CAS No.10024-97-2,NITROUS OXIDE Suppliers,MSDS download

: 7664-41-7
ammonia

: 80937-33-3
oxygen

A: 7727-37-9
nitrogen

B: 10102-43-9
nitrogen(II) oxide

C: 10024-97-2
dinitrogen monoxide

Conditions

Conditions	Yield
With oxygen In neat (no solvent) Fe-ZSM-5 catalyst prepared by ion exchange and heat-treated at 400, 425or 450 °C, 100 % NH3 conversion, 100 % N2 selectivity, 1000 ppm NH3 in 2 % O2-contg. He;	A 100% B 0% C 0%
With catalyst:Fe-mordenite In neat (no solvent) Fe-mordenite catalyst prepared by ion exchange and heat-treated at 425 °C, 92 % NH3 conversion, 99 % N2 selectivity, 1000 ppm NH3 in 2 %O2-contg. He;	A 92% B n/a C 0%
With catalyst:Fe-ZSM-5 In neat (no solvent) Fe-ZSM-5 catalyst prepared by ion exchange and heat-treated at 375 °C, 90 % NH3 conversion, 99 % N2 selectivity, 1000 ppm NH3 in 2 % O2-contg. He;	A 90% B n/a C 0%

...Expand

: [Fe2(2,6-bis[[bis(2-pyridylmethyl)amino]methyl]-4-methylphenolato)(propionato)(NO)2](triflate)2

: 10024-97-2
dinitrogen monoxide

Conditions

Conditions	Yield
With cobaltocene In dichloromethane at 20℃; for 0.0166667h; Kinetics; Time; Temperature; Concentration;	100%

: 7664-41-7
ammonia

A: 7727-37-9
nitrogen

B: 10102-43-9
nitrogen(II) oxide

C: 10024-97-2
dinitrogen monoxide

Conditions

Conditions	Yield
With oxygen In neat (no solvent) Fe-mordenite catalyst prepared by ion exchange and heat-treated at 450 °C, 99 % NH3 conversion, 100 % N2 selectivity, 1000 ppm NH3 in 2 % O2-contg. He;	A 99% B 0% C 0%
With oxygen; platinum high excess O2,500 °C;	A <1 B n/a C n/a
With oxygen; platinum at 300 °C;	A n/a B <9 C n/a

...Expand

: 114581-86-1
[CuI(tris(2-pyridylmethyl)amine)(CH3CN)]2+

: 10102-43-9
nitrogen(II) oxide

A: 133578-96-8
[Cu(tris(2-pyridylmethyl)amine)(H2O)](2+)

B: 10024-97-2
dinitrogen monoxide

Conditions

Conditions	Yield
In water room temp., pH = 7.0; reaction followed by gas chromy.;	A 99% B n/a

...Expand

: ammonium nitrate

A: 7727-37-9
nitrogen

B: 10102-43-9
nitrogen(II) oxide

C: 10102-44-0
Nitrogen dioxide

D: 10024-97-2
dinitrogen monoxide

Conditions

Conditions	Yield
at 220-260°C, nearly 98% N2O, 2% N2; troces of NO and NO2 (0.001%);	A 2% B n/a C n/a D 98%

...Expand

: 1112-04-5
trifluoromethyldifluorophosphine

: 10102-43-9
nitrogen(II) oxide

A: 19162-94-8
Trifluormethylphosphonsaeuredifluorid

B: 10024-97-2
dinitrogen monoxide

Conditions

Conditions	Yield
20°C (7 d); oxydation;	A 98% B n/a

...Expand

: [(copper(II)(tris(2-pyridylmethyl)amine))2(μ-hyponitrite)](2+)

: 10102-43-9
nitrogen(II) oxide

A: 188637-84-5
[copper(I)(tris(2-pyridylmethyl)amine)](1+)

B: [copper(II)(tris(2-pyridylmethyl)amine)(nitrito)](1+)

C: 10024-97-2
dinitrogen monoxide

Conditions

Conditions	Yield
In tetrahydrofuran; methanol for 8h; Solvent; Inert atmosphere; Schlenk technique;	A 96% B 85% C 98%

...Expand

: {Cu2(NO)N6OC36H39}(2+)

: tetrabutylammonium nitrite

A: {Cu2(O)N6OC36H39}(1+)*PF6(1-)={Cu2(O)N6OC36H39}PF6

B: 10024-97-2
dinitrogen monoxide

Conditions

Conditions	Yield
With P(C6H5)3 In not given byproducts: OP(C6H5)3; react. of 1 equiv. N(C4H9)4(NO2) with (Cu2(NO)N6OC36H39)(2+) in presence of P(C6H5)3 (1 equiv.);; elem. anal.;	A 60% B 97%
In not given byproducts: O2; react. of 1 equiv. N(C4H9)4(NO2) with (Cu2(NO)N6OC36H39)(2+);; elem. anal.;	A 60% B 79%

...Expand

: 90065-16-0
Cu2(I)(C6H3(O)(CH2N(C2H4-2-pyridyl)2)2)(1+)

: 10102-43-9
nitrogen(II) oxide

A: {Cu2(O)N6OC36H39}(1+)*PF6(1-)={Cu2(O)N6OC36H39}PF6

B: 10024-97-2
dinitrogen monoxide

Conditions

Conditions	Yield
In dichloromethane exposure of (Cu2N6OC36H39)(1+) to NO(g) in CH2Cl2 at -80 °C, warming;;	A 55% B 96%

...Expand

: trans-hydroxotetraamminenitrosoruthenium(II)

: 7697-37-2
nitric acid

: trans-tetraamminenitratonitrosoruthenium(III) nitrate

B: 7732-18-5
water

C: 10102-44-0
Nitrogen dioxide

D: 2696-92-6
nitrosylchloride

E: 10024-97-2
dinitrogen monoxide

Conditions

Conditions	Yield
In nitric acid byproducts: Cl2; to Ru complex was added concd. HNO3; mixt. heated under reflux for 5 min; cooled to room temp.; ppt. filtered off; washed (water, alc., ether); dried (vac.); recrystd. (aq. HNO3); elem. anal.;	A 95% B n/a C n/a D n/a E n/a

...Expand

: 1194657-31-2
4-nitrosotetrahydro-2H-pyran-4-yl 2,2,2-trichloroacetate

A: 29943-42-8
Tetrahydro-4H-pyran-4-one

B: 10024-97-2
dinitrogen monoxide

C: 76-03-9
trichloroacetic acid

Conditions

Conditions	Yield
With water In methanol; aq. phosphate buffer at 20℃; for 24h; pH=7.4; Kinetics; Reagent/catalyst; Sealed tube;	A n/a B 95% C n/a

...Expand

: 7664-41-7
ammonia

A: 7727-37-9
nitrogen

B: 10024-97-2
dinitrogen monoxide

Conditions

Conditions	Yield
With oxygen In gaseous matrix byproducts: NO; 0.2 g of catalyst, 1000 ppm NH3, 2% O2, He as balance, GHSV=2.0E+5 h**-1, at 450°C; mass spect.;	A 94% B 0%
With oxygen In gaseous matrix byproducts: NO; 0.2 g of catalyst, 1000 ppm NH3, 2% O2, He as balance, GHSV=2.0E+5 h**-1, at 400°C; mass spect.;	A 93% B 0%
With oxygen In gaseous matrix byproducts: NO; 0.2 g of catalyst, 1000 ppm NH3, 2% O2, He as balance, GHSV=2.0E+5 h**-1, at 400°C; mass spect.;	A 92% B 0%

: 1493-13-6
trifluorormethanesulfonic acid

: [Fe2(NO)4(μ-1,3-bis(dimethylamino)-2-propanolate)]2(κ4-N2O2)

A: [Fe2(NO)4(μ-1,3-bis(dimethylamino)-2-propanolate)(μ-OSO2CF3)]

B: 10024-97-2
dinitrogen monoxide

Conditions

Conditions	Yield
In tetrahydrofuran at 0℃; for 1h; Schlenk technique; Inert atmosphere;	A n/a B 93%

...Expand

: 4-nitrosotetrahydro-2H-pyran-4-yl 2,2-dichloropropanoate

A: 29943-42-8
Tetrahydro-4H-pyran-4-one

B: 75-99-0
2,2-Dichloropropionic acid

C: 10024-97-2
dinitrogen monoxide

Conditions

Conditions	Yield
With water In methanol; aq. phosphate buffer at 20℃; for 24h; pH=7.4; Kinetics; Reagent/catalyst; Sealed tube;	A n/a B n/a C 92%

...Expand

: C46H57Fe2N13O4S(2+)*2BF4(1-)

A: C43H49Fe2N10O2(2+)

B: 2C39H41N10O(1-)*2Fe(2+)*2Fe(3+)*4HO(1-)

C: 10024-97-2
dinitrogen monoxide

Conditions

Conditions	Yield
With cobaltocene In dichloromethane for 0.0833333h; Sealed tube; Inert atmosphere;	A n/a B n/a C 91%

...Expand

: 10102-43-9
nitrogen(II) oxide

A: 7727-37-9
nitrogen

B: 80937-33-3
oxygen

C: 10102-44-0
Nitrogen dioxide

D: 10024-97-2
dinitrogen monoxide

Conditions

Conditions	Yield
Irradiation (UV/VIS); irradn. with Al-glitter (wave length:1860,1930 and 1990 A);	A 90% B 90% C 10% D 10%
Irradiation (UV/VIS); irradn. with Al-glitter (wave length:1860,1930 and 1990 A);	A 90% B 90% C 10% D 10%
La0.7Ba0.3Mn0.8In0.1Cu0.1O3 In neat (no solvent) decomposition over catalyst at 1073 K;	A 69.4% B 42.3% C 27.1% D 0%

...Expand

: 7664-41-7
ammonia

: 80937-33-3
oxygen

: 10024-97-2
dinitrogen monoxide

Conditions

Conditions	Yield
manganese(II) oxide In neat (no solvent) catalytic oxidn. of NH3 (300 °C, O2-excess);;	90%
byproducts: N2, NO; excess of O2; at 300 °C; catalyst MnO2/Fe2O3/(eventually) Bi2O3; yield depending on mole ratio O2:NH3 and flow rate;;	90%
cobalt(II) oxide In neat (no solvent) oxidation at 300°C;;

: 7664-41-7
ammonia

: 10024-97-2
dinitrogen monoxide

Conditions

Conditions	Yield
With oxygen 300 °C,with air;	90%
Electrolysis; NH3 soln. contg. CO2;anod contains Pt,Pd or Fe;	14.6%
Electrolysis;

: Nitrite

: tin(ll) chloride

A: 7803-49-8
hydroxylamine

B: 10024-97-2
dinitrogen monoxide

C: 19467-31-3, 173728-04-6
trans-hyponitrous acid

Conditions

Conditions	Yield
In water	A n/a B 90% C n/a

...Expand

: 7782-77-6
cis-nitrous acid

: tin(ll) chloride

A: 7803-49-8
hydroxylamine

B: 10024-97-2
dinitrogen monoxide

C: 19467-31-3, 173728-04-6
trans-hyponitrous acid

Conditions

Conditions	Yield
In water	A n/a B 90% C n/a

...Expand

: copper(II)-hyponitrite

A: 7727-37-9
nitrogen

B: 10102-43-9
nitrogen(II) oxide

C: copper(II) oxide

D: 10024-97-2
dinitrogen monoxide

Conditions

Conditions	Yield
In neat (no solvent) decompn. at 225-230°C;;	A 2-6 B 3-5 C n/a D 90%
In neat (no solvent) decompn. at 225-230°C;;	A 2-6 B 3-5 C n/a D 90%

...Expand

: 7803-49-8
hydroxylamine

A: 10024-97-2
dinitrogen monoxide

B: nitrosyl hydride

Conditions

Conditions	Yield
With hypochloric acid In aq. phosphate buffer at 37℃; pH=7.4;	A n/a B 90%

: 7758-09-0
potassium nitrite

: hydrazin sulfate

A: 7727-37-9
nitrogen

B: 10024-97-2
dinitrogen monoxide

C: 19467-31-3, 173728-04-6
trans-hyponitrous acid

Conditions

Conditions	Yield
In not given at room temp. or upon boiling from equimolar amounts in 3% solns.; no formation of H2N2O2 even in concd. solns. at low temps.; mole ratio of N2O:N2 depends on the mole ratio nitrite:hydrazonium salt;;	A 11% B 89% C 0%

...Expand

: C52H70Fe2N14O5(3+)*3BF4(1-)

: 10024-97-2
dinitrogen monoxide

Conditions

Conditions	Yield
With cobaltocene In dichloromethane for 0.0833333h; Inert atmosphere;	89%
With silver; N,N,N,N-tetraethylammonium tetrafluoroborate In dichloromethane Inert atmosphere; Electrochemical reaction;	89%

: 7803-49-8
hydroxylamine

A: 7727-37-9
nitrogen

B: 10024-97-2
dinitrogen monoxide

Conditions

Conditions	Yield
With Hg2(NO3)2 In not given byproducts: Hg; addn. of 0.04 M NH2OH to 0.005 M Hg2(NO3)2 soln. buffered with acetate at 20°C, autocatalysis of reaction by Hg;;	A 13% B 87%
With Hg2(NO3)2; silver In not given byproducts: Hg; addn. of 0.04 M NH2OH to 0.005 M Hg2(NO3)2 soln. buffered with acetate at 20°C, autocatalysis of reaction by Hg, further catalysis by addn. of collodial Ag soln.;;	A 63% B 34%
With oxygen In not given byproducts: water; Electrolysis; N2O formed on cathode, N2 formed on anode;

: [(copper(II)(tris(2-pyridylmethyl)amine))2(μ-hyponitrite)](2+)

: 10102-43-9
nitrogen(II) oxide

A: [copper(II)(tris(2-pyridylmethyl)amine)(nitrito)](1+)

B: 10024-97-2
dinitrogen monoxide

Conditions

Conditions	Yield
In methanol Inert atmosphere; Schlenk technique;	A 85% B n/a

...Expand

: 463-51-4
Ketene

: 10102-43-9
nitrogen(II) oxide

A: 51060-05-0
fulminic acid

B: 74-90-8
hydrogen cyanide

C: 201230-82-2
carbon monoxide

D: 7732-18-5
water

E: 10024-97-2
dinitrogen monoxide

Conditions

Conditions	Yield
byproducts: H2CO; Irradiation (UV/VIS); photolysis of CH2CO/NO/Ar mixt. with 200 W high pressure Hg lamp (photolysis of CH2CO generates CH2 radicals) in Duran glass tube (20 cm long, 4cm i.d.) at room temp. and ambient pressure;	A 84% B 15% C n/a D n/a E n/a

...Expand

: bis(η5.-pentamethylcyclopentadienyl)(η2-phenyltrimethylsilylacetylene)zirconium

: 10024-97-2
dinitrogen monoxide

: 205107-24-0
(η(5)-C5Me5)2Zr(OCPh=CSiMe3)

Conditions

Conditions	Yield
In neat (no solvent) byproducts: N2; absence of air and moisture; 500 Torr N2O, room temp., 24 h; removal of gases; elem. anal.;	100%
In toluene byproducts: N2; absence of air and moisture; N2O-atmosphere, warming from -78°C to room temp., stirring for 30 min; rsolvent removal, recrystn. (hexane/O(SiMe3)2);	65%
In benzene absence of air and moisture;

: (η(5)-C5Me5)2Zr(Me3SiC.tplbond.C(c-C5H9))

: 10024-97-2
dinitrogen monoxide

: 205107-25-1
(η(5)-C5Me5)2Zr(OC(c-C5H9)=CSiMe3)

Conditions

Conditions	Yield
In neat (no solvent) byproducts: N2; absence of air and moisture; 500 Torr N2O, room temp., 24 h; removal of gases; elem. anal.;	100%
In benzene absence of air and moisture;

: (((p-tolyl)B(pyrazolyl)2)2Py)ScH

: 10024-97-2
dinitrogen monoxide

: (((p-tolyl)B(pyrazolyl)2)2Py)Sc-O-Sc(((p-tolyl)B(pyrazolyl)2)2Py)

Conditions

Conditions	Yield
In benzene-d6 at 80℃; under 760.051 Torr; for 18h; Inert atmosphere; Schlenk technique;	100%

: 34557-54-5
methane

: 10024-97-2
dinitrogen monoxide

A: 67-56-1
methanol

B: 50-00-0
formaldehyd

C: 124-38-9
carbon dioxide

D: 201230-82-2
carbon monoxide

E: 7727-37-9
nitrogen

Conditions

Conditions	Yield
In neat (no solvent) Kinetics; Oxidation of CH4 by N2O in presence of catalyst (773 K): deposited Cu(2+) on carbon;;	A 0.2% B 0.3% C 99.5% D 0% E n/a
In neat (no solvent) Kinetics; byproducts: C2H5OH (small quantity); oxidation of CH4 by N2O in presence of catalyst (773 K): deposited Ti(4+) on carbon;;	A 13.8% B 0% C 86.2% D 0% E n/a
In neat (no solvent) Kinetics; Oxidation of CH4 by N2O in presence of catalyst (773 K): deposited Co(2+) on carbon;;	A 0% B 0% C 75% D 25% E n/a

...Expand

: potassium amide

: 10024-97-2
dinitrogen monoxide

: 20762-60-1
potassium azide

Conditions

Conditions	Yield
byproducts: KOH, NH3; 270-280 °C in rotating furnace; the white layer of KOH and KN3 dissolved in water, the soln. evaporated, KN3 crystd.;	99%
byproducts: KOH, NH3; 270-280 °C in rotating furnace; the white layer of KOH and KN3 dissolved in water, the soln. evaporated, KN3 crystd.;	99%
In ammonia byproducts: KOH, NH3; -70°C;
In ammonia byproducts: KOH, NH3; NH3 (liquid); -70°C;

: 7783-54-2
nitrogen trifluoride

: 7783-70-2
antimony pentafluoride

: 10024-97-2
dinitrogen monoxide

: 12528-55-1
NF2O(1+)*Sb2F11(1-) =(NF2O)(Sb2F11)

Conditions

Conditions	Yield
byproducts: N2; 150°C;	99%
100°C;	0%

...Expand

: 1039748-93-0
N[2-P(CHMe3)2-4-methylphenyl]2V(CH2tBu)2

: 10024-97-2
dinitrogen monoxide

: V(N[4-Me-2-(PiPr2)C6H3]2)(CHtBu)O*0.5C5H10

Conditions

Conditions	Yield
In benzene V-complex reacted with N2O in benzene at 90°C;	99%

: (η5-C5Me5)*W{N(iPr)C(Me)N(iPr)}(NSiMe3)

: 10024-97-2
dinitrogen monoxide

: (η5-C5Me5)W[N(iPr)C(Me)N(iPr)](nitrido)(OSiMe3)

Conditions

Conditions	Yield
at 25℃; for 216h;	99%

: 328396-60-7
bis[2,6-bis(1-naphthyl)phenyl]germylene

: 10024-97-2
dinitrogen monoxide

: 327179-04-4
bis[2,6-bis(1-naphthyl)phenyl]germanone

Conditions

Conditions	Yield
In toluene left standing under N2 for 2 d; solvent evpd. in vacuo;	98%

: potassium diphenylphosphanylborohydride

: 10024-97-2
dinitrogen monoxide

: KOPPh2BH3

Conditions

Conditions	Yield
In tetrahydrofuran soln. of B compd. stirred at room temp. under N2O atm. until gas evolution stopped (ca. 5 min); evapd., elem. anal.;	98%

: K[P((t)Bu)2BH3]

: 10024-97-2
dinitrogen monoxide

: K(1+)*OP(C(CH3)3)2BH3(1-)=K[(C(CH3)3)2OPBH3]

Conditions

Conditions	Yield
In tetrahydrofuran soln. of B compd. stirred at room temp. under N2O atm. until gas evolution stopped (ca. 5 min); evapd., elem. anal.;	98%

: [{(i-Bu)2(aminotroponiminate)Ge(i-Pr)(ZnCl2)}2]

: 10024-97-2
dinitrogen monoxide

: [{(i-Bu)2ATIGe(O)(i-Pr)(ZnCl2)}2]

Conditions

Conditions	Yield
In tetrahydrofuran at 20℃; for 0.5h; Inert atmosphere; Schlenk technique;	98%

: [(C(C6H4P(CH(CH3)2)2)2)IrCl]

: 10024-97-2
dinitrogen monoxide

: C25H36ClIrOP2

Conditions

Conditions	Yield
In benzene-d6 at 20℃; under 760.051 Torr; for 24h;	98%

: 1033858-47-7
ethylenebis(1,3-di-tert-butylcyclopentadienyl)titanium

: 10024-97-2
dinitrogen monoxide

A: 827030-28-4
μ-oxotetrakis(1,3-di-tert-butylcyclopentadienyl)dititanium

B: 1033858-56-8
di-μ-oxotetrakis(1,3-di-tert-butylcyclopentadienyl)dititanium

Conditions

Conditions	Yield
In pentane Ti complex dissolved in pentane; exposed to N2O (1 atm); solvent removed under vac.; extd. into hot toluene; cooled to room temp.and then to -20°C; crystals isolated; elem. anal.;	A 0% B 97%

...Expand

: 382150-90-5
(HC(CMeNC-2,6-i-Pr2C6H3)2)-germanium(II) hydride

: 10024-97-2
dinitrogen monoxide

: 692776-46-8
(HC(CMeNC-2,6-i-Pr2C6H3)2)-germanium(II) hydroxide

Conditions

Conditions	Yield
In toluene under N2 or Ar; dry N2O bubbled into soln. of Ge compd. in toluene at room temp. for 30 min; volatiles removed in vac.; treated with n-hexane; filtered; dried in vac.;	95%

: C20H46BN2P

: 10024-97-2
dinitrogen monoxide

: C20H46BN2OP

Conditions

Conditions	Yield
In toluene at 20℃; under 760.051 Torr; for 24h; Cooling with liquid nitrogen; Inert atmosphere;	94%

: [(2,6-(2,4,6-Me3C6H2)2C6H3)Ge-(1,3,4,5-tetramethylimidazol-2-ylidene)2][(3,5-(CF3)2C6H3)4B]

: 10024-97-2
dinitrogen monoxide

: [(2,6-(2,4,6-Me3C6H2)2C6H3)Ge(O)(1,3,4,5-tetramethylimidazol-2-ylidene)2][(3,5-(CF3)2C6H3)4B]

Conditions

Conditions	Yield
In acetonitrile Inert atmosphere;	94%

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