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This product is a nationally controlled contraband, and the Lookchem platform doesn't provide relevant sales information.

Synthetic route

soda lime

soda lime

calcium cyanamide
156-62-7

calcium cyanamide

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

Conditions
ConditionsYield
With air; copper(II) oxide; copper(II) carbonate; nickel(II) carbonate In neat (no solvent) storage of thin layer of mixt. of lime nitrogen, soda lime and CuO on air for few days; addn. of catalyst, heating in dry stream of air at 400°C, until oxidn. of C is complete; heating up to 3 h at 450°C; acceleration by min. of H2O vapor;;38%
nitrogen(II) oxide
10102-43-9

nitrogen(II) oxide

A

calcium nitrite

calcium nitrite

B

nitrogen
7727-37-9

nitrogen

C

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

D

dinitrogen monoxide
10024-97-2

dinitrogen monoxide

Conditions
ConditionsYield
With calcium oxide 400°C, 21 h;A 0.9%
B n/a
C <1
D n/a
With CaO 400°C, 21 h;A 0.9%
B n/a
C <1
D n/a
dolomite

dolomite

nitric acid
7697-37-2

nitric acid

calcium oxide

calcium oxide

A

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

B

magnesium oxide

magnesium oxide

Conditions
ConditionsYield
In water addn. of HNO3 to dolomite also dissolves Mg; removal as Mg(OH)2 with CaO;;
dolomite

dolomite

nitric acid
7697-37-2

nitric acid

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

Conditions
ConditionsYield
In water dolomite slurry filtered and treated with HNO3; CaCO3 dissolves, and MgCO3 remains undissolved;;
With calcium(II) nitrate In water dolomite dissolved in Ca(NO3)3 soln. containing at most 1% HNO3;;
In water amt. of applied acid insufficient to dissolve also MgCO3;;
dolomite

dolomite

nitric acid
7697-37-2

nitric acid

calcium hydroxide

calcium hydroxide

A

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

B

magnesium oxide

magnesium oxide

Conditions
ConditionsYield
In water addn. of HNO3 to dolomite also dissolves Mg; removal as Mg(OH)2 with Ca(OH)2;;
ammonium nitrate

ammonium nitrate

dolomite

dolomite

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

Conditions
ConditionsYield
In ammonia CaCO3 portion of dolomite dissolves in liquid ammonia containing an equivalent amt. of NH4NO3;;
tricalcium diphosphate

tricalcium diphosphate

nitrosylchloride
2696-92-6

nitrosylchloride

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

Conditions
ConditionsYield
In water intermediately formed nitrogen oxides react to form the nitrates;;
In water intermediately formed nitrogen oxides react to form the nitrates;;
calcium(II) sulfide

calcium(II) sulfide

nitric acid
7697-37-2

nitric acid

A

hydrogen sulfide
7783-06-4

hydrogen sulfide

B

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

Conditions
ConditionsYield
In water
calcium(II) sulfide

calcium(II) sulfide

ammonium nitrate

ammonium nitrate

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

Conditions
ConditionsYield
trituration at moderate temp.;;
trituration at moderate temp.;;
calcium oxide

calcium oxide

A

dinitrogen trioxide
10544-73-7

dinitrogen trioxide

B

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

Conditions
ConditionsYield
With nitrogen oxides; Fe(OH)3 or Al(OH)3 or Cr(OH)3 In water absorption of nitrogen oxides in suspensions of heavy metal hydroxides and with CaO; then interaction of the intermediately formed nitrates;;
With nitrogen oxides In water absorption of nitrogen oxides in suspensions of heavy metal hydroxides and with CaO; then interaction of the intermediately formed nitrates;;
nitrogen
7727-37-9

nitrogen

oxygen
80937-33-3

oxygen

calcium oxide

calcium oxide

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

Conditions
ConditionsYield
In neat (no solvent) High Pressure; react. of atmospheric N2 and O2 with CaO at 800 - 900°C under high pressure;;
In neat (no solvent) High Pressure; react. of atmospheric N2 and O2 with CaO at 800 - 900°C under high pressure;;
nitric acid
7697-37-2

nitric acid

calcium oxide

calcium oxide

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

Conditions
ConditionsYield
With phosphate minerals In water Decompn. of phosphate minerals by HNO3; to avoid pptn. of Ca phosphates during neutralization of Ca(NO3)2 solns. because of residual phosphate, neutralization is done with concd. solns. of Ca(NO3)2 satd. with CaO;;
ammonium nitrate

ammonium nitrate

calcium oxide

calcium oxide

A

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

B

ammonia
7664-41-7

ammonia

C

water
7732-18-5

water

Conditions
ConditionsYield
In neat (no solvent) solving of CaO in molten NH4NO3;;
In neat (no solvent) solving of CaO in molten NH4NO3;;
ammonium nitrate

ammonium nitrate

calcium oxide

calcium oxide

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

Conditions
ConditionsYield
byproducts: NH3; H2O;
ammonium nitrate

ammonium nitrate

calcium oxide

calcium oxide

A

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

B

ammonia
7664-41-7

ammonia

Conditions
ConditionsYield
In water indirect reaction with HNO3; from destillation gases NH4NO3 is formed by HNO3; NH4NO3 reacted with CaO and NH3 again oxidized to form HNO3 which retuens into the cycle;;
silver nitrate

silver nitrate

calcium oxide

calcium oxide

A

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

B

silver(l) oxide
20667-12-3

silver(l) oxide

Conditions
ConditionsYield
heating a mixture of AgNO3 and CaO (50 mol %) at 190°C;;
nitrogen(II) oxide
10102-43-9

nitrogen(II) oxide

Nitrogen dioxide
10102-44-0

Nitrogen dioxide

calcium oxide

calcium oxide

A

calcium nitrite

calcium nitrite

B

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

Conditions
ConditionsYield
In neat (no solvent) ratio nitrate : nitrite depending on temp.;;
In neat (no solvent) ratio nitrate : nitrite depending on temp.;;
nitrogen(II) oxide
10102-43-9

nitrogen(II) oxide

Nitrogen dioxide
10102-44-0

Nitrogen dioxide

calcium oxide

calcium oxide

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

Conditions
ConditionsYield
In neat (no solvent) use of slake lime dehydrated at 400 - 650°C;;
In neat (no solvent) CaO used in coarse-grained or pelltized form;;
In neat (no solvent) use of quicklime calcined at 700 - 750°C;;
oxygen
80937-33-3

oxygen

calcium oxide

calcium oxide

A

nitrogen
7727-37-9

nitrogen

B

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

C

nitrogen(II) oxide
10102-43-9

nitrogen(II) oxide

D

Nitrogen dioxide
10102-44-0

Nitrogen dioxide

Conditions
ConditionsYield
With nitrogen oxides In neat (no solvent) nitrogen oxides (formed by combustion of air or oxidn. of NH3) react at 230-480 °C with CaO and O2 to form Ca(NO3)2 and Ca(NO2)2, the latter decomposes forming CaO, NO, N2; at >480°C also NO2 forms and oxidizes Ca(NO2)2 to Ca(NO3)2;;
With nitrogen oxides In neat (no solvent) nitrogen oxides (formed by combustion of air or oxidn. of NH3) react at 230-480 °C with CaO and O2 to form Ca(NO3)2 and Ca(NO2)2, the latter decomposes forming CaO, NO, N2; at >480°C also NO2 forms and oxidizes Ca(NO2)2 to Ca(NO3)2;;
ammonia
7664-41-7

ammonia

calcium oxide

calcium oxide

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

Conditions
ConditionsYield
In neat (no solvent) surface oxidation of NH3 at 360 °C on lime surfaces containing 0.2-2.5% NiO or CuO as activators;;
In neat (no solvent) surface oxidation of NH3 at 360 °C on lime surfaces containing 0.2-2.5% NiO or CuO as activators;;
tricalcium diphosphate

tricalcium diphosphate

Nitrogen dioxide
10102-44-0

Nitrogen dioxide

A

calcium hydrogen phosphate
7789-77-7

calcium hydrogen phosphate

B

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

Conditions
ConditionsYield
reaction of NO2 with moist Ca phosphate;;
reaction of NO2 with moist Ca phosphate;;
Nitrate

Nitrate

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

Conditions
ConditionsYield
With phosphoric acid byproducts: Na-phosphates; by product of Na phosphate synthesis : treatment of crude phosphate with nitrates (except alkali nitrates and group II nitrates) at elevated temp.;;
With phosphoric acid byproducts: Na-phosphates; by product of Na phosphate synthesis : treatment of crude phosphate with nitrates (except alkali nitrates and group II nitrates) at elevated temp.;;
nitric acid
7697-37-2

nitric acid

A

calcium hydrogen phosphate
7789-77-7

calcium hydrogen phosphate

B

calcium dihydrogen phosphate

calcium dihydrogen phosphate

C

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

Conditions
ConditionsYield
With phosphate minerals Decompn. of phosphate minerals by HNO3;;
nitric acid
7697-37-2

nitric acid

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

Conditions
ConditionsYield
With calcium chloride no reaction at low temp.;0%
With calcium chloride evapn. with excess of HNO3 soln.;>99
With CaCl2 no reaction at low temp.;0%
With CaCl2 evapn. with excess of HNO3 soln.;>99
nitric acid
7697-37-2

nitric acid

calcium chloride

calcium chloride

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

Conditions
ConditionsYield
In water react. at bp. of the soln., eventually under pressure;;
With MnO2 or H2SO4 In water with fuming (brown) HNO3 at 20°C or with highly concd.HNO3 in presence of MnO2 or H2SO4 at 50 - 60°C;;
In water react. at bp. of the soln., eventually under pressure;;
calcium fluoride

calcium fluoride

nitric acid
7697-37-2

nitric acid

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

Conditions
ConditionsYield
In water Ca(NO3)2 as by-product;;
nitric acid
7697-37-2

nitric acid

Phosphate
14265-44-2

Phosphate

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

Conditions
ConditionsYield
With calcium oxide In water addn. of excess of HNO3 to phosphates formed 3Ca(NO3)2*12H2O*HNO3; neutralisation with milk of lime;; pptn.;;
With calcium oxide In water addn. of excess of HNO3 to phosphates formed 3Ca(NO3)2*12H2O*HNO3; neutralisation with milk of lime;; pptn.;;
sulfuric acid
7664-93-9

sulfuric acid

calcium(II) ion

calcium(II) ion

nitric acid
7697-37-2

nitric acid

Phosphate
14265-44-2

Phosphate

A

calcium sulfate

calcium sulfate

B

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

Conditions
ConditionsYield
In neat (no solvent)
In neat (no solvent)
calcium aluminate

calcium aluminate

nitric acid
7697-37-2

nitric acid

A

aluminum trihydroxide

aluminum trihydroxide

B

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

calcium manganese(IV) oxide

calcium manganese(IV) oxide

Conditions
ConditionsYield
With air; glycine In water mixt. blended and heated; calcined at 800-850°C for 2 h; ball milled in ethanol for 24 h; pressed; burn out of binder in vac. at 450°C; sintered at 1100-1550°C for 2 h in air; cooled; XRD; SEM; TEM;100%
calcium(II) nitrate
13477-34-4

calcium(II) nitrate

lanthanum(III) nitrate

lanthanum(III) nitrate

La0.30Ca0.70MnO3.00

La0.30Ca0.70MnO3.00

Conditions
ConditionsYield
With air; glycine In water mixt. blended and heated; calcined at 800-850°C for 2 h; ball milled in ethanol for 24 h; pressed; burn out of binder in vac. at 450°C; sintered at 1100-1550°C for 2 h in air; cooled; XRD; SEM; TEM;100%
diammonium hydrogenphosphate

diammonium hydrogenphosphate

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

calcium hydroxyapatite

calcium hydroxyapatite

Conditions
ConditionsYield
With magnesium(II) nitrate; nitric acid; urea mixing stoich. components solns., heating at 85°C for 192 h or at90°C for 72 h or at 95°C for 48 h; XRD, SEM;99%
With nitric acid; urea mixing stoich. components solns., heating at 85°C for 192 h or at90°C for 72 h or at 95°C for 48 h; XRD, SEM;99%
methanol
67-56-1

methanol

[Cu(pyrimidine-2-olate-N1,N3)2]n*nH2O

[Cu(pyrimidine-2-olate-N1,N3)2]n*nH2O

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

[Cu(pyrimidine-2-olate-N1,N3)2]*0.5Ca(nitrate)2*0.4methanol*0.4water

[Cu(pyrimidine-2-olate-N1,N3)2]*0.5Ca(nitrate)2*0.4methanol*0.4water

Conditions
ConditionsYield
In methanol; water stirring suspn. of copper compd. in 0.05 M soln. of calcium nitrate in 4:1 mixt. of methanol and water for 1 wk at room temp.; elem. anal.;99%
[2,2]bipyridinyl
366-18-7

[2,2]bipyridinyl

diammonium phosphate

diammonium phosphate

cobalt(II) nitrate hexahydrate

cobalt(II) nitrate hexahydrate

hexaammonium heptamolybdate tetrahydrate

hexaammonium heptamolybdate tetrahydrate

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

3C10H8N2*8Ca(2+)*Co(3+)*5H(1+)*31H2O*5H3N*6O4P(3-)*Mo12O44P2(6-)

3C10H8N2*8Ca(2+)*Co(3+)*5H(1+)*31H2O*5H3N*6O4P(3-)*Mo12O44P2(6-)

Conditions
ConditionsYield
In water at 60 - 65℃; for 1h;97%
sodium molybdate

sodium molybdate

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

calcium molybdate

calcium molybdate

Conditions
ConditionsYield
In melt byproducts: NaNO3; melt of NaNO3, 450.+-.5°C, periodically mixed, 40 min; poured into a dish, left to cool, washed repeatedly (10-20 times) with water, dried at 200°C to constant mass, elem. anal.;96.34%
In water contains Cu or Co when precipitated at pH 8 to 8.5;;
With aq. HNO3; aq. NaOH In water High Pressure; adjusted (aq. HNO3/aq. NaOH) pH of Ca compd. soln. to 1.5, soln. of Mo compd. slowly dropped under vigorous stirring, stirred for 45 min, transferred into autoclave, sealed, heated at 150°C for 6 h, cooled naturally to room temp.; product collected by centrifugation, washed several times with distd. water and abs. ethanol, dried at 80°C for 6 h;
In water contains Cu or Co when precipitated at pH 8 to 8.5;;
In ethylene glycol High Pressure; microwave radiation method; each 0.005 mol of Ca(NO3)2 and Na2MoO4 sep. dissolved in ethylene glycol, two solns. mixed and stirred for 30 min, mixt. trensferred into autoclave, heated at 50% of 600 W microwave for 20min (60 s on and 60 s off); white ppt. filtered, washed (distd. H2O, abs. EtOH), dried (80 °C, 24 h, air); XRD;
phosphotungstic acid

phosphotungstic acid

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

calcium phosphotungstate

calcium phosphotungstate

Conditions
ConditionsYield
at 95℃; for 6h;96%
potassium tungstate

potassium tungstate

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

calcium tungstate

calcium tungstate

Conditions
ConditionsYield
In melt byproducts: KNO3; melt of KNO3, 450.+-.5°C, periodically mixed, 40 min; poured into a dish, left to cool, washed repeatedly (10-20 times) with water, dried at 200°C to constant mass, elem. anal.;95.69%
sodium tungstate

sodium tungstate

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

calcium tungstate

calcium tungstate

Conditions
ConditionsYield
With sodium nitrate In melt mixt. of NaNO3, Ca(NO3)2 and Na2WO4 heated in fused quartz tube at 400°C for 40-50 min with periodic stirring of the melt; poured into porcelain cup; cooled; washed with H2O; dried to const. weight at 200°C; elem. anal.;95.24%
In water heating at 1000°C, fluorescent product;
In not given
aluminium trinitrate
7784-27-2

aluminium trinitrate

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

calcium hexaaluminate

calcium hexaaluminate

Conditions
ConditionsYield
In solid Kinetics; in electric furnace at 1670 K; XRD;95%
In solid Kinetics; in electric furnace at 1570 K;90%
In solid Kinetics; in electric furnace at 1770 K;83%
bis(4'-(4'''-benzo-15-crown-5)methyloxy-2,2':6',2''-terpyridine)zinc(II) hexafluorophosphate

bis(4'-(4'''-benzo-15-crown-5)methyloxy-2,2':6',2''-terpyridine)zinc(II) hexafluorophosphate

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

[Ca2(Zn(II)(4'-(4'''-benzo-15-crown-5)methyloxy-2,2':6',2''-terpyridine)2)(NO3)2](hexafluorophosphate)2

[Ca2(Zn(II)(4'-(4'''-benzo-15-crown-5)methyloxy-2,2':6',2''-terpyridine)2)(NO3)2](hexafluorophosphate)2

Conditions
ConditionsYield
In acetonitrile Zn complex dissolved on heating in MeCN, Ca nitrate added in MeCN with stirring, crystn. 2 d; ppt. filtered off, washed with ice-cooled MeCN, dried in vac. at 60 °C, elem. anal.;92%
potassium cyanide

potassium cyanide

1,10-Phenanthroline
66-71-7

1,10-Phenanthroline

ethanol
64-17-5

ethanol

4(CH3)4N(1+)*Nb6Cl18(4-)=((CH3)4N)4Nb6Cl18

4(CH3)4N(1+)*Nb6Cl18(4-)=((CH3)4N)4Nb6Cl18

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

A

[Ca(1,10-phenanthroline)2(H2O)2]2[Nb6Cl12(CN)6]*(1,10-phenanthroline)2*4H2O

[Ca(1,10-phenanthroline)2(H2O)2]2[Nb6Cl12(CN)6]*(1,10-phenanthroline)2*4H2O

B

[Ca(1,10-phenanthroline)2(H2O)3]2[Nb6Cl12(CN)6]*(1,10-phenanthroline)*1.6(EtOH)

[Ca(1,10-phenanthroline)2(H2O)3]2[Nb6Cl12(CN)6]*(1,10-phenanthroline)*1.6(EtOH)

Conditions
ConditionsYield
In ethanol; water aq. soln. Ca(NO3)2 and soln. phen in EtOH were added to aq. soln. Nb complex and KCN; ppt. was collected by centrifugation, washed with H2O, dried under vac.;A 5%
B 90%
cadmium(II) nitrate tetrhydrate

cadmium(II) nitrate tetrhydrate

5-t-butylisophthalic acid
2359-09-3

5-t-butylisophthalic acid

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

[Me2NH2]2[Cd2Ca(5-tert-butylisophthalate)4]

[Me2NH2]2[Cd2Ca(5-tert-butylisophthalate)4]

Conditions
ConditionsYield
In methanol; N,N-dimethyl-formamide High Pressure; mixt. of Cd salt (1 equiv.), acid (2 equiv.) and Ca salt (2 equiv.) in DMF/MeOH (1/1) was heated to 160°C for 4 h in autoclave; heated at160°C for 2 d; cooled to room temp. over 2 d; filtered; washed (DMF, MeOH); dried in air at room temp.; elem. anal.;87%
cadmium(II) nitrate tetrhydrate

cadmium(II) nitrate tetrhydrate

isophthalic acid
121-91-5

isophthalic acid

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

[CdCa(isophthalate)2(N,N-dimethylformamide)2]

[CdCa(isophthalate)2(N,N-dimethylformamide)2]

Conditions
ConditionsYield
In methanol; N,N-dimethyl-formamide High Pressure; mixt. of Cd salt (1 equiv.), acid (2 equiv.) and Ca salt (2 equiv.) in DMF/MeOH (1/1) was heated to 160°C for 4 h in autoclave; heated at160°C for 2 d; cooled to room temp. over 2 d; filtered; washed (DMF, MeOH); dried in air at room temp.; elem. anal.;86%
cadmium(II) nitrate tetrhydrate

cadmium(II) nitrate tetrhydrate

5-Hydroxyisophthalic acid
618-83-7

5-Hydroxyisophthalic acid

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

[CdCa(5-hydroxyisophthalate)2(H2O)2]*Me2NH

[CdCa(5-hydroxyisophthalate)2(H2O)2]*Me2NH

Conditions
ConditionsYield
In methanol; N,N-dimethyl-formamide High Pressure; mixt. of Cd salt (1 equiv.), acid (2 equiv.) and Ca salt (2 equiv.) in DMF/MeOH (1/1) was heated to 160°C for 4 h in autoclave; heated at160°C for 2 d; cooled to room temp. over 2 d; filtered; washed (DMF, MeOH); dried in air at room temp.; elem. anal.;85%
mono-K,Li-heptadecatungstodiphosphate*18H2O 18H2O*K9LiO61P2W17, α1

mono-K,Li-heptadecatungstodiphosphate*18H2O 18H2O*K9LiO61P2W17, α1

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

mono-K,Ca-heptadecatungstodiphosphate*19H2O CaK8O61P2W17*19H2O, α1

mono-K,Ca-heptadecatungstodiphosphate*19H2O CaK8O61P2W17*19H2O, α1

Conditions
ConditionsYield
In water soln. of metal salt added to Li salt by stirring; filtered, soln. pptd. with KCl, filtered, washed with EtOH and Et2O, air-dried, elem. anal.;80%
barite

barite

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

barium(II) nitrate

barium(II) nitrate

Conditions
ConditionsYield
In melt byproducts: CaSO4; ratio of BaSO4 to Ca(NO3)2 = 1:2 because of reversible reaction; quick cooling; crystn. (water);75%
In melt byproducts: CaSO4; ratio of BaSO4 to Ca(NO3)2 = 1:2 because of reversible reaction; quick cooling; crystn. (water);75%
calcium(II) nitrate
13477-34-4

calcium(II) nitrate

sodium chloride
7647-14-5

sodium chloride

sodium nitrate
7631-99-4

sodium nitrate

Conditions
ConditionsYield
In water preparation on cation exchange resins, 52% Ca-nitrate soln., 26% NaCl-soln.;; crystn.;;70%
In water preparation on cation exchange resins, 52% Ca-nitrate soln., 26% NaCl-soln.;; crystn.;;70%
In water equilibrium in aq. soln.;;
2,2′-{1,2-phenylenebis[oxyacetyl(N,N-diethylthiourea)]}

2,2′-{1,2-phenylenebis[oxyacetyl(N,N-diethylthiourea)]}

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

silver nitrate

silver nitrate

C40H56Ag2CaN8O8S4

C40H56Ag2CaN8O8S4

Conditions
ConditionsYield
Stage #1: 2,2′-{1,2-phenylenebis[oxyacetyl(N,N-diethylthiourea)]}; calcium(II) nitrate; silver nitrate In methanol; water at 20℃; for 0.5h;
Stage #2: With triethylamine In methanol; water
67%
(N,N'-2,2-dimethylpropylenedi(3-methoxysalicylideneiminato)Cu dihydrate

(N,N'-2,2-dimethylpropylenedi(3-methoxysalicylideneiminato)Cu dihydrate

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

[Cu(N,N'-2,2-dimethylpropylenedi(3-methoxysalicylideneimine))]2Ca(NO3)2*H2O
954111-03-6

[Cu(N,N'-2,2-dimethylpropylenedi(3-methoxysalicylideneimine))]2Ca(NO3)2*H2O

Conditions
ConditionsYield
In methanol Cu-compd. and 1 equiv. of alkaline earth-compd. were stirred in MeOH for3 h; ppt. was filtered off, dried, elem. anal.;65%
monoaqua 3-methoxysalicylaldehyde-ethyldiamine copper(II)
157143-69-6, 41754-70-5

monoaqua 3-methoxysalicylaldehyde-ethyldiamine copper(II)

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

[Cu(N,N'-ethylenedi(3-methoxysalicylideneimine))]2Ca(NO3)2*2H2O

[Cu(N,N'-ethylenedi(3-methoxysalicylideneimine))]2Ca(NO3)2*2H2O

Conditions
ConditionsYield
In methanol Cu-compd. and 1 equiv. of alkaline earth-compd. were stirred in MeOH for3 h; ppt. was filtered off, dried, elem. anal.;65%
C36H44Au2N2O4P2S2*8H2O

C36H44Au2N2O4P2S2*8H2O

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

nickel(II) acetate tetrahydrate
6018-89-9

nickel(II) acetate tetrahydrate

cobalt(II) diacetate tetrahydrate
6147-53-1

cobalt(II) diacetate tetrahydrate

A

6C26H24P2*12C5H9NO2S(2-)*12Au(1+)*2.01Ni(2+)*3.99Co(3+)*8NO3(1-)*23.01H2O*2.01H(1+)*Ca(2+)

6C26H24P2*12C5H9NO2S(2-)*12Au(1+)*2.01Ni(2+)*3.99Co(3+)*8NO3(1-)*23.01H2O*2.01H(1+)*Ca(2+)

B

2C26H24P2*4C5H9NO2S(2-)*4Au(1+)*2Ni(2+)

2C26H24P2*4C5H9NO2S(2-)*4Au(1+)*2Ni(2+)

Conditions
ConditionsYield
Stage #1: C36H44Au2N2O4P2S2*8H2O; nickel(II) acetate tetrahydrate; cobalt(II) diacetate tetrahydrate With air In methanol at 20℃; for 3h;
Stage #2: calcium(II) nitrate In methanol; water at 20℃; for 168h;
A 65%
B 16%
sodium sulfide

sodium sulfide

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

sodium sulfite
7757-83-7

sodium sulfite

A

calcium sulfate

calcium sulfate

B

sodium sulfate
7757-82-6

sodium sulfate

C

sodium nitrite
7632-00-0

sodium nitrite

Conditions
ConditionsYield
In neat (no solvent) formation at heating under glowing;;A n/a
B n/a
C 60%
manganese(II)carbonate

manganese(II)carbonate

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

citric acid monohydrate
5949-29-1

citric acid monohydrate

[MnCa2(HCit)2(H2O)4]n

[MnCa2(HCit)2(H2O)4]n

Conditions
ConditionsYield
In water High Pressure; under aerobic conditions; Ca salt (1.95 mmol), citric acid hydrate (2 mmol), and MnCO3 (1 mmol) dissolved in H2O, mixt. heated 160°C in sealed teflon tube for 3 d; elem. anal.;60%
N,N'-bis(3-methoxysalicylidene)ethylenediamine
7396-77-2

N,N'-bis(3-methoxysalicylidene)ethylenediamine

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

manganese (II) acetate tetrahydrate
6156-78-1

manganese (II) acetate tetrahydrate

[Mn(MeOsalen)(H2O)2](NO3)

[Mn(MeOsalen)(H2O)2](NO3)

[Mn(MeOsalen)(H2O)2](NO3)*0.25H2O

[Mn(MeOsalen)(H2O)2](NO3)*0.25H2O

Conditions
ConditionsYield
In ethanol at 20℃; for 2h;A 60%
B 20%
4-(2,3,4-tricarboxylphenyl)-2,2':6,2''-terpyridine

4-(2,3,4-tricarboxylphenyl)-2,2':6,2''-terpyridine

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

C24H13N3O6(2-)*Ca(2+)*4H2O

C24H13N3O6(2-)*Ca(2+)*4H2O

Conditions
ConditionsYield
With water at 10 - 140℃; for 72h; Temperature; Autoclave;60%
(tetrahydrothiophene)gold(I) chloride
39929-21-0

(tetrahydrothiophene)gold(I) chloride

2,2′-{1,2-phenylenebis[oxyacetyl(N,N-diethylthiourea)]}

2,2′-{1,2-phenylenebis[oxyacetyl(N,N-diethylthiourea)]}

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

C40H56Au2N8O8S4(2-)*Ca(2+)

C40H56Au2N8O8S4(2-)*Ca(2+)

Conditions
ConditionsYield
Stage #1: (tetrahydrothiophene)gold(I) chloride; 2,2′-{1,2-phenylenebis[oxyacetyl(N,N-diethylthiourea)]}; calcium(II) nitrate With water In methanol at 20℃; for 0.5h;
Stage #2: With triethylamine In methanol at 50℃; for 1h;
60%
calcium(II) nitrate
13477-34-4

calcium(II) nitrate

acetic anhydride
108-24-7

acetic anhydride

calcium acetate
62-54-4

calcium acetate

Conditions
ConditionsYield
In acetic anhydride H2O free;;59%
In acetic anhydride H2O free;;59%
calcium(II) nitrate
13477-34-4

calcium(II) nitrate

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

3,4-dimethylthieno[2,3-b]thiophene-2,5-dicarboxylic acid

3,4-dimethylthieno[2,3-b]thiophene-2,5-dicarboxylic acid

[Ca(DMTDC)(N,N-dimethylformamide)]

[Ca(DMTDC)(N,N-dimethylformamide)]

Conditions
ConditionsYield
at 95℃; for 24h; High pressure;58.7%
2,3-dicarboxypyrazine
89-01-0

2,3-dicarboxypyrazine

calcium(II) nitrate
13477-34-4

calcium(II) nitrate

water
7732-18-5

water

silver nitrate

silver nitrate

Ag2Ca(2,3-pyrazinedicarboxalate)2(H2O)

Ag2Ca(2,3-pyrazinedicarboxalate)2(H2O)

Conditions
ConditionsYield
With sodium hydroxide at 100℃; for 72h; pH=7;57%

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