Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt supplier

Name
Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt
EINECS 264-596-6
CAS No. 63995-70-0
Article Data10
CAS DataBase
Density
Solubility Soluble in water.
Melting Point
Formula C₁₈H₁₂Na₃O₉PS₃
Boiling Point
Molecular Weight 568.429
Flash Point
Transport Information
Appearance
Safety 26
Risk Codes 36/37/38
Molecular Structure
Hazard Symbols Xi
Synonyms Benzenesulfonicacid, 3,3',3''-phosphinidynetris-, trisodium salt (9CI);3,3',3''-Phosphinidynetris[benzenesulfonicacid] trisodium salt;TPPTS;Triphenylphosphine-m-trisulfonic acid trisodiumsalt;Tris(3-sulfophenyl)phosphine trisodium salt;Tris(m-sulfophenyl)phosphinetrisodium salt;Trisodium tris(3-sulfonatophenyl)phosphine;Trisodiumtris(m-sulfonatophenyl)phosphine;Trisodium tris(m-sulfophenyl)phosphine;Tri(m-sulfophenyl)phosphine, sodium salt;
PSA 210.33000
LogP 3.39950

Synthetic route

: 603-35-0
triphenylphosphine

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

Conditions

Conditions	Yield
Stage #1: triphenylphosphine With chlorosulfonic acid; sulfuric acid at 0 - 25℃; Stage #2: With sodium hydroxide In water at 60℃; Temperature; Reagent/catalyst;	98.6%
Stage #1: triphenylphosphine With oleum at 0 - 20℃; for 150h; Stage #2: With sodium hydroxide In water	66%
With sulfuric acid for 168h; Ambient temperature;	11%

: 135265-27-9
tris (3-ethyl phenyl sulfonate) phosphine

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

Conditions

Conditions	Yield
With sodium bromide In water; acetone for 48h; Ambient temperature;	66%

: carbonyl(hydrido)tris{tris(sodium-m-sulphonatophenyl)phosphine}rhodium(I)-nonahydrate

: trans-carbonyl(hydroxy)bis{tris(sodium-m-sulphonatophenyl)phosphine}rhodium(I)-hexahydrate

B: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

Conditions

Conditions	Yield
In water byproducts: H2; (N2 or Ar); refluxing (12 h, vac.); chromy. (Sephadex); elem. anal.;	A 63% B n/a

: 98511-67-2
tris(natrium-m-sulfonatophenyl)phosphanoxid

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

Conditions

Conditions	Yield
With HSiCl

: C18H18N3O6PS3

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

Conditions

Conditions	Yield
With sodium hydroxide

: C21H24N3O6PS3

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

Conditions

Conditions	Yield
With sodium hydroxide

: C24H30N3O6PS3

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

Conditions

Conditions	Yield
With sodium hydroxide

: disodium P-phenyl-3,3'-phosphinediyl-bis(benzenesulfonate)

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

Conditions

Conditions	Yield
With sodium hydroxide; sulfuric acid for 48h; Ambient temperature;

: 603-35-0
triphenylphosphine

thiocyanato: thiocyanato

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: ClSO3H 3: NaOH View Scheme
Multi-step reaction with 3 steps 1: ClSO3H 2: NH3 3: NaOH View Scheme
Multi-step reaction with 3 steps 1: ClSO3H 3: NaOH View Scheme

: 345650-44-4
C18H12Cl3O6PS3

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 2: NaOH View Scheme
Multi-step reaction with 2 steps 1: NH3 2: NaOH View Scheme
Multi-step reaction with 2 steps 2: NaOH View Scheme

: 96723-93-2
tris (3-sulfonatophenyl) phosphine oxide, triacid

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: 1.) Ag2CO3, aq. aerosol OT / 1.) 25 deg C, 24 h, 2.) toluene, reflux, 24 h 2: 89 percent / SiHCl3 / toluene; tetrahydrofuran / 22 h / Heating 3: 66 percent / sodium bromide / H2O; acetone / 48 h / Ambient temperature View Scheme

: 135265-26-8
tris (3-ethyl phenyl sulfonate) phosphine oxide

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 89 percent / SiHCl3 / toluene; tetrahydrofuran / 22 h / Heating 2: 66 percent / sodium bromide / H2O; acetone / 48 h / Ambient temperature View Scheme

: Pt(P(C6H4SO3Na)3)3

: [Pt(μ-OH)(P(m-C6H4SO3Na)3)2]2(2+)

B: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

Conditions

Conditions	Yield
In water pH 13; detected by NMR spectra;

: Pt(H)(P(C6H4SO3Na)3)3(1+)*Cl(1-)*CH3NO2=PtH(P(C6H4SO3Na)3)3Cl*CH3NO2

: trans-[PtCl(H)(P(m-C6H4SO3Na)3)2]

B: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

Conditions

Conditions	Yield
In dimethyl sulfoxide detected by NMR spectra;

: Pd(tris(3-sodium-sulfonatophenyl)phosphane)3

A: Pd(bis(m-sulfophenyl)phosphine trisodium salt)3

B: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

Conditions

Conditions	Yield
In water dilute medium; detected by (13)P NMR spectra;	A 0% B 0%

: 603-35-0
triphenylphosphine

A: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

B: disodium P-phenyl-3,3'-phosphinediyl-bis(benzenesulfonate)

Conditions

Conditions	Yield
Stage #1: triphenylphosphine With sulfuric acid; sulfur trioxide at 25 - 30℃; for 21h; Inert atmosphere; Stage #2: With sodium hydroxide In water Inert atmosphere;

: 79-41-4
poly(methacrylic acid)

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

: 115524-87-3
C22H18O11PS3(3-)*3Na(1+)

Conditions

Conditions	Yield
In water	100%

: 79-41-4
poly(methacrylic acid)

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

: 115524-88-4
C22H17(2)HO11PS3(3-)*3Na(1+)

Conditions

Conditions	Yield
With water-d2	100%

: 107-93-7
(E)-but-2-enoic acid

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

: 115524-91-9
C22H18O11PS3(3-)*3Na(1+)

Conditions

Conditions	Yield
In water at 50℃;	100%

: 107-93-7
(E)-but-2-enoic acid

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

: 115524-92-0
C22H17(2)HO11PS3(3-)*3Na(1+)

Conditions

Conditions	Yield
With water-d2 at 50℃;	100%

: 97-65-4
2-methylenesuccinic acid

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

: 115524-89-5
C23H18O13PS3(3-)*3Na(1+)

Conditions

Conditions	Yield
In water	100%

: 97-65-4
2-methylenesuccinic acid

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

: 115524-90-8, 122865-77-4
C23H17(2)HO13PS3(3-)*3Na(1+)

Conditions

Conditions	Yield
With water-d2	100%

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

: 98511-67-2
tris(natrium-m-sulfonatophenyl)phosphanoxid

Conditions

Conditions	Yield
With dihydrogen peroxide In water for 3h; Ambient temperature;	100%
With dihydrogen peroxide In water Heating;	100%

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

: 79-10-7
acrylic acid

: 115524-85-1
C21H16O11PS3(3-)*3Na(1+)

Conditions

Conditions	Yield
In water	100%

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

: 79-10-7
acrylic acid

: 115524-86-2
C21H15(2)HO11PS3(3-)*3Na(1+)

Conditions

Conditions	Yield
With water-d2	100%

: Ru6C*17CO = [Ru6C(CO)17]

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

: 3Na(1+)*Ru6(C)*16CO*P(C6H4SO3)3(3-)=Ru6(C)(CO)16(P(C6H4SO3Na)3)

Conditions

Conditions	Yield
In methanol N2-atmosphere; refluxing (2 h); evapn. (reduced pressure), washing (hexane), drying (vac.);	100%

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

: 3Na(1+)*Ru3(CO)11(P(C6H4SO3)3)(3-)=Ru3(CO)11(P(C6H4SO3Na)3)

Conditions

Conditions	Yield
In methanol N2-atmosphere, molar ratio = 1 : 1; refluxing (2 h); evapn. (reduced pressure), washing (hexane), drying (vac.);	100%

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

: 6Na(1+)*Ru3(CO)10(P(C6H4SO3)3)2(6-)=Ru3(CO)10(P(C6H4SO3Na)3)2

Conditions

Conditions	Yield
In methanol N2-atmosphere, molar ratio = 1 : 2; refluxing (2 h); evapn. (reduced pressure), washing (hexane), drying (vac.);	100%

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

: 9Na(1+)*Ru3(CO)9(P(C6H4SO3)3)3(9-)=Ru3(CO)9(P(C6H4SO3Na)3)3

Conditions

Conditions	Yield
In methanol N2-atmosphere, molar ratio = 1 : 3; refluxing (2 h); evapn. (reduced pressure), washing (hexane), drying (vac.);	100%

: 39929-21-0
(tetrahydrothiophene)gold(I) chloride

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

: Au(sodiumtriphenylphosphine-3,3',3''-trisulfonate)Cl

Conditions

Conditions	Yield
In water; acetonitrile at 20℃; for 2h; Inert atmosphere;	100%
In dichloromethane; water; acetone ligand in acetone and 9 drops of H2O added dropwise to soln. of 1 equiv.of Au complex in CH2Cl2, stirred at room temp. for 30 min; evapd.(vac.), pptd.(acetone/Et2O 1:2 v/v), filtered (vac.), elem. anal.,;	99%

: 35138-22-8
bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

: C44H32O18P2RhS6(5-)*6Na(1+)*BF4(1-)

Conditions

Conditions	Yield
In water at 20℃; for 0.166667h;	100%

: 10025-99-7
potassium tetrachloroplatinate(II)

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

: [Pt(tris(3-sulfonatophenyl)phosphane sodium salt)3Cl]Cl

Conditions

Conditions	Yield
In water-d2 at 25℃; for 0.25h; Inert atmosphere;	100%

: 39929-21-0
(tetrahydrothiophene)gold(I) chloride

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

: sodium tris(tris(m-sulphonatophenyl)phosphine)gold(I)

Conditions

Conditions	Yield
In dichloromethane; water salt of ligand (3 equiv.) in H2O was added to stirred soln. of Au complex (1 equiv.) in CH2Cl2; mixt. was stirred for 5 h; evapd. (vac.); H2O added to residue; filtered; solvent removed (vac.);	99%

: [Pt2(6,6'-diphenyl-2,2'-bipyridine(-4H))(DMSO)2]

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

: 7732-18-5
water

: [Pt2(6,6'-diphenyl-2,2'-bipyridine(-4H))(P(m-PhSO3Na)3)2]*6H2O

Conditions

Conditions	Yield
In water; acetone Pt complex was added with stirring to soln. of ligand in H2O/acetone (1/1) under Ar; mixt. was stirred at room temp. for 15 h; filtered; concd.; treated with acetone; filtered; washed (acetone); elem. anal.;	99%

...Expand

: 2579-22-8
Phenylpropargyl aldehyde

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

A: 14371-10-9
(E)-3-phenylpropenal

B: 98511-67-2
tris(natrium-m-sulfonatophenyl)phosphanoxid

Conditions

Conditions	Yield
In water Ambient temperature;	A 98% B n/a

...Expand

: fac-triaquatricarbonyltechnetium-99m(1+)

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

: C64H82N20O16S4Zn

: C53H53N10O20PS5(99)Tc(3-)*3Na(1+)

Conditions

Conditions	Yield
at 40 - 65℃; for 0.416667h; Inert atmosphere; Schlenk technique;	98%

...Expand

: chloro(1,5-cyclooctadiene)iridium(I) dimer

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

: chloro(η4-1,5-cyclooctadiene)bis{tris(sodium-m-sulphonatophenyl)phosphine}iridium-hexahydrate

Conditions

Conditions	Yield
In water; toluene (N2 or Ar); addn. of org. compd. in H2O to Ir-complex in toluene with stirring (room temp.), stirring (15 min); phase sepn., extn. org. phase (H2O), washing aq. phases (toluene), evapn. (vac.), chromy. (Sephadex); elem. anal.;	97%

: 2579-22-8
Phenylpropargyl aldehyde

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

A: 98511-67-2
tris(natrium-m-sulfonatophenyl)phosphanoxid

B: 130947-27-2
trans-<α,β-2H2>cinnamaldehyde

Conditions

Conditions	Yield
In water-d2 Ambient temperature;	A n/a B 96%

...Expand

: 10025-99-7
potassium tetrachloroplatinate(II)

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

: cis-dichlorobis{tris(sodium-m-sulphonatophenyl)phosphine}platinum-hexahydrate

Conditions

Conditions	Yield
In water byproducts: KCl; (N2 or Ar); dropwise addn. of Pt-complex in H2O to org. compd. in H2O (room temp.), stirring (20 h); solvent evapn. (vac.);	96%

: (1,5-cyclooctadiene)dimethylplatinum(II)

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

: 67-68-5
dimethyl sulfoxide

: cis-PtMe2(TPPTS)2*DMSO

Conditions

Conditions	Yield
In dimethyl sulfoxide Pt-complex was mixed with ligand under N2, sealed, evacuated, DMSO was added, stirred for 18 h at room temp., CH2Cl2 was added; vac. filtered, washed with CH2Cl2 and Et2O, dried in vac. at 80°Cfor 24 h; elem. anal.;	96%

...Expand

: bis(dimethylgold(III) iodide)

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

: 7732-18-5
water

: cis-Me2AuI(3,3',3''-phosphinidynetris(benzenesulfonic acid) trisodium salt)*5H2O

Conditions

Conditions	Yield
In water; acetone 2 equiv. of P-compd., 0 °C; pptg. with acetone, recrystn.from MeOH-acetone, elem. anal.;	96%

...Expand

: bis(dimethylgold(III) iodide)

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

: 7732-18-5
water

: [cis-Me2Au(3,3',3''-phosphinidynetris(benzenesulfonic acid) trisodium salt)2]I*5H2O

Conditions

Conditions	Yield
In water; acetone 2 equiv. of P-compd., 0 °C, further addn. of 2 equiv. of P-compd.; pptg. with acetone, recrystn. from MeOH-acetone, elem. anal.;	96%
In water; acetone 4 equiv. of P-compd., 0 °C; pptg. with acetone, recrystn.from MeOH-acetone, elem. anal.;	96%

...Expand

: C98H199N3O16*CH4O3S

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

: 3C98H199N3O16*C18H15O9PS3

Conditions

Conditions	Yield
In acetonitrile at 20℃; for 72h; Inert atmosphere; Schlenk technique;	96%

: C90H183N3O42*CH4O3S

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

: 3C90H183N3O42*C18H15O9PS3

Conditions

Conditions	Yield
In acetonitrile at 20℃; for 72h; Inert atmosphere; Schlenk technique;	96%

: fac-triaquatricarbonyltechnetium-99m(1+)

: 63995-70-0
trisodium tris(3-sulfophenyl)phosphine

: C64H82N20O12S4Zn

: C53H53N10O18PS5(99)Tc(3-)*3Na(1+)

Conditions

Conditions	Yield
at 40 - 65℃; for 0.416667h; Inert atmosphere; Schlenk technique;	96%

...Expand

Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt Specification

The Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt, with the CAS registry number 63995-70-0, is also known as Trisodium triphenylphosphine-3,3',3''-trisulfonate. It belongs to the product category of Phosphines. Its EINECS registry number is 264-596-6. This chemical's molecular formula is C₁₈H₁₂Na₃O₉PS₃ and molecular weight is 568.42. What's more, its systematic name is called Trisodium 3-bis(3-sulfonatophenyl)phosphanylbenzenesulfonate.

When you are dealing with Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt, you should be very careful. This chemical is irritating to eyes, respiratory system, skin and may cause inflammation to the skin or other mucous membranes. Therefore, you should be cautious about it. In addition, in case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1) SMILES: c1cc(cc(c1)S(=O)(=O)[O-])P(c2cccc(c2)S(=O)(=O)[O-])c3cccc(c3)S(=O)(=O)[O-].[Na+].[Na+].[Na+]
(2) InChI: InChI=1/C18H15O9PS3.3Na/c19-29(20,21)16-7-1-4-13(10-16)28(14-5-2-8-17(11-14)30(22,23)24)15-6-3-9-18(12-15)31(25,26)27;;;/h1-12H,(H,19,20,21)(H,22,23,24)(H,25,26,27);;;/q;3*+1/p-3
(3) InChIKey: MYAJTCUQMQREFZ-DFZHHIFOAA

Product Name

Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt

Synthetic route

Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt Specification

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