trans-2-bromobutenedioic acid dimethyl ester
triethylamine
A
tetraethylammonium bromide
B
dimethyl diethylaminofumarate
Conditions | Yield |
---|---|
In acetonitrile for 7h; Heating; | A 98.6% B 87% |
Conditions | Yield |
---|---|
In acetonitrile at 60℃; for 72h; | 98% |
Conditions | Yield |
---|---|
With P(C6H5)3 In methanol Stirring of a suspn. of Mo-compd. and PPh3 (MeOH, 1 h).; Filtn. of pptd. green solid, washing with hot MeOH and benzene, drying (vac.), elem. anal.; | A 60% B n/a C >99 |
quinoline
Et4N{Rh(1,5-cyclooctadiene)Br2}
A
{Rh(Br)(1,5-cyclooctadiene)(quinoline)}
B
tetraethylammonium bromide
Conditions | Yield |
---|---|
In dichloromethane addn. of methanol, elimination of CH2Cl2, pptn. filtered off, washed with methanol, air-dried; elem. anal.; | A 53% B n/a |
Conditions | Yield |
---|---|
With C2H4(P2(C6H5)4) In methanol byproducts: (dppe)S2; Boiling of Mo-compd. with dppe (MeOH, 1 h).; Recrystn. of bright green ppt. from a CH2Cl2/hexane mixt., elem. anal.; | A 48% B n/a |
Conditions | Yield |
---|---|
With Petroleum ether durch Zerlegung des entstandenen Aethylsulfats mit wss. Ba(OH)2; |
cis+trans-dibromoethylene
triethylamine
A
tetraethylammonium bromide
B
diethylamine
triethylamine
toluene
Ethyl 2-bromopropionate
A
ethyl 2-diethylaminopropanoate
B
tetraethylammonium bromide
C
triethylamine hydrobromide
Conditions | Yield |
---|---|
at 50℃; |
triethylamine
Ethyl 2-bromopropionate
A
ethyl 2-diethylaminopropanoate
B
tetraethylammonium bromide
C
triethylamine hydrobromide
Conditions | Yield |
---|---|
at 107℃; |
dimethyl 2-bromofumarate
triethylamine
A
tetraethylammonium bromide
B
dimethyl diethylaminofumarate
Conditions | Yield |
---|---|
In acetonitrile for 7h; Heating; |
dimethyl 2,3-dibromobutane-1,4-dicarboxylate
triethylamine
A
tetraethylammonium bromide
B
dimethyl diethylaminofumarate
Conditions | Yield |
---|---|
In acetonitrile for 7h; Heating; |
triethylamine
2-bromobutyric acid ethyl ester
B
butyric acid pin-2-en-10-yl ester
C
tetraethylammonium bromide
Conditions | Yield |
---|---|
at 100℃; |
triethylamine
Ethyl 2-bromopropionate
A
LACTIC ACID
B
tetraethylammonium bromide
Conditions | Yield |
---|---|
nachfolgende Verseifung; |
piperazine
tetraethylammonium hydroxide
bromoacetic acid
B
tetraethylammonium bromide
Conditions | Yield |
---|---|
In water at 80℃; Title compound not separated from byproducts; |
Conditions | Yield |
---|---|
In acetonitrile for 8h; Heating; Title compound not separated from byproducts; | A 216 mg B n/a |
B
tetraethylammonium bromide
Conditions | Yield |
---|---|
In trifluoroacetic acid heating Re-compd. with mixt. of trifluoroaceti acid and trifluoroacetic anhydride (1:1) (Ar atmosphere); washing (solvents), drying (vac., KOH); elem. anal.; | A 75-85 B n/a |
Et4N{Rh(1,5-cyclooctadiene)Br2}
A
Rh(Br)(1,5-cyclooctadiene)(ethylenediamine)
B
tetraethylammonium bromide
Conditions | Yield |
---|---|
With ethylenediamine In dichloromethane pptn. filtered off, washed with CH2Cl2, air-dried; elem. anal.; |
Et4N{Rh(1,5-cyclooctadiene)Br2}
A
Rh(Br)(1,5-cyclooctadiene)(triphenylphosphine)
B
tetraethylammonium bromide
Conditions | Yield |
---|---|
With P(C6H5)3 In methanol; dichloromethane CH2Cl2/MeOH 1:1; elimination of CH2Cl2, filtered off, washed with methanol, air-dried; |
C6H5O(1-)*C6H6O*C8H20N(1+)
benzyl bromide
A
(benzyloxy)benzene
B
tetraethylammonium bromide
C
phenol
Conditions | Yield |
---|---|
In acetonitrile at 20℃; |
Conditions | Yield |
---|---|
In [D3]acetonitrile at 24.84℃; Equilibrium constant; |
tetraethylammonium bromide
Conditions | Yield |
---|---|
With sodium hydride 1.) THF, 2.) CH2Cl2; | 100% |
tetraethylammonium bromide
Conditions | Yield |
---|---|
With sodium hydride 1.) THF, 1 h, 2.) CH2Cl2; | 100% |
1-benzyloxymethyl-9-(4'-β-(dibenzylphosphono)methoxy-2',3'-dideoxy-2',3'-didehydro-β-D-erythrofuranosyl)hypoxanthine
tetraethylammonium bromide
Conditions | Yield |
---|---|
With 5% Pd(II)/C(eggshell); hydrogen In methanol under 760.051 Torr; | 100% |
C32H33N4O9P
tetraethylammonium bromide
Conditions | Yield |
---|---|
With 5% Pd(II)/C(eggshell); hydrogen In methanol under 760.051 Torr; | 100% |
Conditions | Yield |
---|---|
Stage #1: 2-pyridylphenyl-biphenyl-2,2'-silane; methyllithium In tetrahydrofuran; diethyl ether at -78 - 20℃; for 0.5h; Stage #2: tetraethylammonium bromide In tetrahydrofuran; diethyl ether at 20℃; | 100% |
tetraethylammonium bromide
dimethyl sulfate
tetraethylammonium methyl sulfate
Conditions | Yield |
---|---|
In acetonitrile at 20℃; for 0.583333h; | 100% |
tetraethylammonium bromide
methyl trifluoromethanesulfonate
A
methyl bromide
B
tetraethylammonium trifluoromethanesulphonate
Conditions | Yield |
---|---|
In acetonitrile at 20℃; for 0.583333h; Temperature; | A n/a B 100% |
tetraethylammonium bromide
methyl p-toluene sulfonate
tetraethylammonium tosylate
Conditions | Yield |
---|---|
In acetonitrile at 20℃; for 0.583333h; | 100% |
Methyl methanesulfonate
tetraethylammonium bromide
tetraethylammonium methanesulfonate
Conditions | Yield |
---|---|
In acetonitrile at 20℃; for 0.583333h; | 100% |
Conditions | Yield |
---|---|
In toluene; acetonitrile under dry N2, finely divided metal and o-quinone refluxed in toluene (24 h), filtration, addn. of Et4NBr in minimum amount of CH3CN (light-brown solid deposit), stirred (2 h, room temp.), addn. of diethyl ether, pptn.; filtration, evapn.; elem. anal.; | 99% |
[Cs][Re(CO)3(η(5)-7,8-C2B9H11)]
tetraethylammonium bromide
Conditions | Yield |
---|---|
In dichloromethane | 99% |
tetraethylammonium bromide
Conditions | Yield |
---|---|
In water (H3O)2((Mn(H2O)1.5)3(Re6Se8(CN)6)2)*19H2O was stirred in hot aq. soln. Et4NBr for 2 h; ppt. was filtered, washed with water and air-dried; elem. anal.; | 99% |
tetraethylammonium bromide
Conditions | Yield |
---|---|
In dichloromethane byproducts: NaBr, water; N2-atmosphere; equimolar amts., room temp.; filtration, solvent removal from filtrate; can be recrystallized (CH2Cl2/hexane); elem. anal.; | 99% |
tetraethylammonium bromide
Conditions | Yield |
---|---|
In dichloromethane react. mixt. was filtered through Celite, solvent was removed in vacuo; | 99% |
Conditions | Yield |
---|---|
In ammonia aq. NH3; Cu salt and ethylenediamine in aq.NH3 added to soln. of Re complex and Et4NBr in aq.NH3, kept in a closed vessel at room temp. for 2 weeks; filtered, dried, elem. anal.; | 99% |
4,6-bis(4-methoxyphenyl)-thieno[3,4-d]-1,3-dithiol-2-one
tetraethylammonium bromide
Conditions | Yield |
---|---|
With CH3CH2ONa In tetrahydrofuran (Ar); addn. of EtONa to a soln. of ligand in THF, stirring for 40 min, addn. of ammonium salt, then metal salt, react. for 24 h; filtration, washing with water; elem. anal.; | 99% |
Conditions | Yield |
---|---|
With KNCS In water aq. soln. of Ni compd. and aq. soln. of bromide and K salt were combined; kept for 1 wk; elem. anal.; | 99% |
Conditions | Yield |
---|---|
Stage #1: C8H20N(1+)*C41H47B11N5O5(1-) With ammonium bromide In ethylenediamine at 80℃; for 22h; Microwave irradiation; Stage #2: tetraethylammonium bromide In water | 99% |
3,3,3',3'-tetrakis(trifluoromethyl)-1,1'(3H,3'H)-spirobi<2,1-benzoxasilole>
tetraethylammonium bromide
trimethylsilylmethyllithium
Conditions | Yield |
---|---|
Stage #1: 3,3,3',3'-tetrakis(trifluoromethyl)-1,1'(3H,3'H)-spirobi<2,1-benzoxasilole>; trimethylsilylmethyllithium In diethyl ether at -78 - 20℃; for 3h; Stage #2: tetraethylammonium bromide In dichloromethane for 1h; | 99% |
2,3,5,6-tetramethylthiophenol
tetraethylammonium bromide
iron(III) chloride
Conditions | Yield |
---|---|
With Li In methanol N2-atmosphere; addn. of Li-wire to thiol, treatment with FeCl3 and Et4NBr; | 98% |
With Li In ethanol N2-atmosphere; addn. of Li-wire to thiol, treatment with FeCl3 and Et4NBr; | 98% |
tricarbonyl(η6-chlorobenzene)chromium
tetraethylammonium bromide
A
(benzene)tricarbonylchromium
Conditions | Yield |
---|---|
In not given reaction of K2(Cr(CO)5) with (η6-ClC6H5)Cr(CO)3, aq. workup; 1H NMR, IR; | A 98% B 0% |
tricarbonyl(η6-chlorobenzene)chromium
tetraethylammonium bromide
A
(benzene)tricarbonylchromium
Conditions | Yield |
---|---|
In not given reaction of K2(W(CO)5) with (η6-ClC6H5)Cr(CO)3, aq. workup; 1H NMR, IR; | A 98% B 0% C n/a |
[closo-3-triphenylphosphine-3,3-nitrato-3,1,2-RhC2B9H11]
tetraethylammonium bromide
Conditions | Yield |
---|---|
With PPh3 In dichloromethane under Ar, Rh complex dissolved in CH2Cl2 at room temp., PPh3 added withstirring, after 5 min (C2H5)4NBr added, mixt. stirred for 45 min; chromd., treated with heptane, evapd., washed with petroleum ether, dried by suction; | 98% |
tetraethylammonium bromide
Conditions | Yield |
---|---|
In water (N2), heating (sealed Pyrex tube, 110°C, 2 d); dissolving educts excess and KCl (water, methanol), washing (anhydrous eher); semiquantitative microprobe analysis; | 98% |
4-bromotetrahydro-2H-pyran
3,3,3',3'-tetrakis(trifluoromethyl)-1,1'(3H,3'H)-spirobi<2,1-benzoxasilole>
tetraethylammonium bromide
Conditions | Yield |
---|---|
Stage #1: 4-bromotetrahydro-2H-pyran With iodine; magnesium In tetrahydrofuran at 60℃; Inert atmosphere; Stage #2: 3,3,3',3'-tetrakis(trifluoromethyl)-1,1'(3H,3'H)-spirobi<2,1-benzoxasilole> In tetrahydrofuran Inert atmosphere; Reflux; Stage #3: tetraethylammonium bromide In dichloromethane at 20℃; for 1h; | 98% |
tungsten hexacarbonyl
tetraethylammonium bromide
tetraethylammonium bromopentacarbonyltungstate
Conditions | Yield |
---|---|
In 1,4-dioxane heating at reflux, 2 h; after cooling, addn. of petroleum ether, washing (petroleum ether), heated (60°C, under vac. for 2 h to remove unreacted W(CO)6), uptake in THF (under N2), mixture is filtered and stripped; | 97% |
In 1,4-dioxane for 2h; Reflux; | 86% |
In diethylene glycol Anhydrous Et4NBr was heated with an excess of M(CO)6 in dimethyldigol at 120°C under dry N2;; soln. was filtered hot under N2, light petroleum added and cooling at -5°C for ca. 8 h; crystals was washed and dried;; | 90-95 |
In diethylene glycol byproducts: CO; NEt4Br (18 mmol) was heated with an excess of metal hexacarbonyl (23 mmol, purified by sublimation) in O(CH2CH2OMe)2 at ca. 120°C under dry N2;; filtration while hot under N2; addn. of equal amt. of light petroleum (b.p. 40-60°C) and cooling to -5°C for ca. 6 h; the solventwas decanted, the ppt. washed with light petroleum; heating at 60°C (0.001 mm Hg) for ca. 2 h;; | 90-95 |
In 2-methoxy-ethanol byproducts: CO; N2 atmosphere; refluxing (2 h); cooling, solvent removal (vac.), recrystn. (CH2Cl2/hexane); |
Conditions | Yield |
---|---|
In acetonitrile (Et4N)2W3S7Br6 and KSCN boiled for 1 h in Ar, Et4NBr in water added; ppt. filtered, washed with water, ethanol, benzene and ether; elem. anal.; | 97% |
tungsten hexacarbonyl
tetraethylammonium bromide
Conditions | Yield |
---|---|
Stage #1: tungsten hexacarbonyl; potassium hydridotris(3,4,5-trimethyl-1H-pyrazol-1-yl)borate In N,N-dimethyl-formamide at 130℃; for 2.5h; Inert atmosphere; Schlenk technique; Glovebox; Stage #2: tetraethylammonium bromide In water; N,N-dimethyl-formamide at 60℃; Inert atmosphere; Saturated gas; Glovebox; | 97% |
Molecule structure of Tetraethylammonium bromide (CAS NO.71-91-0):
IUPAC Name: Tetraethylazanium bromide
Molecular Formula: C8H20BrN
Molecualr Weight: 210.16 g/mol
Melting Point: 285 °C (dec.)(lit.)
Density: 1.397 g/cm3
Water Solubility: 2795 g/L (25 °C)
Sensitive: hygroscopic
H-Bond Acceptor: 1
Rotatable Bond Count: 4
Exact Mass: 209.077912
MonoIsotopic Mass: 209.077912
Canonical SMILES: CC[N+](CC)(CC)CC.[Br-]
InChI: InChI=1S/C8H20N.BrH/c1-5-9(6-2,7-3)8-4;/h5-8H2,1-4H3;1H/q+1;/p-1
InChIKey: HWCKGOZZJDHMNC-UHFFFAOYSA-M
EINECS: 200-769-4
Product Categories: quarternary ammonium salts; Ammonium Bromides (Quaternary); Quaternary Ammonium Compounds; Ammonium Salts; Greener Alternatives: Catalysis; Phase Transfer Catalysts; Ion-pair Reagents
Tetraethylammonium bromide (CAS NO.71-91-0) is used as reagents of polarographic analysis and the intermediates of pesticide.
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
dog | LD50 | intravenous | 55mg/kg (55mg/kg) | LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES | Journal of Pharmacology and Experimental Therapeutics. Vol. 97, Pg. 48, 1949. |
mouse | LD50 | intraperitoneal | 50mg/kg (50mg/kg) | National Technical Information Service. Vol. AD277-689, | |
mouse | LD50 | intravenous | 14200ug/kg (14.2mg/kg) | Journal de Physiologie Vol. 49, Pg. 220, 1957. | |
mouse | LD50 | oral | > 2gm/kg (2000mg/kg) | LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES | Journal of Pharmacology and Experimental Therapeutics. Vol. 97, Pg. 48, 1949. |
rabbit | LD50 | intravenous | 72mg/kg (72mg/kg) | LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES | Journal of Pharmacology and Experimental Therapeutics. Vol. 97, Pg. 48, 1949. |
rat | LD50 | intraperitoneal | 108mg/kg (108mg/kg) | Pharmacology: International Journal of Experimental and Clinical Pharmacology. Vol. 21, Pg. 256, 1980. | |
rat | LD50 | intravenous | 63mg/kg (63mg/kg) | LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES | Journal of Pharmacology and Experimental Therapeutics. Vol. 97, Pg. 48, 1949. |
rat | LD50 | subcutaneous | 200mg/kg (200mg/kg) | Proceedings of the Society for Experimental Biology and Medicine. Vol. 78, Pg. 708, 1951. |
Hazard Codes: Xi
Risk Statements: 36/37/38
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 26-36-37/39
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36:Wear suitable protective clothing.
S37/39:Wear suitable gloves and eye/face protection.
WGK Germany: 3
RTECS: BS5950000
F: 3
HS Code: 29239000
Tetraethylammonium bromide (CAS NO.71-91-0) is also named as AI3-19150 ; Beparon ; Bromethyl ; Bromure de tetraethylammonium ; Bromure de tetraethylammonium [French] ; Bromure de tetrylammonium ; Bromure de tetrylammonium [INN-French] ; Bromuro de tetrilamonio ; Bromuro de tetrilamonio [INN-Spanish] ; Etambro ; Etamon ; Ethylon ; Etylon ; NSC 36724 ; Sympatektoman ; TEA bromide ; TEAB ; TMD 10 ; Teamon ; Tetraethyl ammonium bromide ; Tetranium ; Tetrylammonii bromidum ; Tetrylammonii bromidum [INN-Latin] ; Tetrylammonium bromide ; USAF DO-32 . Tetraethylammonium bromide (CAS NO.71-91-0) is white to light yellow crystalline solid. It is a quaternary ammonium salt. It is a common source for the tetraethylammonium cation.
About|Contact|Cas|Product Name|Molecular|Country|Encyclopedia
Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog
©2008 LookChem.com,License: ICP
NO.:Zhejiang16009103
complaints:service@lookchem.com Desktop View