Allyl acetate
phenylzinc chloride
A
allylbenzene
B
biphenyl
C
zinc diacetate
Conditions | Yield |
---|---|
tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran Ar atmosphere; stirring (20°C, 5 mole-% catalyst, 5 h); | A 100% B 0% C n/a |
Conditions | Yield |
---|---|
With acetic acid In diethyl ether N2 atmosphere; dropwise addn. of CH3COOH in Et2O to soln. of ZnEt2 (molar ratio Zn/acid 1:2), pptn.; filtration off, washing (Et2O), drying (vac.); | 99% |
Conditions | Yield |
---|---|
at 20℃; for 0.166667h; Inert atmosphere; | A 95% B 82 mg |
Conditions | Yield |
---|---|
In acetic acid Electrolysis; on electrolysis of Na acetate in acetic acid at 280V, 7mA/cmxcm, formation of acetate at Zn anode;; | 85% |
In acetic acid Electrolysis; on electrolysis of Na acetate in acetic acid at 280V, 7mA/cmxcm, formation of acetate at Zn anode;; | 85% |
poly(methacrylic acid)
acetic acid
zinc(II) carbonate
A
zinc diacetate
B
zinc methacryliate acetate
Conditions | Yield |
---|---|
In water at 20℃; for 2h; | A n/a B 43% |
Conditions | Yield |
---|---|
With zinc hydroxide | |
With zinc(II) nitrate |
Conditions | Yield |
---|---|
at 250 - 280℃; Ueberleiten ueber Zinkstaub; |
Conditions | Yield |
---|---|
at 150℃; |
zinc diacetate
Conditions | Yield |
---|---|
With acetic acid In water |
Conditions | Yield |
---|---|
In not given prepn. from ZnCO3 and carboxylic acid in molar ratio 1:2; | |
In not given neutralizing acetic acid with the carbonate; slow evapn.; | |
In water at 100℃; for 3h; |
Conditions | Yield |
---|---|
With chloroform byproducts: H2O; on dehydration of dihydrate with chloroform;; | |
In neat (no solvent) byproducts: H2O; loss of 2 mole H2O at 100 °C;; | |
In neat (no solvent) byproducts: H2O; vac. dehydration at 363 K, according to: G. Maslowska, A. Baranowska, Prod. Eighth Conf. Coord. Chem., Smolenice, Bratislava, 1980, pp. 269-273; |
Conditions | Yield |
---|---|
In neat (no solvent) on react. of acetic anhydride with Zn acetate dihydrate at 10°C for a period of 27 hours;; | |
In neat (no solvent) on react. of acetic anhydride with Zn acetate dihydrate at 10°C for a period of 27 hours;; |
Conditions | Yield |
---|---|
In carbon disulfide byproducts: N2; decompn. of nitrosoacetanilide with Zn dust and forming of Zn acetate and N2;; |
zinc diacetate
Conditions | Yield |
---|---|
With acetic acid In hydrogenchloride; water; acetic acid ZnO dissoln. in solvents mixt.; evapn. to dryness (hot plate, 90°C), further drying (vac. desiccator, 4 h); X-ray diffraction; | |
With acetic acid In water; acetic acid ZnO dissoln. in solvents mixt.; concn. (hot plate, 90°C), air-cooling to room temp. (28+/-2°C), crystn. for 24 h, filtn., washing (ethyl alcohol), drying (vac. desiccator, 2 h); X-ray diffraction; |
Conditions | Yield |
---|---|
In water shaken for 24 h at 25.0°C; evapn. of filtrate to dryness; |
Conditions | Yield |
---|---|
In acetic acid on slow heating of Zn with glacial acetic acid;; |
Conditions | Yield |
---|---|
In acetic acid byproducts: C6H5CH2OCOCH3; addn. of mixt. of benzaldehyde and excess acetic acid to zinc dust, stirring ( room temp., 12 h); filtration; |
zinc diacetate
Conditions | Yield |
---|---|
With H2O In neat (no solvent, solid phase) byproducts: Zn(OH)2; decompn. in solid state (moisture); IR-spectroscopy; |
zinc diacetate
Conditions | Yield |
---|---|
With acetic acid on treating with acetic acid;; | |
With acetic acid | |
With acetic acid | |
With acetic acid on treating with acetic acid;; |
Conditions | Yield |
---|---|
In neat (no solvent) on react. of acetic anhydride with Zn(OH)2 at 138°C for a period of 4 hours;; | |
at 138°C, some acetate is formed;; | |
at 138°C, some acetate is formed;; | |
In neat (no solvent) on react. of acetic anhydride with Zn(OH)2 at 138°C for a period of 4 hours;; |
Conditions | Yield |
---|---|
In water in 0.1n soln.;; | A n/a B >99 |
Conditions | Yield |
---|---|
In water Kinetics; dissolving both components in distilled water; stoichiometric concentrations: Zn 0.1 - 0.8 M, acetate 0.1 - 0.4 M; pH of solution from 4 to 6;; ultrasonic absorptions spectra;; |
Conditions | Yield |
---|---|
2,6-bis[(di-t-butylphosphino)methyl]phenyl palladium trifluoroacetate In benzene CO2 was reacted with ZnMe2 in C6H6 in presence of Pd catalyst at room temp.; | |
Pd(methyl)((1,3-bis[(di-tert-butylphosphino)methyl]benzene)(-1H)) In benzene CO2 was reacted with ZnMe2 in C6H6 in presence of Pd catalyst at 100°C; | |
Pd(acetyl)((1,3-bis[(di-tert-butylphosphino)methyl]benzene)(-1H)) In benzene CO2 was reacted with ZnMe2 in C6H6 in presence of Pd catalyst at 100°C; |
zinc diacetate
(22S)-22-Hydroxy-6β-methoxy-3α,5α-cyclocholest-24-ene
A
(22S)-3β-Acetoxy-22-hydroxycholesta-5,24-diene
B
Acetic acid (S)-1-[(S)-1-((3S,10R,13S)-3-acetoxy-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-17-yl)-ethyl]-4-methyl-pent-3-enyl ester
Conditions | Yield |
---|---|
In acetic acid for 1h; Heating; | A 100% B n/a |
zinc diacetate
Conditions | Yield |
---|---|
In methanol; chloroform at 20℃; for 0.333333h; | 100% |
zinc diacetate
Conditions | Yield |
---|---|
In methanol; chloroform for 0.25h; Heating; | 100% |
Conditions | Yield |
---|---|
In methanol; chloroform for 1h; Heating; | 100% |
zinc diacetate
Conditions | Yield |
---|---|
In methanol; chloroform; water at 20℃; for 0.5h; | 100% |
zinc diacetate
Conditions | Yield |
---|---|
In methanol; chloroform at 20℃; for 0.166667h; | 100% |
Conditions | Yield |
---|---|
In ethanol at 20℃; for 0.166667h; Product distribution / selectivity; | 100% |
Conditions | Yield |
---|---|
100% |
C20H6N4(CH3)4(C2H5)2(C2H4COOC3H6C6H4N(CH3)2)(C2H4COOC2H4SC10H4O2(CH3))
zinc diacetate
Zn(C20H4N4(CH3)4(C2H5)2(C2H4COOC3H6C6H4N(CH3)2)(C2H4COOC2H4SC10H4O2(CH3)))
Conditions | Yield |
---|---|
In methanol treatment of the ligand with a methanol soln. of zinc acetate; | 100% |
zinc diacetate
Conditions | Yield |
---|---|
In methanol; dichloromethane refluxing of porphyrine with Zn(OAc)2 in CH2Cl2-MeOH for 1.5 h under argon; column chromy. (alumina); | 100% |
phosphoric acid
zinc diacetate
water
1,2-diaminocyclohexane
Conditions | Yield |
---|---|
In water hydrothermal conditions, 180°C; | 100% |
Conditions | Yield |
---|---|
In water hydrothermal conditions, molar ratio BPO4:Zn(OAc)2:diaminocyclohexane:water 2:1:2.5:117, , pH=8, 210°C; elem. anal.; | 100% |
Conditions | Yield |
---|---|
In methanol; chloroform dry N2-atmosphere; stirring, refluxing (10 h, dark); evapn. (vac.), washing (MeOH), drying; | 100% |
Conditions | Yield |
---|---|
In methanol | 100% |
sarcosine
zinc diacetate
fullerene-C60
[Zn(C20H8N4((C4H9)2C6H3)3(C6H4)(C10H2N2O4)(C6H4)(CH3NC2H3)C60)]
Conditions | Yield |
---|---|
In toluene C60, C20H10N4((C4H9)2C6H3)3(C6H4)2(C10H2N2O4)(CHO), N-methylglycine (toluene) heated under N2 in dark for 6 h; cooled to 25°C, evapd. to dryness (reduced pressure); chromy. sepd., dissolved (CH3Cl), added Zn(OAc)2 in CH3OH, heated for 30 min; washed twice (H2O), dried (anhydrous Na2SO4), solvent evapd., chromy., reprecipitated from benzene-methanol; | 100% |
Pyromellitic dianhydride
4-hexadecylaniline
zinc diacetate
[Zn(C20H8N4((C4H9)2C6H3)3(C6H4)(C10H2N2O4)(C6H4)(C16H33))]
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide (C20H10N4((C4H9)2C6H3)3(C6H4))NH2, C10H2O6, (C16H33)NH(C6H5) (dry DMF) heated under N2 in dark for 22 h, cooled to 25°C, evapd. to dryness (reduced pressure); chromy., dissolved (CHCl3), added Zn(OAc)2 in CH3OH, heated for 30 min; washed twice (H2O), dried (anhydrous Na2SO4), solvent evapd., chromy., reprecipitated from chloroform-methanol; | 100% |
zinc diacetate
zinc(II) 5-[1'-(hexylaminomethyl)ferrocenyl]-10,15,20-tri(p-tolyl)porphyrin
Conditions | Yield |
---|---|
In methanol; dichloromethane; water Fe(C5H4CH2NH(CH2)5CH3)(C5H4)-substituted porphyrin reacted with ZnOAc2 in CH2Cl2/MeOH/H2O for 10 h; chromy. (SiO2, CH2Cl2/MeOH); elem. anal.; | 100% |
zinc diacetate
zinc(II) 5,10,15-triphenyl-20-(2,6-dimethyl-4-[2-(trimethylsilyl)ethynyl]phenyl)porphyrin
Conditions | Yield |
---|---|
In chloroform reaction for 2.5 h; | 100% |
zinc diacetate
Conditions | Yield |
---|---|
In chloroform reaction for 1 h; | 100% |
zinc diacetate
ZnC20H8N4(C6H5)3C6H2(CH3)2CCC6H4ZnC20H8N4(C6H2(CH3)3)3
Conditions | Yield |
---|---|
In chloroform stirring (room temp., 1 h); filtration, concn.; | 100% |
zinc diacetate
[2-hydroxy-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphinato]zinc(II)
Conditions | Yield |
---|---|
With sodium hydride; Benzaldoxime In methanol; dichloromethane; mineral oil mixt. refluxing in dark for 45 min, solvent complete removal; residue chromy. (silica, DCM), recrystn. (DCM/MeOH); | 100% |
zinc diacetate
Conditions | Yield |
---|---|
In methanol; dichloromethane reaction of zinc compd. with porphyrin deriv. in MeOH/CH2Cl2 at room temp. for 12 h; | 100% |
zinc diacetate
diphenyl[10,20-diphenylporphyrinatozinc(II)-5-yl]phosphine oxide
Conditions | Yield |
---|---|
In methanol; dichloromethane a soln. of zinc acetate in methanol was added to a soln. of porphyrin inCH2Cl2, the mixt. was refluxed for 2 h; ppt. was filtered, washed three times with methanol; | 100% |
zinc diacetate
Zn(C20H8N4(C6H4CH3)3)C6H4CH2NC6H4C(CH3)2COC6H3NO2CHCH
Conditions | Yield |
---|---|
In chloroform (Ar); stirring a soln. of ligand with excess of zinc salt in CHCl3 overnight; column chromy (SiO2); | 100% |
zinc diacetate
meso-pentyldipyrromethane
5-formyl-1,1,3,3-tetramethylisoindolin-2-yloxyl
5,10,15-tri-n-pentyl-20-(1',1',3',3'-tetramethylisoindolin-2'-yloxyl-5'-yl)porphyrinato zinc(II)
Conditions | Yield |
---|---|
With trifluoroacetic acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone In methanol; dichloromethane; chloroform to soln. of 5-formyl-1,1,3,3-tetramethylisoindolin-2-yloxyl, 5-pentyldipyrromethane in CH2Cl2 under Ar, trifluoroacetic acid added, stirred for 20 min, 2,3-dichloro-5,6-dicyano-1,4-benzoquinone added stirred, evapd. to dryness, chromy., refluxed,....; elem. anal.; | 100% |
Conditions | Yield |
---|---|
In chloroform excess of Zn(II) acetate, reflux; | 100% |
zinc diacetate
Conditions | Yield |
---|---|
In chloroform excess of Zn(II) acetate, reflux; | 100% |
zinc diacetate
Conditions | Yield |
---|---|
In chloroform excess of Zn(II) acetate, reflux; | 100% |
Conditions | Yield |
---|---|
In dimethyl sulfoxide stirring; filtn., washing (DMSO, hot H2O, acetone), drying (60°C, 24 h); elem. anal.; | 100% |
The Zinc acetate is an organic compound with the formula C4H6O4Zn. The IUPAC name of this chemical is zinc diacetate. With the CAS registry number 557-34-6, it is also named as acetic acid, zinc salt (2:1). The product's categories are Organic-metal Salt; Catalysis and Inorganic Chemistry; Chemical Synthesis; Zinc. Besides, it is a white crystalline powder, which is used as an astringent and weak antiseptic in medicine.
Physical properties about Zinc acetate are: (1)ACD/LogP: -0.29; (2)ACD/LogD (pH 5.5): -1.07; (3)ACD/LogD (pH 7.4): -2.86; (4)ACD/BCF (pH 5.5): 1; (5)ACD/BCF (pH 7.4): 1; (6)ACD/KOC (pH 5.5): 2.73; (7)ACD/KOC (pH 7.4): 1; (8)#H bond acceptors: 2; (9)#H bond donors: 1; (10)Polar Surface Area: 37.3 Å2; (11)Flash Point: 40 °C; (12)Enthalpy of Vaporization: 23.7 kJ/mol; (13)Boiling Point: 117.1 °C at 760 mmHg; (14)Vapour Pressure: 13.9 mmHg at 25°C.
Preparation: this chemical can be prepared by zinc oxide and acetic acid. This reaction will need reagent hydrogen peroxide.
When you are using this chemical, please be cautious about it as the following:
It is highly flammable and harmful if swallowed. Please keep away from sources of ignition - No smoking. Besides, this chemical is irritating to eyes and very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. When you are using it, wear suitable protective clothing. This material and its container must be disposed of as hazardous waste.
You can still convert the following datas into molecular structure:
(1)SMILES: [Zn+2].[O-]C(=O)C.[O-]C(=O)C
(2)InChI: InChI=1/2C2H4O2.Zn/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2
(3)InChIKey: DJWUNCQRNNEAKC-NUQVWONBAP
(4)Std. InChI: InChI=1S/2C2H4O2.Zn/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2
(5)Std. InChIKey: DJWUNCQRNNEAKC-UHFFFAOYSA-L
The toxicity data is as follows:
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
mouse | LD50 | intraperitoneal | 57mg/kg (57mg/kg) | Toxicology and Applied Pharmacology. Vol. 49, Pg. 41, 1979. | |
rabbit | LDLo | intravenous | 5mg/kg (5mg/kg) | Archives of Internal Medicine. Vol. 37, Pg. 641, 1926. | |
rat | LD50 | oral | 2510mg/kg (2510mg/kg) | Personal Communication from J.V. Marhold, VUOS, 539-18, Pardubice, Czechoslavakia, Mar. 29, 1977Vol. 29MAR1977, |
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