-2, 1344-28-1

aluminum oxide

magnesium(II) nitrate
13446-18-9

magnesium(II) nitrate

(71)Al00136MgO0.29

(71)Al00136MgO0.29

Conditions
ConditionsYield
Stage #1: aluminum oxide; magnesium(II) nitrate In water at 90 - 150℃;
Stage #2: at 800℃;
magnesium(II) nitrate
13446-18-9

magnesium(II) nitrate

ferric nitrate
7782-61-8

ferric nitrate

Reaxys ID: 11371820

Reaxys ID: 11371820

Conditions
ConditionsYield
Stage #1: magnesium(II) nitrate; ferric nitrate With sodium hydroxide; sodium carbonate In water at 50℃; for 0.666667h; pH=10;
Stage #2: at 20 - 650℃; for 8h;
magnesium(II) nitrate
13446-18-9

magnesium(II) nitrate

sodium nitrate
7631-99-4

sodium nitrate

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

hypophosphorous acid
6303-21-5

hypophosphorous acid

hydroxyapatite

hydroxyapatite

Conditions
ConditionsYield
In water
magnesium(II) nitrate
13446-18-9

magnesium(II) nitrate

ammonium vanadate

ammonium vanadate

magnesium orthovanadate

magnesium orthovanadate

Conditions
ConditionsYield
With citric acid In water
magnesium(II) nitrate
13446-18-9

magnesium(II) nitrate

10% Mg/HZSM-5

10% Mg/HZSM-5

Conditions
ConditionsYield
With HZSM-5 In water
sodium hydroxide
1310-73-2

sodium hydroxide

magnesium(II) nitrate
13446-18-9

magnesium(II) nitrate

aluminium trinitrate
7784-27-2

aluminium trinitrate

palladium (II) nitrate

palladium (II) nitrate

sodium carbonate
497-19-8

sodium carbonate

C0.155H2Al0.31Mg0.67O2.465Pd0.02

C0.155H2Al0.31Mg0.67O2.465Pd0.02

Conditions
ConditionsYield
In water at 80℃; for 17h; pH=10;
sodium hydroxide
1310-73-2

sodium hydroxide

magnesium(II) nitrate
13446-18-9

magnesium(II) nitrate

aluminium trinitrate
7784-27-2

aluminium trinitrate

sodium carbonate
497-19-8

sodium carbonate

C0.165H2Al0.33Mg0.67O2.495

C0.165H2Al0.33Mg0.67O2.495

Conditions
ConditionsYield
In water at 80℃; for 17h; pH=10;
bismuth(III) nitrate

bismuth(III) nitrate

magnesium(II) nitrate
13446-18-9

magnesium(II) nitrate

chromium(III) nitrate

chromium(III) nitrate

rubidium nitrate
13126-12-0

rubidium nitrate

ammonium heptamolybdate

ammonium heptamolybdate

nitric acid
7697-37-2

nitric acid

ferric nitrate
7782-61-8

ferric nitrate

potassium nitrate

potassium nitrate

cobalt(II) nitrate

cobalt(II) nitrate

cerous nitrate

cerous nitrate

nickel(II) nitrate

nickel(II) nitrate

catalyst; Mo12Bi0.5Fe2Ce0.5Cr0.4Ni4Mg1.5Co1K0.07Rb0.06Ox(SiO2)42

catalyst; Mo12Bi0.5Fe2Ce0.5Cr0.4Ni4Mg1.5Co1K0.07Rb0.06Ox(SiO2)42

Conditions
ConditionsYield
In water at 250 - 590℃; for 7h;
magnesium(II) nitrate
13446-18-9

magnesium(II) nitrate

pyrographite
7440-44-0

pyrographite

activated carbon-supported magnesium oxide

activated carbon-supported magnesium oxide

Conditions
ConditionsYield
Stage #1: magnesium(II) nitrate; pyrographite In water
Stage #2: With oxygen at 110 - 400℃; for 4h;

Magnesium nitrate hexahydrate Specification

The Magnesium nitrate hexahydrate, with the CAS registry number 13446-18-9, is also known as Dusicnan horecnaty. It belongs to the product categories of Inorganic Salts; Magnesium; Synthetic Reagents; M-N, Puriss p.a. ACS; Analytical Reagents for General Use; Puriss p.a. ACS; Magnesium Salts; MagnesiumMetal and Ceramic Science; Salts; Magnesium Protein Structural Analysis;Optimization Reagents;X-Ray Crystallography;Analytical Reagents;Replacement Kit Items;Water Test;Matrix Modifiers (for Graphite Furnace AAS)Protein Structural Analysis;Atomic Absorption Spectroscopy (AAS); Spectroscopy; Metal and Ceramic Science; ACS GradeSynthetic Reagents; Essential Chemicals; Routine Reagents. Its EINECS registry number is 231-104-6. This chemical's molecular formula is H12MgN2O12 and molecular weight is 256.40648. Its IUPAC name is called magnesium dinitrate hexahydrate. This chemical's classification code is Skin / Eye Irritant.

Physical properties of Magnesium nitrate hexahydrate: (1)ACD/LogP: -0.13; (2)#H bond acceptors: 4; (3)#H bond donors: 1; (4)Enthalpy of Vaporization: 37.72 kJ/mol; (5)Boiling Point: 83 °C at 760 mmHg; (6)Vapour Pressure: 49.8 mmHg at 25°C.

Preparation of Magnesium nitrate hexahydrate: this chemical can be prepared by 30%~50% nitric acid and MgO. This reaction should process in the temperature of 60 °C.

MgO+2HNO3→ Mg(NO3)2+H2O

Uses of Magnesium nitrate hexahydrate: it can be used as a dehydrating agent of concentrated nitric acid in inorganic industry and the manufacture of other magnesium salts, nitrate. In addition, the product can also be used for the manufacture of explosives in the defense industry. What's more, it also can be used to prepare the catalyst and as a strong oxidant.

When you are using this chemical, please be cautious about it as the following:
This chemical may destroy living tissue on contact and may cause burns. In addition, this chemical is oxidising. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. Whenever you will contact it, please wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell seek medical advice immediately (show the label where possible).

You can still convert the following datas into molecular structure:
(1)Canonical SMILES: [N+](=O)([O-])[O-].[N+](=O)([O-])[O-].O.O.O.O.O.O.[Mg+2]
(2)InChI: InChI=1S/Mg.2NO3.6H2O/c;2*2-1(3)4;;;;;;/h;;;6*1H2/q+2;2*-1
(3)InChIKey: MFUVDXOKPBAHMC-UHFFFAOYSA-N

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
rat LD50 oral 5440mg/kg (5440mg/kg)   "Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku," Marhold, J.V., Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha, Czechoslovakia, 1972Vol. -, Pg. 9, 1972.

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